Solder alloy and resin flux cored solder

Abstract

Provided is a solder alloy that contains 0.01 mass % or more and 0.1 mass % or less of Fe, 0.005 mass % or more and less than 0.02 mass % of Co, 0.1 mass % or more and 4.5 mass % or less of Ag, 0.1 mass % or more and 0.8 mass % or less of Cu, and the balance being Sn.

Claims

1. A solder alloy consisting of 0.01 mass % or more and 0.1 mass % or less of Fe, 0.01 mass % or more and 0.015 mass % or less of Co, 0.1 mass % or more and 4.5 mass % or less of Ag, 0.1 mass % or more and 0.8 mass % or less of Cu, and the balance being Sn.

2. The solder alloy according to claim 1 comprising 2.9 mass % or more and 3.1 mass % or less of Ag, and 0.45 mass % or more and 0.55 mass % or less of Cu.

3. A resin flux cored solder comprising an exterior part having a tubular shape and formed of the solder alloy according to claim 1, and flux filled in a space inside the exterior part.

Description

DESCRIPTION OF EMBODIMENTS

(1) Hereinafter, embodiments of the present invention will be described.

(2) A solder alloy of the present invention is composed of tin (hereinafter referred to also as Sn), iron (hereinafter referred to also as Fe), cobalt (hereinafter referred to also as Co), silver (hereinafter referred to also as Ag), and copper (hereinafter referred to also as Cu), in which Sn is a main component.

(3) A content of Fe described above is 0.01 mass % or more and 0.1 mass % or less, preferably 0.02 mass % or more and 0.06 mass % or less. A content of Co described above is 0.005 mass % or more and less than 0.02 mass %, preferably 0.01 mass % or more and 0.019 mass % or less. A content of Ag described above is 0.1 mass % or more and 4.5 mass % or less, preferably 2.9 mass % or more and 3.1 mass % or less. A content of Cu described above is 0.1 mass % or more and 0.8 mass % or less, preferably 0.45 mass % or more and 0.55 mass % or less. Sn described above is a balance other than Fe, Co, Ag, and Cu described above. The balance is meant to be a component(s) other than Fe, Co, Ag, and Cu, and may contain inevitable impurities.

(4) The solder alloy of the present invention can be used as a material constituting a resin flux cored solder used in the manual soldering. The resin flux cored solder is composed of an exterior part formed of the solder alloy having a tubular shape and flux filled in a space inside the exterior part.

(5) The flux is not specifically limited. For example, rosin based flux, synthetic-resin flux, water soluble flux, or the like may be employed.

(6) The resin flux cored solder can be produced by, for example, a method described below. Specifically, a cylindrical ingot made of the solder alloy is cut into two along an axial direction to form two ingot pieces having a concave shape. Then, flux is filled into a concave of one of the ingot pieces and subsequently the other ingot piece is joined to the one ingot piece to have a cylindrical shape. Then, the ingot filled with flux is pressed to have a reduced diameter, thereby forming a wire, and the wire is made to pass through a drawing die to form a resin flux cored solder with a desired diameter (for example, a diameter of about 0.8 mm).

(7) An example of a method for joining a part to be joined such as electronic parts or the like to a substrate using the above-described resin flux cored solder includes a method described below. Specifically, a method includes making a resin flux cored solder to contact the tip of a soldering iron thereby melting a solder alloy, and feeding the molten solder alloy (hereinafter referred to also as a molten solder) to a joining area, at which a substrate and a part to be joined are to be joined together, thereby allowing the molten solder to solidify so that the substrate and the part to be joined are joined together (manual soldering).

(8) As described above, the solder alloy and the resin flux cored solder that is formed using the solder alloy of the present invention can effectively prevent disappearance of a plated layer even as a result of repeated contacts with the plated layer containing Fe as a main component in a molten state.

(9) That is, according to the present invention where the contents of Fe, Co, Ag, and Cu are in the above ranges and the balance is Sn, it is possible to suppress disappearance of the plated layer even as a result of repeated contacts with the plated layer containing Fe as a main component in a molten state.

(10) Further, according to the present invention where the resin flux cored solder includes the exterior part having tubular shape formed of the solder alloy and flux filled in a space inside the exterior part, it is possible to effectively suppress disappearance of the plated layer even as a result of repeated operations where the resin flux cored solder is made to contact the solder iron having a plated layer containing Fe as a main component to thereby melt the solder alloy.

(11) The solder alloy and the resin flux cored solder according to the present invention are not limited to the aforementioned embodiments, and various modifications can be made without departing from the gist of the present invention. Further, it is, of course, that the configurations, methods, or the like, of the above-described plurality of embodiments may be optionally employed and combined (configuration, method, or the like, of one embodiment may be applied to configuration, method, or the like, of another embodiment).

(12) The aforementioned embodiments are described by taking, for example, the case where the solder alloy according to the present invention is used in the manual soldering, but is not limited thereto, and the solder alloy may be used in the flow soldering. In such a case, the solder alloy is kept in a heated and molten state in a solder bath. This method includes immersing the joining area between a substrate and a part to be joined, on which the part to be joined is mounted in advance, in a solder bath filled with the molten solder, or spraying the molten solder fed from the solder bath to the joining area, so that the substrate and the part to be joined are joined together (flow soldering).

EXAMPLES

(13) Hereinafter, examples of the present invention will be described. However, the present invention is not limited to the following examples.

Examples 1 and 2, Comparative Examples 1 and 2

(14) 1. Solder Alloy

(15) Solder alloys were prepared to respectively have compositions of Table 1 below.

(16) 2. Resin Flux Cored Solder

(17) Resin flux cored solders in a diameter of 0.8 mm were prepared using the solder alloys prepared in the above step. The content of flux in the resin flux cored solders was 3.2 wt %. As the flux, 72M flux (manufactured by KOKI COMPANY LIMITED) was employed.

(18) 3. Disappearance Rate of Plated Layer

(19) A soldering iron tip (manufactured by Japan Unix Co., Ltd., product name: P3D-R) having a plated layer, of which a main component is Fe, was heated at 400 C., followed by repeatedly feeding the resin flux cored solder prepared in the above step to the soldering iron tip. A fed amount for one time was 0.018 g. After feeding of the resin flux cored solder was repeated 10,000 times, a cross section of the soldering iron tip was observed, and a thickness of the plated layer was measured. Then, the disappearance rate of the plated layer was calculated from formula 1 below.
Disappearance rate of plated layer (%)=(AB)/A100(1)
(A represents an original thickness of the plated layer, and B represents a thickness of the plated layer after feeding of the resin flux cored solder was repeated 10,000 times.)

(20) TABLE-US-00001 TABLE 1 Composition of solder alloy (mass %) Disappearance ratio Fe Co Ag Cu Sn of plated layer (%) Example 1 0.04 0.015 3.0 0.5 balance 3.72 Example 2 0.02 0.010 3.0 0.5 balance 4.90 Comparative 3.0 0.5 balance 28.25 Example 1 Comparative 0.04 0.040 3.0 0.5 balance 13.12 Example 2

SUMMARY

(21) As shown in Table 1 above, Examples 1 and 2 show the disappearance rates of the plated layer are lower than those of Comparative Examples. That is, the solder alloy with the contents of Fe, Co, Ag, and Cu in the above ranges and the balance of Sn can suppress disappearance of the plated layer even as a result of repeated contacts with the plated layer containing Fe as a main component. The same effect was found when the content of the flux was 4.5%. That is, it is possible to suppress disappearance of the plated layer without the influence of the content of the flux in the resin flux cored solder.