PFAS PROCESSING

Abstract

The processing of PFAS to convert them into safer substances comprises introducing gaseous or vapour phase PFAS into a treatment zone where microwave radiation of predetermined frequency and power level creates a plasma which at least partially dissociates the PFAS. There is also a system for remediating particulate solids, particularly soil, contaminated with PFAS, the method including directing microwave radiation to a body of particulate solids in the closed vessel so as to promote vaporization of PFAS which are then treated by exposure to the microwave produced plasma. Continuous and batch processing apparatus are disclosed. A preheating stage can dry the particulate solids to a pre-determined moisture content, and then a higher energy microwave heating promotes vaporization of PFAS. A partial vacuum created where particulate solids heated by the microwave radiation are yielding up PFAS promotes the vaporization of PFAS. Alternating cycles of high pressure during microwave irradiation and low pressure or partial vacuum can avoid plasma generation in the heating stage while optimizing vaporization of PFAS from the particulate solids.

Claims

1. A method of remediating particulate solids contaminated with PFAS, the method comprising: enclosing particulate solids contaminated with PFAS in a vessel; generating microwave radiation of pre-determined frequency or frequencies and power level or levels; directing the microwave radiation to the particulate solids in the vessel, thereby heating the particulate solids and promoting vaporisation of the PFAS from the particulate solids; creating a partial vacuum at a location where at least a portion of the heated particulate solids are located, thereby further promoting vaporization of the PFAS from the particulate solids; transferring vapour from the vessel to a treatment stage; and treating in the treatment stage the vapour transferred from the vessel, thereby at least partially converting the vaporized PFAS into at least one safer substance.

2. The method according to claim 1, wherein: the step of creating a partial vacuum is performed by creating the partial vacuum in the vessel while the particulate solids are located therein; and wherein the step of directing the microwave radiation comprises directing the microwave radiation into the particulate solids below a surface level of the particulate solids in the vessel, whereby a significant proportion of available energy of the microwave radiation is absorbed into the particulate solids before that energy reaches a gas space above the surface level of the particulate solids, thereby reducing a chance of plasma formation in the gas space above the particulate solids.

3. The method according to claim 1, wherein: the step of directing the microwave radiation is discontinued after a period of heating time; and wherein the step of creating the partial vacuum is performed substantially simultaneously with or after the discontinuation of the step of directing microwave radiation, thereby creating the partial vacuum in the vessel.

4. The method according to claim 1, wherein; the step of directing the microwave radiation is discontinued after a period of heating time; and wherein after the step of directing the microwave radiation is ended, the heated particulate solids are transferred from the vessel to an extraction stage, thereby enabling further contaminated particulate solids contaminated with PFAS to be located in the vessel and to be heated therein, and wherein the step of creating the partial vacuum is performed in the extraction stage.

5. The method according to claim 1, further comprising a plasma inhibition step that inhibits formation of plasma in a gas space above a level of the particulate solids during the step of directing the microwave radiation into the particulate solids.

6. The method according to claim 5 wherein the plasma inhibition step includes directing the microwave radiation to the body of particulate solids in stages comprising: (i) a higher power microwave heating stage during which higher power microwave energy is applied to the particulate solids while simultaneously a pressure within the vessel greater than atmospheric pressure (101 kPa) is maintained; and (ii) a lower power microwave heating stage during which a lower power microwave energy is applied to the particulate solids and simultaneously a partial vacuum is created in the vessel in which the lower power microwave energy is being applied and during which PFAS are being vaporized for removal from the particulate solids, the higher power microwave energy being higher in power than the lower power microwave energy.

7. The method according to claim 6, wherein the higher power microwave heating stage and the lower power microwave heating stage are alternated, thereby improving an effectiveness of PFAS extraction by higher power heating and higher vacuum extraction.

8. The method according to claim 5, wherein the plasma inhibition step includes increasing an amount of inert gas in a gas atmosphere mixed with and surrounding the particulate solids while they are undergoing the heating by the microwave radiation, thereby inhibiting creation of plasma in the gas space above the level of particulate solids in the vessel during the step of directing the microwave radiation into the particulate solids.

9. A method of remediating particulate solids contaminated with PFAS, the method comprising: locating particulate solids contaminated with PFAS in a vessel; generating microwave radiation of pre-determined frequency or frequencies and power level or levels; directing the microwave radiation to the particulate solids in the vessel, thereby heating the particulate solids and promoting vaporisation of the PFAS; transferring vapour from the vessel to a treatment stage; and treating in the treatment stage the transferred vapour, thereby at least partially converting the vapourized PFAS into at least one safer substance; the step of treating the transferred vapour in the treatment stage comprising exposing the transferred vapour to a plasma within a treatment zone, whereby PFAS molecules in the vapour are subject to at least partial dissociation while entering and passing through the treatment zone.

10. The method according to claim 9, wherein the plasma in the treatment zone is created and/or is maintained by directing to the treatment zone microwave radiation from a secondary microwave generator that is operatively associated with the treatment zone.

11. The method according to claim 9, wherein the particulate solids that are contaminated with PFAS and located in the vessel are mixed either intermittently or continuously while the microwave radiation is directed to the particulate solids in the vessel, thereby promoting heating of the particulate solids and vaporisation of the PFAS.

12. The method according to claim 9, wherein: the particulate solids that are contaminated with PFAS are progressively fed into the vessel, either by continuous feeding of the particulate solids or by intermittent feeding of charges of the particulate solids; and the heated particulate solids that have yielded up PFAS by vaporisation are progressively removed from the vessel; the particulate solids being progressively moved from a soil feed location of the vessel to a soil removal location of the vessel while being exposed to the microwave irradiation.

13. The method according to claim 12, wherein the vessel in which the microwave radiation is directed to the particulate solids includes a microwave-transparent wall or window composed of a microwave-transparent material through which the particulate solids are exposed to the microwave radiation.

14. The method according to claim 9, wherein: a batch of the particulate solids contaminated with PFAS is located in the closed vessel, and during the direction of the microwave radiation to the body of particulate solids, the batch is mixed either intermittently or continuously, thereby exposing the batch of particulate solids substantially throughout its volume to the microwave radiation for a vaporisation period during which no further particulate solids are added to the vessel; and wherein the vapour containing the PFAS that is yielded up by the batch is removed from the vessel and treated prior to discharge of the treated particulate solids from the vessel.

15. The method according to claim 9, wherein the particulate solids are subjected to a two-stage heating process comprising: a first lower energy preheating stage in which the particulate solids are heated to vaporize water in the particulate solids and thereby dry the particulate solids to a pre-determined reduced moisture content; and a second higher energy heating stage in which the microwave radiation is directed to the particulate solids in the vessel having the reduced moisture content, thereby promoting vaporization of the PFAS.

16. The method according to claim 9, wherein the vapour containing PFAS yielded by the particulate solids is drawn from the vessel during the directing of the microwave radiation to the particulate solids in the vessel, and wherein the vapour containing PFAS is continuously drawn from the vessel and transferred into the treatment stage during the directing of the microwave radiation to the particulate solids in the vessel by creating a negative pressure downstream of the treatment stage which thereby draws the vapours from the vessel into and through the treatment stage.

17-18. (canceled)

19. The method according to claim 1, wherein; the microwave radiation directed to the particulate solids is generated by a microwave generator; and wherein the microwave radiation is transferred by a waveguide to the vessel through a microwave transparent wall of, or window in, the vessel, the waveguide incorporating a tuner operative to match an impedance of the microwave generator and associated waveguide to an impedance of the particulate solids in the vessel, thereby improving a microwave energy transfer efficiency to the particulate solids.

20. (canceled)

21. An apparatus constructed and operative to perform the method of claim 1, thereby remediating particulate solids contaminated with PFAS, the apparatus comprising: a vessel suitable for enclosure therein of particulate solids contaminated with PFAS; a microwave radiation generator suitable for generating microwave radiation of pre-determined frequency or frequencies and power level or levels; a coupling mechanism enabling the microwave radiation to be directed to the particulate solids in the vessel, thereby heating the particulate solids and promoting vaporisation of the PFAS from the particulate solids; a vacuum apparatus suitable for creating a partial vacuum at a location where at least a portion of the heated particulate solids are located, thereby further promoting vaporization of the PFAS from the particulate solids; a treatment stage; a vapour interconnection suitable for transferring the vapourized PFAS from the vessel to the treatment stage; and a vapour treatment apparatus suitable for treating in the treatment stage the vapourized PFAS transferred from the vessel to the treatment stage, thereby at least partially converting the vaporized PFAS into at least one safer substance.

22. The method of claim 13, wherein the vessel comprises a tube into which particulate solids to be treated are fed, the tube being inclined and being continuously or intermittently vibrated and/or rotated as the solids are fed therethrough, thereby causing the particulate solids to progressively travel by gravity down the inclined tube to an exit therefrom.

23. The method according to claim 9, wherein; the microwave radiation directed to the particulate solids is generated by a microwave generator; and wherein the microwave radiation is transferred by a waveguide to the vessel through a microwave transparent wall of, or window in, the vessel, the waveguide incorporating a tuner operative to match an impedance of the microwave generator and associated waveguide to an impedance of the particulate solids in the vessel, thereby improving a microwave energy transfer efficiency to the particulate solids.

Description

INTRODUCTION TO THE DRAWINGS

[0038] Possible and preferred features of the present invention will now be described with particular reference to the accompanying drawings. However it is to be understood that the features illustrated in and described with reference to the drawings are not to be construed as limiting on the scope of the invention. In the drawings:

[0039] FIG. 1 is a schematic diagram showing apparatus for processing PFAS to at least partially convert them into safer substances.

[0040] FIG. 2 is a schematic diagram showing apparatus for continuous processing of contaminated particulate solids, particularly soil.

[0041] FIG. 3 is a schematic diagram of an apparatus for batch treatment of contaminated particulate solids, particularly soil.

[0042] FIG. 4 is a diagram indicating the process steps for remediation of particulate solids.

DESCRIPTION OF EMBODIMENTS

[0043] Referring to FIG. 1, which shows apparatus for processing PFAS to at least partially convert them into safer substances, gaseous or vapour phase PFAS are introduced in the feed labeled “Gas In” into a treatment zone [6] such as the illustrated (microwave transparent) quartz tube. The treatment zone [6] is irradiated with microwave radiation of predetermined frequency or frequencies and power level or levels so as to create a plasma in the treatment zone [6] so that the plasma in the treatment zone at least partially dissociates the PFAS and produces safer substances including less toxic atoms, molecules and/or radicals which are removed through the outlet labeled “Gas Out”. The PFAS are continuously introduced into the treatment zone [6] and dissociation products are continuously withdrawn with the flow rate and plasma temperature being sufficient to effect substantially complete conversion of the PFAS into safer substances.

[0044] The microwave radiation is generated by a microwave generator [7] and a waveguide [21] transfers the microwave radiation to the treatment zone [6] through a microwave transparent wall of, or window in, the treatment zone which is comprised by the quartz tube walls in FIG. 1. The waveguide [21] incorporates a tuner [8] operative to match impedance of the microwave generator [7] and associated waveguide to the impedance of the load consisting of the PFAS in the treatment zone [6] so as to thereby improve microwave energy transfer efficiency to the treatment zone and improve the plasma creation. The waveguide [21] includes a directional coupler [22] to detect and monitor the reflected power which is used to control the tuner [8] in known manner.

[0045] It is known that microwave electric fields of sufficient strength can induce an ionised gas, also known as a plasma. Under atmospheric conditions air will break down forming a plasma when the electric field stress is in the vicinity of 30 kV/cm. The specific electric field strength to initiate a plasma will depend on many parameters such is temperature, gas ionisation energy and pressure.

[0046] Microwave plasmas are typically initiated in single mode cavities where their resonant nature gives rise to very high field strengths, however plasma can form in non-resonant multimode applicators provided there is sufficient electric field strength. The field strength is proportional to the square root of the applied power level.

[0047] The dimensions and configuration of suitable microwave applicators for plasma processing is very much dependent upon the frequency of operation which can be anywhere between 800 MHz to 30 GHz, however the most likely frequencies are 896 MHz, 915 MHz, 922 MHz and 2.45 GHz as these are commercially used in industry.

[0048] The power levels required will be dependent upon frequency, gas throughput and pressure and could be as low as 1 kW and as high as 300 kW.

[0049] The unique ability of a plasma to cause molecule disassociation into fundamental components is largely due to a combination of the average bulk ion temperature and extremely high individual ion temperatures. Free electrons in the plasma can have very high energy and hence very high individual ion temperatures. The bulk temperatures required are expected to be in the order of 800-1200° C. and the individual ion temperatures may be in the order of 1000 to 10,000° K.

[0050] In each of FIGS. 2 and 3 there is an apparatus for separating per- and poly-fluoroalkyl substances (PFAS) from particulate solids, particularly soil, followed by the destruction of the PFAS. The apparatus will be described with reference to treating contaminated soil. The apparatus comprises a material feeder to deliver soil to the treatment chamber in a closed vessel, which is a rotating treatment chamber (FIG. 2) or a mixing chamber (FIG. 3). The soil contaminated with PFAS and located in the vessel are mixed either intermittently or continuously while being irradiated by microwave radiation so as to promote heating of the soil by dielectric heating and vaporisation of PFAS. The closed vessel has a microwave transparent window for keeping the microwave emitter clean. A microwave generator exposes the soil to microwave energy via an impedance matching tuner. Microwave energy exposed to soil in the treatment chamber substantially completely removes and separates the liquids and PFAS from the soil which is drawn out and processed through a treatment stage utilising a microwave induced plasma to destroy the PFAS, followed by a filter collecting particulates. It is not necessary that the boiling points of the PFAS in the soil being treated are reached in the treatment chamber because the PFAS will vaporise progressively without necessarily reaching boiling point. The treatment stage may be substantially as described above and illustrated with reference to FIG. 1.

[0051] Referring to FIG. 2, PFAS contaminated soil [30] is drawn from the storage hopper [1] and progressively fed into the vessel having the treatment chamber [2] via a screw conveyor [3]. This can be by continuous feeding of soil or by intermittent feeding of charges of soil. In the chamber [2] of the vessel the soil is dielectrically heated by microwave energy to temperatures promoting vaporisation of PFAS (not necessarily gasification) and the soil that has yielded up PFAS by vaporisation is progressively is removed through outlet [4]. The PFAS are removed through outlet [5] as a vapour. The vapour is then passed through a microwave plasma afterburner [6], e.g. operating at suitable temperatures, e.g. above 800° C., and PFAS are destroyed, by dissociation of the PFAS molecules.

[0052] The input [3] and output [4] screw conveyors are lined with microwave chokes [3, 4] to prevent electromagnetic radiation from escaping the treatment chamber.

[0053] The treatment chamber [2] rotates to provide mixing of the soil which helps produce a homogeneous heating profile and release vapours (including PFAS). The treatment chamber [2] is angled to allow a gravity assisted flow of product from input to output assisted by the rotation of the chamber and the input [3] and output [4] screw conveyors. The tubular chamber [2] may also be either continuously or intermittently vibrated as well as rotated so that the soil progressively travels by gravity down the inclined tube to the exit [4] therefrom.

[0054] Vapours are drawn out of the chamber through the gas output [5] and passed through a microwave plasma treatment stage [6] to destroy the PFAS via thermal oxidation and/or dissociation.

[0055] The plasma is produced using a microwave generator [7] operating within the frequency spectrum of 300 MHz to 5 GHz and requires a tuning system [8] in the waveguide [21] for impedance matching.

[0056] The neutralised gases and particulates from the gas stream are then filtered [9] or adsorbed or otherwise processed to render them safe.

[0057] A pump [10] is used to extract the gasses from the treatment chamber and lower the pressure of the system.

[0058] An impedance matching tuner [11] is utilised in the waveguide [22] before the microwave input port, on the generator side, to maximise the amount of electromagnetic energy being absorbed by the soil. Tuning and impedance matching by tuner [11] can help to avoid a need or desirability of using a catalyst (high dielectric loss) in the particulate solids although such use of a catalyst can be possible if desired.

[0059] Electromagnetic energy from a microwave generator [12] operating within the frequency spectrum of 300 MHz to 5 GHz, is delivered to the treatment chamber [2] via waveguide [22].

[0060] Microwave transparent windows between the tuner [11] and treatment chamber [2] prevents soil and gases from entering the microwave waveguide [22].

[0061] Temperature probes [15, 16, 17, 18] are used at both ends of the treatment chamber [2] as well as at each input and output in order monitor the soil and vapour temperatures and enable process control.

[0062] The treatment chamber [2] is insulated with TBD material to maintain required internal temperatures.

[0063] The remediated soil is removed via the output screw conveyor and choke [4].

[0064] Energy levels, heating rates, input and output speed, rotation speed, temperatures and other monitored and controllable inputs and outputs are controlled, monitored and recorded via Touch Screen Computer Control System [19].

[0065] In FIG. 3, a batch of soil [30] contaminated with PFAS is located in chamber [2] of a the closed vessel, and during irradiation by the microwave radiation, the batch is mixed either intermittently or continuously, e.g. by mixer [25] shown as a helical blade, so as to expose the batch of soil solids substantially throughout its volume to the microwave irradiation for a vaporisation period during which no further soil is added to the vessel. This mixing can ensure uniform processing and thorough PFAS extraction. Vapour containing the PFAS yielded up by the batch of soil is removed from the closed vessel for downstream treatment prior to opening of the vessel and discharge of the treated particulate solids therein.

[0066] In the particular apparatus in FIG. 3, the chamber [2] is first opened and a charge of contaminated soil [30] is fed into the chamber. The chamber is closed and the soil therein is irradiated by microwaves from the two generators [12]. The soil in the chamber is continuously or intermittently mixed by any suitable mixer or agitator [25] operating within the chamber so that the soil being treated is thoroughly irradiated to promote dielectric heating leading to vaporisation and removal of the PFAS. The batch processing apparatus of FIG. 3 is otherwise operated substantially the same as the apparatus of FIG. 2.

[0067] The pump [10] which creates suction to draw PFAS out of the treatment chamber [2] and through the treatment stage constituted by the plasma applicator [6] can reduce the vapour pressure in the treatment chamber and hence assist vaporisation of PFAS, although the function of the pump is also to draw the PFAS vapour from the chamber through the treatment stage. Thus the vapour containing PFAS is continuously drawn from the chamber [2] and transferred into the treatment stage [6] during the treatment of the particulate solids in the vessel by creating a negative pressure downstream of the treatment stage which thereby draws vapours from the vessel into and through the treatment stage. However it is also possible that vapour containing PFAS yielded by the soil [30] is drawn from the vessel after the irradiation of the soil in the vessel.

[0068] Because removal of water from the soil [30] being treated which occurs under the effects of the microwave irradiation generally increases the permeability of the soil to microwave energy, the process and apparatus may have a two-stage (or more than two-stage) operation. In particular, in a first-stage, the microwave irradiation is primarily conducted using parameters for vaporising water in the soil. This increases the microwave permeability of the progressively drying soil so that, in a second stage, the power of the microwave radiation generated and transmitted into the treatment chamber [2] is increased to more effectively vaporise PFAS in the at least partially dried soil.

[0069] In a further possible embodiment of the invention, the chamber [2] in which the soil is irradiated may include (or may consist of) a microwave transparent enclosure, e.g. composed of quartz or ceramic or other microwave transparent material, in which the soil resides during the irradiation. The enclosure may comprise for example a quartz or ceramic tube into which soil to be treated is fed, the tube being inclined and either continuously or intermittently vibrated so that the soil progressively travels by gravity down the inclined tube to an exit therefrom. The vibration will promote penetration of the microwave radiation (and heating effects) and/or direct exposure of the soil surfaces and interstices as the soil particles are agitated and loosened and separated and as they mix and migrate. A suitable apparatus may be a vibrator coupled to the tube and used to promote granular flow e.g. of the type in the mining industry or other industries where flow of particulates in a tube or pipe or the like is required. The vibration frequency and amplitude, and the angle of inclination of the tube, will be parameters that affect the soil movement speed through the irradiation zone, and these parameters may be selectively variable and may be empirically determined to optimise the process.

[0070] In both of the particular embodiments of FIGS. 2 and 3, the soil can be subject to a two-stage heating process comprising: a first preheating stage in which the soil is heated to vaporize water and thereby dry the soil to a pre-determined moisture content, and a second higher energy heating stage in which microwave irradiation of the soil having the reduced moisture content occurs to promote vaporization of PFAS. The first preheating stage in which the soil is heated to dry the soil to a pre-determined moisture content can be performed at least partially before the soil is fed to the closed vessel, i.e. upstream of the soil inlet to the chamber [2]. The first preheating stage may comprise or include conventional heating by conduction or thermal (IR) radiation, (including before introduction into the chamber [2] of the closed vessel), and induction heating by low power microwave may also or alternatively be used. The microwave generator [12] used for the PFAS vaporization second heating stage can be operated at a lower power level for the first preheating stage.

[0071] In both of the particular embodiments of FIGS. 2 and 3 and in variations thereof, the apparatus may include means for creating a partial vacuum where soil [30] is heated by the microwave radiation directed into the chamber [2] of the closed vessel so as to promote vaporization of PFAS from the soil. The operation of the pump [10] in the illustrated embodiments is one possible arrangement for effecting this suction.

[0072] In a first possible arrangement the means for creating a partial vacuum is performed by creating the partial vacuum in the closed vessel while the soil [30] is located therein and, unlike FIG. 3, the microwave radiation is directed into the soil [30] below the surface level of the soil in the closed vessel whereby a significant and preferably major proportion of the available energy is absorbed in the soil before that energy reaches the gas space above the soil surface. This reduces the chance of plasma formation in the gas space above the soil which is more likely to occur in a lower vapour pressure space.

[0073] In a second possible arrangement having the means for creating a partial vacuum, the directing of microwave radiation into the soil is discontinued after a period of heating time, and substantially simultaneously with or after the discontinuation of the step of directing microwave radiation the partial vacuum is created in the closed vessel. This also reduces the likelihood of plasma formation and arcing occurring in the gas space when the suction step is performed to lower the vapour pressure.

[0074] In a third possible arrangement having the means for creating a partial vacuum, and applicable to the batch system of FIG. 3, after the step of directing microwave radiation to heat the particulate solids is ended, the heated soil is then transferred from the chamber [2] in the closed vessel to a separate extraction stage, thereby enabling further contaminated soil [30] to be located in the chamber [2] of the closed vessel for being heated therein, and the means for creating the partial vacuum is operated to create the partial vacuum e.g. in a closed chamber of the separate extraction stage to promote vaporization of PFAS from the heated soil. This separates the vaporization under the partial vacuum from the microwave heating so the plasma formation/arcing is not a risk in the suction operation.

[0075] Also in both of the particular embodiments of FIGS. 2 and 3 and in variations thereof, the apparatus may includes means for effecting a plasma inhibition to inhibit formation of plasma in a gas space above the level of soil during the step of directing microwave radiation into the soil to cause heating thereof. For example, the plasma inhibition may be effected by performing the microwave heating of the soil in two stages consisting of (i) a higher power heating stage during which higher power microwave energy is applied to the soil [30] while simultaneously a pressure within the chamber [2] of the vessel greater than atmospheric pressure (101 kPa) is maintained, and (ii) a lower power microwave heating stage in which a lower power level of microwave radiation is applied to the soil and simultaneously a partial vacuum is created in the vessel in which the lower power microwave radiation is being applied and during which PFAS are being vaporized for removal from the soil. In this embodiment, the higher power microwave heating stage and lower power microwave heating stage may be alternated so as to improve the effectiveness of PFAS extraction by higher power heating and higher vacuum extraction.

[0076] Alternatively, to the two stage heating, or in conjunction therewith, the plasma inhibition may include substantially increasing the amount of inert gas, particularly helium or neon or argon, in the gas atmosphere mixed with and surrounding the soil [30] undergoing heating by microwave radiation so as to thereby inhibit the creation of a plasma in the gas space above the level of soil [30] in the chamber [2] of the vessel where microwave irradiation is occurring. The high ionization temperature of helium particularly inhibits the creation of a plasma in the gas.

[0077] In both of the particular embodiments of FIGS. 2 and 3 and in variations thereof, the apparatus may further include a means for sizing the particulate solids generally, or soil in the particular embodiments, prior to locating the body of particulate solids in the chamber [2] of the closed vessel to optimize the sizes of the particulate solids to achieve desirable dielectric properties of the particulate solids for their microwave heating. Sizing of the particulate can enable matching or optimization of microwave penetration depths in different soils, concrete, asphalt, etc. Sizing may be performed by any suitable apparatus such as those used in mineral processing technologies, including crushing and sizing. Such sizing can be most desirable for remediation of PFAS contaminated concrete, paving, asphalt, bitumen, tarmac etc. so as to increase the surface area of the particulate solids and promote extraction of PFAS therefrom.

[0078] The diagram of FIG. 4 illustrates the processes of the invention used for remediation of contaminated solid particulate materials. The treatment to vaporise PFAS can be performed by the apparatus of FIG. 2 (continuous processing) or of FIG. 3 (batch processing). The vacuum production may comprise application of suction as exemplified in FIG. 2 to draw vaporised PFAS from the heating and vaporising chamber through the treatment zone. Alternatively, the vacuum production may comprise means for effecting any of the alternative vacuum creating embodiments described herein, including: [0079] applying a partial vacuum while microwave energy is applied into the particulate solids in the closed vessel below the surface, or [0080] applying the vacuum upon or after discontinuation of the microwave heating of particulate solids in the closed vessel, or [0081] transferring the heated particulate solids from the closed vessel in which the microwave heating has occurred to a separate closed extraction chamber to which the vacuum is applied.

[0082] In FIG. 4 the PFAS vapour treatment by plasma may comprise the treatment as described in relation to FIG. 1.

[0083] It will be seen that the particular preferred embodiments of possible apparatus embodying the present invention described and illustrated herein can be used to effectively remediate soil contaminated with PFAS. The processed soil may be of better quality for re-introduction to the environment since lower temperatures are used in the PFAS extraction compared to prior soil heating systems. The apparatus can be sufficiently small scale to be transported to a site where the contaminated soil to be treated is located and the apparatus can be set up and operated at the site by systematically collecting soil throughout the site and processing it according to the method and apparatus of the invention for immediate return.

[0084] It is to be understood that various alterations, modifications and/or additions may be made to the features of the possible and preferred embodiment(s) of the invention as herein described without departing from the spirit and scope of the invention.