Thermal stability of geometrically complex-shaped smart susceptors
10893580 ยท 2021-01-12
Assignee
Inventors
- Landon K. Henson (Seattle, WA, US)
- Marc R. Matsen (Seattle, WA, US)
- John R. Hull (Seattle, WA, US)
- Lee C. Firth (Seattle, WA, US)
- Tunde A. Olaniyan (Bothell, WA, US)
Cpc classification
H05B2206/023
ELECTRICITY
International classification
Abstract
A smart susceptor assembly including an electromagnetic flux source such as one or more inductors, a geometrically complex-shaped susceptor having one or more contours, and a cladding on or over the susceptor. The cladding can alter both the thermal performance and the electrical operation of the smart susceptor assembly. With regard to thermal performance, the cladding can function as a passive heat exchanger to dissipate thermal energy across the surface of the susceptor. With regard to electrical operation, the cladding can provide a current path after portions of the susceptor heat and become low or non-magnetic.
Claims
1. A smart susceptor assembly, comprising: an electromagnetic flux field source configured to generate an electromagnetic flux field; a susceptor comprising one or more contours and positioned adjacent to the electromagnetic flux field source, wherein the susceptor comprises a leveling temperature and a Curie temperature; and an electrically conductive cladding positioned on or over the susceptor and electrically coupled to the susceptor, wherein: the electrically conductive cladding is thermally conductive; the susceptor and the electrically conductive cladding provide a receptacle configured to receive a flowable material to be heated within the receptacle during a heating process; and the smart susceptor assembly comprises only one leveling temperature and only one Curie temperature.
2. The smart susceptor assembly of claim 1, wherein the smart susceptor assembly is configured to transfer a flow of electrical current from the susceptor to the electrically conductive cladding prior to a region of the susceptor exceeding the Curie temperature.
3. The smart susceptor assembly of claim 2, wherein the electrically conductive cladding prevents a thermal overheating in the susceptor during operation of the smart susceptor assembly.
4. The smart susceptor assembly of claim 1, wherein the electromagnetic flux field source comprises at least one linear induction coil, wherein any portion of the linear induction coil that has a magnetic field influence on any portion of the susceptor during operation of the smart susceptor assembly is straight or linear.
5. The smart susceptor assembly of claim 1, wherein: the electrically conductive cladding comprises at least one of copper, silver, gold, bronze, and/or non-magnetic copper-nickel; the electrically conductive cladding has a thickness of about 0.53 millimeters (mm) to about 9.525 mm; and the susceptor comprises at least one of an iron alloy, a nickel alloy, a cobalt alloy, and/or a ferrous nickel-cobalt alloy.
6. The smart susceptor assembly of claim 1, wherein the cladding physically contacts the susceptor.
7. The smart susceptor assembly of claim 6, wherein the cladding is formed over at least 25% of a surface of the susceptor.
8. The smart susceptor assembly of claim 6, wherein the cladding is formed over 100% of a surface of the susceptor.
9. The smart susceptor assembly of claim 1, wherein: the electromagnetic flux field source comprises one or more induction coils; and at least one of the one or more induction coils is a linear induction coil, wherein any portion of the linear induction coil that has a magnetic field influence on any portion of the susceptor during operation of the smart susceptor is straight or linear.
10. A smart susceptor assembly, comprising: an electromagnetic flux field source configured to generate an electromagnetic flux field; a susceptor comprising one or more contours and positioned adjacent to the electromagnetic flux field source wherein: at a temperature of 75 F. and an applied field of about 5 oersted (Oe) to about 350 Oe, the susceptor has a magnetic permeability of about 50 Newtons per amp squared (N/A.sup.2) to about 800 N/A.sup.2; and at a leveling temperature of the susceptor and the applied field of about 5 Oe to about 350 Oe, the susceptor has a magnetic permeability of about 1 Oe to about 1.5 Oe; and an electrically conductive cladding positioned on or over the susceptor and electrically coupled to the susceptor, wherein the electrically conductive cladding has a magnetic permeability of about 1 to about 1.5 at a temperature of 75 F. and at the leveling temperature of the susceptor, wherein: the electrically conductive cladding is thermally conductive; the susceptor and the electrically conductive cladding provide a receptacle configured to receive a material to be heated within the receptacle during a heating process; and the smart susceptor assembly comprises only one leveling temperature and only one Curie temperature.
11. The smart susceptor assembly of claim 10, wherein: the electrically conductive cladding comprises at least one of copper, silver, gold, bronze, and/or non-magnetic copper-nickel; and the susceptor comprises at least one of an iron alloy, a nickel alloy, a cobalt alloy, and/or a ferrous nickel-cobalt alloy.
12. The smart susceptor assembly of claim 11, wherein: the electrically conductive cladding has a thickness of about 0.53 millimeters (mm) to about 9.525 mm; the electromagnetic flux field source comprises one or more induction coils; and at least one of the one or more induction coils is a linear induction coil, wherein any portion of the linear induction coil that has a magnetic field influence on any portion of the susceptor during operation of the smart susceptor is straight or linear.
13. A method for heating a material, comprising: positioning a material in proximity to a susceptor of a smart susceptor assembly, wherein: the smart susceptor assembly comprises an electrically conductive cladding electrically coupled to the susceptor; the electrically conductive cladding is thermally conductive; the susceptor comprises one or more contours and is positioned adjacent to an electromagnetic flux field source of the smart susceptor assembly; the smart susceptor assembly comprises only one leveling temperature and only one Curie temperature; and the susceptor and the electrically conductive cladding provide a receptacle configured to receive a material to be heated within the receptacle; placing the material to be heated within the receptacle; emitting an electromagnetic flux field from the electromagnetic flux field source onto the susceptor thereby flowing a current through the susceptor and heating the susceptor toward a leveling temperature of the susceptor; and transferring a current flow from the susceptor to the electrically conductive cladding prior to a temperature of a region of the susceptor exceeding a Curie temperature of the susceptor.
14. The method of claim 13, further comprising transferring at least a portion of the current that flows through the susceptor to the electrically conductive cladding as the temperature of the region of the susceptor reaches the leveling temperature.
15. The method of claim 13, further comprising applying a first current to one or more linear induction coils, thereby resulting in the emitting the electromagnetic flux field from the electromagnetic flux field source, wherein any portion of the linear induction coil that has a magnetic field influence on any portion of the susceptor during operation of the smart susceptor assembly is straight or linear.
16. The method of claim 15, further comprising applying a second current that is lower than the first current to the one or more induction coils subsequent to the applying of the first current.
17. The method of claim 16, wherein the first current is about 1500 amps (A) to about 1700 A and the second current is about 500 A to about 700 A.
18. The method of claim 13, wherein the electrically conductive cladding comprises at least one of copper silver, gold, bronze, and non-magnetic copper-nickel.
19. The method of claim 18, wherein the electrically conductive cladding has a thickness of about 0.53 millimeters (mm) to about 9.525 mm.
20. The method of claim 13, wherein: at a temperature of 75 F. and an applied field of about 5 oersted (Oe) to about 350 Oe, the susceptor has a magnetic permeability of about 50 Newtons per amp squared (N/A2) to about 800 N/A2; and at the leveling temperature of the susceptor and the applied field of about 5 Oe to about 350 Oe, the susceptor has a magnetic permeability of about 1 Oe to about 1.5 Oe.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings, which are incorporated in, and constitute a part of this specification, illustrate implementations of the present teachings and, together with the description, serve to explain the principles of the disclosure. In the figures:
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(9) It should be noted that some details of the figures have been simplified and are drawn to facilitate understanding of the present teachings rather than to maintain strict structural accuracy, detail, and scale.
DETAILED DESCRIPTION
(10) Reference will now be made in detail to exemplary implementations of the present teachings, examples of which are illustrated in the accompanying drawings. Generally, the same reference numbers will be used throughout the drawings to refer to the same or like parts.
(11) As discussed above, smart susceptors are a useful tool in manufacturing and other uses due, in part, to their ability for thermal self-regulation. In flat (i.e., planar or blanket) configurations, the smart susceptor can maintain a generally uniform temperature across the entirety of the susceptor, for example, within 20, or within 10 F. of the leveling temperature for which it is designed. The smart susceptor can be designed to approach a predetermined leveling temperature by, for example, selecting the percentage of one or more component materials of the susceptor, such as the percentage of one or more metal or metal alloy components. The leveling temperature is also dependent to a lesser extent on magnetic field strength and other factors.
(12) Smart susceptors can be employed in many different uses and configurations. In some uses, the susceptor can be formed to encase or sheathe a solid structure that is to be heated to a specific temperature, for example, during a drying or curing process. In other uses, the susceptor can be formed or contoured to provide a receptacle. The receptacle may be used, for example, to store and heat a material such as a thermoset, thermoplastic, or mold material, or configured for other uses. For example, U.S. patent application Ser. No. 15/791,683 titled Induction Molding for Parts Having Thermoplastic Portions, Filed Oct. 24, 2017, discusses a molding structure and process including a smart susceptor. As these materials are typically heated to a critical processing temperature or other target temperature for use, and overheating above the target temperature is avoided, the smart susceptor lends itself particularly well to such processes as the smart susceptor is self-regulating with regard to temperature.
(13) Forming a susceptor to have a geometrically complex shape with one or more contours has been found to alter the thermal performance of the susceptor compared to the performance of a flat, planar, or blanket configuration. In some cases, thermal runaway and overheating at one or more locations of the contoured susceptor can occur.
(14) The smart susceptor assembly 100 of
(15) During numerical simulation of a structure similar to that depicted in
(16) In one implementation of the present teachings, to mitigate the preferred current paths through the susceptor and their adverse effects, a localized electrically conductive skin or cladding 200 is provided on or over the susceptor 102 as depicted in the partially exploded perspective depiction of
(17) The cladding 200 can be an electrically conductive material such as copper, silver, gold, platinum, bronze, and non-magnetic copper-nickel. In general, the cladding 200 may be or include a layer of a material that has a lower magnetic permeability than the material from which the susceptor is formed, a high thermal conductivity, and a high electrical conductivity. At an applied magnetic field of about 5 oersted (Oe) to about 350 Oe and a temperature of 75 F., Kovar has a magnetic permeability of about about 50 Newtons per amp squared (N/A.sup.2) to about 500 N/A.sup.2, depending on the magnitude of the applied magnetic field. Generally, at 75 F. and the applied magnetic field of about 5 Oe to about 350 Oe, suitable susceptors will have a magnetic permeability of about 50 N/A.sup.2 to about 800 N/A.sup.2. At an applied magnetic field of about 5 Oe to about 350 Oe and at the leveling temperature, for example 788 F., susceptors can have a magnetic permeability of about 1 N/A.sup.2 to about 1.5 N/A.sup.2. Being non-magnetic, copper cladding 200 has a magnetic permeability of 1 at all working temperatures, and the cladding 200 will generally have a magnetic permeability of about 1 to about 5 at all working temperatures, depending on the material. Kovar can have a thermal conductivity of 17 Watts/meter-Kelvin (W/mK). The cladding 200 can have a thermal conductivity ranging from about 200 W/mK to about 400 W/mK and an electrical conductivity of at least about 1E7 siemens per meter (S/m), for example, ranging from about 1E7 S/m to about 6E7 S/m, depending on the material.
(18) In an implementation, the cladding 200 can alter both the thermal performance and the electrical operation of the geometrically complex-shaped susceptor 102 compared to a susceptor without cladding 200.
(19) With regard to thermal performance, the cladding 200 can function as a passive heat exchanger to dissipate thermal energy from the overheated regions 110 that tend to reach thermal equilibrium at a temperature above the leveling temperature to the underheated regions 114 that tend to reach thermal equilibrium at a temperature of less than 10 F. below the leveling temperature. In this capacity, the cladding 200 provides passive regulation of the temperature across the surface of the susceptor 102, both on an exterior surface 204 and an interior surface 206 of the susceptor 102. This decreases the range of temperature across the surface of the susceptor 102 and allows for more precise thermal control of heating of the flowable material 106 within the receptacle 104.
(20) With regard to electrical operation, the cladding 200 can provide a current path after one or more regions or portions of the susceptor 102 become low permeability and non-magnetic after reaching the Curie temperature. As described above, at relatively low temperatures the susceptor 102 is highly permeable to an electromagnetic flux field and the skin depth is small. At these relatively low temperatures, the electrical resistance of the susceptor 102 is high. When placed into an electromagnetic flux field generated from the induction coil 108, the susceptor 102 begins to inductively heat, the skin depth of the susceptor 102 increases and the magnetic permeability decreases, thereby attenuating the electrical resistance of the susceptor 102 and reducing the heating effect. The susceptor 102 becomes increasingly nonmagnetic, at which point the electric current begins to flow through the cladding 200 rather than the susceptor 102. Once the susceptor 102 begins to cool, the skin depth decreases, the magnetic permeability increases, and the electric current from the induction coil begins to flow through the susceptor 102, and the susceptor 102 begins to heat until reaching the leveling temperature. However, as described above, with a geometrically complex-shaped susceptor 102 absent cladding 200, current continues to flow through the susceptor and the susceptor can continue to heat well above the Curie temperature. By including the cladding 200, as portions of the susceptor 102 reach the Curie temperature and the susceptor 102 becomes magnetically low-permeable to non-permeable, the current resulting from the magnetic field generated by the inductor begins to flow through the cladding 200, thereby preventing overheating of the susceptor 102 above its designed Curie temperature.
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(22) In an implementation, the cladding 200 can have a thickness of about 0.53 millimeters (mm) to about 9.525 mm, or about 1.5875 mm to about 3.175 mm. A cladding 200 that is excessively thin results in an insufficient heating effect and high resistance to current flow, while a cladding 200 that is excessively thick adds weight and expense.
(23) The cladding 200 can be formed on the exterior surface 204 of the susceptor 102 as depicted in
(24) The cladding 200 can be formed on or over the susceptor 102 using any suitable process. For example, the cladding 200 can be spray coated onto the susceptor 102, for example, by suspending particles of the cladding 200 material within a solvent to form a cladding solution, spray coating the solution onto the susceptor 102, and removing the solvent from the solution using, for example, a drying process. The spray coating process may include the use of an optional mask to define one or more areas on the surface of the susceptor 102 where the cladding 200 will be formed. In another formation process, the cladding 200 can be pre-formed into a desired shape that matches contours of the susceptor 102 and the subsequently physically attached to the susceptor 102 using, for example, an electrically and thermally conductive adhesive. In another implementation, the cladding 200 can be brazed onto the surface of the susceptor 102. In yet another implementation, the cladding 200 can be electrodeposited onto the surface of the susceptor 102.
(25) Where the cladding 200 does not cover 100% of the surface of the susceptor 102, the location of the cladding 200 can vary, for example, depending on the shape of the article to which it is being attached and other design considerations. The location of the cladding 200 may be determined through modeling (e.g., computer simulation) or other techniques, where the cladding 200 extends over the susceptor 102 on, and in proximity to, the overheated regions 110, thereby providing a preferred electric current path once the overheated regions 110 approach the leveling temperature. In another implementation, overheated regions 110 may be discovered during use or characterization of the smart susceptor, at which point the cladding 200 may be added to the surface of the susceptor 102 to mitigate localized overheating.
(26) As discussed above relative to
(27) A smart susceptor design that includes cladding has a reduced sensitivity to the specific placement of the induction coil as well as to variations of electric current through the induction coils. This allows for a simplified design of the induction coils, thereby reducing production costs. In some designs, as depicted in
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(30) Modeling of structures similar to those of depicted in
(31) A smart susceptor including cladding in accordance with the present teachings can be used in various ways depending on the specific application. A process or method 700 for heating an article using a smart susceptor is depicted in the flow chart or flow diagram of
(32) In one implementation, as at 702, a material to be heated, for example, a flowable material 414, 512 such as a thermoset, thermoplastic, or mold material is placed in proximity to a susceptor 412, 506 that is part of a smart susceptor assembly 400, 500. The susceptor 412, 506 may have a geometrically complex shape, for example, with a plurality of contours that form a receptacle 410, 514, where the flowable material is placed into the receptacle 410, 514. The smart susceptor assembly 400, 500 further includes a cladding layer (cladding) 402, 508 on or over an exterior and/or interior surface of the susceptor 412, 506. The susceptor 412, 506 is positioned relative to one or more segments of one or more induction coils 404, 406, 502, as shown at 704. The induction coils 404, 406, 502 can include straight or linear induction coils 404, 502, longitudinally curved induction coils 406, or a combination of both.
(33) Subsequently, as shown at 706, a current is applied to the induction coils 404, 406, 502. The current results in the induction coils 404, 406, 502 emitting a magnetic flux field onto the susceptor 412, 506 which results in resistive heating of the susceptor 412, 506, which begins to heat the flowable material 414, 512 within the receptacle 410, 514 of the susceptor 412, 506. In an implementation, a relatively high current of about 1500 A to about 1700 A, for example about 1600 A, can be applied to the induction coils 404, 406, 502 to quickly bring the susceptor 412, 506 to the leveling temperature for which it was designed, thereby heating the flowable material 414, 512 to a target temperature. For purposes of explanation, the target temperature is 788 F. and the smart susceptor 400, 500 is designed for a leveling temperature of 788 F. or higher that is sufficient to heat the flowable material 414, 512 to the target temperature. At relatively low temperatures, the susceptor 412, 506 is highly permeable to the electromagnetic flux field and the skin depth of the susceptor 412, 506 is small. As the susceptor 412, 506 heats and approaches the leveling temperature, the magnetic permeability of the susceptor 412, 506 decreases, the current flow through the susceptor 412, 506 decreases, and the current flow through the cladding 402, 508 increases. Once a portion of the susceptor reaches the Curie temperature, that portion of the susceptor generally becomes magnetically low-permeable to non-permeable and non-magnetic, and current flow is transferred to the cladding.
(34) During heating of the susceptor 412, 506, a temperature at one or more susceptor locations can be monitored. As the susceptor 412, 506 approaches the leveling temperature at the one or more monitored locations, the current applied to the induction coils 404, 406, 502 can be ramped downward or otherwise decreased as at 708 to maintain the susceptor 412, 506 at the leveling temperature using the reduced current. In an implementation, the current applied to the induction coils 404, 406, 502 can be reduced to about 500 A to about 700 A, for example to about 600 A. The initial relatively high current of 1500 A to 1700 A thus rapidly heats the susceptor 412, 506 to its designed leveling temperature, thereby rapidly bringing the flowable material 414, 512 to the target temperature, while the reduced current of between about 500 A and 700 A maintains the susceptor 412, 506 at leveling temperature and the flowable material 414, 512 at the target temperature.
(35) Once the flowable material 414, 512 reaches the target temperature, the molding process of the flowable material 414, 512 can be performed. This molding process can including inserting the upper assembly 510 into the heated flowable material 414, 512 within the receptacle 410, 514. The molding process can then continue according to known techniques, as at 710.
(36) Thus a smart susceptor assembly according to an implementation of the present teachings can include a susceptor having a geometrically complex shape. In such a configuration, the susceptor typically can have overheated regions that exceed the leveling temperature and can result in thermal runaway. Simultaneously, the susceptor typically can have underheated regions that are more than 10 F. under the leveling temperature. By adding cladding that can include one or more discrete cladding structures to one or more surfaces of the susceptor, the electrical operation of the smart susceptor and the thermal profile of the susceptor during use is altered. In one aspect, the range of temperatures across the surface of the susceptor upon reaching thermal equilibrium is decreased to a mean temperature that approaches the leveling temperature for which the smart susceptor is designed.
(37) It will be appreciated that the article to be heated may include any solid, liquid, or gaseous material, or any combination of two or more of a solid, a liquid, or a gas, including fiber/fabric layers such as carbon fiber layers pre-impregnated with a thermally curable resin. The smart susceptor assembly may be used to heat one or more materials during any number of manufacturing, testing, production, etc., processes related to various fields of endeavor such as vehicle manufacture or testing (e.g., aerospace vehicles, military vehicles, transportation vehicles, etc.), manufacture and testing of consumer products, etc.
(38) Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the present teachings are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements. Moreover, all ranges disclosed herein are to be understood to encompass any and all sub-ranges subsumed therein. For example, a range of less than 10 can include any and all sub-ranges between (and including) the minimum value of zero and the maximum value of 10, that is, any and all sub-ranges having a minimum value of equal to or greater than zero and a maximum value of equal to or less than 10, e.g., 1 to 5. In certain cases, the numerical values as stated for the parameter can take on negative values. In this case, the example value of range stated as less than 10 can assume negative values, e.g. 1, 2, 3, 10, 20, 30, etc.
(39) While the present teachings have been illustrated with respect to one or more implementations, alterations and/or modifications can be made to the illustrated examples without departing from the spirit and scope of the appended claims. For example, it will be appreciated that while the process is described as a series of acts or events, the present teachings are not limited by the ordering of such acts or events. Some acts may occur in different orders and/or concurrently with other acts or events apart from those described herein. Also, not all process stages may be required to implement a methodology in accordance with one or more aspects or implementations of the present teachings. It will be appreciated that structural components and/or processing stages can be added or existing structural components and/or processing stages can be removed or modified. Further, one or more of the acts depicted herein may be carried out in one or more separate acts and/or phases. Furthermore, to the extent that the terms including, includes, having, has, with, or variants thereof are used in either the detailed description and the claims, such terms are intended to be inclusive in a manner similar to the term comprising. The term at least one of is used to mean one or more of the listed items can be selected. As used herein, the term one or more of with respect to a listing of items such as, for example, A and B, means A alone, B alone, or A and B. Further, in the discussion and claims herein, the term on used with respect to two materials, one on the other, means at least some contact between the materials, while over means the materials are in proximity, but possibly with one or more additional intervening materials such that contact is possible but not required. Neither on nor over implies any directionality as used herein. The term conformal describes a coating material in which angles of the underlying material are preserved by the conformal material. The term about indicates that the value listed may be somewhat altered, as long as the alteration does not result in nonconformance of the process or structure to the illustrated implementation. Finally, exemplary indicates the description is used as an example, rather than implying that it is an ideal. Other implementations of the present teachings will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure herein. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the present teachings being indicated by the following claims.
(40) Terms of relative position as used in this application are defined based on a plane parallel to the conventional plane or working surface of a workpiece, regardless of the orientation of the workpiece. The term horizontal or lateral as used in this application is defined as a plane parallel to the conventional plane or working surface of a workpiece, regardless of the orientation of the workpiece. The term vertical refers to a direction perpendicular to the horizontal. Terms such as on, side (as in sidewall), higher, lower, over, top, and under are defined with respect to the conventional plane or working surface being on the top surface of the workpiece, regardless of the orientation of the workpiece.