COMPOSITION COMPRISING A PARTICULAR OXIDATION DYEING BASE, AT LEAST ONE ASSOCIATIVE POLYMER AND AT LEAST ONE FATTY SUBSTANCE

Abstract

Composition comprising a particular oxidation dyeing base, at least one associative polymer and at least one fatty substance Composition comprising a particular oxidation dyeing base, at least one associative polymer and at least one fatty substance. The invention relates to a composition comprising at least one particular dyeing base, at least one cellulosic associative polymer, and at least one fatty substance, the total content of fatty substance being greater than or equal to 30% by weight, relative to the total weight of the composition.

Claims

1-19. (canceled)

20. A composition comprising: 2-(methoxymethyl)benzene-1,4-diamine of formula (I), addition salts thereof, solvates thereof, solvates of its salts thereof, or mixtures of two or more thereof: ##STR00012## at least one cellulosic associative polymer, at least one fatty substance in a total amount of greater than or equal to 30% by weight, relative to the total weight of the composition.

21. The composition of claim 20, wherein the at least one cellulosic associative polymer is chosen from cationic cellulosic associative polymers.

22. The composition of claim 20, wherein the at least one cellulosic associative polymer is chosen from hydroxyethylcelluloses of formula (Ib): ##STR00013## wherein: R represents an ammonium group RaRbRcN.sup.+Q.sup., wherein Ra, Rb, and Rc are independently chosen from a hydrogen atom or a linear or branched C.sub.1-C.sub.30 alkyl, and Q.sup. represents an anionic counterion; R represents an ammonium group RaRbRcN.sup.+Q.sup., wherein Ra, Rb, and Rc are independently chosen from a hydrogen atom or a linear or branched C.sub.1-C.sub.30 alkyl, and Q.sup. represents an anionic counterion; wherein at least one of the radicals Ra, Rb, Rc, Ra, Rb, and Rc represents a linear or branched C.sub.8-C.sub.30 alkyl; n, x, and y are independently chosen from an integer between 1 and 10 000.

23. The composition of claim 22, wherein the at least one cellulosic associative polymer is chosen from cationic cellulosic associative polymers of formula (Ib), wherein R represents trimethylammonium halide, and R represents dimethyldodecylammonium halide.

24. The composition of claim 20, comprising at least one liquid fatty substance.

25. The composition of claim 20, comprising at least one solid fatty substance.

26. The composition of claim 20, wherein the total amount of 2-(methoxymethyl)benzene-1,4-diamine(s) of formula (I), addition salts, solvates thereof, solvates of its salts thereof, or mixtures of two or more thereof, ranges from 0.001% to 20% by weight, relative to the total weight of the composition.

27. The composition of claim 20, wherein the total amount of the cellulosic associative polymer(s) ranges from 0.01% to 20% by weight, relative to the total weight of the composition.

28. The composition of claim 20, wherein the total amount of the fatty substance(s) is greater than or equal to 35% by weight, relative to the total weight of the composition.

29. The composition of claim 24, wherein the total amount of the liquid fatty substance(s) is greater than or equal to 35% by weight, relative to the total weight of the composition.

30. The composition of claim 20, further comprising at least one oxidation coupler.

31. The composition of claim 30, wherein the at least one oxidation coupler is chosen from 6-hydroxybenzomorpholine, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino-5-ethylphenol, addition salts thereof, solvates thereof, solvates of their salts thereof, or mixtures of two or more thereof.

32. The composition of claim 20, further comprising at least one surfactant.

33. The composition of claim 20, further comprising at least one sequestrant.

34. The composition of claim 20, further comprising at least one alkaline agent.

35. The composition of claim 34, wherein the at least one alkaline agent is chosen from alkanolamines, aqueous ammonia, carbonates, bicarbonates, or mixtures of two or more thereof.

36. The composition of claim 20, wherein the composition is free or substantially free of any chemical oxidizing agent.

37. The composition of claim 20, further comprising at least one chemical oxidizing agent.

38. A method for dyeing keratin fibers, comprising mixing (A) a dye composition with (B) an oxidizing composition, Wherein the dye composition (A) comprises: 2-(methoxymethyl)benzene-1,4-diamine of formula (I), addition salts thereof, solvates thereof, solvates of its salts thereof, or mixtures of two or more thereof: ##STR00014## at least one cellulosic associative polymer, at least one fatty substance in a total amount of greater than or equal to 30% by weight, relative to the total weight of the composition, and wherein the oxidizing composition (B) comprises at least one chemical oxidizing agent.

39. A kit comprising: a first compartment comprising a dye composition (A), wherein the dye composition (A) comprises: 2-(methoxymethyl)benzene-1,4-diamine of formula (I), addition salts thereof, solvates thereof, solvates of its salts thereof, or mixtures of two or more thereof: ##STR00015## at least one cellulosic associative polymer, at least one fatty substance in a total amount of greater than or equal to 30% by weight, relative to the total weight of the composition, and a second compartment comprising an oxidizing composition (B), wherein the oxidizing composition (B) comprises at least one chemical oxidizing agent.

Description

EXAMPLES

[0371] In the examples that follow, all the amounts are given as weight percentage of active material (AM) relative to the total weight of the composition (unless stated otherwise).

Example 1

[0372] Dyeing Composition

[0373] Composition A1 according to the present invention and comparative composition A2 were prepared using the ingredients of which the contents are indicated in the table below:

TABLE-US-00001 TABLE 1 A1 A2 (invention) (comparative) EDTA 0.2 0.2 MONOETHANOLAMINE 4.44 4.44 2-METHOXYMETHYL-P- 0.9 0.9 PHENYLENEDIAMINE PARAFFINUM LIQUIDUM 60 60 (liquid petroleum jelly) PEG-40 HYDROGENATED CASTOR 1 1 OIL SODIUM LAURYL SULFATE 1.24 1.24 ASCORBIC ACID 0.12 0.12 SODIUM METABISULFITE 0.22 0.22 COCO-GLUCOSIDE 3 3 HYDROXYBENZOMORPHOLINE 0.9 0.9 POLYQUATERNIUM-67 1 HYDROXYETHYLCELLULOSE 1 Water qs 100 qs 100

[0374] Oxidizing Composition

[0375] The oxidizing composition B was prepared from the ingredients of which the contents are indicated in the table below:

TABLE-US-00002 TABLE 2 B SODIUM SALICYLATE 0.035 TOCOPHEROL 0.1 TETRASODIUM PYROPHOSPHATE 0.04 HYDROGEN PEROXIDE 6 CETEARYL ALCOHOL 6 HEXADIMETHRINE CHLORIDE 0.15 POLYQUATERNIUM-6 0.2 PARAFFINUM LIQUIDUM 20 TETRASODIUM ETIDRONATE 0.06 PHOSPHORIC ACID qs pH 2.2 PEG-4 RAPESEEDAMIDE 1.2 GLYCERIN 0.5 STEARETH-20 5 Water qs 100

[0376] Dyeing Protocol

[0377] The dye compositions A1 and A2 are each mixed with the oxidizing composition B in a 1+1 weight ratio.

[0378] Each of the mixtures is applied to locks of hair containing 90% natural white (NW) hair in a proportion of 3 g of mixture per 1 g of hair.

[0379] After a leave-on time of 30 minutes on a hot plate at 27 C., the hair is rinsed, washed with L'Oral Professionnel Pro Classics universal concentrated shampoo, diluted to 10%, and dried.

[0380] Results

[0381] The colouring of the hair is evaluated in the L*a*b* system, using a Konica Minolta CM-3600A spectrocolorimeter (illuminant D65, angle 10, specular component included) in the CIELab system.

[0382] In this system, L* represents the lightness. The lower the value of L*, the darker and more powerful the colouring obtained. The chromaticity is measured by the values a* and b*, a* representing the red/green axis and b* the yellow/blue axis.

[0383] The results are given in the table below.

TABLE-US-00003 TABLE 3 L* Process A1 + B (invention) 24.42 Process A2 + B (comparative) 27.68

[0384] The composition according to the invention leads to a lower value of L*, thus to a more powerful coloration, compared to the comparative composition.

Example 2

[0385] Dyeing Composition

[0386] Composition A3 according to the present invention and comparative composition A4 were prepared using the ingredients of which the contents are indicated in the table below:

TABLE-US-00004 TABLE 4 A3 A4 (invention) (comparative) EDTA 0.2 0.2 MONOETHANOLAMINE 4.44 4.44 2-METHOXYMETHYL-P- 5.9 mmol PHENYLENEDIAMINE Sulfate de 2-(2,5-diaminophnyl)thanol 5.9 mmol PARAFFINUM LIQUIDUM 60 60 (liquid petroleum jelly) PEG-40 HYDROGENATED CASTOR 1 1 OIL SODIUM LAURYL SULFATE 1.24 1.24 ASCORBIC ACID 0.12 0.12 SODIUM METABISULFITE 0.22 0.22 COCO-GLUCOSIDE 3 3 HYDROXYBENZOMORPHOLINE 0.9 0.9 POLYQUATERNIUM-67 1 1 HYDROXYETHYLCELLULOSE 1 1 Water qs 100 qs 100 pH 10.7 +/ 0.2 10.7 +/ 0.2

[0387] Oxidizing Composition

[0388] The oxidizing composition B was prepared from the ingredients of which the contents are indicated in the table below:

TABLE-US-00005 TABLE 5 B SODIUM SALICYLATE 0.035 TOCOPHEROL 0.1 TETRASODIUM PYROPHOSPHATE 0.04 HYDROGEN PEROXIDE 6 CETEARYL ALCOHOL 6 HEXADIMETHRINE CHLORIDE 0.15 POLYQUATERNIUM-6 0.2 PARAFFINUM LIQUIDUM 20 TETRASODIUM ETIDRONATE 0.06 PHOSPHORIC ACID qs pH 2.2 PEG-4 RAPESEEDAMIDE 1.2 GLYCERIN 0.5 STEARETH-20 5 Water qs 100

[0389] Dyeing Protocol

[0390] The dye compositions A3 and A4 are each mixed with the oxidizing composition B in a 1+1 weight ratio; the resulting mixtures having a pH of 10.0+/0.2.

[0391] Each of the mixtures is applied to locks of hair containing 90% natural white (NW) hair and 90% permanent-waved natural white (PW) hair, in a proportion of 5 g of mixture per 1 g of hair.

[0392] After a leave-on time of 30 minutes on a hot plate at 27 C., the hair is rinsed, washed with L'Oral Professionnel Pro Classics universal concentrated shampoo, diluted to 10%, and dried.

[0393] Results

[0394] The colouring of the hair is evaluated in the L*a*b* system, using a Konica Minolta CM-3600A spectrocolorimeter (illuminant D65, angle 10, specular component included) in the CIELab system.

[0395] In this system, L* represents the lightness. The lower the value of L*, the darker and more powerful the colouring obtained. The chromaticity is measured by the values a* and b*, a* representing the red/green axis and b* the yellow/blue axis.

[0396] The selectivity is represented by the colour difference E between the locks of dyed natural (NW) hair and dyed permanent-waved (PW) hair, E being obtained from the formula:

E={square root over ((L*L.sub.0*).sup.2+(a*a.sub.0*).sup.2+(b*b.sub.0*).sup.2)}

in which L* represents the intensity and a* and b* represent the chromaticity of the dyed natural hair, and L.sub.0* represents the intensity and a.sub.0* and b.sub.0* represent the chromaticity of the dyed permanent-waved hair. The lower the value of E, the lower the selectivity and the more uniform the colouration along the hair.

[0397] The results are given in the table below.

TABLE-US-00006 TABLE 6 L a b E Process A3 + B (invention) NW 23.81 6.35 6.49 4.29 PW 21.34 4.8 3.34 Process A4 + B (comparative) NW 27.54 4.13 10.45 6.33 PW 23.59 3.22 5.59

[0398] The compositions according to the invention lead to lower values of L*, thus to a more powerful coloration, compared to the comparative composition.

[0399] The composition according to the invention A3 leads to a lower value of E, and thus to better selectivity, compared to the comparative composition A4.