METHOD AND DEVICE FOR DRAWING THIN GLASS RIBBONS
20240002271 · 2024-01-04
Assignee
Inventors
- Holger Wegener (Alfeld, DE)
- Rainer Schwertfeger (Eschershausen, DE)
- Stefan GIEHL (Alfeld, DE)
- Karl-Heinz SCHMIDT (Grünplan, DE)
Cpc classification
International classification
Abstract
A device for drawing glass ribbons is provided. The device includes a drawing tank and a nozzle in the drawing tank. The drawing tank holds a glass melt. The nozzle has a nozzle slot through which the glass melt emerges downward. The nozzle slot has two ends, a length, and a width, the length being greater than the width. The nozzle slot is curved downward toward the two ends in a drawing direction so that the two ends are lower than a center of the nozzle slot. The width changes from the center towards the two ends.
Claims
1. A device for drawing glass ribbons, comprising: a drawing tank for holding a glass melt; and a nozzle in the drawing tank, the nozzle having a nozzle slot through which the glass melt emerges downward, wherein the nozzle slot has two ends, a length, and a width, the length being greater than the width, wherein the nozzle slot is curved downward toward the two ends in a drawing direction so that the two ends are lower than a center of the nozzle slot, and wherein the width changes from the center towards the two ends.
2. The device of claim 1, wherein the width tapers from the center toward the ends so that the width is greater in the center than at the two ends.
3. The device of claim 1, wherein the nozzle slot has a height that runs parallel to the drawing direction and has first and second side regions.
4. The device of claim 3, wherein the nozzle has a projection in each of the first and second side regions, wherein the projection has a volume configured to hold the glass melt, the projection extending along the drawing direction, wherein the volume is defined by an interior space of the projection.
5. The device of claim 4, further comprising a radius of curvature defined by a height of the projection and a length of the projection.
6. The device of claim 4, wherein the projection has a first ratio of a length of the projection to a height of the projection that is less than 2.8.
7. The device of claim 4, wherein the projection has a ratio of a height of the interior space to a width of the interior space that is greater than 0.2 and less than 2.
8. The device of claim 7, wherein the height of the interior space is greater than 10 mm and less than 80 mm.
9. The device of claim 3, wherein the nozzle slot has a curvature in the first and second side regions.
10. The device of claim 9, wherein the curvature has a radius that is greater than 100 mm and less than 260 mm.
11. The device of claim 3, wherein the projection of the first side region has a first curved portion that is situated opposite to a second curved portion of the projection of the second side region.
12. The device of claim 4, wherein the width of the projection is based on the width of the nozzle slot, and wherein the width of the projection is greater than 1 mm and less than 15 mm.
13. The device of claim 4, wherein the projection has a lower wall that closes off the interior space in the drawing direction.
14. The device of claim 1, wherein the nozzle slot has a feature selected from a group consisting of: a curvature up to the two ends, a curvature to the two ends, a curvature with an inflection point, and any combinations thereof.
15. The device of claim 1, wherein the nozzle slot has a shape selected from a group consisting of oval, elliptical, concave, and lenticular in plan view.
16. The device of claim 1, further comprising a plurality of heating elements arranged on the drawing tank, the plurality of heating elements being divided into different electrical heating circuits.
17. The device of claim 1, further comprising a ribbon shaping region and a plurality of temperature controlling devices, the plurality of temperature controlling devices being spatially distributed in the shaping region.
18. A method for drawing thin glass ribbons, comprising: providing a glass melt of glass in a drawing tank; drawing the glass melt downward from a nozzle in a drawing direction to form a thin glass ribbon, the nozzle having a nozzle slot with first and second side regions and a projection extending along the drawing direction in each of the first and second side regions, wherein the projection has a volume configured to counteract constriction of the thin glass ribbon; cooling the thin glass ribbon after emerging from the passage opening until the thin glass ribbon falls has a temperature below a glass transition temperature of the glass; and contacting the thin glass ribbon with drawing rollers that transmit tensile forces to the thin glass ribbon in the drawing direction, wherein the drawing rollers contact the glass at a temperature of the glass below the glass transition temperature.
19. The method of claim 18, wherein the tensile forces are divided at the projection into a vertical and a horizontal force component and a deformation force acting opposite to the tensive forces is generated in the glass ribbon.
20. The method of claim 18, wherein the thin glass ribbon has a thickness of not more than 70 m.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0037] The disclosure is explained in more detail below with reference to the appended figures. In the figures, identical reference signs in each case denote identical or corresponding elements. More specifically:
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044]
[0045]
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[0050]
DETAILED DESCRIPTION
[0051]
[0052] After emerging from the nozzle 4, the glass ribbon 10 is cooled in or below the shaping region 14 until it falls below the glass transition temperature T.sub.g. Drawing rollers 15, by means of which tensile forces are transmitted to the glass ribbon 10, are preferably arranged below the cooling device 3, that is to say preferably in the cold region. The temperature of the glass at the point of contact with the drawing rollers is preferably at most 200 C., particularly preferably at most 100 C. Contacting the glass with drawing rollers only in the cold region, i.e., below T.sub.g, particularly preferably at temperatures of at most 200 C., has proven advantageous in reducing the probability of breakage. Moreover, there is greater freedom in the selection of material for the drawing rollers at low temperatures. Thus, the drawing rollers can have an elastomer surface, which exhibits only slight slippage.
[0053] Preferably, at least two pairs of drawing rollers 15 are arranged spaced apart transversely to the drawing direction Z, wherein the pairs of drawing rollers grip the glass ribbon 10 on both sides in the region of the borders 11 in each case between two drawing rollers 15. Depending on the desired thickness of the glass ribbon 10, the tensile force transmitted by the drawing rollers 15 is adapted or adjusted. According to one embodiment, in the case of a lesser thickness, the tensile force can therefore be set higher than in the case of a desired greater thickness, that is to say a thicker glass ribbon 10. Accordingly, the glass ribbon 10 is preferably adjusted to a desired thickness by the tensile force transmitted by the drawing rollers 15 and is drawn out of the nozzle 4 as a glass melt 9.
[0054]
[0055] The lower region of
[0056]
[0057] In order to achieve an effect on the forces acting during the drawing of the glass ribbon 10, however, the lower wall 21 is curved, in particular curved continuously, preferably also linearly or exponentially, along the length L and with respect to the height H. In this way, it is possible to achieve a uniformly curved profile, wherein the lower wall 21 of the projection 20 ideally forms a gentle transition to a lower boundary 30 of the central region 8c of the nozzle slot 5. In the best case, the lower wall 21 and the lower boundary 30 of the central region 8c form a single surface, and therefore the curvature of the lower wall 21 preferably begins in the side region 8b and extends as far as a lower end 23 of the projection. At the lower end 23, the lower wall 21 adjoins the end wall 22 and can be connected to the latter in one piece or as two pieces.
[0058] The lower wall 21 and/or the lower boundary 30 preferably close off the nozzle 4 or the drawing tank 2 at the bottom and, in particular, the lower boundary 30 runs horizontally. In this case, the nozzle slot is arranged in the lower boundary 30 and the lower wall 21, in particular in such a way that the glass melt 9 can flow out, or at least can be drawn out, of the lower end 23, thus enabling the glass ribbon 10 to be drawn out in terms of width at the borders 11 at the lower end 23. In terms of its length L, therefore, the nozzle slot 5 can also extend beyond the lower end, as illustrated in
[0059] The height H of the nozzle 4 from the lower end 23 to an upper wall 24 of the nozzle 4, and the length Lv of the projection 20 in the side region 8a, 8b determine the radius R. In order to set the radius R of curvature of the nozzle slot 5 or of the lower wall 21 to values which, ideally, decrease toward the lower end 23, preferably between 160 mm and 200 mm, the height of the projection 20 is between 20 mm and 40 mm. A more important dependency relationship is the ratio of the height H of the nozzle 4 to the width By of the projection 20, which is also illustrated in schematic plan view in
[0060] In order to define or provide an optimum interior space of the projection 20 and thereby set the viscosity of the glass melt 9, the width By of the projection 20 is calculated on the basis of the nozzle slot width Bs.
Bv=2Bs to 5Bs
[0061] Along the length, the projection 20 preferably extends beyond the lower end 23, and therefore the end wall 22 may run obliquely and/or in a curved manner from the upper wall 24. The upper opening in the upper wall 24 of the nozzle 4 is preferably wider and/or longer than the lower wall 21 but, in particular, wider and/or longer than the width Bs of the nozzle slot.
[0062]
[0063]
[0064] Depending on the desired width of the glass ribbon 10 and/or the tensile force, the radius R of curvature of the nozzle slot 5 may also be the same, i.e., may preferably not decrease in the direction of the lower end. However, it is particularly important that no kink is formed at the transition from the lower wall 21 to the lower boundary 30 of the central region 8c since a kink leads to a more or less punctiform nonuniform, or unequal, distribution of forces. Particularly a nonuniform distribution of the deformation forces Uh and Uv can lead to local changes in the thickness or width of the viscous glass, and it is therefore no longer possible to ensure a stable deformation process or parameters or glass properties that are the same across the width of the glass ribbon 10.
[0065] With the nozzle 4 having the nozzle slot 5 curved in length L, width B and height H, it is possible overall to produce wider glass ribbons from a given drawing tank width than would be possible without the curvatures. It is even possible to draw glass thicknesses of less than 100 m and even less than 50 m.
TABLE-US-00001 TABLE 1 Change in the width of the glass ribbon when using a nozzle slot with projections. Glass thickness Width without projection Width with projection (m) (mm) (mm) 1000 560 640 500 490 620 100 400 590
[0066] In comparison with the embodiment of the device 1 illustrated in
[0067] For particularly precise cooling across the width of the glass ribbon 10, provision can be made for the cooling kiln 40 to have a plurality of cooling and/or heating sections 41, which are arranged side-by-side/one below the other and preferably adjacent to one another. At least one cooling and/or heating section 41, preferably a plurality of such sections, more preferably all the cooling and/or heating sections 41 comprise/comprises a thermocouple 42 for measuring and controlling the temperature. The cooling and/or heating sections 41 are preferably tile-shaped and, in particular, are arranged side-by-side in the manner of tiling. This should be interpreted to mean that the cooling and/or heating sections are designed as tiles, or shaped as rectangles, squares or hexagons, in particular such that the cooling and/or heating sections 41 can be arranged adjacent to one another without any free space in between. Such an embodiment is illustrated in
[0068] To control the temperature of the glass ribbon 10, it is envisaged that the device 1 has at least one temperature measuring device 45. In particular, the temperature measuring device 45 is designed in such a way that the temperature of the glass ribbon 10 can be detected or measured across the width, preferably the entire width, of the glass ribbon. As shown in
[0069] In some cases, e.g., when a nozzle 4 that is optimized for a particular glass thickness is used for the production of a different glass thickness, it may be necessary to control the temperature of the glass ribbon 10 as early as the shaping region 14. In another embodiment, the device 1 therefore has at least one, in particular a plurality of spatially distributed, cooling and/or heating units 50, which are preferably arranged in the shaping region 14. In this case, the cooling and/or heating units 50 can be configured in such a way that the cooling and/or heating units 50 can each heat and/or cool the glass ribbon 10 locally, at least in some region or regions, in a selective manner, thus enabling the width of the glass ribbon 10 to be selectively set in the shaping region 14. This means that the cooling or heating does not take place across the entire width of the glass ribbon 10 but that the temperature of the glass ribbon 10 can be varied locally in desired regions. It is thus possible to implement nonhomogeneous and/or homogeneous cooling or heating across the width of the glass ribbon.
[0070] It is therefore a particular preference that different heating and/or cooling units 50 be arranged in a spatially distributed manner, in particular in a manner distributed transversely to the glass ribbon 10, to enable control to be exerted over the local distribution of glass in the glass ribbon 10 and also to enable relatively small adjustments of the distribution of glass to be performed. In this case, the heating and/or cooling units 50 are, for example, arranged in a manner distributed over the entire area of the shaping region 14, preferably at a height greater than 5%, preferably greater than 10%, preferably greater than 15% and/or at a height less than 50%, preferably less than 30%, of the length of the shaping region 14, wherein the length of the shaping region 14 is, in particular, transverse to the width of the glass ribbon 10. Here, the length of the shaping region 14 can be between 100 mm and 300 mm. In other words, the heating and/or cooling units 50 can be arranged between the nozzle 4 and the cooling kiln 40, thus enabling fine adjustment of the thickness of the glass ribbon 10, for example. This also makes it possible to use a single nozzle slot 5 to draw different glass ribbons with a wider range of different glass thicknesses than the range for which the nozzle slot 5 is actually optimized.
[0071] In this way, it is possible, in the case of relatively thin glass with a concave thickness distribution in the center of the glass ribbon 10, for example, to use different heating and/or cooling units 50 to lower the glass temperature or increase the viscosity of the glass. As a result, shaping is ended earlier, and the glass is not drawn out as thinly in this region as would be the case without these heating and/or cooling units 50. In order to be able to regulate the temperature in a tailored manner at desired positions of the glass ribbon 10, it is conceivable for a plurality of heating and/or cooling units 50 to be arranged along, or, with respect to the width of the glass ribbon 10, side-by-side, and/or diagonally, or transversely. It is likewise possible for a plurality of heating and/or cooling units 50 to be arranged one below the other, in particular in the drawing direction. Depending on the application, provision may be made for between two and six heating and/or cooling units 50 to be arranged side-by-side, one below the other and/or diagonally with respect to one another.
[0072] As an advantageous possibility, the heating and/or cooling units 50 can each be designed as air or water coolers and, in particular, can generate an air flow, water jet, water droplets, mist and/or an aerosol, as illustrated schematically in
[0073] However, it is also possible for the heating and/or cooling units 50 to be designed as indirect heating and/or cooling units 50, e.g., as closed conduit systems in which at least one medium circulates, ensuring, in particular, that the glass ribbon 10 does not have any contact with another medium, e.g., water. In this case, heating and/or cooling units 50 are designed in such a way that they each emit or absorb thermal energy, or can carry away thermal energy. It is conceivable for at least one conduit of such a conduit system to be aligned transversely or parallel to the drawing direction. In order to detect the temperature, preferably of the medium and/or of the glass ribbon, it is possible to provide a temperature measuring device 45 which, in particular, is arranged at at least one, preferably at each, heating and/or cooling unit 50, thus making it possible, for example, also to measure the thermal energy removed from the glass ribbon 10. Without limitation to the abovementioned embodiments, it is also possible to use a combination of direct and indirect heating and/or cooling units 50. Irrespective of whether the heating and/or cooling units 50 cool or heat indirectly or directly, it is possible to conceive of different shapes of the cross sections of the heating and/or cooling units 50, e.g., a round, oval or a polygonal shape, such as a rectangle or a hexagon.
[0074] In this case, it is possible in each case to vary the distance between a heating and/or cooling unit 50 and the glass ribbon 10. Fine adjustment of, for example, cooling by air cooling can thus be made possible by adjustment of the air volume. In this case, the glass becomes thicker, the greater the air volume passed through per unit time. Another, very effective variant of air cooling is to add atomized water, resulting in the formation of an aerosol. Depending on the water volume, this aerosol can transport significantly more thermal energy than pure dry air, wherein the aerosol or atomized water or some other atomized liquid can also be mixed with air or a special gas composition for effective cooling.
[0075] When using a heating and/or cooling unit 50, e.g., in the form of a water and/or air cooler, its position or distance from the glass ribbon 10 can be varied. In this case, the glass becomes thicker, the smaller the distance between the water cooler and the glass ribbon 10. Heating units have the same effect, only in reverse, enabling the glass ribbon 10 to be made thinner in desired regions. In this case, the heating units can be designed as air and/or heating-coil-based heating units. To enable the heating and/or cooling units 50 to be set precisely, it is possible to provide a temperature measuring device 45, which is arranged between the nozzle 4 and the heating and/or cooling units 50.
[0076] In another embodiment, the device 1 has a crucible 55 for holding and homogenizing refined glass, on which preferably at least one outlet pipe 56 with a specially adapted diameter, which, in particular, opens into the drawing tank 2, is arranged. The glass can thus be transported from the crucible 55 into the drawing tank 2 through the outlet pipe 56. In this case, the device can have at least one, preferably a plurality or even a multiplicity of, heating elements 60, wherein at least one heating element 60 is arranged at least on the drawing tank 2, the outlet pipe 56 and/or the crucible 55. In accordance with the example shown in
[0077] For the purposes of the disclosure, heating elements 60 are understood to be apparatuses which are suitable and provided for the purpose of outputting energy to the drawing tank 2, the outlet pipe 56 and/or the crucible 55 and/or the contents thereof. This energy can be output in the form of thermal energy, for example, or else electrical energy or, for example, magnetic energy. In this case, the heating elements 60 can have one or more heating coils and/or flanges, which can surround the drawing tank 2, the outlet pipe 56 and/or the crucible 55 at least partially or completely in at least one direction. In general, the drawing tank 2, the outlet pipe 56, the crucible 55 and/or the contents thereof can therefore be heated directly by means of thermal energy supplied by the heating elements 60, or the drawing tank 2, the outlet pipe 56 and/or the crucible 55 can be brought to self-heating by, for example, induction or power supply, preferably by means of at least one or more, in particular, flanges. It is conceivable here that a flow of current through the drawing tank 2, the outlet pipe 56 and/or the crucible 55 is generated by means of at least two flanges, or at least one flange is used to generate a magnetic field which supplies the drawing tank 2, the outlet pipe 56 and/or the crucible 55 with energy by induction. The drawing tank 2, the outlet pipe 56 and/or the crucible 55 can therefore advantageously comprise a heat- and/or current-conducting material, e.g., a metal. In general, heating by means of the heating elements 60 can be performed, in particular, indirectly and preferably over a relatively large area and thus the formation of glass defects, for example, can be reduced. Fine adjustment of the temperature, in particular locally, is also possible.
[0078] Without limitation to the example in
[0079] In another embodiment, the drawing tank 2 has a plurality of, in particular at least four, heating elements 60, preferably in such a way that the heating of the drawing tank 2 is divided preferably into three electric heating circuits. The heating circuits can also be interpreted as zones of the heating tank 2 which are arranged differently, in particular in terms of space, or perform heating in different ways and which, for example, can each heat defined volume regions of the glass in the drawing tank. In this case, the heating circuits 62 of the drawing tank 2 are preferably arranged in series as regards the length L of the nozzle slot 5 in order to control the glass distribution in the drawing tank 2 in the transverse direction or along the length L of the nozzle slot 5. Thus, the glass distribution at the nozzle slot 5 and the throughput of the glass volume at the nozzle 4 can be adjusted by means of the temperature management of the outlet pipe 56 and of the drawing tank 2. The heating elements 60 are preferably arranged in such a way that at least two or three, in particular a plurality of, heating circuits 62 are formed. In this case, at least two of the heating circuits 62 and/or heating elements 60 can be arranged laterally with respect to the drawing tank 2, in particular in such a way that at least three heating circuits 62 are formed, of which at least one further heating circuit 62 is arranged centrally with respect to the drawing tank 2. In this case, each heating circuit 62 can be surrounded, or delimited or enclosed, by at least two heating elements 60.
[0080] Therefore, the object can also be achieved in general, without restriction to specific features of particular embodiments, by a device 1 for drawing glass ribbons 10 from a glass melt 9, wherein the device 1 has a crucible 55 for holding a melt consisting of refined glass and an outlet pipe 56 for conveying the glass melt into a drawing tank 2, wherein at least the drawing tank 2 has a plurality of heating elements 60, which are preferably arranged transversely with respect to a length L of a nozzle slot 5 of a nozzle 4 through which the glass melt 9 can emerge downward, wherein the device 1 has at least one, in particular a plurality of, cooling and/or heating units 50, which are arranged in the shaping region 14. In this embodiment too, the nozzle slot 5 is preferably curved downward in the drawing direction Z toward the ends 7a, 7b of the nozzle slot 5 in a first 8a and a second 8b side region, in particular throughout or continuously, and therefore the ends 7a, 7b are lower than a central region 8c of the nozzle slot 5 arranged between the ends 7a, 7b. In order to homogenize the glass, a stirring unit can be provided in the crucible 55, in particular the number of revolutions of which per unit time is adjustable.
LIST OF REFERENCE SIGNS
[0081] 1 device for drawing glass ribbons [0082] 2 drawing tank [0083] 3 cooling device [0084] 4 nozzle [0085] 5 nozzle slot [0086] 6 walls of the nozzle or nozzle slot [0087] 7a first end [0088] 7b second end [0089] 8a first side region of the nozzle slot [0090] 8b second side region of the nozzle slot [0091] 8c central region of the nozzle slot [0092] 9 glass melt [0093] 10 glass ribbon [0094] 11 borders [0095] 14 shaping region [0096] 15 drawing rollers [0097] 20 projection [0098] 21 lower wall of the projection [0099] 22 end wall of the projection [0100] 23 lower end of the projection [0101] 24 upper wall of the nozzle [0102] 25 lateral walls [0103] 30 lower boundary of the central region [0104] 40 cooling kiln [0105] 41 cooling and/or heating sections [0106] 42 thermocouple [0107] 45 temperature measuring device [0108] 50 cooling and/or heating units [0109] 55 crucible [0110] 56 outlet pipe [0111] 60 heating elements [0112] 61 heating circuit of the outlet pipe [0113] 62 heating circuit of the drawing tank [0114] B width [0115] Bk width of a glass ribbon produced with a curved nozzle slot [0116] Bp width of a glass ribbon produced with a parallel nozzle slot [0117] Bs width of the nozzle slot [0118] By width of the projection [0119] H height of the nozzle/height of the projection [0120] L length of the nozzle slot [0121] Lv length of the projection [0122] R radius of curvature [0123] W inflection point of the curvature [0124] Z drawing direction