Additives to litho inks to eliminate ink feedback
10875338 ยท 2020-12-29
Assignee
Inventors
- Ramasamy Krishnan (North Brunswick, NJ)
- Jeff Jones (Chicago, IL)
- Matthias Helliblau (Seligenstadt, DE)
Cpc classification
C09D11/03
CHEMISTRY; METALLURGY
International classification
C09D11/101
CHEMISTRY; METALLURGY
C09D11/03
CHEMISTRY; METALLURGY
Abstract
Provided are web-offset lithographic ink compositions that contain an alkyl thioether surfactant, an alkoxylated modified rosin, or a combination thereof. The ink compositions can be oil-based inks or water-based inks that can be radiation-curable. The resulting ink compositions can be used in web-offset lithographic printing to substantially reduce or eliminate the ink feedback and ink build-up that occurs during printing. Also provided are methods for reducing or eliminating ink feedback and build-up during lithographic printing processes.
Claims
1. A radiation-curable web-offset lithographic ink composition, comprising: a colorant; a varnish; and a water-soluble alkoxylated modified rosin, wherein the modified rosin is 10% to 70% alkoxylated; wherein the modified rosin is present in an amount of from at or about 0.1% to at or about 10% by weight of the ink composition; wherein the ink is a lithographic ink; and wherein the ink is energy-curable; and wherein the ink is suitable for use in a lithographic system wherein the printing plate is continuously treated with an aqueous fountain solution.
2. The composition of claim 1, wherein the modified rosin is selected from among a methoxylated modified rosin, ethoxylated modified rosin, propoxylated modified rosin and butoxylated modified rosin.
3. The composition of claim 1, wherein the modified rosin is at least 50% alkoxylated.
4. The composition of claim 1, wherein the modified rosin is an ethoxylated modified rosin.
5. The composition of claim 1, further comprising an ingredient selected from among a vehicle, a clay, an emulsion stabilizer, a wax, an oil and an emulsifier, or any combination thereof.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1)
(2)
(3)
DETAILED DESCRIPTION OF THE INVENTION
A. Definitions
(4) The definitions of the technical and scientific terms provided herein encompass definitions intended at the time of filing this application. These definitions are not meant to be restrictive, as there can be other aspects to the definitions that are not recited, such as those commonly understood by one of skill in the art to which the invention(s) belong. All patents, patent applications, published applications and publications, websites and other published materials referred to throughout the entire disclosure herein, unless noted otherwise, are incorporated by reference in their entirety. In the event that there are pluralities of definitions for terms herein, those in this section prevail.
(5) It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the subject matter claimed. In this application, the use of the singular includes the plural unless specifically stated otherwise. In this application, the use of or means and/or unless stated otherwise. Furthermore, use of the term including as well as other forms, such as includes, and included is not limiting.
(6) As used herein, ranges and amounts can be expressed as about a particular value or range. About also includes the exact amount. Hence about 10% means about 10% and also 10%.
(7) As used herein, the singular forms a, an and the include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a composition comprising an alkyl thioether includes compositions with one or a plurality of alkyl thioethers.
(8) As used herein, tinting and ink feedback or feedback refer to the weak appearance of color on a non-image area of the printed material. Tinting occurs when pigment, with or without other ink ingredients, becomes solubilized or emulsified into the fountain solution and is transferred to the non-image area of the printed material. Tinting can also occur from the formation of an inverse emulsion, i.e., when the emulsion being formed is ink-in-water rather than the necessary water-in-ink. The formation of an inverse emulsion will cause the ink to transfer back through the dampening system where it will either contaminate the fountain trough or pile on the dampening rollers.
(9) As used herein, scumming and ink build-up or build-up refer to the appearance of color on the printed material that occurs when non-image areas of the plate accept and transfer ink to the blanket and from there to the printed material.
B. Web-Offset Lithographic Ink Compositions
(10) Provided herein are web-offset lithographic ink compositions that include a water-soluble alkyl thioether surfactant, an alkoxylated modified rosin, or a combination thereof. For example, the alkoxylated modified rosin can be a highly alkoxylated modified rosin. Suitable highly alkoxylated modified rosins include highly ethoxylated modified rosins. The web-offset lithographic ink compositions reduce, if not eliminate, ink feedback and excessive ink build-up that occurs during the web-offset lithographic printing process. Due to this feature, the ink compositions are advantageous over existing prior art web-offset lithographic ink compositions. The web-offset lithographic ink compositions provided herein can be any type of lithographic ink. For example, the web-offset lithographic inks can be oil-based inks or water-based inks. The inks can be radiation-curable inks, such as electron-beam cured inks or ultra-violate cured inks. The ink compositions can be used in any web-offset lithographic printing process where elimination of ink feedback is desired. For example, the ink compositions provided herein can be used in lithographic, or offset, printing, such as high speed web-offset lithographic printing.
(11) In an exemplary embodiment, the web-offset lithographic ink compositions can be formulated to contain from about 0.01 to 5% of a water-soluble alkyl thioether surfactant or from about 1 to 10% of an alkoxylated modified rosin. In another embodiment the web-offset lithographic ink composition can be formulated to contain both a water-soluble alkyl thioether surfactant and an alkoxylated modified rosin. In some exemplary embodiments, the web-offset lithographic ink compositions are oil-based ink compositions. In other exemplary embodiments, the web-offset lithographic ink compositions are radiation-curable ink compositions, such as electron-beam curable ink compositions.
(12) 1. Water-Soluble Alkyl Thioether Surfactant
(13) The web-offset lithographic ink compositions provided herein can include a water-soluble alkyl thioether surfactant. Water-soluble alkyl thioether surfactants are typically used in fountain solutions to improve ozone resistance and to inhibit changes in hue and to provide equilibrium surface tension reduction. These surfactants, however, have not been used as additives in web-offset lithographic inks, for example in oil-based web-offset lithographic inks. Suitable water-soluble alkyl thioether surfactants that can be incorporated in the ink compositions provided herein include any ether derivative where the oxygen is replaced by sulfur. Such surfactants are known in the art and can be purchased from suppliers such as Air Products (Allentown, Pa.) and Burlington Chemical (Greensboro, N.C.).
(14) Examples of suitable alkyl thioethers for use in the ink compositions provided herein include 2,3-dihydroxypropyl-2-hydroxy-3-(2-ethylhexyloxy)propyl sulfide; 2,3-dihydroxypropyl-2-hydroxy-3-dodecyloxypropyl sulfide; 2,3-dihydroxypropyl-2-hydroxy-3 -hexadecyloxypropyl sulfide; 2,3-dihydroxypropyl-2-hydroxy-3-tetradecyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3-butoxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3 -octyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3 -nonyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3-decyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3 -dodecyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3 -hexadecyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3 -tetradecyloxypropyl sulfide; 2-hydroxyethyl-2-hydroxy-3-(2-ethylhexyloxy)propyl sulfide; and 2-dodecyl-2-hydroxy-3-butoxypropyl sulfide. Any other suitable water-soluble alkyl thioether known to those of skill in the art also can be used in the ink compositions provided herein.
(15) A particular example of an alkyl thioether surfactant used in exemplary embodiments of the invention is commercially available as EnviroGem 360 from Air Products and Chemicals (Allentown, Pa.). EnviroGem 360 is a high-performance nonionic superwetting and coalescing surfactant (100% active liquid). EnviroGem 360 surfactant greatly reduces dynamic and equilibrium surface tension and also provides low foam and film formation/coalescing benefits. EnviroGem 360 can be used in a variety of waterborne applications, for example, as a component of fountain solutions to provide efficient and effective wetting of printing plates and foam control.
(16) In the web-offset lithographic ink compositions provided herein, the total amount of alkyl thioether surfactant as a percentage (%) by weight of the ink composition (wt %>) can be, e.g., from at or about 0.01% to at or about 5%>, such as 0.01% to 0.05%, 0.01% to 0.1%, 0.01% to 0.2%, 0.01% to 0.3%, 0.01% to 0.4%, 0.01% to 0.5%, 0.01% to 0.6%, 0.01% to 0.7%, 0.01% to 0.8%, 0.01% to 0.9%, 0.01% to 1%, 0.01% to 1.5%, 0.01% to 2%, 0.01% to 2.5%, 0.01% to 3%, 0.01% to 3.5%, 0.01% to 4%, 0.01% to 4.5%, 0.01% to 5%, 0.05% to 0.1%, 0.05% to 0.2%, 0.05% to 0.3%, 0.05% to 0.4%, 0.05% to 0.5%, 0.05% to 0.6%, 0.05% to 0.7%, 0.05% to 0.8%, 0.05% to 0.9%, 0.05% to 1%, 0.05% to 1.5%, 0.05% to 2%, 0.05% to 2.5%, 0.05% to 3%, 0.05% to 3.5%, 0.05% to 4%, 0.05% to 4.5%, 0.05% to 5%, 0.1% to 0.2%, 0.1% to 0.3%, 0.1% to 0.4%, 0.1% to 0.5%, 0.1% to 0.6%, 0.1% to 0.7%, 0.1% to 0.8%, 0.1% to 0.9%, 0.1% to 1%, 0.1% to 1.5%, 0.1% to 2%, 0.1% to 2.5%, 0.1% to 3%, 0.1% to 3.5%, 0.1% to 4%, 0.1% to 4.5%, 0.1% to 5%, 0.2% to 0.3%, 0.2% to 0.4%, 0.2% to 0.5%, 0.2% to 0.6%, 0.2% to 0.7%, 0.2% to 0.8%, 0.2% to 0.9%, 0.2% to 1%, 0.2% to 1.5%, 0.2% to 2%, 0.2% to 2.5%, 0.2% to 3%, 0.2% to 3.5%, 0.2% to 4%, 0.2% to 4.5%, 0.2% to 5%, 0.3% to 0.4%, 0.3% to 0.5%, 0.3% to 0.6%, 0.3% to 0.7%, 0.3% to 0.8%, 0.3% to 0.9%, 0.3% to 1%, 0.3% to 1.5%, 0.3% to 2%, 0.3% to 2.5%, 0.3% to 3%, 0.3% to 3.5%, 0.3% to 4%, 0.3% to 4.5%, 0.3% to 5%, 0.4% to 0.5%, 0.4% to 0.6%, 0.4% to 0.7%, 0.4% to 0.8%, 0.4% to 0.9%, 0.4% to 1%, 0.4% to 1.5%, 0.4% to 2%, 0.4% to 2.5%, 0.4% to 3%, 0.4% to 3.5%, 0.4% to 4%, 0.4% to 4.5%, 0.4% to 5%, 0.5% to 0.6%, 0.5% to 0.7%, 0.5% to 0.8%, 0.5% to 0.9%, 0.5% to 1%, 0.5% to 1.5%, 0.5% to 2%, 0.5% to 2.5%, 0.5% to 3%, 0.5% to 3.5%, 0.5% to 4%, 0.5% to 4.5%, 0.5% to 5%, 0.6% to 0.7%, 0.6% to 0.8%, 0.6% to 0.9%, 0.6% to 1%, 0.6% to 1.5%, 0.6% to 2%, 0.6% to 2.5%, 0.6% to 3%, 0.6% to 3.5%, 0.6% to 4%, 0.6% to 4.5%, 0.6% to 5%, 0.7% to 0.8%, 0.7% to 0.9%, 0.7% to 1%, 0.7% to 1.5%, 0.7% to 2%, 0.7% to 2.5%, 0.7% to 3%, 0.7% to 3.5%, 0.7% to 4%, 0.7% to 4.5%, 0.7% to 5%, 0.8% to 0.9%, 0.8% to 1%, 0.8% to 1.5%, 0.8% to 2%, 0.8% to 2.5%, 0.8% to 3%, 0.8% to 3.5%, 0.8% to 4%, 0.8% to 4.5%, 0.8% to 5%, 0.9% to 1%, 0.9% to 1.5%, 0.9% to 2%, 0.9% to 2.5%, 0.9% to 3%, 0.9% to 3.5%, 0.9% to 4%, 0.9% to 4.5%, 0.9% to 5%, 1% to 1.5%, 1% to 2%, 1% to 2.5%, 1% to 3%, 1% to 3.5%, 1% to 4%, 1% to 4.5%, 1% to 5%, 1.5% to 2%, 1.5% to 2.5%, 1.5% to 3%, 1.5% to 3.5%, 1.5% to 4%, 1.5% to 4.5%, 1.5% to 5%, 2% to 2.5%, 2% to 3%, 2% to 3.5%, 2% to 4%, 2% to 4.5%, 2% to 5%, 2.5% to 3%, 2.5% to 3.5%, 2.5% to 4%, 2.5% to 4.5%, 2.5% to 5%, 3% to 3.5%, 3% to 4%, 3% to 4.5%, 3% to 5%, 3.5% to 4%, 3.5% to 4.5%, 3.5% to 5%, 4% to 4.5%, 4% to 5%, or 4.5% to 5% by weight of the ink composition. Generally, the ink compositions contain less than 5% alkyl thioether surfactant. For example, the web-offset lithographic ink compositions provided herein contain up to at or about 0.01%, 0.1%>, 0.2%>, 0.3%>, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5% or 5% alkyl thioether surfactant, based on the weight of the composition.
(17) Provided herein are exemplary web-offset lithographic ink compositions that contain a water-soluble alkyl thioether surfactant. The web-offset lithographic ink compositions provided herein can be used to reduce or eliminate ink feedback and build-up that commonly occurs during the lithographic printing process. Exemplary of such ink compositions contain an oil-based ink and from at or about 0.01% to at or about 5% of a water-soluble alkyl thioether surfactant. For example, the ink compositions can contain an oil-based ink and at or about 0.3% of a water-soluble alkyl thioether surfactant.
(18) 2. Alkoxylated Modified Rosin
(19) Provided herein are web-offset lithographic ink compositions that contain an alkoxylated modified rosin. Rosin is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene components. Rosin is mainly a mixture of C2o, tricyclic fused-ring, monocarboxylic acids, typified by the free acid form (i.e., abietic acid), represented by the following formula:
(20) ##STR00001##
(21) Rosins can be modified, such as by the addition of functional groups. For example, a rosin can be modified by adding one or more alkoxy groups. A rosin can be modified so that it is a highly alkoxylated modified rosin. A highly alkoxylated modified rosin is a rosin that is more than or about 10% alkoxylated, but less than or about 70% alkoxylated. For example, the highly alkoxylated modified rosins used in the ink compositions provided herein can between from or between about from 10% alkoxylated to 70% alkoxylated, such as 10% to 20%, 10% to 30%, 10% to 40%, 10% to 45%, 10% to 50%, 10% to 55%, 10% to 60%, 10% to 70%, 20% to 30%, 20% to 40%, 20% to 45%, 20% to 50%, 20% to 55%, 20% to 60%, 20% to 70%, 30% to 40%, 30% to 45%, 30% to 50%, 30% to 55%, 30% to 60%, 30% to 70%, 40% to 45%, 40% to 50%, 40% to 55%, 40% to 60%, 40% to 70%, 50% to 55%, 50% to 60%, 50% to 70%, 55% to 60%, 55% to 70%, and 60% to 70% alkoxylated. Generally, the alkoxylated modified rosin is less than 70% alkoxylated. For example, the alkoxylated modified rosins used in the ink compositions provided herein are at least or about at least 10%, 20%, 30%, 40%, 45%, 50%, 55%, 60%, but less than 70% alkoxylated. Suitable rosins that can be modified by alkoxylation and used in the ink compositions provided herein include gum rosin, wood rosin and tall oil rosin. Highly alkoxylated modified rosin compounds are also typically used in the printing industry as a component of fountain solutions, but have not been used as additives to web-offset lithographic inks.
(22) Suitable alkoxylated modified rosins that can be incorporated in the compositions provided herein include alkoxylated modified rosins such as methoxy modified (i.e., methoxylated) rosins, ethoxy modified (i.e., ethoxylated) rosins, propoxy modified (i.e., propoxylated) rosins, butoxy modified (i.e., butoxylated) rosins, and any other alkoxy modified rosin that will be known to those of skill in the art. Such modified rosins are known in the art and can be purchased from suppliers such as Ethox Chemicals (Greenville, S.C.), Eastman Chemical Company (Kingsport, Tenn.), Lawter (Chicago, Ill.) and MWV (Richmond, Va.).
(23) A particular example of an alkoxylated modified rosin used in exemplary embodiments of the invention is Ethox 4614 (Ethox Chemicals, Greenville, S.C.). Ethox 4614 is a water-soluble highly ethoxylated modified rosin that is at least 50% ethoxylated.
(24) In the compositions provided herein, the total amount of alkoxylated modified rosin as a percentage (%>) by weight of the composition (wt %>) can be, e.g., from at or about 0.1% to at or about 10%, such as 0.1% to 0.5%, 0.1% to 0.75%, 0.1% to 1%, 0.1% to 1.5%, 0.1% to 2%, 0.1% to 2.5%, 0.1% to 3%, 0.1% to 3.5%, 0.1% to 4%, 0.1% to 4.5%, 0.1% to 5%, 0.1% to 5.5%, 0.1% to 6%, 0.1% to 6.5%, 0.1% to 7%, 0.1% to 7.5%, 0.1% to 8%, 0.1% to 8.5%, 0.1% to 9%, 0.1% to 9.5%, 0.1% to 10%, 0.5% to 0.75%, 0.5% to 1%, 0.5% to 1.5%, 0.5% to 2%, 0.5% to 2.5%, 0.5% to 3%, 0.5% to 3.5%, 0.5% to 4%, 0.5% to 4.5%, 0.5% to 5%, 0.5% to 5.5%, 0.5% to 6%, 0.5% to 6.5%, 0.5% to 7%, 0.5% to 7.5%, 0.5% to 8%, 0.5% to 8.5%, 0.5% to 9%, 0.5% to 9.5%, 0.5% to 10%, 0.75% to 1%, 0.75% to 1.5%, 0.75% to 2%, 0.75% to 2.5%, 0.75% to 3%, 0.75% to 3.5%, 0.75% to 4%, 0.75% to 4.5%, 0.75% to 5%, 0.75% to 5.5%, 0.75% to 6%, 0.75% to 6.5%, 0.75% to 7%, 0.75% to 7.5%, 0.75% to 8%, 0.75% to 8.5%, 0.75% to 9%, 0.75% to 9.5%, 0.75% to 10%, 1% to 1.5%, 1% to 2%, 1% to 2.5%, 1% to 3%, 1% to 3.5%, 1% to 4%, 1% to 4.5%, 1% to 5%, 1% to 5.5%, 1% to 6%, 1% to 6.5%, 1% to 7%, 1% to 7.5%, 1% to 8%, 1% to 8.5%, 1% to 9%, 1% to 9.5%, 1% to 10%, 1.5% to 2%, 1.5% to 2.5%, 1.5% to 3%, 1.5% to 3.5%, 1.5% to 4%, 1.5% to 4.5%, 1.5% to 5%, 1.5% to 5.5%, 1.5% to 6%, 1.5% to 6.5%, 1.5% to 7%, 1.5% to 7.5%, 1.5% to 8%, 1.5% to 8.5%, 1.5% to 9%, 1.5% to 9.5%, 1.5% to 10%, 2% to 2.5%, 2% to 3%, 2% to 3.5%, 2% to 4%, 2% to 4.5%, 2% to 5%, 2% to 5.5%, 2% to 6%, 2% to 6.5%, 2% to 7%, 2% to 7.5%, 2% to 8%, 2% to 8.5%, 2% to 9%, 2% to 9.5%, 2% to 10%, 2.5% to 3%, 2.5% to 3.5%, 2.5% to 4%, 2.5% to 4.5%, 2.5% to 5%, 2.5% to 5.5%, 2.5% to 6%, 2.5% to 6.5%, 2.5% to 7%, 2.5% to 7.5%, 2.5% to 8%, 2.5% to 8.5%, 2.5% to 9%, 2.5% to 9.5%, 2.5% to 10%, 3% to 3.5%, 3% to 4%, 3% to 4.5%, 3% to 5%, 3% to 5.5%, 3% to 6%, 3% to 6.5%, 3% to 7%, 3% to 7.5%, 3% to 8%, 3% to 8.5%, 3% to 9%, 3% to 9.5%, 3% to 10%, 3.5% to 4%, 3.5% to 4.5%, 3.5% to 5%, 3.5% to 5.5%, 3.5% to 6%, 3.5% to 6.5%, 3.5% to 7%, 3.5% to 7.5%, 3.5% to 8%, 3.5% to 8.5%, 3.5% to 9%, 3.5% to 9.5%, 3.5% to 10%, 4% to 4.5%, 4% to 5%, 4% to 5.5%, 4% to 6%, 4% to 6.5%, 4% to 7%, 4% to 7.5%, 4% to 8%, 4% to 8.5%, 4% to 9%, 4% to 9.5%, 4% to 10%, 4.5% to 5%, 4.5% to 5.5%, 4.5% to 6%, 4.5% to 6.5%, 4.5% to 7%, 4.5% to 7.5%, 4.5% to 8%, 4.5% to 8.5%, 4.5% to 9%, 4.5% to 9.5%, 4.5% to 10%, 5% to 5.5%, 5% to 6%, 5% to 6.5%, 5% to 7%, 5% to 7.5%, 5% to 8%, 5% to 8.5%, 5% to 9%, 5% to 9.5%, 5% to 10%, 5.5% to 6%, 5.5% to 6.5%, 5.5% to 7%, 5.5% to 7.5%, 5.5% to 8%, 5.5% to 8.5%, 5.5% to 9%, 5.5% to 9.5%, 5.5% to 10%, 6% to 6.5%, 6% to 7%, 6% to 7.5%, 6% to 8%, 6% to 8.5%, 6% to 9%, 6% to 9.5%, 6% to 10%, 6.5% to 7%, 6.5% to 7.5%, 6.5% to 8%, 6.5% to 8.5%, 6.5% to 9%, 6.5% to 9.5%, 6.5% to 10%, 7% to 7.5%, 7% to 8%, 7% to 8.5%, 7% to 9%, 7% to 9.5%, 7% to 10%, 7.5% to 8%, 7.5% to 8.5%, 7.5% to 9%, 7.5% to 9.5%, 7.5% to 10%, 8% to 8.5%, 8% to 9%, 8% to 9.5%, 8% to 10%, 8.5% to 9%, 8.5% to 9.5%, 8.5% to 10%, 9% to 9.5%, 9% to 10%, or 9.5% to 10%, by weight of the composition. Generally, the compositions contain less than 10 wt % alkoxylated modified rosin. For example, the compositions provided herein can contain up to at or about 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, or 10% alkoxylated modified rosin, based on the weight of the ink composition.
(25) Provided herein are exemplary web-offset lithographic ink compositions that contain an alkoxylated modified rosin. The web-offset lithographic ink compositions provided herein can be used to reduce or eliminate ink feedback and build-up that commonly occurs during the lithographic printing process. Exemplary of such ink compositions contain an oil-based ink and from at or about 0.1% to at or about 10% of an alkoxylated modified rosin. For example, the ink compositions can contain an oil-based ink and at or about 3% of an alkoxylated modified rosin. In another example, the ink compositions can contain an oil-based ink and at or about 4% of an alkoxylated modified rosin. Another exemplary embodiment contains a radiation-curable ink and from at or about 0.1% to at or about 10% of an alkoxylated modified rosin. For example, the ink compositions can contain a radiation-curable ink, such as an electron-beam cured ink, and at or about 3% of an alkoxylated modified rosin.
(26) 3. Offset Lithographic Ink
(27) Provided herein are web-offset lithographic ink compositions containing a water-soluble alkyl thioester surfactant, an alkoxylated modified rosin, or a combination thereof. The web-offset lithographic inks used in the compositions provided herein can be oil-based inks or water-based inks. In some embodiments, the web-offset lithographic inks can be radiation-curable inks, such as electron-beam cured or ultra-violet cured inks. The web-offset lithographic inks used in the compositions provided herein can contain a large number of components, including, but not limited to those listed below in Table 1. As shown in Table 1, an oil-based ink composition can include, for example, one or more ingredients selected from among varnishes, vehicles (gel, insert or G80), clays, pigment bases, emulsion stabilizers, waxes, water, gel linseed, linseed oil, castor oil, soy oil, lubricants, emulsifiers and oils. Typically, such as in the exemplary ink compositions provided herein, when increasing or decreasing the amount of water-soluble alkyl thioether surfactant or alkoxylated modified rosin in the ink composition, the amount of varnish, such as the gel vehicle, can be decreased or increased, respectively.
(28) TABLE-US-00001 TABLE 1 Materials useful in formulating typical oil-based ink compositions Material Description Phenolic free 45% phenolic modified rosin ester, ink oil (Sun Chemical; flow varnish 1 Hopkinsville, KY) Phenolic free 47% phenolic modified rosin ester, ink oil (Sun Chemical; flow varnish 2 Hopkinsville, KY) Gel vehicle 49% phenolic modified rosin ester, 9% soy, ink oil, gellant (Sun (varnish) Chemical; Hopkinsville, KY) Insert vehicle 50% phenolic modified rosin ester, 9% soy, ink oil, gellant (Sun Chemical; Hopkinsville, KY) G80 vehicle 22% soy, 10% 140 melt hydrocarbon, 43% phenolic modified rosin ester, ink oil, gallant (Sun Chemical; Hopkinsville, KY) Clay compound 50% kaolin clay compound Black pigment Black base, uncoated flat carbon black, HC varnish, ink oil, alkyd (Sun Chemical; Frankfort, IN) Cyan pigment Phthalo cyan flush (Sun Chemical; Muskegon, MI) Rubine pigment Lithol rubine flush (Sun Chemical; Muskegon, MI) Rubine pigment Lithol rubine flush (Apollo Colors; Rockdale, IL) Yellow pigment AAA Yellow 12 flush (Sun Chemical; Muskegon, MI) Orange pigment Orange base for toning ink (Apollo Colors, Rockdale, IL) Bentone compound Organoclay rheological additive Optilith 3 Emulsion stabilizer (Hexion; Columbus, OH) Microcrystalline Hydrocarbon wax produced from petroleum wax compound Wax compound PTFE (Teflon) wax compound Water Water Gelled linseed oil Gelled linseed oil Soybean oil Soybean oil Linseed oil Linseed oil Water fighter Polymerized castor oil OSO lubricant Gelled petroleum oil (Agip; Cabot, PA) Emulsifier Dimer acid TRO (Turkey Red Oil) Sulfonated castor oil N100 ink oil Paraffinic oil Magie 500 Oil Petroleum oil (Calumet M500, Calumet; Indianapolis, IN) Magie 470 Oil Petroleum oil (Calumet M470, Calumet; Indianapolis, IN)
(29) The web-offset lithographic ink compositions provided herein contain a water-soluble alkyl thioether surfactant or an alkoxylated modified rosin, such as a highly ethoxylated modified rosin, or a combination thereof. The ink compositions provided herein can be oil-based inks or water-based inks. The inks can be radiation-curable inks, such as electron-beam cured or ultra-violet cured. Use of these ink compositions in printing, for example in web-offset lithographic printing, improves printing and reduces or eliminates ink feedback and ink build-up, key problems in lithography. The ink compositions can be used in a wide variety of printing applications, such as in heat-set offset ink printing, sheet fed printing, newspaper printing, and energy-curable offset ink printing.
C. Examples
Example 1
(30) Examples of representative web-offset lithographic oil-based ink compositions in various colors that include one or more of the components identified in Table 1 are Inks 1-4, described in Table 2 below. The oil-based ink compositions shown in Table 2 are only examples of typical oil-based inks that do not contain a water-soluble alkyl thioether surfactant or alkoxylated modified rosin and should not be viewed as limiting.
(31) TABLE-US-00002 TABLE 2 Composition (in wt. %) of comparative oil-based inks not containing a water-soluble thioether surfactant or alkoxylated modified rosin Description (see Table 1 for Ink 1 Ink 2 Ink 3 Ink 4 specific details) (black) (Cyan) (rubine) (yellow) Phenolic free flow 0.0 0.0 0.0 7.0 varnish 1 Phenolic free flow 0.0 0.0 6.3 0.0 varnish 2 Gel vehicle 0.0 21.5 19.8 27.0 (varnish) Insert vehicle 0.0 0.0 0.0 0.0 G80 vehicle 0.0 10.0 7.6 4.5 Clay compound 0.0 10.0 10.0 8.5 Black pigment 83.0 0.0 0.0 0.0 Cyan pigment 0.0 39.0 0.0 0.0 Rubine pigment 0.0 0.0 40.0 0.0 (Sun Chemical) Rubine pigment 0.0 0.0 0.0 0.0 (Apollo Colors) Yellow pigment 0.0 0.0 0.0 28.0 Orange pigment 0.0 0.0 0.0 0.3 Bentone compound 1.0 1.5 1.5 2.0 Emulsion stabilizer 0.3 0.0 0.0 0.0 Microcrystalline 0.0 5.0 5.0 5.0 wax compound Wax compound 0.3 0.0 0.0 0.0 Water 0.0 0.0 0.0 3.0 Gelled linseed oil 0.0 0.0 1.0 0.0 Soybean oil 4.0 0.0 0.0 0.0 Linseed oil 0.0 0.0 0.0 0.0 Water fighter 1.5 1.0 0.0 1.5 OSO lubricant 0.0 3.0 0.0 3.0 Emulsifier 1.0 0.0 0.0 0.2 Alkyl thioether surfactant/ 0.0 0.0 0.0 0.0 alkoxylated modified rosin TRO (sulfonated castor oil) 0.0 0.3 0.4 0.0 N100 ink oil 3.0 0.0 0.0 0.0 Petroleum ink oil 5.8 8.7 8.5 10.0 Total (wt. %) 100 100 100 100
(32) The following Table 3 provides exemplary web-offset lithographic oil-based ink compositions that contain 0.3% of a water-soluble alkyl thioether surfactant, EnviroGem 360 (Air Products, Allentown, Pa.). These compositions are simply exemplary and should not be viewed as limiting.
(33) TABLE-US-00003 TABLE 3 Composition (in wt. %) of oil-based inks containing water-soluble alkyl thioether surfactant Description (see Table 1 for Ink 5 Ink 6 Ink 7 Ink 8 specific details) (black) (Cyan) (rubine) (yellow) Phenolic free flow 0.0 0.0 0.0 0.0 varnish 1 Phenolic free flow 0.0 0.0 0.0 0.0 varnish 2 Gel vehicle 0.0 26.0 26.7 33.0 (varnish) Insert vehicle 0.0 0.0 0.0 0.0 G80 vehicle 0.0 0.0 0.0 0.0 Clay compound 0.0 9.0 9.0 9.0 Black pigment 79.0 0.0 0.0 0.0 Cyan pigment 0.0 39.0 0.0 0.0 Rubine pigment 0.0 0.0 0.0 0.0 (Sun Chemical) Rubine pigment 0.0 0.0 40.0 0.0 (Apollo Colors) Yellow pigment 0.0 0.0 0.0 28.0 Orange pigment 0.0 0.0 0.0 0.3 Bentone compound 0.0 0.0 0.0 0.0 Emulsion stabilizer 0.3 0.0 0.0 0.0 Microcrystalline 0.0 0.0 0.0 0.0 wax compound Wax compound 0.5 0.7 0.7 0.7 Water 7.0 11.0 8.0 11.0 Gelled linseed oil 0.0 0.0 0.0 0.0 Soybean oil 3.0 0.0 0.0 0.0 Linseed oil 0.0 4.0 4.0 4.0 Water fighter 1.5 0.0 0.0 0.0 OSO lubricant 0.0 3.0 3.0 3.0 Emulsifier 0.5 0.5 0.0 0.5 Alkyl thioether 0.3 0.3 0.3 0.3 surfactant (EnviroGem 360) TRO (sulfonated 0.0 0.0 0.3 0.0 castor oil) N100 ink oil 3.0 0.0 0.0 0.0 Petroleum ink oil 5.0 6.6 8.1 10.3 Total (wt. %) 100 100 100 100
(34) A comparison of the tack, Laray viscosity (L viscosity) and yield (L yield) between comparative oil-based inks from Table 2 (Inks 1-4) and exemplified oil-based inks containing a water-soluble alky thioether surfactant (Inks 5-8) from Table 3 is provided in Tables 5 and 6 below.
(35) The importance of tack is that it is not so excessive that it doesn't allow effective transfer of ink from the rollers to the plate and then to the blanket and on to the substrate being printed. Inks can also be tack graded in descending sequence to allow for better trapping of one color over another. Inks with too much tack can cause the surface of the paper to pick off and interfere with transfer onto subsequent printing units and copies.
(36) Tack can be measured using an inkometer as generally available on the market. The inkometer is able to provide reliable data on ink tack by simulating the dynamic conditions that occur in the printing process. In testing tack, the inkometer actually measures the integrated forces involved in ink film splitting and the effects of speed, film thickness, temperature and solvent evaporation on these forces.
(37) The test results are given in numerical values (in gram-meters) representing the torque required to work the ink film at known rates, with predetermined film thickness and temperature. These torque readings are actually measurements of the tack of the ink.
(38) The electronic inkometer simplifies ink testing with push-button operation and a digital display of temperature, tack, RPM and test time. For purposes of the above testing, a Thwing-Albert Inkometer (West Berlin, N.J.) was used.
(39) The viscosity and yield values were measured with a Laray viscometer. The Laray viscometer determines the viscosity of a wide range of liquids and viscous materials by measuring the time required for a rod to travel a specified distance. For example, the viscosity of a liquid can be measured using a Laray viscometer, a Laray Timer TMI 92-15 (0.00 second resolution), a temperature probe capable of measuring in 0.5 C. increments, a Laray computer program, a water bath maintained at 251 C., approximately 2 to 3.5 grams of sample fluid or liquid and a spatula. Initially, the instruments should be checked for cleanliness and overall proper condition. The Laray viscometer should be leveled. The temperature should also be checked and the instrument should be controlled at 251 C. A draft-controlled cabinet can be used to maintain the temperature of 251 C. The Laray rod can be wetted using the spatula without overworking the sample. The liquid sample is preferably deposited uniformly around the Laray rod. Consistency in this initial step for testing different samples is likely to result in more consistent data. The Laray rod can then be dropped into the fluid sample using force sufficient to equal a drop time of approximately one second.
(40) A standard Laray test can be accomplished using the drop sequences listed in Table 4 below.
(41) TABLE-US-00004 TABLE 4 Laray test drop sequences 1.sup.st Drop 1.00-1.15 seconds 2.sup.nd Drop 1.85-2.15 seconds 3.sup.rd Drop 2.85-3.15 seconds 4.sup.th Drop 3.85-4.10 seconds 5.sup.th Drop 4.80-5.00 seconds
(42) It should be understood that a weight capable of dropping the rod within the specified time range can be selected and adjusted as appropriate for each drop sequence listed in Table 4. It is generally preferable to avoid or minimize multiple drops for each time range. The weight, in kilograms, and the time, in seconds, should be recorded along with the collar temperature in degrees Centigrade. The recorded test data can then be uploaded to the Laray program that can calculate the viscosity, yield value, and shortness ratio.
(43) The results can be recorded from these calculations. For the purposes of these measurements, the viscosity at 2500 sec1 shear rate is defined as the ability of the sample fluid to resist deformation or flow, and is measured in poise (1 poise=0.1 Pascal second). The yield value at 2.5 sec shear rate is the hypothetical force required to initiate flow and is measured in dynes/cm. Finally, the shortness ratio is the ratio of yield value to viscosity.
(44) An alternative to the standard Laray test is the Vertis Laray method. The Vertis Laray method involves preparing a sample and placing the sample on the Laray rod as described above. A 700 g weight is then placed on the rod before it is dropped. The rod is then pulled back so that the sample can be redistributed around the collar and the rod. The rod is then dropped two consecutive times with the 700 g weight while recording the time. The drop-times are preferably within +0.1 seconds of each other. The average of the drop times is set as the initial time. The rod can then be dropped three more times: once with a 500 g weight, once with a 300 g weight, and once with a 100 g weight. The time should be recorded for each drop. The collar temperature should also be recorded in degree Centigrade. The recorded data is then uploaded into the Laray program which can then calculate the viscosity, yield value, and shortness ratio as defined above.
(45) For purposes of comparing the properties of the comparative oil-based inks not containing a water-soluble alkyl thioether surfactant listed in Table 2 (Inks 1-4) to the oil-based inks containing a water-soluble alkyl thioether surfactant listed in Table 3 (Inks 5-8), 1 minute and 5 minute tack tests were conducted. As shown in Tables 5 and 6, the addition of a water-soluble alkyl thioether surfactant to the oil-based inks does not affect desirable ink properties such as tack, viscosity and yield, but does, as discussed below, alleviate the ink feedback problem.
(46) TABLE-US-00005 TABLE 5 Properties of comparative oil-based inks not containing a water-soluble alkyl thioether surfactant Ink 1 Ink 2 Ink 3 Ink 4 (black) (Cyan) (rubine) (yellow) 1 Tack Test (g .Math. m) 5.0 5.4 5.2 5.2 5 Tack Test (g .Math. m) 6.3 7.5 7.8 7.4 Laray Viscosity 102 52 59 80 Laray Yield 1443 1440 1760 1606
(47) TABLE-US-00006 TABLE 6 Properties of oil-based inks containing a water-soluble alkyl thioether surfactant Ink 1 Ink 2 Ink 3 Ink 4 (black) (Cyan) (rubine) (yellow) 1 Tack Test (g .Math. m) 5.0 5.0 5.2 5.6 5 Tack Test (g .Math. m) 6.4 6.7 Laray Viscosity 73 55 58 69 Laray Yield 1060 1580 1710 2660
(48) The web-offset lithographic oil-based ink compositions were tested to compare the effect the presence of a water-soluble alkyl thioether surfactant had on ink feedback and ink build-up. Testing involved a web offset heat-set press (Didde Corporation, Springboro, Ohio).
(49) A 5 minute trial using oil-based comparative Ink 4 (see Table 2), a lower tack laser yellow ink that did not contain any alkyl thioether surfactants, was run on a Didde press using 2 notches, a 20% water setting, and densities of 0.95, 0.96 and 0.99. After 5 minutes, residue ink accumulated on the ink roller and thus presented a significant feedback problem. There was particularly high accumulation of yellow ink on the far left edge of the bottom ink roller, as well as several bands of yellow ink that accumulated across the entire bottom ink roller. The results are illustrated in
(50) A trial using comparative Ink 4 (see Table 2), a yellow ink which did not contain any alkyl thioether surfactant, was run on a Didde press at a press speed of 100 fpm on 30# abibo paper with a 5% image. The fountain solution used was Printeasy 2050 (5 oz/gallon). After the run was complete, there was accumulation of ink feedback on the bottom ink roller. The results are illustrated in
Example 2
(51) Several web-offset lithographic oil-based ink compositions were prepared and are shown below in Table 7. Ink 9 (comparative) is an oil-based Dingley yellow laser ink that did not contain any alkoxylated modified rosin. The exemplified compositions (Inks 10-11) are oil-based ink compositions that contained about 3% or about 4% of a water-soluble highly ethoxylated rosin, Ethox 4614 (Ethox Chemicals, Greenville, S.C.).
(52) TABLE-US-00007 TABLE 7 Compositions (in wt. %) of oil-based inks containing water-soluble alkoxylated modified rosin Ink 9 Ink 10 Ink 11 Description (comparative) (3% rosin) 4% rosin) Phenolic free flow 7.0 7.0 7.0 varnish 1 Phenolic free flow 0.0 0.0 0.0 varnish 2 Gel vehicle 27.0 24.0 23.0 (varnish) Insert vehicle 0.0 0.0 0.0 G80 vehicle 4.5 4.5 4.5 Clay compound 8.5 8.5 8.5 Black pigment 0.0 0.0 0.0 Cyan pigment 0.0 0.0 0.0 Rubine pigment 0.0 0.0 0.0 (Sun Chemical) Rubine pigment 0.0 0.0 0.0 (Apollo Colors) Yellow pigment 28.0 28.0 28.0 Orange pigment 0.3 0.3 0.3 Bentone compound 2.0 2.0 2.0 Emulsion stabilizer 0.0 0.0 0.0 Microcrystalline 5.0 5.0 5.0 wax compound Wax compound 0.0 0.0 0.0 Water 3.0 3.0 3.0 Gelled linseed oil 0.0 0.0 0.0 Soybean oil 0.0 0.0 0.0 Linseed oil 0.0 0.0 0.0 Water fighter 1.5 1.5 1.5 OSO lubricant 3.0 3.0 3.0 Emulsifier 0.2 0.2 0.2 Alkoxylated 0.0 3.0 4.0 modified rosin (Ethox 4614) TRO (sulfonated 0.0 0.0 0.0 castor oil) N100 ink oil 0.0 0.0 0.0 Petroleum ink oil 10.0 10.0 10.0 Total (wt. %) 100 100 100
(53) A trial using comparative Ink 9 (Table 7) was run on a Didde press. There was significant accumulation of yellow ink feedback in the form of multiple scattered dark yellow bands on the bottom ink roller after the trial run was complete. The results are illustrated in
Example 3
(54) Six electon beam (EB) cured offset lithographic inks containing 3% of a water-soluble highly ethoxylated rosin, Ethox 4614, were prepared, each containing a different pigment color (Ink 13=cyan; Ink 14=magenta; Ink 15=yellow; Ink 16=black; Ink 17=green; Ink 18=brown). A comparative EB cured offset lithographic ink was prepared that did not contain the modified rosin (Ink 12). The ink formulations are set forth in Table 8 below, where the pigment of Inks 13-18 is cyan, magenta, yellow, black, green, or brown, respectively.
(55) TABLE-US-00008 TABLE 8 Composition (in wt. %) of electron-beam cured offset inks Ink 12 Inks 13-18 Description (comparative) (3% rosin) Aldehyde resin (Laropal 26.0 23.0 A81; BASF; Germany Inhibitor 2.0 2.0 Energy-curable polyester 18.0 18.0 acrylate (Ebecryl 871; Cytec; Woodland Park, NJ) Polyester acrylate 10.0 10.0 Alkoxylated modified 0 3.0 rosin (Ethox 4614) Low viscosity epoxy 16.0 16.0 acrylate Hyperdispersant 0.5 0.5 Pigment 14.5 14.5 Talc 5.0 5.0 PE wax 1.0 1.0 PTFE wax 1.0 1.0 Propoxylated neopentyl 6.0 6.0 glycol diacrylate monomer (2PO NPGDA) Total (wt. %) 100 100
(56) Print trials using comparative Ink 12 and exemplary Inks 13-18 (Table 8) were run on a Drent Goebel VSOP press (Eerbeek, Netherlands) and a Goss VSOP press (Durham, N.H.) using a coated board substrate and Rycoline PrintEasy 4600 fountain solution (Sun Chemical, Chicago, Ill.). In all print trials that used the comparative Ink 12, there was severe accumulation of ink feedback on the bottom ink roller after the run was complete. Print trials that used exemplary Inks 13-18 that contained 3% Ethox 4614 completely eliminated the ink feedback. The addition of the highly ethoxylated modified rosin to Inks 13-18 resulted in a substantial reduction of ink feedback on the bottom roller.
(57) It will be apparent to those skilled in the art that various modifications and variation can be made in the present invention without departing from the spirit or scope of the invention. Thus, it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.