OUTER RING FOR AN OIL PUMP AND A METHOD FOR MANUFACTURING THE SAME

Abstract

Disclosed are an outer ring for an oil pump having an increased number and size of open pores in a surface of a molded article and a method for manufacturing the outer ring.

Claims

1. A method for manufacturing an outer ring for an oil pump, the method comprising: mixing a pre-alloy powder with a copper mixture to prepare a mixed powder; compacting the mixed powder into a compact; sintering the compact to prepare a sintered body; and sinter hardening the sintered body, wherein the pre-alloy powder comprises: 1.35 wt.% to 1.65 wt.% of chromium; 0.16 wt.% to 0.24 wt.% of molybdenum; 0.10 wt.% to 0.25 wt.% of manganese; and a balance of iron, and wherein the copper mixture comprises: 15 wt.% to 18 wt.% of carbon; 8 wt.% to 9 wt.% of manganese sulfide; 55 wt.% to 57 wt.% of copper; and 19 wt.% to 20 wt.% of a lubricant.

2. The method according to claim 1, wherein the copper mixture is mixed in an amount in a range of 3 parts to 5 parts by weight based on 100 parts by weight of the pre-alloy powder.

3. The method according to claim 1, wherein the compact is compacted to a density of 6.8 g/cc or more.

4. The method according to claim 1, wherein the sintering is carried out at a temperature in a range of 1,110° C. to 1,150° C. for 15 minutes to 40 minutes.

5. The method according to claim 1, wherein the sintering is carried out in a gas atmosphere containing nitrogen and hydrogen.

6. The method according to claim 1, wherein the copper has a particle size in a range of 300 mesh to 350 mesh.

7. An outer ring for an oil pump, the outer ring comprising: iron (Fe), chromium (Cr), molybdenum (Mo), manganese (Mn), sulfur (S), carbon (C), and copper (Cu).

8. The outer ring according to claim 7, wherein the outer ring comprises 1.30 wt.% to 1.60 wt.% of the chromium, 0.16 wt.% to 0.23 wt.% of the molybdenum, 0.30 wt.% to 0.50 wt.% of the manganese, 0.10 wt.% to 0.20 wt.% of the sulfur, 0.51 wt.% to 0.70 wt.% of the carbon, 1.81 wt.% to 2.22 wt.% of the copper, and a balance of the iron.

9. The outer ring according to claim 7, wherein pores having a size of 100 .Math.m or more are present in 10% or more of a surface of the outer ring.

10. The outer ring according to claim 7, wherein the outer ring has a HV0.3 micro-hardness of 550 or more and a HV10 macro-hardness of 280 or more.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0023] The above and other features of the present disclosure arel now be described in detail with reference to certain embodiments thereof, illustrated in the accompanying drawings which are given hereinbelow by way of illustration only, and thus are not limitative of the present disclosure, and wherein:

[0024] FIG. 1 illustrates a morphology of a surface of a product prepared in Example 1; and

[0025] FIG. 2 illustrates a morphology of a surface of a product prepared in Comparative Example 1.

DETAILED DESCRIPTION

[0026] The objects described above, as well as other objects, features and advantages, should be clearly understood from the following embodiments with reference to the attached drawings. However, the present disclosure is not limited to the embodiments, and may be embodied in different forms. The embodiments are suggested only to offer a thorough and complete understanding of the disclosed context and to sufficiently inform those having ordinary skill in the art of the technical concept of the present disclosure.

[0027] Like reference numbers refer to like elements throughout the description of the figures. In the drawings, the sizes of structures may be exaggerated for clarity. It should be understood that, although the terms “first”, “second”, etc. may be used herein to describe various elements, these elements should not be construed as being limited by these terms, which are used only to distinguish one element from another. For example, within the scope defined by the present disclosure, a “first” element may be referred to as a “second” element, and similarly, a “second” element may be referred to as a “first” element. Singular forms are intended to include plural forms as well, unless the context clearly indicates otherwise.

[0028] It should be further understood that the term such as “comprises” or “has”, when used in this specification, specifies the presence of stated features, integers, steps, operations, elements, components or combinations thereof, but does not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof. In addition, it should be understood that, when an element such as a layer, film, region, or substrate is referred to as being “on” another element, it can be directly on the other element, or an intervening element may also be present. It should also be understood that when an element such as a layer, film, region, or substrate is referred to as being “under” another element, it can be directly under the other element, or an intervening element may also be present.

[0029] Unless the context clearly indicates otherwise, all numbers, figures, and/or expressions that represent ingredients, reaction conditions, polymer compositions and amounts of mixtures used in the specification are approximations that reflect various uncertainties of measurement occurring inherently in obtaining these figures, among other things. For this reason, it should be understood that, in all cases, the term “about” should be understood to modify all numbers, figures and/or expressions. In addition, when numerical ranges are disclosed in the description, these ranges are continuous, and include all numbers from the minimum to the maximum, including the maximum within each range, unless otherwise defined. Furthermore, when the range refers to an integer, it includes all integers from the minimum to the maximum, including the maximum within the range, unless otherwise defined.

[0030] It should be understood that, in the specification, when a range is referred to regarding a parameter, the parameter encompasses all figures including end points disclosed within the range. For example, the range of “5 to 10” includes figures of 5, 6, 7, 8, 9, and 10, as well as arbitrary sub-ranges, such as ranges of 6 to 10, 7 to 10, 6 to 9, and 7 to 9, and any figures, such as 5.5, 6.5, 7.5, 5.5 to 8.5, and 6.5 to 9, between appropriate integers that fall within the range. In addition, for example, the range of “10% to 30%” encompasses all integers that include numbers such as 10%, 11%, 12%, and 13%, as well as 30%, and any sub-ranges, such as 10% to 15%, 12% to 18%, or 20% to 30%, as well as any numbers, such as 10.5%, 15.5%, and 25.5%, between appropriate integers that fall within the range.

[0031] The present disclosure relates to a method for manufacturing an outer ring for an oil pump having an increased number and size of open pores in the surface of a molded article, and an outer ring manufactured by the method.

Method of Manufacturing Outer Ring

[0032] The method for manufacturing an outer ring for an oil pump according to the present disclosure includes mixing a pre-alloy powder with a copper mixture to prepare a mixture, compacting the mixed powder into a compact, and sintering the compact.

Mixed Powder Preparation

[0033] In this step, the pre-alloy powder is mixed with the copper mixture to prepare a mixture.

[0034] The pre-alloy powder may contain iron (Fe), chromium (Cr), molybdenum (Mo), and manganese (Mn).

[0035] In one embodiment, the pre-alloy powder contains in a range of 1.35 wt.% to 1.65 wt.% of chromium, 0.16 wt.% to 0.24 wt.% of molybdenum, 0.10 wt.% to 0.25 wt.% of manganese, and the balance of iron.

[0036] In one embodiment, the copper mixture is mixed in an amount in a range of 3 parts to 5 parts by weight based on 100 parts by weight of the pre-alloy powder. At this time, when the content of the copper mixture is less than 3 parts by weight, the hardness of the product may not reach the desired value, and the size of the coarse pores may be lowered, and when the content is higher than 5 parts by weight, processing efficiency may be reduced.

[0037] In another embodiment, the copper mixture contains carbon (C), manganese sulfide (MnS), copper (Cu), and a lubricant. Here, addition of the copper powder enables the structure of the material to be strengthened and coarse pores to be obtained.

[0038] The lubricant is not particularly limited, but amide wax is used in the present disclosure.

[0039] In one embodiment, the copper mixture contains in a range of 15 wt.% to 18 wt.% of carbon, 8 wt.% to 9 wt.% of manganese sulfide, 55 wt.% to 57 wt.% of copper, and 19 wt.% to 20 wt.% of a lubricant. At this time, when the content of copper is less than 55 wt.%, the hardness of the surface of the compact may be lowered. When the content is higher than 57 wt.%, the dimensional change before and after sintering may be excessively increased.

[0040] The copper has a particle size in a range of 300 mesh to 350 mesh, in one embodiment, 320 mesh to 330 mesh. In this case, when the copper particle size is less than 300 mesh, the magnitude of dimensional change before and after sintering may be large. When the copper particle size is higher than 350 mesh, there is a risk of the size of the coarse pores being reduced.

Compacting

[0041] In this step, the mixed powder is molded into a compact.

[0042] The compact is obtained by compacting the mixture to a density of 6.8 g/cc or more.

Sintering

[0043] In this step, the compact is sintered to prepare a sintered body. Specifically, the compact is sintered at a temperature in a range of 1,110° C. to 1,150° C. for 15 minutes to 40 minutes. Due to the sintering, the lubricant is finally thermally decomposed and removed.

[0044] The sintering may be carried out in a gas atmosphere containing nitrogen and hydrogen, and in one embodiment, the ratio of nitrogen to hydrogen is in a range of 8:2 to 9:1.

Sinter Hardening

[0045] In this step, the sintered body is cooled and hardened.

[0046] The cooling may be carried out using a fan, at a cooling rate in a range of 2° C./s to 3° C./s.

[0047] The method may further include, after cooling, tempering the sintered body at a relatively low temperature, and the tempering may be performed at a temperature in a range of 180° C. to 220° C. for 1 hour to 2 hours.

Outer Ring

[0048] The outer ring manufactured by the method for manufacturing an outer ring for an oil pump according to the present disclosure contains iron (Fe), chromium (Cr), molybdenum (Mo), manganese (Mn), sulfur (S), carbon (C), and copper (Cu).

[0049] The outer ring more contains 1.30 wt.% to 1.60 wt.% of chromium, 0.16 wt.% to 0.23 wt.% of molybdenum,0.30 wt.% to 0.50 wt.% of manganese, 0.10 wt.% to 0.20 wt.% of sulfur, 0.51 wt.% to 0.70 wt.% of carbon, 1.81 wt.% to 2.22 wt.% of copper, and the balance of iron. Here, the chromium and molybdenum are matrix-reinforcing elements. When the chromium is present in an amount less than 1.30 wt.%, the strength may be reduced, or 5% or more of bainite may be formed. When the chromium is present in an amount higher than 1.60 wt.%, the dimensional change may increase. In addition, when molybdenum, which is a matrix-reinforcing element, is present in an amount less than 0.16 wt.%, the strength decreases and the stability of the martensite structure is lowered, thereby increasing brittleness. In addition, when the manganese is present in an amount less than 0.30 wt.%, workability may be reduced, and when the manganese is present in an amount greater than 0.50 wt.%, the compacting pressure may be increased and strength may be reduced. In addition, when the sulfur is present in an amount less than 0.10 wt.%, workability may be reduced, and when the sulfur is present in an amount of 0.20 wt.%, an increase in compacting pressure and a decrease in strength may occur. In addition, when the carbon, which is a matrix-reinforcing element, is present in an amount less than 0.51 wt.%, 5% or more of bainite is formed, thereby decreasing strength, and when the carbon is present in an amount greater than 0.70 wt.%, residual austenite may be formed, and micro-hardness may be reduced.

[0050] The copper serves to reinforce the matrix, pores are created at the positions where copper powder particles are present by diffusion during sintering, and when the copper is present in an amount less than 1.81 wt.%, the number of opened pores may decrease. When the copper is present in an amount greater than 2.22 wt.%, the matrix may be strengthened, but the dimensional change after sintering may increase.

[0051] In one embodiment, pores having a size of 100 .Math.m or more are formed in 10% or more of the surface of the outer ring, and the molded product has a HV0.3 micro-hardness of 550 or more and a HV10 macro-hardness of 280 or more.

[0052] Hereinafter, the present disclosure is described in more detail with reference to specific examples. However, the following examples are provided only for better understanding of the present disclosure, and thus should not be construed as limiting the scope of the present disclosure.

Example

[0053] A pre-alloy powder containing iron, chromium, molybdenum, and manganese was mixed with a copper mixture containing carbon, manganese sulfide, copper, and a lubricant, and then a die was filled with the mixture and punched to produce a compact. Then, the compact was sintered at 1,120° C. for 20 minutes in a gas atmosphere containing nitrogen and hydrogen (nitrogen:hydrogen = 6:1) and then sufficiently cooled using a fan to produce a product having the composition shown in Table 1 below (However, the balance of iron (Fe) is omitted, and the particle size of the copper powder that was added when mixing the raw materials is shown in Table 1. Also, the article was molded in the form of a general outer ring for an oil pump.)

[0053] TABLE-US-00001 Composition Copper particle size Example 1 1.5Cr-0.2Mo-0.37Mn-0.12S-0.6C-2.0Cu 325 mesh Example 2 1.5Cr-0.2Mo-0.36Mn-0.11 S-0.6C-1.9Cu 325 mesh Example 3 1.5Cr-0.2Mo-0.39Mn-0.13S-0.6C-2.2Cu 325 mesh

[0054] FIG. 1 illustrates the result of observation of the surface of the product prepared in Example 1. It can be seen from FIG. 1 that a large number of pores having a size of 100 .Math.m or more are observed.

Comparative Example

[0055] A product having the composition shown in Table 2 below was prepared in the same manner as in Example described above.

[0055] TABLE-US-00002 Composition Copper particle size Comparative Example1 1.5Cr-0.2Mo-0.38Mn-0.12S-0.6C-2.0Cu 325 Mesh Comparative Example 2 1.5Cr-0.2Mo-Mn-0.13S-0.6C 325 Mesh Comparative Example 3 1.5Cr-0.2Mo-0.37Mn-0.12S-0.6C-3.0Cu 325 Mesh Comparative Example 4 1.5Cr-0.2Mo-0.36Mn-0.13S-0.6C-2.0Cu 200 Mesh Comparative Example 5 1.5Cr-0.2Mo-0.37Mn-0.12S-0.6C-2.0Cu 400 Mesh

[0056] FIG. 2 illustrates the result of observation of the surface of the product prepared in Comparative Example 1. It can be seen from FIG. 2 that a large number of small-sized pores are observed.

Experimental Example 1

[0057] The sintering density, hardness, yield strength, tensile strength, and dimensional change of the product according to Examples 1 to 3 and Comparative Examples 1 to 5 were measured, and are shown in Table 3 below.

[0057] TABLE-US-00003 Density Micro-hardness (Hv 0.3) Macro-hardness (Hv 10) Yield strength (MPa) Tensile strength (MPa) Inner-diameter dimensiona l change (%) Example 1 6.87 634 335 649 852 1.0002 Example 2 6.87 634 335 649 852 1.0002 Example 3 6.87 634 335 649 852 1.0002 Comparativ e Example 1 6.87 634 335 649 852 1.0002 Comparativ e Example 2 6.91 529 274 586 792 0.9990 Comparativ e Example 3 6.93 665 358 689 899 1.0011 Comparativ e Example 4 6.86 629 321 629 839 1.0005 Comparativ e Example 5 6.89 658 342 660 861 1.0002

[0058] As is apparent from the foregoing, the present disclosure provides a method for manufacturing an outer ring having a high surface macro-hardness while maintaining a density of 6.80 g/cc or more and having many coarse pores in the surface thereof.

[0059] The effects of the present disclosure are not limited to those mentioned above. It should be understood that the effects of the present disclosure include all effects that can be inferred from the description of the present disclosure.

[0060] The present disclosure has been described in detail with reference to some embodiments thereof. However, it will be appreciated by those having ordinary skill in the art that changes may be made in these embodiments without departing from the principles and spirit of the present disclosure.