Novel Remediating Composition
20200398322 ยท 2020-12-24
Inventors
Cpc classification
International classification
Abstract
The present invention comprises a method of making and using a remediating composition for remediating contamination resulting from improper use or handling, or natural causes that would otherwise be damaging to, for example, the environment. Sources of contaminants include petroleum products, chemical and nuclear waste spills, biotoxin blooms, or combinations thereof. The method comprises allowing a heat-dried, particulate remediating composition to contact an amount of contaminated material for a time adequate to reduce the level of the contaminant in the contaminated material. Thereafter, testing of the previously contaminated material shows measurably lower amounts (often below measurable levels) of the contaminant, resulting in decontaminated material. Further, testing the newly-contaminated remediating composition shows far lower levels of the contaminants than would be expected when taking into account the original amounts of contaminants and remediating composition, and the amount remaining in the now-decontaminated material. The remediating composition remediates (reverses or stops) environmental damage.
Claims
1. A method to remediate a contaminated material comprising at least one contaminant in a said contaminated material requiring remediation prior to disposal, said at least one contaminant including one or more of a chemical, petroleum, and nuclear waste, said method comprising contacting said contaminated material with a remediating composition, said remediating composition comprising an amount of one of dried ground lodgepole pine material, jack pine material, or a mixture comprising both said lodgepole pine and jack pine material, where subsequent testing of the remediating composition contacted with said at least one contaminant shows one of no presence of the at least one contaminant, or presence of the contaminant at far lower levels than expected.
2. The method of claim 1 wherein said at least one contaminant comprises one or more of: a source of gasoline range organics, a source of diesel range organics, a source of oil range organics, Radium 226 waste, and Radium 228 waste, and heavy metals wherein said contacting comprises a period of time after which the amount of each said at least one contaminant in the contaminated material is remediated to an amount less than an amount permitted for proper to disposal.
3. The method of claim 2 wherein said mixture comprises soil.
4. The method of claim 1 wherein said contaminant comprises any one or more of oil, heavy metals, biomedical waste, and pesticides.
5. The method of claim 1 wherein the ground lodgepole pine is heat dried before use and the ratio of remediating composition added to contaminated material is between about 1:1 and about 3:1.
6. A method to remediate contaminants comprising contacting contaminated material and a remediating composition to form a mixture, said remediating composition comprising resins and wood-based cellulosic fiber sourced from heat-dried lodgepole pine wherein the ratio of said remediating composition added to said contaminated material is between about 1:1 and 5:1 wherein said contaminated material comprises any one or more of Arsenic, Barium, Cadmium, Chromium, Lead, Selenium, Silver, Mercury, Sodium, Magnesium, and Calcium.
7. The method of claim 6 wherein the contaminated material may further comprise any one or a mixture of: particulate matter comprising one or more of soil and ground materials, one or more liquids comprising polluted water, soft surfaces, and hard surfaces.
8. A method for remediating TPH-GRO (total petroleum hydrocarbons-gas range organics) contamination of a material containing TPH-GRO, said method comprising contacting said TPH-GRO contaminated material with a remediating composition that comprises resins and wood-based cellulose fiber from dried lodgepole pine material.
9. The method of claim 8 wherein the level of TPH-GRO in the contaminated material is reduced by more than 50%.
10. The method of claim 8 wherein said material further comprises TPH-DRO and said method reduces a level of TPH-DRO in the material wherein the remediating composition is mixed with the contaminated material in a mass ratio of between about 1:1 and 3:1, remaining in contact for at least twenty minutes reducing TPH-GRO by more than 50% and reducing TPH-DRO by more than 50%.
11. The method of claim 8 wherein upon contacting for a time period at least 5 minutes, wherein after said time period the contaminant cannot be physically separated from the remediating composition.
12. The method of claim 8 wherein the contaminated material is mixed in a 1:1 ratio by mass with the remediating composition to form a mixture, said method resulting in a mixture having both less TPH-GRO and less TPH-DRO than was present in the contaminated material.
13. The method of claim 8 wherein TPH-GRO is reduced by more than 80% and TPH-DRO is reduced by more than 80%.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
[0033] The present invention describes and discloses methods of making and using certain compositions for use in remediating certain polluting materials. Generally, the invention comprises an amount of a Remediating Composition, a contaminated material, and adequate contact time between the Remediating Composition and the contaminated material.
[0034] The steps for making the Remediating Composition comprise, generally, grinding a resin-containing tree or trees, thereafter heat drying the ground tree material. Specifically, the resin-containing tree is pine. It may be jack pine, lodge pole pine, or other species. It is preferably live when harvested. It is thought that the makeup of resin in a pine tree of a certain age, including lodge pole pine, may be more beneficial to the claimed use, however, using pine or lodge pole pine of other ages will also provide remediating effects. While other pine species, such as jack pine, exhibit comparable resin profiles and are included as a viable pine source in the present invention, the effectiveness of compositions made using jack pine and in accordance with the disclosure herein is not as effective in remediation as lodgepole pine. Lodgepole pine and jack pine comprise the following resin/terpene profiles:
TABLE-US-00001 TABLE 1 Terpenes in Lodgepole and Jack pine trees Mean content of terpenes (PPM) (1 SE) of lodgepole and jack pine trees. Mean content (ppm) Terpene P-value Lodgepole pine Jack pine Borneol P < 0.001 14.67 3.18 4.18 1.64 Bornyl acetate P = 0.004 45.95 12.55 42.52 3.41 Camphene P < 0.001 88.47 8.30 30.32 4.51 Camphor P = 0.041 6.69 1.93 2.21 0.85 3-Carene P < 0.001 1738.14 321.80 226.99 44.95 -Caryophyllene P < 0.001 16.02 3.32 5.47 2.24 -Copaene P < 0.001 13.70 2.68 1.09 0.78 -Cubebene P = 0.273 2.50 1.46 0.79 0.63 p-Cymene P < 0.001 32.06 5.11 2.90 1.71 -Humulene P < 0.001 42.35 7.30 3.19 1.42 Limonene P < 0.001 848.64 164.35 203.25 48.89 Linalool P = 0.220 64.73 9.02 117.74 16.68 Myrcene P < 0.001 435.45 45.48 100.18 15.71 Ocimene P < 0.001 31.75 8.21 0.00 0.00 -Phellandrene P < 0.001 175.77 17.93 1.62 1.38 -Phellandrene P < 0.001 9096.72 960.59 157.21 40.39 -Pinene P < 0.001 949.81 132.72 2518.14 328.27 -Pinene P < 0.001 921.46 127.02 283.98 43.68 Pulegone P = 0.039 30.21 6.81 107.13 22.81 Sabinene P < 0.001 141.94 17.74 7.12 2.17 -Terpinene P < 0.001 15.39 2.95 0.00 0.00 -Terpinene P < 0.001 23.81 5.42 0.00 0.00 Terpineol P < 0.001 53.64 8.55 16.50 6.59 Terpinolene P < 0.001 352.79 48.44 47.07 13.04 -Thujone P = 0.122 2.25 0.84 1.85 1.20 Total P < 0.001 15144.92 1463.47 3881.44 395.26
[0035] Significant differences were found in constitutive levels of resin terpenes between the two species of lodgepole pine and jack pine. Phloem samples from each tree were processed for comparison of induced levels of monoterpenes and for analysis of enantiomeric composition. Data on nine monoterpenes (3-carene, limonene, linalool, myrcene, -phellandrene, -pinene, -pinene, pulegone, terpinolene) and the total of all of the 26 terpenes measured were analyzed. See Comparison of lodgepole and jack pine resin chemistry: implications for range expansion by the mountain pine beetle, Dendroctonus ponderosae (Coleoptera: Curculionidae) Erin L. Clark, Published Feb. 11, 2014, Pubed 24688833. This study pointed out clear differences, and certain similarities among the resin of related pine.
[0036] Without limiting the invention to this concept, it is believed that the specific make up of constitutive resin chemistry may play a part in the remediating application. Lower levels of alpha-pinene and higher levels of 3-carene in lodge pole pine as compared to jack pine is expected to play a role in remediation. The relative amounts of these terpenes are dictated to a degree by environmental pressures, e.g., altitude, temperature, insect infestation. Further, differences between Jack pine and lodge pole pine in wounding-induced phloem accumulation of five major terpenes were also found. Finally, for all but three of the 26 monoterpenes considered, lodgepole pine had higher levels of 20 of the 23 terpenes with the exceptions of linalool, pulegone, and alpha pinene. Total terpenes were also higher in lodgepole pine than in its cousin, jack pine. These differences in resin chemistry are believed to contribute to the effect of the Remediating Composition. It is hypothesized that the relative volume or content of certain resins may cause synergism or catalytic effects during remediation and, therefore, it is preferred, but not necessarily required, that the combination of resins as found in the tree be employed in the process described herein. It is also possible that the tree's sap composition at the time of harvest may contribute to the Remediating Composition's efficacy. While lodgepole pine is preferred for use in the present invention, other pine such as jack pine or mixtures of pine may exhibit similar effects when employed in a Remediating Composition as described herein.
[0037] In order to make the Remediating Composition of the present invention, a lodgepole pine, preferably live or within about two years after the tree's death, is processed. The typical stripping process before pelletizing can only remove so much off the exterior of the lodgepole tree. It is noted that at least some exterior limbs containing pine needles and an amount of tree bark remain after the stripping process and, therefore, are processed in the present invention with the trunk. Because the resin and sap in the wood material are believed to contribute to the invention's characteristics, it is possible that harvesting the trees at certain times of the year may yield material more effective for Remediating Composition than at others. Determining the more preferred time of year to harvest at certain latitudes would be within the ordinary skill in the art. The tree material comprising resin, and which may include some amount of bark and pine needles, is then ground. The size of the ground material can be selected in accordance with the intended use. Particles may be flakes, nuggets, or another form similar to other products on the market that are used to absorb and clean up spills of liquid or semi-liquid materials. Once ground, flaked, or pelletized the material is heat-dried. The temperature may be selected based on the size of the particles, typically between 450 and 700 degrees Fahrenheit while tumbling to a moisture content of about 15%, generally avoiding charring and flaming. The moisture content of the finished composition is not critical, give or take a few percent. While it is preferable that charring and flaming are avoided in order to preserve the resin chemistry, minor charring and/or flaming of some of the material does not markedly reduce the efficacy of the whole of the Remediating Composition. In general, the heat-dried process requires a short time, somewhat dependent on the size of the equipment employed. It is not unusual to reach the desired moisture range by heat-drying for 3-5 minutes. It is believed that efficient heat drying without over exposure to heat preserves the efficacy of the Remediating Composition.
[0038] In a preferred embodiment certain resins are predominant in relative volume. These levels are not required for the material to be effective, although it is thought these levels foster higher levels of effectiveness in remediation. It is believed that the relative volume or content of certain resins cause either synergism or catalytic effects during remediation and, therefore, it is preferred, but not necessarily required that the combination of resins be employed as found in the tree, without alteration other than as may result from the treatment described herein.
[0039] The invention encompasses methods to absorb, adsorb and/or otherwise reduce to safe levels certain contaminants in a contaminated material, said methods comprise mixing a contaminated material with an amount of the inventive Remediating Composition. Adequate contact may include a layer of the Remediating Composition to fully cover the contaminated object or its surface. If the contaminated material is fungible, and thorough mixing will not increase the hazard more than reasonably tolerated, the Remediating Composition and the contaminated material should be thoroughly mixed for best results. Additional, periodic mixing may also be helpful. Upon mixing the Remediating Composition with a liquid or semi-liquid to be remediated, there is, most often, an exothermic reaction. It is theorized that the exothermic reaction is a result of friction created by expansion of the inventive remediating material opening the cellulosic fiber which, in turn, encapsulates the contaminant.
[0040] Various analyses of the Remediating Composition have been performed. Specifically, the composition has been tested, for example, with oil and with lead.
[0041] Case Study #1 Oil Contaminated from Car Dealer: An amount of the Remediating Composition was provided to demonstrate and evaluate its remediation capabilities of oil-contaminated soil. The hydration, mixing, sampling, and laboratory testing results were performed by a qualified laboratory. Tests performed were not only to study remediation but also to evaluate leaching and were also performed according to EPA Method 8015B. The test results showed that the Remediating Composition removes diesel range organics (DRO). The results provide an indication of the ability of the Remediating Composition to retain absorbed petroleum hydrocarbons that would otherwise remain in the environment.
[0042] Results also indicate that Remediating Composition interaction with contaminated oil is critical. Visually, the product did not appear to have reached oil saturation during the tests. It may be inferred that some of the hydrocarbons extracted were from oil that did not receive complete mixing.
[0043] Case Study #2 Lead: Sample contaminated soil was collected from a shooting range. Residual lead pellets were removed from the soil. The base soil was analyzed for total lead employing EPA Method 6010, Preparation Method EPA 3050.
[0044] Test samples of the base soil were prepared, weighing one half pound. Next, portions of dehydrated Product were weighed. Test samples contained equal amounts of Product and lead-contaminated soil. The Product was allowed to hydrate for approximately two minutes before being mixed with the contaminated soil. After two minutes of mixing the Remediating Composition with the contaminated soil, samples of the treated soil were sent out for laboratory analysis.
[0045] Data collected clearly showed that the Remediating Composition effectively removes a significant portion of lead contamination from soil. Experiments conducted since these tests indicate that if the hydration water was introduced into the mixture (soil washing), a greater lead removal level is expected to the soil.
[0046] Generally, the Remediating Composition of the present invention works through contact. The Remediating Composition (or Product) is mixed with contaminated material (hereafter, Mixture). The mixture is allowed to remain in contact for a time period. Generally, though, remediation by the Remediating Composition of the present invention is not as time based as it is based on amount of Remediating Composition used relative to the amount of material to be remediated. As a general rule of thumb, but not for the purpose of limitation, where the Remediating Composition and the Contaminated Material is mixed in a ratio of about 1 to about 1, substantially complete remediation of the Contaminated Material can be expected in about 4 to about 12 hours; in a ratio of about 2 to about 1, substantially complete remediation of most of the Contaminated material can be expected to be remediated in about 2 to about 4 hours; and in a ratio of about 3 to about 1, remediation of most of the contaminated material can be expected in about 1 to 2 hours. Further, when the combined Remediating Composition and Contaminated Material is left in-situ, it will continue to remediate indefinitely. The contamination remedied in this manner does not re-appear.
[0047] Where measurement and testing facilities and turn-around makes it possible, remediation efforts should include periodic remixing followed by testing, and, perhaps, addition of more Remediating Composition followed by testing until the level of the subject contaminant or contaminants is reduced to below toxic levels, or to levels permissible for either regular or controlled disposal.
[0048] To remediate a contaminated material in liquid form, it is recommended to mix about 1 part Contaminated Material and 1 part combined Remediating Composition/hydration. After 2 hours of contact in the mixture, retesting is recommended to measure contamination levels. Remediation is declared when the amount of contaminant detected is either undetectable or meets an outside standard. More Remediating Composition may be needed to reduce the contamination that remains to a level that complies with EPA (or other) standards. If needed, additional Remediating Composition may be mixed in, and additional time allowed. This routine may be repeated until the combination of Contaminated Material and Remediating Composition complies with the applicable EPA or other standard.
[0049] Contaminants addressed by the present invention are many. Some of the more important materials that may be remediated by the present invention include oily material. One example of using the inventive Remediating Composition comprised remediation of 5780 mg/kg TPH-GRO (C6-C10 volatile petroleum hydrocarbons) and 404000 mg/kg TPH-DRO (C10-C28 extractable Petroleum Hydrocarbons) by mixing the material combination in a 1:1 ratio by mass with the Remediating Composition. Testing thereafter showed TPH-GRO (volatile hydrocarbons) was reduced to 504 mg/kg (about 9% of the pretesting concentration) and TPH-DRO (extractable hydrocarbons) was decreased to 55900 mg/kg (about 14% of the pretesting concentration). These reductions in concentrations were clearly not the result of simple dilution. Additional trials showed similar results.
[0050] Generally, the approach for use of the inventive remediating material with fungible materials just described is similar to the use of the remediating material with liquids and with liquid/solid mixtures. However, because of the liquid phase in the liquid/solid mixtures, remediating material should be added slowly, with continual mixing and sequential testing. It is possible that remediation of some liquids will occur relatively quickly. Slow addition with periodic testing may, then, provide a more economical approach.