METHODS AND DEVICES FOR INTRODUCING SEPARATION LINES INTO TRANSPARENT BRITTLE FRACTURING MATERIALS
20200376603 ยท 2020-12-03
Assignee
Inventors
- Andreas ORTNER (Gau-Algesheim, DE)
- Clemens KUNISCH (Arnsheim, DE)
- Frank-Thomas Lentes (Bingen, DE)
- Jens Ulrich Thomas (Mainz, DE)
- Kurt Nattermann (Ockenheim, DE)
- Michael Kluge (Offenbach am Main, DE)
Cpc classification
Y02P40/57
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
B23K26/08
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0676
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0624
PERFORMING OPERATIONS; TRANSPORTING
B23K26/359
PERFORMING OPERATIONS; TRANSPORTING
C03B33/0222
CHEMISTRY; METALLURGY
B23K26/0736
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0608
PERFORMING OPERATIONS; TRANSPORTING
International classification
B23K26/359
PERFORMING OPERATIONS; TRANSPORTING
B23K26/067
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for preparing a workpiece for separation is provided that includes providing a workpiece that is transparent for light of a pulsed laser beam, splitting the laser beam into two partial beams using an optical system, directing both partial beams onto the workpiece, and moving the workpiece and the partial beams relative to one another. The partial beams are directed onto the workpiece incident at different angles to the normal of the irradiated surface and superimposed inside the workpiece such that the partial beams interfere with one another to form a sequence of intensity maxima inside the workpiece. The intensity at the intensity maxima is sufficiently high to modify the material of the workpiece so that a chain-like periodic pattern of material modifications is formed along a path defining a separation line.
Claims
1. A method for preparing a workpiece for separation, comprising: providing a workpiece that is transparent for light of a pulsed laser beam; splitting the pulsed laser beam into two partial beams; directing the two partial beams onto a surface of the workpiece incident at different angles to a normal of the surface and superimposed on one another inside the workpiece to form a sequence of intensity maxima inside the workpiece, the sequence of intensity maxima being lined up one after another along an overlapping area of the two partial beams, the intensity maxima being sufficient to modify a material of the workpiece so that a chain-like periodic pattern of material modifications is formed; and moving the workpiece and the two partial beams relative to one another such that the multitude of chain-like periodic patterns are produced along a separation line.
2. The method of claim 1, wherein the step of splitting the pulsed laser beam into two partial beams comprises directing the pulsed laser beam through an optical system.
3. The method of claim 1, wherein the two partial beams comprise a first partial beam that is a Bessel beam generated using an axicon and a second partial beam that is superimposed with the first partial beam in the area in which the first partial beam forms a line focus.
4. The method of claim 3, further comprising shaping the second partial beam in the form of a Gaussian beam.
5. The method of claim 1, wherein the step of splitting the pulsed laser beam comprises splitting so that intensities of the two partial beams differ by no more than a factor of 5.
6. A glass or glass ceramic workpiece, comprising: two surfaces with an inside therebetween; and a pattern of material modifications in the inside, each material modification being surrounded by a compression zone, wherein the pattern of material modifications comprises material modifications arranged in a regular sequence along a line.
7. The workpiece of claim 6, wherein the pattern of material modifications comprises material modifications arranged in adjacent lines one behind another to define a plane in the inside, and wherein the adjacent lines extend from one of the two surfaces to the other of the two surfaces.
8. The workpiece of claim 6, wherein the two surfaces are opposite faces of a sheet shaped workpiece.
9. The workpiece of claim 6, wherein the two surfaces are concentric lateral surfaces of a tubular shaped workpiece.
10. The workpiece of claim 6, comprising a thickness between the two surfaces of between 10 m and 50 mm, preferably between 1 mm and 20 mm.
11. The workpiece of claim 6, comprising a thickness between the two surfaces of between 1 mm and 20 mm.
12. The workpiece of claim 6, further comprising a quotient () of a total length of the material modifications and a thickness (d) between the two surfaces is:
13. A glass or glass ceramic workpiece, comprising: two surfaces with an inside therebetween; and a fracture edge between the two surfaces, the fractured edge comprising lines extending next to each other and being defined by material modifications that are arranged in a regularly chain-like pattern one behind the other with a center distance along the lines between 1 m and 100 m and a diameter from 0.2 m to 5 m, and which are each surrounded by a compression zone.
14. A device for preparing a workpiece for separation, comprising: a laser configured to generate a pulsed laser beam; an optical system positioned to receive the pulsed laser beam, configured to split the pulsed laser beam into two partial beams, and configured to direct the two partial beams them onto the workpiece; a positioning device configured to position the two partial beams incident on the workpiece at different angles relative to a normal of the surface and superimposed inside the workpiece so that the two partial beams interfere with one another to form, inside the workpiece, a sequence of intensity maxima successively arranged along an overlapping area of the two partial beams, wherein the laser is configured to generate the pulsed laser beam of sufficient intensity to modify a material of the workpiece so that a chain-like periodic pattern of material modifications is produced in the material, and wherein the positioning device is configured to move the laser and the workpiece relative to one another so that the chain-like periodic pattern of material modifications are generated along a separation line.
15. The device of claim 14, wherein the optical system is configured so that the two partial beams have intensities that differ by no more than a factor of 100.
16. The device of claim 14, wherein the optical system comprises a plano-convex axicon with a planar side and a convex side with a cone shape.
17. The device of claim 14, wherein the optical system comprises a central opening and a concave-convex axicon, the concave-convex axicon having a convex side with a truncated cone shape and a concave side with a truncated cone shape, wherein the central opening is configured to direct the pulsed laser beam through the concave-convex axicon.
18. The device of claim 14, wherein the optical system comprises a biconvex axicon having two convex sides and a central area between the two convex sides that is filled with air, wherein the two convex sides each have a truncated cone shape but with different angles of inclination.
19. The device of claim 14, wherein the optical system comprises three plano-convex axicons each having a convex side, wherein the convex sides have a truncated cone shape.
20. The device of claim 14, wherein the optical system comprises a concentric ring grating.
21. The device of claim 14, wherein the optical system comprises three axicons in the form of concentric ring gratings, with at least two of the three axicons having central planar areas.
22. The device of claim 14, wherein the optical system comprises: an arrangement configured to generate a ring beam from the pulsed laser, the ring beam having a beam profile that has an infinitesimal intensity on a beam axis and a maximum intensity along a circular ring around the beam axis; and a frustoconical axicon arranged downstream, in a beam direction, of the arrangement the frustoconical axicon, wherein power fractions of the central beam and the ring beam are adjustable through a ratio of a frustoconical surface of the axicon to a beam diameter of the ring beam incident on the axicon.
23. The device of claim 14, wherein the optical system comprises an axicon triplet consisting of three axicons arranged one behind the other, wherein the three axicons comprise a first axicon, in a beam direction, that generates a divergent ring beam, a second axicon that is configured to parallelize the divergent ring beam to a parallelized ring beam, and a third axicon that is configured to convert the parallelized ring beam a converging ring beam.
Description
BRIEF DESCRIPTION OF THE FIGURES
[0033] The invention will now be described in more detail with reference to the accompanying figures in which the same reference numerals denote the same elements, and wherein:
[0034]
[0035]
[0036]
[0037]
[0038]
[0039]
[0040]
[0041]
[0042]
[0043]
[0044]
[0045]
[0046]
[0047]
[0048]
[0049]
[0050]
[0051]
[0052]
[0053]
[0054]
[0055]
[0056]
[0057]
DETAILED DESCRIPTION
[0058]
[0059] The multiplicity of lines 18 extending parallel to one another are produced by moving the workpiece 2, by a positioning device, perpendicular to the irradiation direction of the partial beams. Coordination between the pauses between the pulses or bursts of the laser that is employed as the radiation source and the relative velocity between the workpiece and the device of the invention allows to predefine the horizontal spacing of the lines 9 of modifications 8.
[0060] In an alternative embodiment, the workpiece is moved in the direction of the optical axis during the modification process by the laser, which causes a continuous material modification. This modification may subsequently be opened by etching. This creates a filamentary channel with a diameter of less than 200 mm, preferably less than 100 m, more preferably less than 50 m, and most preferably less than 20 m in thick glasses.
[0061] The modifications 8 are arranged with a horizontal spacing 31 and a vertical spacing 32 to each other. The vertical spacing 32 of the modifications 8 along a line 18 ranges from 1 m to 100 m. Since the modifications are the result of interference of the two partial beams 41 and 42, the vertical spacing 32 of the modifications 8, i.e. the density of the modifications 8 along line 18 can be defined by adjusting the energy ratios between the zero and first order interference areas. If the first order intensity is increased compared to the zero order intensity, the vertical spacing 32 decreases. This results in a filamentary modification channel that can be opened by etching the material. The centers of the modifications 8 have a vertical center distance 33. The diameter of the modifications is in a range from 0.2 m to 5 m. The diameter refers to the channels themselves. The stress zones around the channels may extend further into the material.
[0062] Overall, a regular pattern of material compression areas and depletion areas is produced in the material of the workpiece, with tension zones overlapping in such a way and being so strong that cracks spread along the plane of the workpiece and allow for later breaking along the plane.
[0063] Instead of producing linear parallel modifications, the method of the invention may also be used to produce inner cutouts with regular or irregular contours in sheet-like substrates. This may be achieved with or without producing auxiliary cuts.
[0064] Furthermore, the method of the invention can be used for inline severing beads of float glass, downdraw glass and overflow fusion glass, in the cold and hot zones (glass temperature T<annealing point). In the case of downdraw glass and float glass it is possible to treat glasses with a larger thickness. Changes in the width of the glass ribbon are compensated by mounting the optical system that modifies the laser beam on a displaceable bridge, as a unit. This is possible due to the fact that an arbitrarily long dashed focus can be generated. A change in thickness can therefore be compensated for alone by the length of the focus, without tracking or readjustment, provided the focus is longer than the thickness of the downdraw glass, overflow fusion glass, or float glass.
[0065] The severing of the beads or cutting to size of the ribbon in the longitudinal section may also be effected in a roll-to-roll process. The glass ribbon may also have coatings, such as protective coatings.
[0066] The modifications 8 are shown in
[0067] In the figures described below, the direction of incidence of the partial beams 41, 42 is always denoted by z, which corresponds to the direction of incidence 51 of the dashed focus in
[0068]
[0069]
[0070] The same pattern is shown in
[0071]
[0072] As shown in
[0073]
[0074] Without being limited to a special configuration of the optical system, the laser light is particularly preferably split up in such a way that the two partial beams, i.e. in particular the ring beam and the central beam, have comparable intensities. Comparable intensities is understood to mean that the intensities differ by no more than a factor of 5, preferably by no more than a factor of 3, most preferably by no more than a factor of 1.5. In this way, a strong intensity variation is achieved in the interference pattern of the partial beams that are superimposed inside the workpiece.
[0075] In order to produce the Bessel beam, a ring beam is formed into the partial beam 41, for example by means of an axicon, which ring beam then forms a line-shaped Bessel focus, which in turn is caused to interfere with a central beam, i.e. the second partial beam 42, in the elongated interference area 43. The length L (66) of interference area 43 is defined by the diameter D.sub.r of the ring beam and its opening angle 2 (reference numeral 64): L=D.sub.r/tan .
[0076]
[0077] Essentially, the opening angle in the material (reference numeral 71) is smaller than the opening angle in air, according to the law of refraction:
sin =n sin .
TABLE-US-00001 Half opening angle in air 9.7 Half opening angle in the material 6.7 Laser wavelength 1064 nm Longitudinal periodicity 157 m
[0078] The situation of
[0079] The periodicity of distance 33 of the intensity maxima as produced by the interference is determined by the central wavelength of the beam source and the opening angle of the ring beam 2 according to P=2/sin.sup.2 .
[0080] According to a preferred embodiment of the invention, the interference zone is formed in such a way, by suitable choice of the laser wavelength and the beam parameters of the partial beams 41, 42 (in particular the opening angle), that the quotient of the sum of individual lengths l.sub.i of all modifications i, measured in the beam direction and the thickness d of the substrate is greater than 0.5 according to a preferred embodiment, preferably 0.7, most preferably >0.9.
[0081] According to one embodiment of the invention, the workpiece 2 according to the invention therefore has material modifications 17 along a line 18, for which the following applies:
with k=0.5, preferably k=0.7, more preferably k=0.9, most preferably k=0.95.
[0082]
[0083] The ratio of beam width 48 to the width of the planar truncated face determines the power ratio of the two partial beams 41 and 42. This ratio can preferably be selected such that the partial beams preferably have a similar power as far as possible. For example, in one embodiment of the invention, the ratio of beam width 48 to planar truncated face can be selected such that the power ratio of the partial beams 41, 42 ranges from 0.75 to 1.25. This ratio can be predetermined by the shape and arrangement of the involved optical components, in particular by the shape of the truncated side of the axicon.
[0084] In the embodiment of optical system 6 according to
[0085] In the embodiment of optical system 6 according to
[0086] A convex-concave axicon 93 is used in the embodiment of optical system 6 according to
[0087] In the embodiment of optical system 6 according to
[0088] For the embodiment of optical system 6 according to
[0089] In the embodiment of optical system 6 according to
[0090] In a front view of the glass body 81 as seen in the beam direction, the highest points of the trenches appear as concentric rings (
[0091] For the embodiment of optical system 6 according to
[0092] The incident laser beam first impinges on the first axicon 81a by which it is converted into a ring-shaped beam 111 that extends obliquely to the optical axis. The second axicon 81b converts the beam 111 into a tubular partial beam 112, which in turn is converted into a partial beam 41 by the third axicon or glass body 81c. For further shaping the central partial beam 42, a beam converter 83 is arranged between the second glass body 81b and the third glass body 81c. Beam converter 83 may, for example, be a telescope or a beam attenuator. As in the previously described embodiments of the optical system 6, partial beams 41 and 42 interfere in an interference area 43 which is repeated periodically along the further beam path.
[0093] The device described above by way of various embodiments of the optical system 6 is used to perform a method for preparing a workpiece 2 for separation. Once a workpiece 2 has been provided, which is transparent to the light of a pulsed laser beam, the laser beam is split into at least two partial beams 41, 42 by the optical system 6. Both partial beams 41, 42 are directed onto the workpiece 2 in such a way that the partial beams 41 and 42 are incident on the workpiece 2 at different angles to the normal of the irradiated surface 21 and are superimposed in the interior of the workpiece 2. The partial beams 41, 42 overlap or interfere with one another in such a way that a sequence of intensity maxima 45 is formed inside the workpiece 2, which are lined up one after the other along the overlapping area 43 of the partial beams 41, 42. The intensity at the intensity maxima 45 is sufficiently high to modify the material of the workpiece 2 so that a chain-like periodic pattern 9 of material modifications 8 is produced, while the workpiece 2 and the partial beams 41, 42 are moved relative to one another such that a multitude of chain-like periodic patterns 9 of material modifications 8 are produced along a path defining a separation line 11. In a later step, the workpiece 2 can be divided into multiple pieces by mechanical breaking along the separation line 11.
[0094] The exemplary embodiments of
[0095] The aforementioned exemplary embodiments furthermore have in common that the second partial beam is a parallel beam. According to a further preferred embodiment it is therefore furthermore contemplated that the second partial beam 42 is shaped as a parallel beam. Other variants are also conceivable in this respect. For example, two axicons with different tip angles could generate the partial beams. In this case, two Bessel-like beams or two conical beams having different convergence angles would be caused to interfere. As can also be seen from the figures, partial beams 41, 42 that are collinear to one another are generally preferred according to a further embodiment of the invention.
[0096]
[0097] In a further embodiment (
[0098]
[0099] A further embodiment is resulting (
[0100] The examples of
[0101] The exemplary embodiments of
[0102] In order to be able to estimate the influence of the individual optical components on the intensity distribution in the focus, the 10 ps pulse (4 pulses per burst) of a Pharos UKP laser (1030 nm, 100 kHz repetition rate) with a mean beam power of 100 mW is successively imaged, in variant 1 initially only by one axicon, in variant 2 by a combination of two phase plates and one axicon, and in variant 3 by a combination of two phase plates and three axicons (in which case the middle axicon is an truncated axicon, as described above, and all axicons have a roof angle of 20) and the intensity distribution in the focus is measured using a camera (e.g. of the Coherent Lasercam HR type) with a microscope lens fitted thereto, by continuously moving the camera through the focus area along the optical axis while recording the lateral intensity distribution of the laser beam in the focus. The video recorded in this way allows to determine the intensity distribution along the optical axis in the focus area, in relative units.
[0103]
[0104]
LIST OF REFERENCE NUMERALS
[0105] 2 Workpiece [0106] 3 Laser [0107] 4 Laser beam [0108] 6 Optical system [0109] 8 Material modification [0110] 9 Periodic pattern of 8 [0111] 11 Separation line [0112] 13 Positioning device [0113] 16 Compression zone [0114] 17 Fracture edge [0115] 18 Parallel lines [0116] 19 Plane with material modifications [0117] 41, 42 Partial beams [0118] 41a, 41b, 42a, 42b Partial beams when using multiple axicons [0119] 21 Surface of 2 [0120] 22, 24 Surfaces of 2 [0121] 31 Horizontal spacing of modifications [0122] 32 Vertical spacing of modifications [0123] 33 Vertical center distance of modifications [0124] 43 Overlap or interference area of 41, 42 [0125] 43a, 43b Overlap or interference area when using multiple axicons [0126] 45 Intensity maximum [0127] 47 Diameter of 42 [0128] 48 Diameter of laser beam [0129] 63 Diameter of 41 [0130] 64 Opening angle of 41 [0131] 66 Length of 45 [0132] 51 Direction of incidence of dashed focus [0133] 71 Opening angle of 41 in the material of 2 [0134] 81 Glass body of phase mask [0135] 81a, 81b, 81c Axicons in the form of concentric ring gratings [0136] 82 Trench height of phase mask [0137] 83 Beam converter [0138] 91 Plano-convex axicon [0139] 91a, 91b, 91c Plano-convex axicons when using multiple axicons [0140] 92 Plano-convex axicon with conical structure on the planar side [0141] 93 Convex-concave axicon [0142] 94 Biconvex axicon [0143] 95 Planar side of 91 [0144] 96 Convex side of 91 [0145] 98 Conical structure on the planar side of 97 [0146] 99 Convex side of 97 [0147] 100 Planar side of 92 [0148] 101 Convex side of 93 [0149] 102 Concave side of 93 [0150] 103 Central opening of 93 [0151] 104a, 104b Central beams when using 92 [0152] 105a, 105b Interference areas when using 92 [0153] 106 First convex side of 94 [0154] 107 Second convex side of 94 [0155] 108 Central area of 94 [0156] 109 Planar side of 81 [0157] 110a, 110b Central planar areas of 81 [0158] 111 Partial beam [0159] 120 Diffractive component [0160] 121 Imaging lens [0161] 122 Objective lens [0162] 123 Focal length of 121 [0163] 124 Focal length of 122 [0164] 125 Fourier plane of 4f setup [0165] 130 First axicon arrangement [0166] 131 First axicon of 130 [0167] 132 Second axicon of 130 [0168] 135 Third axicon [0169] 140 Second axicon arrangement [0170] 141 First axicon of 140 [0171] 142 Second axicon of 140 [0172] 145 Plano-concave axicon [0173] 148 Planar surface of 145 [0174] 150 Arrangement for generating a donut beam [0175] 151 First spiral phase plate of 150 [0176] 152 Second spiral phase plate of 150 [0177] 165 Dashed focus [0178] 170 Donut beam [0179] 180 Ring beam [0180] 190 Central beam