Barrier tape for seaming and repair of barrier sheets
10850483 ยท 2020-12-01
Assignee
Inventors
- Gary Kolbasuk (Sioux Falls, SD, US)
- Tom Stoebner (Sioux Falls, SD, US)
- Dan Smith (Sioux Falls, SD, US)
Cpc classification
B32B2405/00
PERFORMING OPERATIONS; TRANSPORTING
B32B2264/0207
PERFORMING OPERATIONS; TRANSPORTING
B32B2556/00
PERFORMING OPERATIONS; TRANSPORTING
B32B2272/00
PERFORMING OPERATIONS; TRANSPORTING
B32B2274/00
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B27/306
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/246
PERFORMING OPERATIONS; TRANSPORTING
B32B2264/104
PERFORMING OPERATIONS; TRANSPORTING
International classification
E02D31/00
FIXED CONSTRUCTIONS
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B27/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A barrier tape comprises a barrier section comprising one or more barrier layers and one or more adhesive layers adhered to a face of the barrier section. The barrier tape can be used to join together adjacent barrier sheets or to patch a breach in a barrier sheet to form a barrier assembly.
Claims
1. A barrier assembly comprising: a flat or substantially flat first barrier film; and one or more pieces of barrier tape affixed to the first barrier film, each piece of the barrier tape comprising: a barrier section comprising one or more inner polar tape layers each formed predominantly from ethylene vinyl alcohol and a pair of outer non-polar tape layers each formed predominantly from polyethylene, wherein a first of the pair of outer non-polar tape layers is positioned on a first side of the one or more inner polar tape layers and a second of the pair of outer non-polar tape layers is positioned on a second side of the one or more inner polar tape layers; a pair of tape tie layers each formed predominantly from polyethylene grafted with maleic anhydride, each of the pair of tape tie layers being positioned between the one or more inner polar tape layers and a corresponding one of the pair of outer non-polar tape layers; and one or more adhesive layers adhered to a face of the barrier section.
2. The barrier assembly of claim 1, wherein the first barrier film comprises one or more polar film layers and one or more non-polar film layers.
3. The barrier assembly of claim 2, wherein each of the one or more non-polar film layers comprises a polyolefin and each of the one or more polar film layers comprises ethylene vinyl alcohol.
4. The barrier assembly of claim 1, further comprising a flat or substantially flat second barrier film at least partially overlapping the first barrier film, wherein the one or more pieces of barrier tape join the first barrier film to the second barrier film.
5. The barrier assembly of claim 4, wherein the second barrier film overlaps the first barrier film along a lateral seam, and wherein the one or more pieces of barrier tape join the first and second barrier films along the lateral seam.
6. The barrier assembly of claim 4, wherein the first barrier film comprises a breach therethrough and the second barrier film comprises a barrier film patch covering the breach such that the seam substantially surrounds the breach, wherein the one or more pieces of barrier tape joins the barrier film patch to the first barrier film around a seam.
7. The barrier assembly of claim 4, wherein the second barrier film provides a barrier to water vapor and at least one of methane, radon, and volatile organic compounds.
8. The barrier assembly of claim 4, wherein the second barrier film comprises one or more polar film layers and one or more non-polar film layers.
9. The barrier assembly of claim 8, wherein each of the one or more non-polar film layers comprises a polyolefin and each of the one or more polar film layers comprises ethylene vinyl alcohol.
10. The barrier assembly of claim 4, wherein the second barrier film comprises: one or more inner polar film layers each formed predominantly from ethylene vinyl alcohol; a pair of outer non-polar film layers each formed predominantly from polyethylene, wherein a first of the pair of outer non-polar film layers is positioned on a first side of the one or more inner polar film layers and a second of the pair of outer non-polar film layers is positioned on a second side of the one or more inner polar film layers; and a pair of film tie layers each formed predominantly from polyethylene grafted with maleic anhydride, each of the pair of film tie layers being positioned between the one or more inner polar film layers and a corresponding one of the pair of outer non-polar film layers.
11. The barrier assembly of claim 4, wherein one the flat or substantially flat second barrier film is configured for use in a building construction application or as a barrier geomembrane.
12. The barrier assembly of claim 4, wherein the flat or substantially flat second barrier film is configured as an underslab vapor barrier.
13. A barrier assembly comprising: a flat or substantially flat first barrier film; and one or more pieces of barrier tape affixed to the first barrier film; wherein the first barrier film comprises; one or more inner polar film layers each formed predominantly from ethylene vinyl alcohol; a pair of outer non-polar film layers each formed predominantly from polyethylene, wherein a first of the pair of outer non-polar film layers is positioned on a first side of the one or more inner polar film layers and a second of the pair of outer non-polar film layers is positioned on a second side of the one or more inner polar film layers; and a pair of film tie layers each formed predominantly from polyethylene grafted with maleic anhydride, each of the pair of film tie layers being positioned between the one or more inner polar film layers and a corresponding one of the pair of outer non-polar film layers; and wherein each of the one or more pieces of the barrier tape comprises: a tape barrier section comprising one or more polar barrier layers and one or more non-polar barrier layers; and one or more adhesive layers adhered to a face of the barrier section.
14. The barrier assembly of claim 13, wherein the barrier section of each of the one or more pieces of barrier tape and the first barrier film provides a barrier to water vapor and at least one of methane, radon, and volatile organic compounds.
15. The barrier assembly of claim 13, wherein each of the one or more non-polar barrier layers comprises a polyolefin and each of the one or more polar barrier layers comprises ethylene vinyl alcohol.
16. The barrier assembly of claim 13, wherein the flat or substantially flat first barrier film is configured for use in a building construction application or as a barrier geomembrane.
17. The barrier assembly of claim 13, wherein the flat or substantially flat first barrier film is configured as an underslab vapor barrier.
18. The barrier assembly of claim 13, further comprising a flat or substantially flat second barrier film at least partially overlapping the first barrier film, wherein the one or more pieces of barrier tape join the first barrier film to the second barrier film.
19. A barrier assembly comprising: a flat or substantially flat first barrier film with a breach therethrough; one or more pieces of barrier tape affixed to the first barrier film and covering the breach, each piece of the barrier tape comprising: a barrier section comprising one or more inner polar tape layers each formed predominantly from ethylene vinyl alcohol and a pair of outer non-polar tape layers each formed predominantly from polyethylene, wherein a first of the pair of outer non-polar tape layers is positioned on a first side of the one or more inner polar tape layers and a second of the pair of outer non-polar tape layers is positioned on a second side of the one or more inner polar tape layers; a pair of tape tie layers each formed predominantly from polyethylene grafted with maleic anhydride, each of the pair of tape tie layers being positioned between the one or more inner polar tape layers and a corresponding one of the pair of outer non-polar tape layers; and one or more adhesive layers adhered to a face of the barrier section.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1)
(2)
(3)
(4)
(5)
(6)
(7)
DETAILED DESCRIPTION
(8) In the following Detailed Description, reference is made to the accompanying drawings which form a part hereof. The drawings show, by way of illustration, specific examples in which the barrier tapes described herein can be practiced. These examples are described in sufficient detail to enable those skilled in the art to practice, and it is to be understood that other embodiments can be utilized and that structural changes can be made without departing from the scope of the present disclosure. Terms indicating direction, such as front, rear, left, right, up, and down, are generally used only for the purpose of illustration or clarification and are not intended to be limiting. The following Detailed Description is not to be taken in a limiting sense, and the scope of the present disclosure is defined by the appended claims and their equivalents.
(9) This disclosure describes barrier tapes that can be used for joining adjacent barrier sheets together at a seam, e.g., so that the barrier sheets can cover a larger area, or for patching holes in a barrier sheet. Examples of barrier sheets that can be used with the barrier tapes described herein include, but are not limited to, underslab barrier sheets, such as the barrier sheet sold under the trademark VAPOR BLOCK PLUS sold by Raven Industries, Inc., Sioux Falls, S. Dak., USA, such as the VAPOR BLOCK PLUS 20; barrier geomembranes, row mulch barriers; external wall vapor barriers, and the like. The barrier tapes described herein can include one or more barrier layers that can retard migration of water vapor and other compounds, such as methane or radon, in substantially the same way that the barrier sheets that the barrier tape is seaming or repairing.
(10)
(11) The barrier section 12 includes one or more layers configured to provide a barrier to one or more compounds or compositions to which the barrier tape 10 is intended to provide a barrier. In an example, the barrier section 12 includes one or more generally non-polar layers, such as one or more non-polar layers 18 formed predominantly from a non-polar material, such as a polyolefin, for example polyethylene (PE) or polypropylene (PP). In an example, each of the one or more non-polar layers 18 can be formed entirely or substantially entirely with polyethylene and will, therefore, be referred to herein as a polyethylene layer 18 for the sake of brevity. The use of a generally non-polar material, such as polyethylene, can allow the barrier tape 10 to provide a barrier to polar materials, such as water (H.sub.2O) or polar pollutants, either alone or dissolved in water or another polar solvent. Non-polar materials, such as polyethylene, are known, however, to have generally poor barrier properties with respect to gases, such as oxygen gas (O.sub.2) or to non-polar materials, such as benzene (C.sub.6H.sub.6), radon (Rn), methane (CH.sub.4), VOCs, and other non-polar pollutants. Polyolefins, such as polyethylene can also provide for relatively high impact strength and resistance to tearing, in particular if a relatively low-density polyolefin is used. Examples of low-density polyolefins that can be used include, but are not limited to, one or more of low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), metallocene linear low-density polyethylene (mLLDPE), very-low density polyethylene (VLDPE), or ultra-low density polyethylene (ULDPE) plastomer polymers, or polyolefins other than polyethylene with similar densities.
(12) In order to also provide a barrier to non-polar materials or gases, such as non-polar pollutants, the barrier tape 10 also includes one or more generally polar layers, such as one or more polar layers 20 formed predominantly from a polar material capable of providing a barrier to non-polar compounds, such as ethylene vinyl alcohol (EVOH), nylon, polyester, polyethylene terephthalate (PET), poly-vinyl alcohol (PVOH), or polyvinylidene chloride (PVDC). In an example, each of the one or more polar layers 20 can be formed entirely or substantially entirely with EVOH and will, therefore, be referred to herein as an EVOH layer 20 for the sake of brevity. However, it will be understood that the one or more polar layers 20 could comprise multiple layers of different materials, such as one or more nylon layers adjacent to one or more EVOH layers. In an example, the one or more polar layers 20 can comprise two outer nylon layers with one or more EVOH layers sandwiched between the outer nylon layers, or vice versa, two outer EVOH layers that sandwich one or more nylon layers. The use of a generally polar material, such as EVOH or nylon, can allow the barrier tape 10 to provide a barrier to non-polar materials, including non-polar pollutants such as benzene, radon, and methane. Polar materials, such as EVOH or nylon, are known, however, to have poor barrier properties with respect to polar materials, such as water vapor. The combination of the one or more non-polar layer 18, such as the polyethylene layers 18, and the one or more polar layers 20, such as one or more EVOH layers 20, can allow the barrier tape 10 to provide a barrier to both polar materials, including water vapor and polar pollutants, and non-polar materials, including non-polar pollutants such as benzene, radon, methane, and other VOCs.
(13) Because the one or more non-polar layers 12 are formed from a non-polar compound, e.g., a polyolefin, such as polyethylene, and the one or more polar layers 20 are formed from a polar compound, e.g., EVOH, a non-polar layer 18 typically will not bond or be joined directly with a polar layer 20. Therefore, the barrier section 12 of the barrier tape 10 can also include one or more tie layers 22 that can bond to both the non-polar layers 18 and the polar layers 20. The composition of each tie layer 22 can depend on the corresponding composition of the non-polar layer 18 and the polar layer 20 that the tie layer 22 is bonding together. The composition of a particular tie layer 22 can be chosen so that it can form a mechanical bond or chemical bond, or both, with both the non-polar layer 18 and the polar layer 20. For example, wherein the one or more non-polar layers 18 comprise polyethylene and the one or more polar layers 20 comprise EVOH, the one or more tie layers 22 can comprise polyethylene grafted with maleic anhydride (MA). The polyethylene of the tie layer 22 can directly bond to the polyethylene so that the tie layer 22 will be bonded to the polyethylene layer 18. The maleic anhydride grafts can form an ester bond with the EVOH in the EVOH layer 20 so that the tie layer 22 will be bonded to the polar layer 20, e.g., so that the barrier section 12 forms a single structure with all layers 18, 20, 22 bonded together.
(14) In an example, shown in
(15) In an example, the barrier section 12 can have an overall thickness of from about 2 mils (about 0.05 millimeters (mm)) to about 40 mils (about 1 mm), such as from about 5 mils (about 0.13 mm) to about 20 mils (about 0.5 mm), such as from about 7 mils (0.18 mm) to about 10 mils (about 0.25 mm). In an example, the total thickness of the one or more polar layers 20 (e.g., the thickness of the single polar layer 20 shown in
(16) In an example, the one or more non-polar layers 18 can comprise a polyolefin having a base density of from about 0.85 grams per cubic centimeter (g/cm.sup.3) to about 0.97 g/cm.sup.3, such as from about 0.875 g/cm.sup.3 to about 0.932 g/cm.sup.3, for example from about 0.91 g/cm.sup.3 to about 0.92 g/cm.sup.3, such as from about 0.912 g/cm.sup.3 to about 0.920 g/cm.sup.3. However, the overall density of the non-polar layers 18 can be varied outside of these ranges, for example with the addition of additives, such as stabilizers, colorants, or fillers, which can increase the overall density of the layer 18. In an example, the one or more polar layers 20 can comprise a polar material, such as EVOH or nylon, having a base density from about 1 g/cm.sup.3 to about 1.5 g/cm.sup.3, such as from about 1.1 g/cm.sup.3 to about 1.25 g/cm.sup.3, such as about 1.17 g/cm.sup.3. However, like the one or more non-polar layers 18, the overall density of the one or more polar layers 20 can be altered by the addition of stabilizers, colorants, or fillers. In an example, the tie layers 22 can comprise a material having a base density of from about 0.85 g/cm.sup.3 to about 1 g/cm.sup.3, such as from about 0.875 g/cm.sup.3 to about 0.95 g/cm.sup.3, for example about 0.91 g/cm.sup.3. As mentioned above, additives can be added to each layer 18, 20, 22, if desired. Additives can include stabilizers, such as phosphate stabilizers or phenolic stabilizers. In some examples, a UV or other light stabilizer can be added to one or more layers 18, 20, 22 of the barrier section 12 to protect the barrier section 12 in the event that the barrier tape 10 is to be left out in the sun for an extended period of time.
(17) Fillers can be added to any of the layers 18, 20, 22, for example to modify the density of the layer 18, 20, 22. e.g., to increase or decrease the overall density, to reduce the overall cost of a layer 18, 20, 22, or to improve a material property such as toughness. Examples of fillers include, but are not limited to, calcium carbonate or ground-up recycled materials, such as recycled rubber or other plastics.
(18) The barrier properties of the barrier section 12 can be similar to those of the barrier sheets that the barrier tape 10 is intended to seam or repair. For example, the barrier tape 10 can be specified for use with underslab barrier sheets, which are often specified based on barrier properties with respect to the transmission of water vapor, radon, methane, VOCs, and oxygen.
(19) The transmission of water vapor through the barrier section 12 can be defined as a water vapor transmission rate (WVTR), for example as defined by ASTM standard test method E96 or ASTM standard test method F1249. In an example, the barrier section 12 has a WVTR of about 0.004 grams per hour per square meter (g/hr-m.sup.2) or less, such as about 0.003 g/hr-m.sup.2 or less, for example about 0.0028 g/hr-m.sup.2 or less.
(20) The transmission of radon (Rn) through the barrier section 12 can be defined as a diffusion coefficient for radon, for example as defined by the K124/02/95 test method accredited by the Czech Accreditation Institute. In an example, the barrier section 12 can have a diffusion coefficient for radon of no more than 1.510.sup.13 square meters per second (m.sup.2/s) (e.g., 1.510.sup.13 m.sup.2/s or less, such as 1.310.sup.13 m.sup.2/s or less, for example 1.110.sup.13 m.sup.2/s or less.
(21) The transmission of methane (CH.sub.4) through the barrier section 12 can be defined as the permeability coefficient of the material to methane, also referred to as methane permeance, for example as defined by ASTM standard test method D1434. In an example, the barrier section 12 has a methane permeance of 210.sup.10 square meters per day per atmosphere (m.sup.2/day.Math.atm) or less, such as 1.710.sup.10 m.sup.2/day.Math.atm or less. Barrier properties of the barrier section 12 with respect to methane can also be defined as the gas transmission rate (GTR). In an example, the gas transmission rate is 0.4 milliliters per square meter per day per atmosphere (ml/m.sup.2.Math.day.Math.atm) or less, such as 0.32 ml/m.sup.2.Math.day.Math.atm or less.
(22) The transmission of volatile organic compounds, such as benzene, ethyl benzene, toluene, or xylene, through the barrier section 12 can be defined as a permeability coefficient for each compound. In an example, the barrier section 12 has a permeability coefficient for benzene of 1010.sup.13 m.sup.2/s or less, such as about 710.sup.13 m.sup.2/s or less, for example about 610.sup.13 m.sup.2/s, such as about 510.sup.13 m.sup.2/s or less, for example about 410.sup.13 m.sup.2/s or less. In an example, the barrier section 12 has a permeability coefficient for toluene of about 1510.sup.13 m.sup.2/s or less, such as about 1010.sup.13 m.sup.2/s or less, for example about 810.sup.13 m.sup.2/s or less. In an example, the barrier section 12 has a permeability coefficient for ethyl benzene of about 3510.sup.13 m.sup.2/s or less, such as about 3010.sup.13 m.sup.2/s or less, for example about 2710.sup.13 m.sup.2/s or less. In an example, the barrier section 12 has a permeability coefficient for xylene (e.g., a mix of ortho-, meta-, and para-xylenes) of about 3010.sup.13 m.sup.2/s or less, such as about 2510.sup.13 m.sup.2/s or less, for example about 2110.sup.13 m.sup.2/s or less.
(23) The transmission of oxygen gas (O.sub.2) through the barrier section 12 can be defined as the O.sub.2 transmission rate, for example as described by ASTM standard test D3985. In an example, the barrier section 12 can have an O.sub.2 transmission rate of about 2 cubic centimeters per square meter per day (cm.sup.3/m.sup.2.Math.day) or less, such as about 1.5 cm.sup.3/m.sup.2.Math.day or less, for example about 1 cm.sup.3/m.sup.2.Math.day or less, such as 0.9 cm.sup.3/m.sup.2.Math.day or less. The transmission of O.sub.2 through the barrier section 12 can also be defined as the O.sub.2 permeation, for example as described by ASTM standard test D3985. In an example, the O.sub.2 permeation can be about 25 cubic centimeter mils per square meter per day (cm.sup.3.Math.mil/m.sup.2.Math.day) or less, such as about 20 cm.sup.3.Math.mil/m.sup.2.Math.day or less, for example about 15 cm.sup.3.Math.mil/m.sup.2.Math.day or less, such as about 10 cm.sup.3.Math.mil/m.sup.2.Math.day or less, for example about 9 cm.sup.3.Math.mil/m.sup.2.Math.day or less.
(24) In an example, these permeability coefficients for the barrier section 12 can be compared to a barrier sheet made just from polyethylene (e.g., a LLDPE barrier), which can have a permeability coefficient as high as 60010.sup.13 m.sup.2/s for benzene, as high as 80010.sup.13 m.sup.2/s for toluene, as high as 110010.sup.13 m.sup.2/s for ethyl benzene, and as high as 90010.sup.13 m.sup.2/s for xylene (e.g., a mix of ortho-, meta-, and para-xylenes), and an O.sub.2 transmission rate of greater than 200 cm.sup.3/m.sup.2.Math.day.
(25) In an example, the barrier tape 10 can be relatively resistant to tearing. In an example, the barrier tape 10 has a tear resistance, such as is measured by tongue tear testing under ASTM standard test D751, of at least about 15 Newtons (about 3.4 pounds force (lb.sub.f)), such as at least about 20 Newtons (about 4.5 lb.sub.f), for example at least about 25 Newtons (about 5.6 lb.sub.1), such as at least about 25.8 Newtons (about 5.8 lb.sub.f), for example about 26.2 Newtons (about 5.88 lb.sub.f).
(26) The one or more adhesive layers 14 can comprise any adhesive material that will adhere to the barrier section 12. e.g., to an outer layer of the barrier section 12 such as one of the non-polar layers 18 or one of the polar layers 20. In an example, the adhesive material of the one or more adhesive layers 14 can comprise an adhesive that relatively strongly adheres to polyolefins of the non-polar layers 18, such as polyethylene. In an example, the one or more adhesive layers 14 can comprise a pressure sensitive adhesive, such as an acrylic-based pressure sensitive adhesive, a synthetic elastomeric pressure sensitive adhesive, or a rubber-based pressure sensitive adhesive. However, other adhesives can be used without varying from the scope of the present disclosure.
(27) The adhesive layer 14 can have an adhesive strength. e.g., an adhesion value as measured by the peel adhesion testing under the Pressure Sensitive Tape Council (PSTC) standard test PSTC 101, of at least about 30 ounces-force per inch (oz.sub.f/in.) to steel, such as at least about 35 oz.sub.f/in., for example at least about 40 oz.sub.f/in., such as at least about 50 oz.sub.f/in, for example at least about 55 oz.sub.f/in., such as at least about 60 oz.sub.f/in., for example at least about 64 oz.sub.f/in., such as at least about 65 oz.sub.f/in., for example at least about 70 oz.sub.f/in., such as at least about 80 oz.sub.f/in., for example at least about 90 oz.sub.f/in., such as at least about 100 oz.sub.f/in., for example at least about 125 oz.sub.f/in., such as at least about 140 oz.sub.f/in., for example at least about 144 oz.sub.f/in., such as at least 150 oz.sub.f/in. (with all adhesion values being measured for the adhesive to steel).
(28) The thickness of the one or more adhesive layers 14 can be selected to be large enough so that the one or more adhesive layers 14 provide adequate adhesion to the barrier section 12 and to the surface to which the barrier tape 10 is being adhered, including the ability to properly adhere to more irregular surfaces (such as those that can be present on a rough surface such as concrete). However, in some examples, the thickness of the one or more adhesive layers 14 can be selected to not be so large as to overly adversely affect the overall barrier properties of the barrier tape 10, e.g., because the adhesive layer 14 can provide a pathway through the adhesive through which materials can diffuse or permeate. In an example, the thickness of the one or more adhesive layers 14 can be from about 2 mils (about 0.05 mm) to about 20 mils (about 0.5 mm), such as from about 5 mils (about 0.13 mm) to about 17 mils (about 0.43 mm).
(29) The barrier tape 10 can have a width that is large enough to provide for seaming between adjacent barrier sheets (as described below with respect to
(30) As mentioned above, the one or more adhesive layers 14 allow the barrier tape 10 to be adhered to another structure. For example,
(31) The barrier tape 30 can be used for seaming between either barrier sheet 32A, 32B shown in
(32)
(33) The barrier tapes described above can also be used to repair damaged barrier sheets, for example by patching tears or holes in a barrier sheet.
(34)
(35) As noted above, the hole or other breach 62 shown in
(36)
(37) The barrier properties of the barrier section 92 will act to maintain the barrier to water vapor and at least one of methane, radon, and VOCs that is provided by the barrier sheet 80 across the entire barrier assembly 96. Each barrier tape piece 90 can be applied so that the adhesive layer 94 is in contact with a top surface of the barrier patch 84 at a first joining interface 98 and with a top surface of the barrier sheet 80 at a second joining interface 100. The barrier tape pieces 90 span between the first joining interface 98 and the second joining interface 100 to anchor the barrier patch 84 to the barrier sheet 80. The overlapping and spanning barrier tape pieces 90 seal or substantially seal any gap between the barrier sheet 80 and the barrier patch 84. The barrier properties of the barrier section 92 of the barrier tape pieces 90 will act to maintain the barrier to water vapor and at least one of methane, radon, and VOCs that is provided by the barrier sheet 80 and the barrier patch 84 across the entire barrier assembly 76.
(38) The barrier tape 10 described herein can be used with other applications or procedures. For example, the barrier tape 10 can be used to join or couple barrier sheets, such as the barrier sheets 32, 60, or 80, to fixtures such as pipes or pipe boots or building structures.
(39) The above Detailed Description is intended to be illustrative, and not restrictive. For example, the above-described examples (or one or more elements thereof) can be used in combination with each other. Other embodiments can be used, such as by one of ordinary skill in the art upon reviewing the above description. Also, various features or elements can be grouped together to streamline the disclosure. This should not be interpreted as intending that an unclaimed disclosed feature is essential to any claim. Rather, inventive subject matter can lie in less than all features of a particular disclosed embodiment. Thus, the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as a separate embodiment. The scope of the invention should be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled.
(40) In the event of inconsistent usages between this document and any documents so incorporated by reference, the usage in this document controls.
(41) In this document, the terms a or an are used, as is common in patent documents, to include one or more than one, independent of any other instances or usages of at least one or one or more. In this document, the term or is used to refer to a nonexclusive or, such that A or B includes A but not B, B but not A, and A and B, unless otherwise indicated. In this document, the terms including and in which are used as the plain-English equivalents of the respective terms comprising and wherein. Also, in the following claims, the terms including and comprising are open-ended, that is, a molding system, device, article, composition, formulation, or process that includes elements in addition to those listed after such a term in a claim are still deemed to fall within the scope of that claim. Moreover, in the following claims, the terms first, second, and third, etc. are used merely as labels, and are not intended to impose numerical requirements on their objects.
(42) Values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of about 0.1% to about 5% or about 0.1% to 5% should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1% to 0.5%, 1.1% to 2.2%, 3.3% to 4.4%) within the indicated range. The statement about X to Y has the same meaning as about X to about Y, unless indicated otherwise. Likewise, the statement about X, Y, or about Z has the same meaning as about X, about Y, or about Z, unless indicated otherwise.
(43) The Abstract is provided to comply with 37 C.F.R. 1.72(b), to allow the reader to quickly ascertain the nature of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
(44) Although the invention has been described with reference to exemplary embodiments, workers skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the invention.