Method of producing a magnetic structure
10854223 ยท 2020-12-01
Assignee
Inventors
Cpc classification
H01F41/22
ELECTRICITY
G11B5/3903
PHYSICS
H01F10/324
ELECTRICITY
G11B5/3906
PHYSICS
International classification
H01F41/30
ELECTRICITY
H01F10/32
ELECTRICITY
Abstract
A device and to a method of producing a device, wherein the method includes, inter alia, providing a substrate and generating at least two mutually spaced-apart cavities within the substrate. In accordance with the invention, each cavity has a depth of at least 50 m. The cavities are filled up with magnetic particles, wherein the magnetic particles enter into contact with one another at points of contact, and wherein cavities are formed between the points of contact. At least some of the magnetic particles are connected to one another at their points of contact, specifically by coating the magnetic particles, wherein the cavities are at least partly penetrated by the layer produced in the coating process, so that the connected magnetic particles form a magnetic porous structure.
Claims
1. A device comprising: a substrate comprising at least two mutually spaced-apart cavities, each cavity comprising a depth of at least 50 m, wherein the cavities are filled up with magnetic particles which enter into contact with one another at points of contact and form cavities between the points of contact, and wherein at least some of the magnetic particles are connected to one another at their points of contact by means of a coating, specifically in such a manner that the cavities are at least partly penetrated by the coating and such that the connected magnetic particles consequently form a magnetic porous structure, wherein the cavities each comprise, at their portion which is lower when viewed in the direction of depth, a tapered portion which is filled with a material comprising a higher level of saturation magnetization as compared to that of the magnetic particles.
2. The device as claimed in claim 1, wherein each cavity comprises an aspect ratio of at least 4:1 or 6:1 or 10:1.
3. The device as claimed in claim 1, wherein each cavity comprises a lateral extension of 250 m or less, or of 100 m or less, or of 50 m or less, or of 25 m or less.
4. The device as claimed in claim 1, wherein the substrate has a soft magnetic coating applied onto it which extends across the cavities filled with the magnetic particles so as to seal the cavities.
5. The device as claimed in claim 1, wherein the cavities are formed within the substrate such that a residual thickness, which remains in the direction of depth, between the deepest point of the cavity and that outer side of the substrate which is adjacent to said deepest point amounts to from 10 m to 100 m.
6. The device as claimed in claim 1, wherein the substrate comprises a base substrate and a covering substrate comprising at least two openings which fully extend through said covering substrate, wherein the openings within the covering substrate comprise a distance which is identical to a distance between at least two cavities within the base substrate, and wherein the covering substrate is joined to the base substrate such that the at least two openings within the covering substrate become congruent with the at least two cavities within the base substrate.
7. A microfabricated magnetic measuring bar comprising: a substrate comprising at least two mutually spaced-apart cavities, each cavity comprising a depth of at least 50 m, wherein the cavities are filled up with magnetic particles which enter into contact with one another at points of contact and form cavities between the points of contact, and wherein at least some of the magnetic particles are connected to one another at their points of contact by means of a coating, specifically in such a manner that the cavities are at least partly penetrated by the coating and such that the connected magnetic particles consequently form a magnetic porous structure; wherein the cavities each comprise, at their portion which is lower when viewed in the direction of depth, a tapered portion which is filled with a material comprising a higher level of saturation magnetization as compared to that of the magnetic particles, and a magnetic sensor configured to determine the magnetic field strength emanating from the device in that it is moved past the porous magnetic structures at a distance from the substrate and along an outer side of the substrate, specifically on that outer side of the substrate which is located opposite the opening of the respective cavity.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Embodiments of the present invention will be detailed subsequently referring to the appended drawings, in which:
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DETAILED DESCRIPTION OF THE INVENTION
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(19) In accordance with the invention, the cavity 11a has a depth l of at least 50 m. In accordance with some embodiments, the cavity 11a may also have an aspect ratio l/d of at least 4:1 or of at least 6:1 or even of at least 10:1. This means that the depth l is at least four times or six times or even ten times as large as the lateral extension of the width d.
(20) With regard to the aspect ratio and the depth of penetration l, what was said above incidentally also applies to the right-hand cavity 11b and to any further cavities which may exist within the substrate 10.
(21) The cavities 11a, 11b each comprise an opening 14 toward their surroundings. Particles may be filled into said openings 14, for example.
(22) As is shown in
(23) At points of contact, said magnetic particles 12 come into contact with one another, cavities forming between the points of contact. In accordance with the invention, the magnetic particles 12 are coated by using a coating process, e.g. an ALD (Atomic Layer Deposition) process.
(24) On account of said coating, at least some of the magnetic particles 12 connect to one another at their points of contact, in that the cavities are at least partly penetrated by the layer produced during coating. Advantageously, as a result of said coating all of the magnetic particles 12 connect to one another at their points of contact in that the cavities are fully penetrated by the layer generated during coating.
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(26) In the embodiment shown in
(27) The interconnected magnetic particles 12 form a magnetic porous structure 13.
(28) In some embodiments, the cavities 11a, 11b may have an aspect ratio of 10:1 and more. In addition, the cavities 11a, 11b may have a depth (of penetration) of 75 m and more, of 85 m and more, or of 100 m and more. This is a clear difference as compared to magnetic coatings which have been applied onto the substrate by means of common deposition processes. Due to the inventive minimum depths of penetration in connection with the above-mentioned high aspect ratios, it is possible to generate magnetic porous structures 13 which have high magnetic flux densities, the amounts of which are many times higher than those of conventionally deposited structures.
(29)
(30) As can be seen in
(31) The cavities 11a to 11g extend into the substrate 10 to such a depth that a residual thickness h.sub.p which remains, in the direction of depth 24, between the deepest point 25 of the cavity 11a to 11g and that outer side, here the lower side 10d, which is opposite the deepest point 25, of the substrate 10 amounts to from approx. 10 m to 100 m.
(32) In other words, the substrate 10 has a residual thickness h.sub.p on its side 10d which is located opposite the cavities 11a to 11g. Said residual thickness h.sub.p has a dimension of from 10 m to 100 m.
(33) All of the cavities 11a to 11g are filled up with loose magnetic particles 12. Introduction of the loose magnetic particles 12 into the cavities 11a to 11g may be performed by using a doctor blade on them, for example. Advantageously, the loose magnetic particles 12 comprise a hard magnetic material, in particular NdFeB (neodymium-iron-boron). Subsequently, the loose magnetic particles 12 are coated by using a coating process, e.g. an ALD process.
(34) As can be seen in
(35) The additional coating 16 may be applied onto the substrate 10 by means of known methods, e.g. by means of chemical vapor deposition, sputtering and the like. The additional coating 16 may protect and/or seal the cavities 11a to 11g against penetration of, e.g., dirt, dust, humidity and the like.
(36) The additional coating 16 may also be applied onto the substrate 10 by means of, e.g., sputtering, electrodeposition or PECVD, and offers several advantages. To achieve reliable protection against corrosion, the porous magnetic structures 13 should be sealed on all sides, advantageously hermetically, on the one hand. On the other hand, considerable improvement in the magnetic properties is achieved when the magnetic flux of the magnetic porous structures 13 may be closed by applying a soft magnetic additional coating 16, e.g. Fe or NiFe. The additional coating 16 may also comprise several layers, e.g. a dielectric layer and a soft magnetic layer.
(37) As was mentioned at the outset, the inventive arrangement may comprise an aspect ratio l/d, which may amount to at least 4:1 or at least 6:1 or, in some embodiments, at least 10:1. An advantage of embodiments of the inventive arrangement of
(38) With electrodeposited or sputtered magnetic structures as are described in conventional technology, the aspect ratios l/d mostly remain clearly below 1, however.
(39) As depicted in
(40) In
(41) The curve 31 shows the magnetic flux density versus the aspect ratio for a bar magnet having a diameter of 25 m. The curve 32 shows the magnetic flux density versus the aspect ratio for a bar magnet having a diameter of 50 m. The curve 33 shows the magnetic flux density versus the aspect ratio for a bar magnet having a diameter of 100 m. The curve 34 shows the magnetic flux density versus the aspect ratio for a bar magnet having a diameter of 200 m. The curve 35 shows the magnetic flux density versus the aspect ratio for a bar magnet having a diameter of 400 m.
(42) For example, with a bar magnet having a width of 50 m (comparable to a magnetic porous structure 13), the increase in the aspect ratio l/d of from 0.1 to 10 results in an increase in the magnetic flux density by an order of magnitude. By using the new, particle-based manufacturing method, such aspect ratios lid are readily possible especially for small magnetic porous structures (d<100 m). In comparison, aspect ratios of 0.1 are typical for galvanic magnetic layers. Layer thicknesses of 1-20 m are typical electroplating thicknesses. A layer thickness of 50 m would be already very large in terms of electroplating thicknesses and would be very hard to implement technically since any follow-up processes performed at elevated temperatures may easily result in stress-induced delamination of the galvanic structures. However, since the magnetic effect depends on the volume, the invention proposes provision of structures having dimensions (l) of at least 50 m or also more than 100 m, for example.
(43) The cavities 11a to 11g are introduced into the substrate 10 advantageously while using a dry-etching process. Here, the substrate 10 may comprise silicon, for example. If the etching is performed in a time-controlled manner, etching may be performed down to a residual thickness h.sub.p of 50 to 100 m. The depths of the etched cavities 11 and, thus, also h.sub.p may vary considerably across the substrate 10, however. A residual thickness h.sub.p which is considerably smaller and better defined may be achieved if the etching process is limited by a stop layer. In order to accurately control the depth of penetration of an etchant, the substrate 10 may therefore additionally comprise an etch stop layer.
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(45) However, one cannot only achieve a residual thickness h.sub.p which is better defined, but also a residual thickness h.sub.p which is considerably smaller as compared to conventional technology. For example, an Si wafer having buried etch stop layers 41 made of SiO.sub.2 in the form of a so-called SOI (Silicon-On-Insulator) substrate may be used.
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(47) The etch stop layer 41 is arranged between the substrate 10 and the SOI layer 42. The etch stop layer 41 may comprise silicon oxide or silicon nitride. However, the etch stop layer 41 may also comprise a metal, a metal oxide or a metal nitride. In principle, the layer thickness of the buried etch stop layer 41 may range from 100 nm to 1 m.
(48) The SOI layer 42 may comprise a layer thickness ranging from 10 m to 100 m or a layer thickness ranging from 50 m to 100 m. The distance h.sub.p might thus be reduced to few micrometers while using such an SOI substrate, i.e. a substrate 10 having an etch stop layer 41 and an SOI layer 42. However, to ensure sufficient mechanical stability, SOI layer thicknesses ranging from 1 m to 100 m are useful. The thickness of the SOI layer 42, which may consist of monocrystalline silicon, for example, may be set to almost any value.
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(53) The manufacturing process of
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(55) In order to further increase the field line density, the cavities 11 to be filled may be tapered in the area of their deepest point 25. This is possible, e.g., by anisotropically etching a trench having slanted sidewalls in aqueous KOH or TMAH solution prior to dry etching.
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(57) As depicted in
(58) In combination with the respectively deepest point 25 of a cavity 11, the slanted sidewalls 52, 53 form a tapered portion. Thus, a tapered portion 25, 52, 53 is formed in a portion 54 of the cavities 11 which is at the bottom/which is the lowest portion when viewed in the direction of depth 24. In other words, the cavities 11 have a tapered portion 25, 52, 53 at their portion 54 which is lower when viewed in the direction of depth 24.
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(60) As depicted in
(61) Moreover, an additional coating which may comprise several layers may be applied onto the substrate 10 in the present case, too.
(62) In the embodiment described with reference to
(63) To solve this problem, a substrate 10 having cavities 11 may alternatively also be produced, in the manner depicted in
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(65) The covering substrate 10 depicted in
(66) Such a joined substrate 10 is shown in
(67) As can be seen, the openings 61a, 61b within the covering substrate 10 have the same mutual distance X.sub.1 as do the distances X.sub.2 of the cavities, or trenches, 51a, 51b within the base substrate 10. Thus, when the covering substrate 10 is joined with the base substrate 10, the openings 61a, 61b within the covering substrate 10 become congruent with the cavities, or trenches, 51a, 51b of the base substrate 10.
(68) Thus, the base substrate 10 forms a common substrate 10 together with the covering substrate 10. The cavities, or trenches, 51a, 51b which are configured within the base substrate 10 and resemble truncated pyramids, here form, together with the continuous openings 61a, 61b formed within the covering substrate 10, the cavities 11 provided within the common substrate 10. In some embodiments of the invention, the cavities 11 may comprise a depth l of at least 50 m at an aspect ratio l/d of at least 4:1 or 6:1 or 10:1.
(69) In addition, said joined cavities 11 each comprise a tapered portion at their respectively lower portion when viewed in the direction of depth 24, as was already explained above with reference to
(70) In accordance with the invention, these two-part, as it were, cavities 11 are also refilled with loose magnetic particles 12 and are subsequently solidified to form magnetic porous structures 13 while using a coating process.
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(72) It may be advantageous to use silicon as the starting material for the base substrate 10 when producing cavities 11 in accordance with
(73) If the covering substrate 10 comprises plastic, the continuous openings 61a, 61b might be introduced into the covering substrate 10 by drilling, for example. If the covering substrate 10 comprises silicon, the continuous openings 61a, 61b might be introduced into the covering substrate 10 by using a dry-etching method, for example. If the base substrate 10 comprises silicon, the cavities, or trenches, 51a, 51b might be introduced into the base substrate 10 by using, for example, a wet-chemical etching method, e.g. by anisotropic etching of silicon in an aqueous KOH or TMAH solution.
(74) As was already mentioned at the outset, the tapered portions 25, 52, 53 in the lower portions 54 of the cavities 11 ensure that the field line density present at the exit ends of the magnetic porous structures 13, which, as we know, adapt to the respective shape of the cavities 11 and therefore also comprise a tapered portion, is increased.
(75) A further increase in the field line density may be achieved by implementing the tapering part of the magnetic porous structures 13 from a material having a higher saturation magnetization. As shown in
(76) The device shown in
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(80) Essentially,
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(82) By partially removing the substrate 10, which evidently may also comprise materials other than silicon, the magnetic porous structures would accordingly be only partly exposed.
(83) By exposing the magnetic porous structures 13, the device may have mechanical flexibility imparted thereon. The layer structure comprising the etch stop layer 41 and the SOI layer 42 may here also serve as a flexible carrier layer. Moreover, a coating of, e.g., soft magnetic material might be applied onto the free-standing portions of the magnetic porous structures 13.
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(86) In
(87) Subsequently, the substrate 10 may be removed completely or at least in portions, e.g. by means of etching in the XeF.sub.2 gas phase. As is shown in
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(89) At first,
(90) As was already explained above with reference to
(91) The cavities 11 extend from the upper side 10a a direction of depth 24 through the substrate 10 and to the lower side 10d in. Each cavity 24 has a lower portion 25 located in said direction of depth 24.
(92) Since the inventive device 1201 comprises at least two magnetic porous structures 13, it may be used as a magnetic measuring bar.
(93) The magnetic sensor 1202 is configured to determine the magnetic field strength emanating from the device 1201 in that it is moved past the porous magnetic structures 13 at a distance from the substrate 10 and along an outer side 10d of the substrate 10, specifically on that outer side 10d of the substrate 10 which is located opposite the opening 14 of the respective cavity 11.
(94) As becomes clear from a comparison of
(95) Accordingly, the direction of depth 24 also points in the opposite direction. However, the direction of depth 24 still continues to describe that direction in which the cavities 11 have been introduced into the substrate 10. Thus, each cavity 11 continues to comprise a portion 25 which is lower when viewed in the direction of depth 24.
(96) A residual thickness h.sub.p is present between said portion 25, which is lower when viewed the direction of depth, and that outer side of the substrate 10, namely the lower side 10d, which is closest to said portion.
(97) The magnetic sensor 1202 is arranged opposite said very outer side 10d of the substrate 10. The magnetic sensor 1202 is spaced apart from said substrate side 10d by a measure of h.sub.s. As is indicated by the arrow 1204, the magnetic sensor 1202 may be moved relative to the device 1201, i.e. relative to the magnetic porous structures 13, at a roughly constant distance h.sub.s. The magnetic sensor 1202 here moves essentially in parallel with the outer side 10d, to which it is opposite, of the substrate 10.
(98) Since the distance of the magnetic sensor 1202 from the opposite outer side 10d of the substrate 10 is advantageously within the range of few micrometers, it is desirable to design the surface of the outer side 10d of the substrate to be as planar as possible.
(99) To achieve this, in conventional magnetic measuring bars of conventional technology, the upper side 10a of the substrate 10, i.e. that outer side 10a of the substrate 10 which comprises the openings 14 of the cavities, is coated with an additional coating. Said additional coating is then planarized by means of grinding and polishing.
(100) In accordance with the inventive utilization of the device 1201 as a magnetic measuring bar it is suggested to simply turn over the substrate 10, as shown in
(101) In principle, all of the devices described above with reference to
(102) An advantage here is that the vertical distance h.sub.s between the sensor 1202 and the pole exit ends 25 of the porous, hard magnetic pole structures 13 may be reduced. The smaller h.sub.s, the higher the magnetic flux density at the location of the sensor. The distance measure h.sub.s is limited, inter alia, by the distance h.sub.p between the magnetic porous structures 13 and the surface 10d of the magnetic measuring bar 1201. In addition to the upper side 10d of the substrate 10, this may be layers, e.g., which protect the measuring bar 1201 from mechanical damage and corrosion and which may easily have thicknesses of more than 200 m in a conventional known magnetic measuring bar.
(103) In the inventive magnetic measuring bar 1201, considerably smaller distances are possible. The cavities 11 defining the geometry of the magnetic porous pole structures 12 may be generated e.g. by means of dry etching (DRIE) in the case of an Si substrate 10. The residual thickness h.sub.p, which remains in this case, with regard to the lower side 10d of the wafer 10 may be set to a measure of advantageously from 10 m to 100 m, which is clearly less than the above-mentioned thickness of 200 m of conventional technology.
(104) In general, both planar and three-dimensionally shaped substrates 10 made of most varied materials may be used for producing magnetic measuring bars 1201 on the basis of porous hard magnetic molded bodies 13, provided that the materials used withstand the inventive manufacturing processes explained above without being damaged.
(105) As was described with reference to
(106) If in said devices of
(107) In the case depicted in
(108) The inventive magnetic measuring bar furthermore results in the following advantages: Particularly high-performing magnetic materials having a high level of remanence and coercive field strength may be used as the measuring bar, such as NdFeB, which renders them considerably less sensitive toward external magnetic fields and elevated temperatures as compared to classic magnetic tapes while guaranteeing a stronger signal. The measuring bar may be integrated both on planar substrates and on components comprising a complex three-dimensional geometry and being made from a multitude of different materials. Hard magnetic structures having high aspect ratios and field distributions which are improved accordingly may be manufactured. One of the surfaces of the substrate serves as a surface of the measuring bar. In the event of an Si substrate, the surface is completely planar. Additionally, the hard magnetic structures are protected against environmental influences and/or corrosion of any kind in a simple manner.
(109) With such an inventive magnetic measuring bar, magnetic position detection exhibiting a particularly high level of resolution may be implemented in devices and installations of any kind.
(110) Exemplary embodiments of the invention provide a method of producing a three-dimensional magnetic measuring bar, wherein for structures having lateral dimensions d of up to 500 m, aspect ratios L/d>1 may be produced, for structures having lateral dimensions d of up to 50 m, aspect ratios L/d>10 may be produced, the magnetic flux of the magnetic pole structures 13 may be closed, on their rear sides, with a soft magnetic layer in each case, tapering of the magnetic poles 13 on their front sides may be achieved, e.g., by combining anisotropic etching and deep etching, tapering of the magnetic poles 13 made from a ferromagnetic material having a higher level of saturation magnetization may be produced as compared to a hard magnetic material forming the magnetic poles 13, and magnetic pole structures 13 may be integrated both on planar and three-dimensionally shaped substrates 10 made of most varied materials, provided that the materials used withstand the process of manufacturing the porous molded bodies 13 without being damaged.
(111)
(112) Above-described embodiments are independent of a specific size (e.g. diameter or lateral dimension). The magnetic particles 12 may have diameters of, e.g., from 1 m to 20 m, from 2 m to 15 m, or 5 m to 12 m. Other magnetic particles 12 may have diameters or lateral dimensions ranging from 0.1 m to 20 m, 0.5 m to 5 m, or 0.8 m to 1.2 m, for example.
(113) Even though above-described embodiments have been described to the effect that the magnetic porous structure 13 comprises cavities which are at least partly connected to one another, one may also achieve, in particular with a particle size of <2 m, by means of the coating process, for the porous structure 13 to be sealed, i.e. for the cavities between the particles 12 to be closed.
(114) Even though above-described embodiments have been described to the effect that the substrate 10 has a planar shape, the substrate 10 may also have other shapes. For example, the substrate 10 may have a curved shape (e.g. a dome structure) or a shape in which portions are planar and/or bent.
(115) Even though some aspects have been described within the context of a device, it is understood that said aspects also represent a description of the corresponding method, so that a block or a structural component of a device is also to be understood as a corresponding method step or as a feature of a method step. By analogy therewith, aspects that have been described within the context of or as a method step also represent a description of a corresponding block or detail or feature of a corresponding device.
(116) The method steps described may also be performed in any order other than that indicated in the claims.
(117) While this invention has been described in terms of several embodiments, there are alterations, permutations, and equivalents which fall within the scope of this invention. It should also be noted that there are many alternative ways of implementing the methods and compositions of the present invention. It is therefore intended that the following appended claims be interpreted as including all such alterations, permutations and equivalents as fall within the true spirit and scope of the present invention.
SOURCES
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