2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating and method for preparation thereof

Abstract

Provided are a 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating and a preparation method thereof, the raw materials of which comprising, by mass ratio: 2-mercaptobenzothiazole modified graphene oxide 5-20; a matrix resin 30-70; a leveling agent 0.5-1.0; a defoamant 0.5-1.0; a dispersant 0.5-1.0; a film-forming additive 0.5-1.0; a diluent 20-35. The method for the 2-mercaptobenzothiazole modified graphene oxide comprises first reacting graphene oxide with cyanuric chloride, then reacting with 2-mercaptobenzothiazole.

Claims

1. A method for preparing 2-mercaptobenzothiazole modified graphene oxide, wherein: step 1: a certain amount of graphene oxide, cyanuric chloride and sodium bicarbonate are taken into a flask, a certain volume of N, N-dimethylformamide is taken to disperse it, stirred for 0.5-4 hours at room temperature, heated to 50 C. and stirred for 10-24 hours, then cooled and filtered to obtain the precipitation; wherein graphene oxide, cyanuric chloride and sodium bicarbonate are graphene oxide:cyanuric chloride:sodium bicarbonate=1-30 g:1-8 mol:1-20 mol according to the feed ratio, and the volume of N, N-dimethylformamide is 100-2000 ml; step 2: the precipitation in step 1, 2-mercaptobenzothiazole and potassium hydroxide are taken into a flask, a certain volume amount of acetone is taken to disperse them and react for 6-10 hours, cooled and filtered and ##STR00003## is obtained; wherein the precipitation, 2-mercaptobenzothiazole and potassium hydroxide are precipitation:2-mercaptobenzothiazole:potassium hydroxide=130 g:18 mol:18 mol according to the feed ratio, the volume of acetone is 100-2000 ml.

2. A 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating, wherein the raw materials of which comprises, by mass ratio: TABLE-US-00003 2-mercaptobenzothiazole modified graphene oxide 5-20 parts matrix resin 30-70 parts leveling agent 0.5-1.0 parts defoamant 0.5-1.0 parts dispersant 0.5-1.0 parts film-forming additive 0.5-1.0 parts diluent 20-35 parts, wherein the 2-mercaptobenzothiazole modified graphene oxide is synthesized from graphene oxide, cyanuric chloride, and 2-mercaptobenzothiazole.

3. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the matrix resin is selected from at least one of epoxy resin, fluorocarbon resin, amino resin, acrylic resin, polyurethane resin, alkyd resin and polyester resin.

4. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the leveling agent is selected from one of organosilicon, acrylic acid and monobutyl ether.

5. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the defoamant is selected from one of organosilicon defoamants, inorganic silicon defoamants and non-organosilicon defoamants.

6. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the dispersant is a self-fluxing dispersant or wetting dispersant.

7. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the film-forming additive is selected from one of butyl benzyl alcohol acetate, ethylene glycol butyl ether glycolic acid ester, ethylene glycol phenyl ether, dibasic acid dimethyl esters, propylene glycol propyl ether and dibasic acid diethyl ester.

8. The 2-mercaptobenzothiazole modified graphene oxide anti-corrosion coating according to claim 2, wherein the diluent is selected from one of 1,4-butanediol diglycidyl ether, ethylene glycol diglycidyl ether, acetone, xylene, n-butanol and methyl isobutyl ketone, absolute ethanol, ethyl acetate, butyl acetate.

Description

DRAWINGS

(1) FIG. 1 shows the infrared spectra of 2-mercaptobenzothiazole modified graphene oxide in embodiment 1.

(2) FIG. 2 is a scanning electron micrograph of 2-mercaptobenzothiazole modified graphene oxide in embodiment 1.

(3) FIG. 3 is XRD spectra of 2-mercaptobenzothiazole modified graphene oxide in embodiment 1.

DETAILED DESCRIPTION

(4) The contents of the present invention are described in detail below with embodiments.

Embodiment 1

(5) (1) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide

(6) A. 10 g of graphene oxide, 2 mol of cyanuric chloride and 6 mol of sodium bicarbonate were taken to disperse in 1000 ml of N, N-dimethylformamide, and filled it with nitrogen for protection, stirred for 2 hours at room temperature, heated to 50 C., stirred for 22 hours. After the reaction, precipitation was obtained by washing 5 times with N, N-dimethylformamide, washing 2 times with water and drying for 24 hours in vacuum.

(7) B. 10 g of precipitation in A was taken, 2 mol of 2-mercaptobenzothiazole and 2 mol of potassium hydroxide were dispersed in 1000 ml of acetone, and filled it with nitrogen for protection, and stirred at 45 C. for 8 h, after the reaction was finished, the precipitation was obtained by washing with acetone five times, washing with water twice and drying in vacuum for 24 hours. The infrared spectra of 2-mercaptobenzothiazole modified graphene oxide were shown in FIG. 1, corresponding to the characteristic peaks of functional groups. Scanning electron micrograph (SEM) was shown in FIG. 2, there are obvious folds in the lamellae. The XRD spectra of the 2-mercaptobenzothiazole modified graphene oxide were shown in FIG. 3. The peak of graphene oxide is obviously weakened and characteristic peak of graphitization appears after the modified graphene oxide.

(8) (2) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide Composite Anti-Corrosion Coating

(9) 5 parts of modified graphene oxide, 30 parts of epoxy resin, 0.5 parts of organosilicon, 0.5 parts of defoamant BYK302, 0.5 parts of dispersant BYK101, 0.5 parts of ethylene glycol phenyl ether and 20 parts of 1,4-butanediol glycidyl ether were mixed and dispersed evenly by the disperser for 4 hours. After filtration, 2-mercaptobenzothiazole modified graphene oxide composite anti-corrosion coating was obtained. Its anticorrosive properties were shown in Table 1.

Embodiment 2

(10) (1) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide

(11) A. 20 g of graphene oxide, 4 mol of cyanuric chloride and 12 mol of sodium bicarbonate were dispersed in 1500 ml of N, N-dimethylformamide, and filled it with nitrogen for protection, stirred for 3 hours at room temperature, heated to 50 C., and stirred for 24 hours. After the reaction, the precipitation was obtained by washing 5 times with N, N-dimethylformamide, washing twice with water and drying for 24 hours in vacuum.

(12) B. 20 g of precipitation in A was taken, 4 mol of 2-mercaptobenzothiazole and 4 mol of potassium hydroxide were dispersed in 1500 ml of acetone, and filled it with nitrogen for protection, and stirred at 45 C. for 10 h, after the reaction was finished, the precipitation was obtained by washing with acetone five times, washing with water twice and drying in vacuum for 24 hours.

(13) (2) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide Composite Anti-Corrosion Coating

(14) 10 parts of modified graphene oxide, 50 parts of epoxy resin, 0.8 parts of organosilicon, 0.6 parts of defoamant BYK302, 0.6 parts of dispersant BYK101, 0.8 parts of ethylene glycol phenyl ether and 30 parts of 1,4-butanediol glycidyl ether were mixed and dispersed evenly by the disperser for 4 hours. After filtration, 2-mertozobenthiazole modified graphene oxide composite anti-corrosion coating was obtained. Its anticorrosive properties were shown in Table 1.

Embodiment 3

(15) (1) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide

(16) A. 30 g of graphene oxide, 6 mol of cyanuric chloride and 18 mol of sodium bicarbonate were dispersed in 2000 ml of N, N-dimethylformamide, and filled it with nitrogen for protection, stirred for 4 hours at room temperature, heated to 50 C., and stirred for 24 hours. After the reaction, the precipitation was obtained by washing 5 times with N, N-dimethylformamide, washing 2 times with water and drying for 24 hours in vacuum.

(17) B. 30 g of precipitation in A was taken, 6 mol of 2-mercaptobenzothiazole and 6 mol of potassium hydroxide were dispersed in 2000 ml of acetone, and filled it with nitrogen for protection, and stirred at 50 C. for 10 h, after the reaction was finished, the precipitation was obtained by washing with acetone five times, washing with water twice and drying in vacuum for 24 hours.

(18) (2) Preparation of 2-Mercaptobenzothiazole Modified Graphene Oxide Composite Anti-Corrosion Coating

(19) 20 parts of modified graphene oxide, 70 parts of acrylic resin, 0.8 parts of organosilicon, 1 parts of defoamant BYK302, 1 parts of dispersant BYK101, 0.8 parts of ethylene glycol phenyl ether and 20 parts of ethyl acetate were mixed and dispersed evenly by disperser for 4 hours. After filtration, 2-mercaptobenzothiazole modified graphene oxide composite anti-corrosion coating was obtained. Its anticorrosive properties were shown in Table 1.

(20) TABLE-US-00002 TABLE 1 The corrosion test of anti-corrosion coating in embodiments 1 to 3 Index name Embodiment 1 Embodiment 2 Embodiment 3 Test method acid paint film does not foam and rust for 700 h GB/T 9274 resistance (5% H.sub.2SO.sub.4, 25 C.) alkali resistance (3% NaOH, paint film does not foam and rust for 900 h GB/T 9274 25 C.) salt solution paint film does not foam and rust for 1000 h GB/T 1763 resistance (3% NaCl, 25 C.) salt spray resistance paint film does not foam and rust for 1000 h GB/T 1771

(21) As mentioned above, these are only preferred embodiments of the present invention, so the scope of implementation of the present invention cannot be limited accordingly. That is, the equivalent changes and modifications made according to the patent scope and description content of the present invention should still be within the scope of the present invention.