A STEEL CORD

Abstract

The invention provides a steel cord for rubber reinforcement. The steel cord comprises a core strand and at least three outer strands twisted around the core strand, the core strand comprises at least one first core filament and multiple first outer filaments twisted around the first core filament, each outer strand comprises a number of second filaments, at least one of multiple first outer filaments is preformed prior to being twisted into the core strand, and at least one of second steel filaments is straight prior to being twisted to form each outer strand. The steel cord has improved performance on core filament migration.

Claims

1.-10. (canceled)

11. A steel cord for rubber reinforcement, said steel cord comprising a core strand and at least three outer strands twisted around said core strand, said core strand comprising at least one first core filament and multiple first outer filaments twisted around said at least one first core filament, each said outer strand comprising a number of second filaments, wherein at least one of said multiple first outer filaments is preformed prior to being twisted into said core strand, and at least one of said a number of second steel filaments is straight prior to being twisted to form each said outer strand.

12. The steel cord as claimed in claim 11, wherein all of said multiple first outer filaments are preformed prior to being twisted into said core strand.

13. The steel cord as claimed in claim 11, wherein said at least one first core filament is preformed prior to being twisted into said core strand.

14. The steel cord as claimed in claim 11, wherein all of said a number of second steel filaments are straight prior to being twisted to form said outer strand.

15. The steel cord as claimed in claim 11, wherein the preforming onto said first core filament or said first outer filament is single crimping, double crimping in two different planes, or polygonal preforming.

16. The steel cord as claimed in claim 11, wherein the preformed first outer filament comprises continuous waves A and continuous waves B along its length, said wave A is different from said wave B in wave height, said wave A has a wave height ranging from 1.05d.sub.1 to 4d.sub.1 in mm, d.sub.1 being the diameter of said first outer filament, said wave B has a wave height ranging from 0.5D.sub.1 to 1.5D.sub.1 in mm, D.sub.1 being the diameter of the enveloping circle of said first outer filaments.

17. The steel cord as claimed in claim 16, wherein said wave A has a wave height ranging from 1.05d.sub.1 to 3.5d.sub.1 in mm, said wave B has a wave height ranging from 0.7D.sub.1 to 1.2D.sub.1 in mm.

18. The steel cord as claimed in claim 13, wherein the preformed first core filament comprises continuous waves C along its length, said wave C has a wave height ranging from 1.05d.sub.2 to 4d.sub.2 in mm, d.sub.2 being the diameter of said first core filament.

19. The steel cord as claimed in claim 18, wherein said wave C has a wave height ranging from 1.05d.sub.2to 3.5d.sub.2in mm.

20. An off-the-road tire, comprising multiple belt layers and carcass, wherein said belt is reinforced by said steel cords as claimed in claim 11.

Description

BRIEF DESCRIPTION OF FIGURES IN THE DRAWINGS

[0023] FIG. 1 shows a steel cord with a structure of 77+1.

[0024] FIG. 2 shows the preformed steel filament and the straight steel filament which are untwisted from a steel cord

MODE(S) FOR CARRYING OUT THE INVENTION

[0025] The steel filaments for a steel cord are made from a wire rod.

[0026] The wire rod is firstly cleaned by mechanical descaling and/or by chemical pickling in a H.sub.2SO.sub.4 or HCl solution in order to remove the oxides present on the surface. The wire rod is then rinsed in water and is dried. The dried wire rod is then subjected to a first series of dry drawing operations in order to reduce the diameter until a first intermediate diameter.

[0027] At this first intermediate diameter, e.g. at about 3.0 to 3.5 mm, the dry drawn steel wire is subjected to a first intermediate heat treatment, called patenting. Patenting means first austenitizing until a temperature of about 1000 C. followed by a transformation phase from austenite to pearlite at a temperature of about 600-650 C. The steel wire is then ready for further mechanical deformation.

[0028] Thereafter the steel wire is further dry drawn from the first intermediate diameter until a second intermediate diameter in a second number of diameter reduction steps. The second diameter typically ranges from 1.0 mm to 2.5 mm.

[0029] At this second intermediate diameter, the steel wire is subjected to a second patenting treatment, i.e. austenitizing again at a temperature of about 1000 C. and thereafter quenching at a temperature of 600 to 650 C. to allow for transformation to pearlite.

[0030] If the total reduction in the first and second dry drawing step is not too big a direct drawing operation can be done from wire rod till second intermediate diameter.

[0031] After this second patenting treatment the steel wire is usually provided with a brass coating: copper is plated on the steel wire and zinc is plated on the copper. A thermo-diffusion treatment is applied to form the brass coating. Alternatively, the steel wire can be provided with a ternary alloy coating, including copper, zinc and a third alloy of cobalt, titanium, nickel, iron or other known metal.

[0032] The brass coated or ternary alloy coated steel wire is then subjected to a final series of cross-section reductions by means of wet drawing machines. The final product is a steel wire with a carbon content above 0.60 per cent by weight, e.g. higher than 0.70 per cent by weight, or higher than 0.80 per cent by weight, or even higher than 0.90 per cent by weight, with a tensile strength typically above 2000 MPa, e.g. above 3800-2000d Mpa, or above 4100-2000d MPa or above 4400-2000d MPa (d is the diameter of the steel wire) and adapted for the reinforcement of elastomer products.

[0033] Steel wires adapted for the reinforcement of tyres typically have a final diameter ranging from 0.05 mm to 0.60 mm, e.g. from 0.10 mm to 0.40 mm. Examples of filament diameters are 0.10 mm, 0.12 mm, 0.15 mm, 0.175 mm, 0.18 mm, 0.20 mm, 0.22 mm, 0.245 mm, 0.28 mm, 0.30 mm, 0.32 mm, 0.35 mm, 0.38 mm, 0.40 mm.

[0034] After the preparation of the steel filaments, at least one steel filament which will be located in the outer layer of the core strand, preferably all the steel filaments in the outer layer of the core strand, is subjected to a preforming process, and then all the steel filaments are subjected to the twisting process to form a steel cord.

[0035] The preforming process is single crimping, double crimping in two different planes, or polygonal preforming. Preferably, it is a single crimping since it leads less strength loss to the steel filament.

[0036] FIG. 1 illustrates a first embodiment. The steel cord 100 has a structure of 77+1, the first core filament 105 and the first outer filaments 110 are preformed prior to the twisting process, and each outer strand has the filaments 115 and the filament 120 which is in the core of the outer strand, the filaments 115 and 120 are straight prior to the twisting process, a filament 125 is wrapped around the outer strands. FIG. 2 shows the different wave form of the filament 105, 110, 115 and 120. Wave C, the wave form of the filament 105, is caused by preforming deformation only. Wave A, the smaller wave form of the filament 110, is caused by preforming deformation mainly in addition to twisting process. Wave B, the bigger wave form of the filament 110, is caused by twisting process mainly in addition to preforming deformation. The wave forms of the filament 115 and 120 are caused by twisting process only, the wave form of the filament 115 and the wave form of the filament 120 have different wave height since the filament 115 and the filament 120 have the different twisting process. As shown in FIG. 2, wave height is measured by firstly drawing a line between two adjacent wave crests when the filament is projected by a profile project, and then measuring the shortest distance from the wave trough to the line (see the example of Wave A, Wave B and Wave C). This short distance is the wave height, including the steel filament diameter.

[0037] A comparison test is done. Table 1 summarizes the result.

TABLE-US-00001 TABLE 1 First embodiment Reference 1 Reference 2 Structure 7 7 + 1 7 7 + 1 7 7 + 1 Filament diameter in the core 0.25 0.25 0.25 strand and the outer strands (mm) Preformed filament first core filament and first core filament no first outer filaments Straight filament second filaments first outer filaments and all filaments of second filaments the steel cord Preforming type single crimping single crimping no Average wave height 0.358 no no of wave A (mm) Average enveloping 0.75 0.75 0.75 circle diameter D1 (mm) Average wave height 0.664 0.658 0.662 of Wave B (mm) Average wave height 0.329 0.336 no of wave C (mm) Core filament 135 11 9 anchorage force (N)

[0038] The core filament anchorage force is tested by a method with the following steps: firstly, make a rubberized sample embedded with the 4 steel cords which are arranged in parallel, the distance between two adjacent steel cords is 5 mm measured from the center of one steel cord to the center of another steel cord, the rubberized sample has a size of 2202515 mm (lengthwidthheight); secondly, select one end of the rubberized sample, remove the rubber compound of the selected end and leave the steel cords in, and ensure the rest of the rubberized sample having a length of one inch; thirdly, unravel the outer strands and the first outer filaments from the steel cords of the selected end to expose the first core filaments; fourthly, pull one of the first core filaments out of the rubberized sample and record the required force. The recorded force is the core filament anchorage force.

[0039] From the above table, it is clear that the invention steel cord has quite high improvement on core filament anchorage force compared with the reference. The anchorage force of preforming the first outer filaments is 10 times higher than the anchorage force of preforming the first core filament only. The improved anchorage force reduces the risk of core filament migration.

[0040] A second embodiment is a 7(1+6+12) steel cord. Each strand of the steel cord has three layers structure, a core, an intermediate layer and an outer layer. The filaments in the intermediate layer and the outer layer are preformed prior to the twisting process, and the rest filaments of the steel cord are straight prior to the twisting process. The preformed first outer filaments comprise continuous waves A and continuous waves B along its length, wave A has a wave height of 0.290 mm and wave B has a wave height of 0.558 mm.