CORE-SHELL CATALYST, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF TO CATALYTIC OZONATION

Abstract

The invention relates to a core-shell structured catalyst comprising a core covered with a shell, the core is made of hematite, tourmaline, germanium, maifanite or kaolin. The invention also provides a method for preparing the catalyst including mixing raw materials of the core with water to form seed-balls with a particle size of 2-4 mm; mixing the seed-balls with raw materials of the shell and water, such that the seed-balls are covered with the raw materials of the shell to form pellets with a particle size of 3-5 mm; processing the pellets at 60-90 C. and then calcining to active the pellets at 450-550 C. to obtain a core-shell structured catalyst. The invention further discloses use of the core-shell structured catalyst in the ozone oxidation reaction. In the invention, a core-shell structured catalyst with good morphology and catalytic performance is prepared, and the production cost of the catalyst is reduced.

Claims

1. A core-shell structured catalyst, comprising a core covered with a shell, wherein the core has a particle size of 2-4 mm, the shell has a thickness of 0.5-1.5 mm; the core is made of hematite, tourmaline, germanium, maifanite or kaolin, the shell is made of -type alumina and an active ingredient, the active ingredient is selected from the group consisting of lanthanum oxide, copper oxide, titanium oxide, manganese oxide, iron oxide, cerium oxide and any combination thereof .

2. The core-shell structured catalyst according to claim 1, wherein the mass ratio of the -type alumina to the active ingredient is 90-96:4-10.

3. A method for preparing the core-shell structured catalyst according to claim 1, comprising the steps of: (1) mixing the raw material of the core with water to form seed-balls with a particle size of 2-4 mm, wherein the raw material of the core is hematite, tourmaline, germanium, maifanite or kaolin; (2) mixing the seed-balls with raw materials of the shell and water, such that the seed-balls are covered with the raw materials of the shell to form pellets with a particle size of 3-5 mm, wherein the raw materials of the shell are -type alumina and an active ingredient, and the active ingredient is selected from the group consisting of lanthanum oxide, copper oxide, titanium oxide, manganese oxide, iron oxide, and cerium oxide and any combination thereof; and (3) processing the pellets at a constant temperature of 60-90 C. for 10-24 hrs, and then calcining to active the pellets at 450-550 C. for 2-5 hrs, to obtain the core-shell structured catalyst.

4. The method according to claim 3, wherein in step (1), the raw material of the core has a particle size of 200-325 mesh.

5. The method according to claim 3, wherein in step (1), the mass ratio of the raw material of the core to water is 1-2:1.

6. The method according to claim 3, wherein in step (2), the mass ratio of the seed-balls to the raw materials of the shell and water is 1.5-2.5:1.

7. The method for preparing a core-shell structured catalyst according to claim 3, wherein in steps (1) and (2), granulation is performed by a spheronization molding process.

8. The method for according to claim 7, wherein in step (1), the granulation is performed by a spheronizer, and the spheronization molding process comprises placing the raw material of the core to a disc of the spheronizer and spraying a mist of water as a binder to form seed-balls, wherein the rotation speed of the disc of the spheronizer is 30-70 rpm.

9. The method according to claim 7, wherein in step (2), the granulation is performed by a spheronizer, and the spheronization molding process comprises placing the seed-balls, the raw materials of the shell to a disc of the spheronizer and spraying a mist of water as a binder to form pellets, wherein the rotation speed of the disc of the spheronizer is 20-60 rpm.

10. The method according to claim 3, further comprising: applying the core-shell structured catalyst in an ozone oxidation reaction.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0029] FIG. 1 is an optical photograph of the core-shell structured catalyst according to Example 1;

[0030] FIG. 2 is an optical photograph showing the magnetic properties of the sample according to Example 1;

[0031] FIG. 3 is an energy dispersive X-ray spectrum of iron element of the core-shell structured catalyst according to Example 1;

[0032] FIG. 4 is an X-ray diffraction spectrum of the core-shell structured catalyst according to Example 1;

[0033] FIG. 5 is an X-ray diffraction spectrum of the core-shell structured catalyst according to Example 7;

[0034] FIG. 6 shows the removal rate of sodium oxalate in the catalytic ozonation reactions of sodium oxalate by different catalysts.

DETAILED DESCRIPTION OF THE INVENTION

[0035] The invention will be further illustrated in more detail with reference to the accompanying drawings and embodiments. It is noted that, the following embodiments only are intended for purposes of illustration, but are not intended to limit the scope of the present invention.

EXAMPLE 1

[0036] This example provides a method for preparing a core-shell structured catalyst, including the following steps:

[0037] (1) Hematite was ground and sieved through a 325 mesh sieve to obtain the hematite powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the hematite powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and then water was sprayed into the spheronizing disc at a rate of 50 kg/L, when small balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use.

[0038] (2) The seed-balls were added into a spheronizing disc containing the raw materials of the shell, which were CuO and -type alumina with a mass ratio of 4:96.

[0039] (3) The rotation speed of the spheronizing disc was set as 20-60 rpm, with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0040] (4) The collected pellets were placed in a sealed system and processed at 90 C. for 24 hrs.

[0041] (5) The pellets obtained in step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (450 C.) in the kiln for 3 hrs to form an ozone oxidation catalyst.

[0042] FIG. 1 is an optical photograph of the product of Example 1. From the picture, it can be seen that the surface of the particles has a color resulted from the mixture of white alumina and black copper oxide; the internal part of the particles being cut is red hematite. It shows that the particles with a core-shell structure were prepared successfully by this process. FIG. 2 is an optical photograph showing the product of Example 1 being attracted onto a magnet, which indicates that the sample has a good magnetic property. FIG. 3 is an energy dispersive X-ray spectrum of iron element of the product of Example 1. It can be seen, from the figure, that the iron element is intensively distributed inside the particles, which demonstrates the core-shell structure of the sample. FIG. 4 is an X-ray diffraction spectrum of the product of Example 1. Characteristic peaks of copper oxide, hematite, and -alumina can be seen from the spectrum.

EXAMPLE 2

[0043] This example provides a method for preparing the core-shell structured catalyst, including the following steps:

[0044] (1) Tourmaline was ground and sieved through a 325 mesh sieve to obtain the tourmaline powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the tourmaline powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and then water was sprayed into the spheronizing disc at a rate of 50 kg/L, when balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use.

[0045] (2) The seed-balls were added into a spheronizing disc containing the raw materials of the shell, which were La.sub.2O.sub.3, TiO.sub.2 and -type alumina with a mass ratio of 10:90.

[0046] (3) The rotation speed of the spheronizing disc was set as 20-60 rpm with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0047] (4) The collected pellets were placed in a sealed system and processed at 60 C. for 24 hrs.

[0048] (5) The pellets obtained of step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (550 C.) in the kiln for 3 hrs to form an ozone oxidation catalyst.

EXAMPLE 3

[0049] This example provides a method for preparing a core-shell structured catalyst, including the following steps:

[0050] (1) Germanite was ground and sieved through a 325 mesh sieve to obtain the germanite powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the germanite powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and then water was sprayed into the spheronizing disc at a rate of 50 kg/L, when balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use as.

[0051] (2) The seed-balls were added into a spheronizing disc containing the raw materials of the shell, which were TiO.sub.2, Fe.sub.2O.sub.3 and -type alumina with a mass ratio of 4:96.

[0052] (3) The rotation speed of the spheronizing disc was set as 20-60 rpm with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0053] (4) The collected pellets were placed in a sealed system and processed at 90 C. for 24 hrs.

[0054] (5) The pellets processed obtained of step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (500 C.) in the kiln for 3 hrs to form an ozone oxidation catalyst.

EXAMPLE 4

[0055] This example provides a method for preparing a core-shell structured catalyst, including the following steps:

[0056] (1) Kaolin was ground and sieved through a 325 mesh sieve to obtain the kaolin powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the kaolin powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and water was sprayed into the spheronizing disc at a rate of 50 kg/L, when balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use.

[0057] (2) The seed-balls were added into a spheronizing disc containing the raw materials of the shell, which were MnO.sub.2 and -type alumina with a mass ratio of 4:96.

[0058] (3) The rotation speed of the spheronizing disc was set as 20-60 rpm with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0059] (4) The collected pellets were collected in a sealed system and processed at 90 C. for 24 hrs.

[0060] (5) The pellets obtained in step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (450 C.) in the kiln for 3 hrs to form an ozone oxidation catalyst.

EXAMPLE 5

[0061] This example provides a method for preparing a core-shell structured catalyst, including the following steps:

[0062] (1) Hematite was ground and sieved through a 325 mesh sieve to obtain the hematite powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the hematite powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and water was sprayed into the spheronizing disc at a rate of 50 kg/L, when small balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use.

[0063] (2) The seed-balls were added into a spheronizing disc containing the raw materials of the shell, which were Fe.sub.2O.sub.3 and -type alumina with a mass ratio of 4:96.

[0064] (3) The rotation speed of the spheronizing disc was set as to 20-60 rpm with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0065] (4) The collected pellets were placed in a sealed system and processed at 90 C. for 24 hrs.

[0066] (5) The pellets obtained in step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature (450 C.) area in the kiln for 3 hrs to form an ozone oxidation catalyst.

EXAMPLE 6

[0067] This example provides a method for preparing a core-shell structured catalyst, including the following steps:

[0068] (1) Maifanite was ground and sieved through a 200 mesh sieve to obtain the maifanite powder. A spheronization molding process was performed by a spheronizer, a spheronizing disc having a diameter of 1-3 m was selected, and the maifanite powder was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and then water was sprayed into the spheronizing disc at a rate of 50 kg/L, when small balls with a diameter of about 2-4 mm were obtained, the desired seed-balls were took out and ready for use.

[0069] (2) The seed-balls were added into a spheronizing disc containing the raw material of the shell, which were CeO.sub.2 and -type alumina with a mass ratio of 10:90.

[0070] (3) The rotation speed of the spheronizing disc was set as 20-60 rpm with a water spraying rate of 50 kg/h, such that the particles have a good sphericity. When the particle size was within the range of 3-5 mm, the product was continuously collected to obtain spherical pellets.

[0071] (4) The collected pellets were placed in a sealed system and processed at 90 C. for 24 hrs.

[0072] (5) The pellets obtained in step (4) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (450 C.) for 3 hrs to form an ozone oxidation catalyst.

EXAMPLE 7

[0073] Using the above method, the catalyst was prepared by one-step spheronization molding process, the specific process was as follows:

[0074] (1) -type alumina of 325 mesh was uniformly mixed with copper oxide to obtain a mixture, wherein the mixture contains 4-10 wt % of copper oxide. The spheronization molding was performed by a spheronizer. A spheronizing disc having a diameter of 1-3 m was selected, and the mixture was added continuously into the operating spheronizing disc at a feed rate of 100 kg/h, and a suitable amount of water was sprayed into the spheronizing disc at a rate of 50 kg/L, when the diameter of pellets was about 3-5 mm, the pellets were took out and ready for use.

[0075] (2) The collected pellets were placed in a sealed system and processed at 90 C. for 24 hrs.

[0076] (3) The pellets obtained in step (2) were added into a vertical kiln. By controlling the discharging speed at the bottom of the kiln, the pellets were adjusted to stay at a constant temperature area (450 C.) in the kiln for 3 hrs to form an ozone oxidation catalyst.

[0077] FIG. 5 is an X-ray diffraction spectrum of the sample of Example 7. Characteristic peaks of copper oxide, hematite, and y-alumina can be seen from the spectrum.

EXAMPLE 8

[0078] The catalyst of the invention was applied to degradation of sodium oxalate-containing wastewater by the catalytic ozonation, and the specific steps were as follows:

[0079] Sodium oxalate was selected as the simulated pollutant, and the concentration of sodium oxalate in the aqueous sodium oxalate solution was 1.2 g/L. The catalysts of Examples 1 and 7 of the present invention were added to the formulated aqueous sodium oxalate solutions respectively, wherein the mass-volume ratio of the catalyst and the aqueous solution was 10 g: 1 L. Magnetic stirring or mechanical stirring was performed to ensure that the uniform reaction inside the reaction container. Ozone was then introduced, and the ratio of the amount of ozone to the wastewater was 0.5 g: 1 L. The reaction time was 4 h.

[0080] The removal rates of sodium oxalate under two conditions were compared, and the results are shown in FIG. 6. It can be seen from the FIG. 6 that, the respective removal rate of sodium oxalate is 87.5% and 90% by separately using the catalyst prepared by the present invention (a catalyst produced by the two-step spheronization molding process) and the catalyst prepared by the one-step spheronization molding process in the catalytic ozonation reaction, which indicates that the method of the present invention does not affect the catalytic performance of the catalyst and can reduce the production cost. In addition, alumina and hematite are stable as carriers in physical and chemical properties and hardly solved in water, which greatly reduce the catalyst loss and prolong the service life of the catalyst.

[0081] The above description is only preferred embodiments of the present invention and not intended to limit the present invention, it should be noted that those of ordinary skill in the art can further make various modifications and variations without departing from the technical principles of the present invention, and these modifications and variations also should be considered to be within the scope of protection of the present invention.