METHOD FOR PRODUCING A COMPONENT BY MEANS OF AN ADDITIVE MANUFACTURING METHOD USING A LASER
20200361035 · 2020-11-19
Assignee
Inventors
Cpc classification
B22F10/32
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B23K26/08
PERFORMING OPERATIONS; TRANSPORTING
B22F10/322
PERFORMING OPERATIONS; TRANSPORTING
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
B22F2999/00
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0006
PERFORMING OPERATIONS; TRANSPORTING
B22F10/50
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0626
PERFORMING OPERATIONS; TRANSPORTING
B23K35/3066
PERFORMING OPERATIONS; TRANSPORTING
B23K26/082
PERFORMING OPERATIONS; TRANSPORTING
B33Y30/00
PERFORMING OPERATIONS; TRANSPORTING
B22F10/322
PERFORMING OPERATIONS; TRANSPORTING
B23K26/126
PERFORMING OPERATIONS; TRANSPORTING
B23K35/286
PERFORMING OPERATIONS; TRANSPORTING
B22F10/28
PERFORMING OPERATIONS; TRANSPORTING
B33Y40/00
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0665
PERFORMING OPERATIONS; TRANSPORTING
B22F2999/00
PERFORMING OPERATIONS; TRANSPORTING
B22F10/50
PERFORMING OPERATIONS; TRANSPORTING
Y02P10/25
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B23K26/06
PERFORMING OPERATIONS; TRANSPORTING
B23K26/08
PERFORMING OPERATIONS; TRANSPORTING
B23K26/12
PERFORMING OPERATIONS; TRANSPORTING
B23K35/28
PERFORMING OPERATIONS; TRANSPORTING
B23K35/30
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y40/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method for producing a component by means of an additive manufacturing method using a laser is proposed, the method comprising the following steps: (a) providing a metal powder, (b) applying a powder layer (18) of the metal powder to a build platform (14) of a process chamber (12), (c) introducing a first process gas into the process chamber (12), (d) melting a first selected region (36) of the applied powder layer (18) by means of a laser in a first atmosphere which includes the first process gas, (e) introducing a second process gas into the process chamber (12), wherein the second process gas differs from the first process gas at least in terms of its composition and/or its pressure, and (f) melting a second selected region (38) of the applied powder layer (18) by means of the laser in a second atmosphere which includes the second process gas, wherein the second selected region (38) differs from the first selected region (36).
Claims
1. Method for producing a component by means of an additive manufacturing method using a laser, the method comprising the following steps: (a) providing a metal powder, (b) applying a powder layer of the metal powder to a build platform of a process chamber, (c) introducing a first process gas into the process chamber, (d) melting a first selected region of the applied powder layer by means of a laser in a first atmosphere which includes the first process gas, (e) introducing a second process gas into the process chamber, wherein the second process gas differs from the first process gas at least in terms of its composition and/or its pressure, and (f) melting a second selected region of the applied powder layer by means of the laser in a second atmosphere which includes the second process gas, wherein the second selected region differs from the first selected region.
2. Method according to claim 1, furthermore comprising repeating, in particular repeating multiple times, at least steps (a) to (d) and/or repeating, in particular repeating multiple times, steps (e) and (f).
3. Method according to claim 1, wherein the metal powder is a metal alloy, in particular aluminium alloy, or the metal powder is composed of at least 55% Fe, in particular at least 75% Fe and at most 99% Fe, in particular at most 80% Fe, preferably at least 1% Ni, in particular at least 10% Ni and at most 24% Ni, preferably at least 1% Cr, in particular at least 8% Cr and at most 35% Cr, and also at least one additional alloying element selected from the group consisting of C, Mo, Mn, Cu, W, V, Si, Ta, Nb and Ti.
4. Method according to claim 1, wherein the first process gas and/or the second process gas include(s) at least one gas selected from the group consisting of: argon, helium, nitrogen, carbon monoxide, carbon dioxide, methane, propane, hydrogen and oxygen.
5. Method according to claim 1, wherein the first process gas and the second process gas include hydrogen, wherein the concentration of hydrogen in the first process gas is higher than the concentration of hydrogen in the second process gas.
6. Method according to claim 1, wherein during the melting in step (d) and/or in step (f) a pressure in the process chamber is varied.
7. Method according to claim 1, furthermore comprising at least partially heat treating the applied layer during the melting in step (d) and/or in step (f) and/or at least partially heat treating the applied layer after the melting in step (d) and/or in step (f), wherein the heat treatment comprises melting, sintering, annealing, stress relief annealing, diffusion annealing or low hydrogen annealing, with the heat treatment preferably being effected by means of a defocused laser.
8. Method according to claim 1, furthermore comprising arranging a glass plate at a predetermined distance from the applied powder layer, the predetermined distance being in a range from 0.5 mm to 20.0 cm and preferably from 1.0 cm to 10.0 cm, wherein the first process gas and/or the second process gas are introduced into the process chamber in such a way that a laminar gas flow above the applied powder layer is generated.
9. Method according to claim 1, wherein the laser oscillates during the melting in step (d) and/or in step (f), and/or a power and/or a focus of the laser are varied during the melting in step (d) and/or in step (f).
10. Method according to claim 1, wherein the melting in step (d) is carried out in such a way that the first selected region is at least partially melted again, and/or the melting in step (f) is carried out in such a way that the second selected region is at least partially melted again.
11. Method according to claim 1, furthermore comprising applying or introducing at least one alloying element, especially in the form of a suspension, onto/into the applied powder layer in the first selected region and/or in the second selected region.
12. Method according to claim 11, wherein the alloying element is applied or introduced by means of a printhead.
13. Method according to claim 1, wherein the melting in step (d) is carried out in such a way that the first selected region after a subsequent cooling has a first metallurgical structure, wherein the melting in step (f) is carried out in such a way that the second selected region after a subsequent cooling has a second metallurgical structure, and wherein the second metallurgical structure differs from the first metallurgical structure.
14. Method according to claim 1, furthermore comprising changing between the first process gas and the second process gas by moving a sealing slide (56) within the process chamber relative and in particular parallel to the build platform.
15. Apparatus for producing a component by means of an additive manufacturing method using a laser, comprising: a process chamber having a build platform, an application apparatus, in particular a doctor blade, for applying a powder layer of a metal powder to the build platform, a process gas nozzle for introducing process gas into the process chamber, at least one laser source for emitting a laser onto the powder layer and a valve assembly for the selective supply of process gas to the process gas nozzle, wherein the valve assembly has at least a first valve path and a second valve path, wherein the valve assembly is connectible to a first process gas source and to a second process gas source, wherein the first valve path and the second valve path are actuable separately from one another in such a way that a first process gas from the first process gas source and/or a second process gas from the second process gas source are selectively introducible into the process chamber by means of the process gas nozzle.
16. Apparatus according to claim 15, furthermore comprising a control apparatus for automatically controlling the valve assembly on the basis of numerical data which define the geometric form of the component to be produced.
17. Apparatus according to claim 15, furthermore comprising a sealing slide, wherein the sealing slide is movable within the process chamber relative and preferably parallel to the build platform.
18. Apparatus according to claim 17, wherein the sealing slide is connected to the application apparatus, wherein the application apparatus is movable relative to the build platform.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0169] Further optional details and features of the invention are apparent from the following description of preferred examples shown diagrammatically in the figures.
[0170] In the figures:
[0171]
[0172]
[0173]
[0174]
[0175]
[0176]
[0177]
EMBODIMENTS OF THE INVENTION
[0178]
[0179] In the embodiment shown, the control apparatus 34 is furthermore designed to control the laser source 22, the build platform 14 and the application apparatus 16.
[0180] The method for producing a component by means of an additive manufacturing method using a laser is described in detail hereafter on the basis of
[0181] As shown in
[0182] As shown in
[0183] As shown in
[0184] Subsequently, the control apparatus 34 lowers the build platform 14 by a predetermined distance which corresponds to the height of a further powder layer 18 to be subsequently applied. For this further powder layer 18, too, the first process gas is introduced and a first selected region of the further powder layer is melted, and/or the second process gas is introduced and a second selected region of the powder layer is melted. These steps can be repeated as required until the component has been completely produced layer-by-layer. In the process, each further molten layer or regions0 thereof, during subsequent cooling, forms a permanent bond with the layer located directly underneath.
[0185] Since the process gas used as protective gas has an influence on the phase transformation of a metal alloy, but does not interact significantly, if at all, with the metal powder or with the solidified component, the process gas is changed within a build job, preferably within a build plane, in order to achieve different properties in different regions of the build job or of the build plane. Expediently, scan vectors/regions to be selectively melted on a build plane having the same target property are collectively exposed by means of the laser, since a change of process gas takes longer than a change from one scan position to the next.
[0186] In addition to the use of discrete process gases, these can also be continuously mixed with varying composition. This allows, for example, graded materials to be produced. In particular, steels can be carburized using carbon-releasing process gases and the austenite proportion can be increased by nitrogen or nitrogen-containing atmosphere as opposed to purely inert process gases. A low proportion of oxygen in the process gas (a few percent) can reduce the proportion of carbon by means of oxidation. Using hydrogen-containing atmosphere, especially in the case of aluminium, can generate a porosity in the material in a controlled manner depending on the hydrogen content. This is based on the fact that the solubility of hydrogen in aluminium in the liquid state is markedly higher than in the solid state. On solidification, the no longer soluble hydrogen is expelled in the form of small pores. Depending on the original partial pressure of hydrogen in the process gas atmosphere, or dissolved in the aluminium melt, large or small pores, or even no pores, are formed.
[0187] The method can be modified as follows.
[0188] During the melting of the first selected region and/or of the second selected region, a pressure in the process chamber can be varied.
[0189] During the melting of the first selected region and/or of the second selected region, the applied layer can be at least partially heat treated. Alternatively or additionally, the method can furthermore comprise at least partially heat treating the applied layer after that of the first selected region and/or of the second selected region. For example, the heat treatment can be effected by means of a defocused laser. The first process gas and/or the second process gas can be introduced into the process chamber in such a way that a laminar gas flow above the applied powder layer is generated. Furthermore, a glass plate can be arranged at a predetermined distance from the applied powder layer, the predetermined distance being in a range from 0.5 mm to 20.0 cm and preferably from 1.0 cm to 10.0 cm. The laser can oscillate during the melting of the first selected region and/or of the second selected region. The melting of the first selected region and/or of the second selected region can be carried out in such a way that the first selected region and/or the second selected region are at least partially melted again. A power and/or a focus of the laser can be varied during the melting of the first selected region and/or of the second selected region.
[0190]
[0191] The Schaeffler diagram shown in
[0192] The strong influence of nitrogen on the nickel equivalent is evident in the Schaeffler diagram by the factor 7.5. Other diagrams known from the prior art, such as for example the DeLong diagram, even indicate a factor of 30 for the influence of nitrogen. This means that for the abovedescribed shift along the arrow 40 the nitrogen proportion in an alloy only needs to be increased by a proportion of less than 1%.
[0193] In order to be able to significantly modify the developing microstructure of an alloy by a minor change in nickel or chromium equivalent, it is necessary for the alloy composition of the starting powder to be close to a boundary region in the Schaeffler diagram. This is illustrated by the plotted alloys along the arrows 40 and 42 in the Schaeffler diagram. Various methods can be used in this case to achieve a particular alloy composition. Firstly, a base material having the desired alloy composition may be atomized directly. Secondly, pre-atomized powders of various alloys may be mixed or supplemented with particular elemental powders. Here, however, sufficient mixing of the powders should be ensured in order to achieve a uniform chemical composition within a build job.
[0194]
[0195]
[0196] With the apparatus 10 of
[0197] The explanations hereinbelow apply equally both to the method described in connection with
[0198] By changing the process gas, the chemical composition of the material is modified in a spatially delimited manner in particular by the following proportions. An increase in the carbon proportion by up to 1.0%, in particular 0.2%, more particularly 0.08% and yet more particularly 0.03% can be realized via CO.sub.2 or CO. To increase the carbon content, in particular process gases having a CO.sub.2 proportion of from 100% down to 20% or in particular down to 5% and especially in the case of high alloy steels down to 2%, can be used in order to set the desired effect.
[0199] A reduction in the carbon content is possible by means of oxygen-containing process gases having an oxygen content of up to 15%, in particular an oxygen content of up to 5%, especially an oxygen content of 2%. The reduction in the carbon proportion here is in particular up to 70%, especially up to 30% of the initial content.
[0200] Nitrogen oxides NOx may also be used as process gases. This can simultaneously increase the nitrogen content and reduce the carbon content. This is of interest in particular when the intention is to influence the hardenability and the maximum achievable hardness.
[0201] An increase in the nitrogen content can be effected both by nitrogen of technical grade purity and by mixtures of nitrogen with inert gases, such as for example helium, argon, or other active gases, such as for example CO.sub.2, CO. The nitrogen proportion here may optionally be up to 100%, preferably up to 20% and in particular up to 2%.
[0202] The nitrogen proportion in the material in the process changes preferably by up to 0.6%, in particular up to 0.2%, especially in particular up to 0.05% and by a minimum of 0.01%, in particular
[0203] by a minimum of 0.03% and especially 0.08%.
[0204] Not all alloying elements are expediently convertible into a gaseous state or usable as such in the process. In order to modify the chemical composition by means of such elements, alloying elements can also be used in the solid state as described above. For improved meterability of the alloying elements in the printhead, these can in particular be printed in the form of a suspension. The materials used here are in particular chromium, silicon, molybdenum and titanium and possibly carbon, for example in the form of graphite. Chemical compounds with these elements, such as for example oxides, carbides or nitrides, are optionally also applicable, possibly also as a solution.
[0205] The powders which are applied with a printhead, especially in the form of a suspension, have a particle size which is far below the size of the material particles applied with the doctor blade, which have a size of approx. 10-100 m. The size of the particles applied by the printhead is in particular of the magnitude of below 10 m, in particular below 3 m and more particularly below 1 m.
[0206] The proportions of the mentioned alloying elements that are applied with the printhead are, proportional to the mass of the materials applied by the doctor blade, only up to at most 20%, in particular at most 7% and more particularly up to at most 2%.
[0207] Starting materials based on iron are in particular composed correspondingly:
[0208] At least 55%, in particular at least 75%, at most 99%, in particular at most 80% iron.
[0209] Preferably at least 1%, in particular at least 10% and at most 24% nickel.
[0210] Preferably at least 1% chromium, in particular at least 8% chromium and at most 35% chromium.
[0211] Additional alloying elements are typically: carbon, molybdenum, manganese, copper, tungsten, vanadium, silicon, tantalum, niobium and titanium.
[0212] The elements nitrogen and optionally carbon can on the one hand be greatly reduced in the starting material in order to achieve a large modification of the microstructure properties by addition of these elements in the SLM process (SLMselective laser melting). The nitrogen proportion and the carbon proportion can be limited to 0.1%, in particular 0.04%, more particularly to up to 0.01%. On the other hand, already relatively high nitrogen and carbon contents of for example 0.2% in the starting material may be used and these then reduced locally in the process.
[0213]
[0214] The aim of the apparatus 10 is to realize differing material and alloying states in a layer plane. To this end, gas changes are required not only once, but multiple times, for example more than 100 gas changes, over the entire process duration. One problem with this is that a large gas volume in the system always has to be exchanged. On account of the large gas volume, the system is sluggish and a change takes a very long time, for example a few minutes. Since the gas change takes place by way of a displacement with the new process gas, this is accompanied by high gas consumption and high costs. The apparatus of
[0215]