MULTI-WAVELENGTH LIGHT-EMITTING SEMICONDUCTOR DEVICES
20230040688 · 2023-02-09
Assignee
Inventors
Cpc classification
H01S5/32375
ELECTRICITY
H01S5/18386
ELECTRICITY
H01S5/32358
ELECTRICITY
H01S5/18305
ELECTRICITY
H01S2301/176
ELECTRICITY
H01S5/18397
ELECTRICITY
H01S5/18391
ELECTRICITY
H01S5/18394
ELECTRICITY
International classification
Abstract
A multi-wavelength light-emitting semiconductor device and a method of fabricating the same are disclosed. The semiconductor device includes a substrate, a first reflector on the substrate, a light emission layer on the first reflector, second reflectors on corresponding active regions; and apertures on corresponding active regions. The light emission layer includes active regions. Each of the active regions includes a primary emission wavelength different from each other.
Claims
1. A semiconductor device, comprising: a substrate; a first reflector on the substrate; a light emission layer on the first reflector, wherein the light emission layer comprises active regions, and wherein each of the active regions comprises a primary emission wavelength different from each other; second reflectors on corresponding active regions; and apertures on corresponding active regions.
2. The semiconductor device of claim 1, wherein the light emission layer comprises a III-V compound semiconductor material with a nitrogen atom concentration between about 0% and about 5% of the group V materials.
3. The semiconductor device of claim 1, wherein the light emission layer comprises a III-V compound semiconductor material with an indium atom concentration between about 0% and about 20% of the group III materials.
4. The semiconductor device of claim 1, wherein the light emission layer comprises a gallium arsenide-based dilute nitride semiconductor material, an indium phosphide-based dilute nitride semiconductor material, or a gallium phosphide-based dilute nitride semiconductor material; and wherein the gallium arsenide-based dilute nitride semiconductor material comprises gallium arsenide nitride (GaAsN), indium gallium arsenide nitride (InGaAsN), or aluminum gallium antimonide phosphide nitride (AlGaSbPN).
5. The semiconductor device of claim 1, wherein the light emission layer comprises gallium indium nitride arsenide antimonide (GalnNAsSb) with a nitrogen atom concentration between about 0% and about 5% of the group V materials, an indium atom concentration between about 0% and about 20% of the group III materials, and an antimony atom concentration between about 0% and about 6% of the group V materials.
6. The semiconductor device of claim 1, wherein each of the second reflectors comprises a stack of dielectric layers; and wherein the stack of dielectric layers comprises a metal oxide, a metal sulfide, a metal halide, an oxynitrides, or a combination thereof.
7. The semiconductor device of claim 1, wherein each of the apertures comprises a III-V compound semiconductor material with an aluminum atom concentration between about 80% and about 100% of the group III materials.
8. The semiconductor device of claim 1, further comprising insulating structures on corresponding second reflectors, wherein the insulating structures are substantially aligned with corresponding apertures.
9. The semiconductor device of claim 1, further comprising grating structures on corresponding second reflectors, wherein the grating structures have periodic patterns different from each other, and wherein the grating structures comprise a polymeric material.
10. The semiconductor device of claim 1, further comprising: insulating structures disposed on the substrate; and contact structures surrounding corresponding insulating structures.
11. The semiconductor device of claim 1, further comprising: grating structures disposed on the substrate; and contact structures surrounding corresponding grating structures.
12. A method, comprising: forming a bottom reflector on a first side of a substrate; forming a light emission layer with first and second active regions on the bottom reflector, wherein the first and second active regions comprise an initial primary emission wavelength; forming first and second top reflectors on the first and second active regions, respectively; forming first and second apertures on the first and second active regions, respectively; performing an anneal process on the first and second active regions to shift the initial primary emission wavelength to first and second primary emission wavelengths, respectively, wherein the first and second primary emission wavelengths are different from each other.
13. The method of claim 12, wherein performing the anneal process on the first and second active regions comprises: selectively annealing the first active region at a first annealing condition to shift the initial primary emission wavelength of the first active region to the first primary emission wavelength; and selectively annealing the second active region at a second annealing condition to shift the initial primary emission wavelength of the second active region to a second primary emission wavelength, wherein the first and second annealing conditions are different from each other.
14. The method of claim 12, wherein performing an anneal process on the first and second active regions comprises performing a laser anneal process.
15. The method of claim 12, further comprising: forming first and second capping structures on the first and second top reflectors, wherein thicknesses of the first and second capping structures are different from each other.
16. The method of claim 15, wherein forming the first and second capping structures comprises: depositing a layer of polymeric material over the light emission layer; and transferring a mold pattern on the layer of polymeric material.
17. The method of claim 12, further comprising: forming first and second grating structures on the first and second top reflectors, wherein periodic patterns of the first and second grating structures are different from each other.
18. The method of claim 17, wherein forming the first and second grating structures comprises: depositing a layer of polymeric material over the light emission layer; and transferring a mold pattern on the layer of polymeric material.
19. The method of claim 12, further comprising: forming first and second capping structures on a second side of the substrate, wherein thicknesses of the first and second capping structures are different from each other; and/or forming first and second grating structures on a second side of the substrate, wherein periodic patterns of the first and second grating structures are different from each other.
20. The method of claim 12, wherein forming the light emission layer comprises epitaxially growing, on the bottom reflector, a dilute nitride semiconductor material with a nitrogen atom concentration between about 0% and about 5% of the group V materials.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0041] Aspects of this disclosure are best understood from the following detailed description when read with the accompanying figures.
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[0050] Illustrative embodiments will now be described with reference to the accompanying drawings. In the drawings, like reference numerals generally indicate identical, functionally similar, and/or structurally similar elements. The discussion of elements with the same annotations applies to each other, unless mentioned otherwise.
DETAILED DESCRIPTION
[0051] The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the process for forming a first feature over a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. As used herein, the formation of a first feature on a second feature means the first feature is formed in direct contact with the second feature. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition does not in itself dictate a relationship between the embodiments and/or configurations discussed herein.
[0052] Spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper,” and the like, may be used herein for ease of description to describe one element or feature’s relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
[0053] It is noted that references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” “exemplary,” etc., indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Further, when a particular feature, structure or characteristic is described in connection with an embodiment, it would be within the knowledge of one skilled in the art to effect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
[0054] It is to be understood that the phraseology or terminology herein is for the purpose of description and not of limitation, such that the terminology or phraseology of the present specification is to be interpreted by those skilled in relevant art(s) in light of the teachings herein.
[0055] In some embodiments, the terms “about” and “substantially” can indicate a value of a given quantity that varies within 5% of the value (e.g., ±1 %, ±2 %, ±3 %, ±4 %, ±5 % of the value). These values are merely examples and are not intended to be limiting. The terms “about” and “substantially” can refer to a percentage of the values as interpreted by those skilled in relevant art(s) in light of the teachings herein.
[0056]
[0057] In some embodiments, VCSEL 102A is formed by the following: active region 108A; aperture 110A; oxidation layer 112A; second reflector 114A; passivation layers 116 on sidewalls of second reflector 114A; first contact 118A; second contact 120A; and the portions of first reflector 106 and substrate 104 underlying active region 108A. Similarly, VCSEL 102B is formed by the following: active region 108B; aperture 110B; oxidation layer 112B; second reflector 114B; passivation layers 116 on sidewalls of second reflector 114B; first contact 118B; second contact 120B; and the portions of first reflector 106 and substrate 104 underlying active region 108B. And, VCSEL 102C is formed by the following: active region 108C; aperture 110C; oxidation layer 112C; second reflector 114C; passivation layers 116 on sidewalls of second reflector 114C; first contact 118C; second contact 120C; and the portions of first reflector 106 and substrate 104 underlying active region 108C. Though
[0058] Substrate 104 can be a semiconductor material, such as silicon (Si), germanium (Ge), silicon germanium (SiGe), gallium arsenide (GaAs), gallium phosphide (GaP), indium phosphide (InP), other suitable III-V compound semiconductor materials, diamond, compounds of group IV of the periodic table, and a combination thereof. In some embodiments, substrate 104 can include a stack of a Ge epitaxial layer on a Si layer, a stack of SiGe epitaxial layer on a Si layer, or other stacks of a semiconductor epitaxial layer on a Si layer, a GaAs layer, a GaP layer, an InP layer, or a diamond layer. In some embodiments, substrate 104 can be doped with n-type or p-type dopants. In some embodiments, substrate 104 can include GaAs with Si dopants. In some embodiments, substrate 104 can include GaAs with zinc (Zn) dopants.
[0059] First reflector 106 can be disposed on front side 104f of substrate 104. In some embodiments, first reflector 106 can include a conductive distributed Bragg reflector (DBR). First reflector 106 can include a stack of n-type or p-type semiconductor layers 109A-109B arranged in an alternating configuration. Semiconductor layers 109A-109B can have materials different from each other and refractive indices different from each other. In some embodiments, semiconductor layers 109A-109B can include epitaxially-grown materials or deposited materials. In some embodiments, semiconductor layers 109A-109B can include GaAs, aluminum gallium arsenide (AlGaAs), indium gallium arsenide (InGaAs), aluminum arsenide (AlAs), indium aluminum arsenide (InAIAs), other suitable III-V compound semiconductor materials, or a combination thereof. Semiconductor layers 109A-109B can include n-type or p-type dopants. In some embodiments, semiconductor layer 109A can include a III-V compound semiconductor material with a higher aluminum (Al) content (e.g., atomic concentration of Al atoms between about 80% and about 99%) and a lower refractive index than that of the III-V compound semiconductor material of semiconductor layer 109B, which can have an atomic concentration of Al atoms between about 5% and about 20%. In some embodiments, semiconductor layer 109A can include AlGaAs and semiconductor layer 109B can include GaAs. Both semiconductor layers 109A-109B can include Si, Ge, tellurium (Te), sulfur (S), or selenium (Se) dopants to form n-type semiconductor layers 109A-109B or can include carbon (C), beryllium (Be), magnesium (Mg), or zinc (Zn) dopants to form p-type semiconductor layers 109A-109B.
[0060] Similar to first reflector 106, each of second reflectors 114A-114C can include a conductive DBR. Second reflectors 114A-114C with first reflector 106 form the vertical cavities of VCSELs 102A-102C. Each of second reflectors 114A-114C can include a stack of p-type or -n-type semiconductor layers 113A-113B arranged in an alternating configuration. The discussion of semiconductor layers 109A-109B applies to semiconductor layers 113A-113B, unless mentioned otherwise. In some embodiments, semiconductor layer 113A can include AlGaAs and semiconductor layer 113B can include GaAs. Semiconductor layers 109A-109B can include C, Be, Mg, or Zn dopants to form p-type semiconductor layers 113A-113B or can include Si, Ge, Te, S, or Se dopants to form n-type semiconductor layers 113A-113B. In some embodiments, dimensions of each second reflectors 114A-114C along an X-axis and/or a Y-axis can be about 20 .Math.m and dimensions of each second reflectors 114A-114C along a Z-axis can range between about 5 .Math.m and about 20 .Math.m. The growth direction of semiconductor layers 109A-109B and 113A-113B is along a Z-axis. The sidewalls of second reflectors 114A-114C can be covered by passivation layers 116 including an insulation material, such as oxides or nitrides to protect second reflectors 114A-114C from oxidation.
[0061] In some embodiments, instead of including a conductive DBR, each of second reflectors 114A-114C can include a non-conductive DBR. The non-conductive DBR can include a stack of two dielectric layers with different refractive indices arranged in an alternating configuration. The dielectric layers can include dielectric materials, such as magnesium fluoride, silicon oxide, tantalum pentoxide, zinc sulfide, titanium dioxide, aluminum oxide, silicon oxynitrides, cadmium sulfide, other suitable dielectric metal oxides, metal sulfides, metal halides, oxynitrides, or a combination thereof.
[0062] In some embodiments, light emission layer 107 can be disposed on first reflector 106. Light emission layer 107 can include one or more quantum well structures configured to emit light. The primary emission wavelength of the light emitted by light emission layer 107 can depend on the energy band gaps of the materials of the one or more quantum well structures. The one or more quantum well structures can be formed by one or more layers of dilute nitride materials included in light emission layer 107. The one or more layers of dilute nitride materials can include epitaxially-grown materials or deposited materials.
[0063] The one or more layers of dilute nitride materials can be substantially lattice matched to the material of substrate 104, according to some embodiments. In some embodiments, the dilute nitride materials can include a III-V compound semiconductor material with group III material(s) having about 50% atomic concentration of the total atomic concentration of the III-V compound semiconductor material and group V material(s) having about 50% atomic concentration of the total atomic concentration of the III-V compound semiconductor material. The group III material(s) of the dilute nitride material can include indium (In) atoms with an atomic concentration between about 0% and about 20% of the total atomic concentration of the group III material(s) for lattice matching the dilute nitride materials with the material (e.g., GaAs) of substrate 104. The group V material(s) of the dilute nitride material can include nitrogen atoms that have an atomic concentration between about 0% and about 5% of the total atomic concentration of the group V material(s). The atomic concentration of nitrogen atoms in the III-V compound semiconductor materials can reduce the energy band gaps of the III-V compound semiconductor materials and tune the emission wavelength of the dilute nitride materials to be longer than that of the III-V compound semiconductor materials without nitrogen atoms.
[0064] In some embodiments, light emission layer 107 can include a gallium arsenide-based dilute nitride material, an indium phosphide-based dilute nitride material, or a gallium phosphide-based dilute nitride material. In some embodiments, light emission layer 107 can include gallium arsenide nitride (GaAsN), indium gallium arsenide nitride (InGaAsN), gallium arsenide nitride antimonide (GaAsNSb), gallium indium nitride arsenide antimonide (GalnNAsSb), indium phosphide (InP), indium gallium arsenide (InGaAs), indium gallium arsenide nitride (InGaAsN), gallium arsenide antimonide (GaAsSb), indium gallium arsenide antimonide nitride (InGaAsSbN), gallium antimonide phosphide (GaSbP), gallium antimonide phosphide nitride (GaSbPN), indium gallium antimonide phosphide nitride (InGaSbPN), aluminum gallium antimonide phosphide nitride (AlGaSbPN), aluminum arsenide antimonide (AlAsSb), indium aluminum arsenide antimonide (InAIAsSb), indium aluminum arsenide antimonide nitride (InAIAsSbN), indium aluminum arsenide (InAIAs), indium aluminum arsenide antimonide (InAIAsSb), indium aluminum arsenide nitride (InAIAsN), indium aluminum arsenide nitride antimonide (InAIAsNSb), other suitable dilute nitride materials, or combinations thereof. In some embodiments, light emission layer 107 can include GalnNAsSb with a nitrogen atom concentration between about 0% and about 5%, an indium atom concentration between about 0% and about 20%, and an antimony atom concentration between about 0% and about 6%. In some embodiments, the thickness of light emission layer 107 can range from about 1 nm to about 20 nm. In some embodiments, light emission layer 107 can include multiple quantum well structures.
[0065] In some embodiments, light emission layer 107 includes active regions 108A-108C with primary emission wavelengths that are different from each other, and as a result, VCSELs 102A-102C emit light with primary emission wavelengths that are different from each other. The primary emission wavelengths of active regions 108A-108C are tuned to be different from each other by selectively processing each of active regions 108A-108C, which is described in detail below with reference to
[0066] In some embodiments, apertures 110A-110C can be disposed on active regions 108A-108C, respectively. Apertures 110A-110C can confine the flow of drive current to active regions 108A-108C, respectively, and consequently define the shape and size of the emission window (e.g., define the diameter of a circular or cylindrical emission window) of active regions 108A-108C, respectively. In some embodiments, each of apertures 110A-110C can include an Al-based III-V compound semiconductor layer with a concentration of Al atoms between about 80% and about 99%. In some embodiments, each of apertures 110A-110C can include a layer of AlGaAs, AlAs, InAIAs, AlGaSbP, AlAsSb, InAlAsSb, InAIAsSb, other suitable Al-based III-V compound semiconductor materials, or combinations thereof. In some embodiments, the Al-based III-V compound semiconductor layer includes an epitaxially-grown material or a deposited material.
[0067] In some embodiments, each of apertures 110A-110C can have a thickness along a Z-axis between about 5 nm and about 50 nm. In some embodiments, each of apertures 110A-110C can have a thickness along a Z-axis between about 10 nm and about 20 nm. In some embodiments, each of apertures 110A-110C can have a dimension D1 (e.g., width or diameter) along an X-axis between about 8 .Math.m and about 12 um. The dimensions of apertures 110A-110C along an X-axis can be defined by the lateral dimensions of oxidation layers 112A-112C surrounding apertures 110A-110C, respectively. Oxidation layers 112A-112C can include an oxide of the Al-based III-V compound semiconductor material of apertures 110A-110C. The oxide material of oxidation layers 112A-112C blocks the flow of drive current to the portions of active regions 108A-108C underlying oxidation layers 112A-112C. The oxide material also funnels the flow of drive current, and consequently increases current density. In addition, the oxide material blocks light emission from light emission layer 107 and focuses the light emission through apertures 110A-110C. In some embodiments, oxidation layers 112A-112C can have a thickness along a Z-axis substantially equal to the thickness of apertures 110A-110C.
[0068] In some embodiments, first contacts 118A-118C can be disposed on second reflectors 114A-114C, respectively, to inject charge carriers into second reflectors 114A-114C and can include a conductive material. For a top-emitting configuration of VCSELs 102A-102C, each of first contacts 118A-118C can include an opening 119 that is aligned to a corresponding one of apertures 110A-110C to allow emission of light from active regions 108A-108C through second reflectors 114A-114C. Each opening 119 can have a dimension D2 (e.g., width or diameter) along an X-axis that is substantially equal to or greater than dimension D1 of apertures 110A-110C. In some embodiments, first contacts 118A-118C can have annular-shaped structures.
[0069] In some embodiments, second contacts 120A-120C can be disposed on back-side 104b of substrate 104 to inject charge carriers into first reflector 106 and can include a conductive material. For a top-emitting configuration of VCSELs 102A-102C, each of second contacts 120A-120C is formed as a continuous layer on each of the portions of substrate 104 corresponding to VCSELs 102A-102C, as shown in
[0070] In some embodiments, instead of first contacts 118A-118C on second reflectors 114A-114C, VCSELs 102A-102C can have first contacts 3318A-3318C between second reflectors 114A-114C and active regions 108A-108C, as shown in
[0071]
[0072]
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[0074] In some embodiments, first contacts 418A-418C can be disposed on second reflectors 114A-114C, respectively, and can include a conductive material. For a back-emitting configuration of VCSELs 402A-402C, each of first contacts 418A-418C are formed as continuous layers on second reflectors 114A-114C, respectively.
[0075] In some embodiments, second contacts 420A-420C can be disposed on back-side 104b of substrate 104 and can include a conductive material. For a back-emitting configuration of VCSELs 402A-402C, second contacts 420A-420C can include openings (not labelled), in which grating structures 422A-422C are disposed. Grating structures 422A-422C are aligned to corresponding apertures 110A-110C to allow emission of light from active regions 108A-108C through substrate 104. The openings can have dimensions D3 (e.g., width or diameter) along an X-axis that is substantially equal to or greater than dimension D1 of apertures 110A-110C. In some embodiments, second contacts 420A-420C can have annular-shaped structures. Grating structures 422A-422C can have periodic patterns that are different from each other along an X-axis, a Y-axis, and/or a Z-axis and can have thicknesses that vary from each other along a Z-axis. Grating structures 422A-422C can be used to tune the primary emission wavelength of light emitting from active regions 108A-108C through substrate 104. Grating structures 422A-422C can also be used for selective processing of active regions 108A-108C, as described in detail below with reference to
[0076]
[0077] In some embodiments, VCSELs 502A-502C can include tunnel junction structures 523A-523C disposed between apertures 110A-110C and active regions 108A-108C. In some embodiments, instead of being disposed between apertures 110A-110C and active regions 108A-108C, tunnel junction structures 523A-523C can be disposed between apertures 110A-110C and second reflectors 514A-514C (not shown). In some embodiments, instead of being disposed between apertures 110A-110C and active regions 108A-108C, tunnel junction structures 523A-523C can be disposed between apertures 110A-110C and first reflectors 106 of
[0078]
[0079] In operation 605, a first reflector is formed on a first side of a substrate. For example, as shown in
[0080] Referring to
[0081] Referring to
[0082] Referring to
[0083] Referring to
[0084] Referring to
[0085] Following the selective anneal of active region 708A, as shown in
[0086] Following the selective anneal of active region 708B, as shown in
[0087] In some embodiments, one or more of the annealing conditions (e.g., temperature, duration, etc.) can be different between the first, second, and third sets of annealing conditions. In some embodiments, the annealing temperature can be the same (e.g., about 600° C.) in the first, second, and third sets of annealing conditions, and the annealing duration can be different from each other in the first, second, and third sets of annealing conditions. In some embodiments, the laser spot size used in the laser anneal process can range between about 10 .Math.m and 20 .Math.m. Though the selective annealing of active regions 708A-708C is illustrated as being performed in the order of active region array, the selective annealing can be performed in any order. For example, active region 708C can be selectively annealed after active region 708A. And, active region 708B can be selectively annealed after active region 708C.
[0088] In some embodiments, the annealing process can be performed on back side 104b of substrate 104, instead of performing on the front side of the structure, as shown in
[0089] Referring to
[0090] In some embodiments, operation 635 may not be performed if first contacts 3318A-3318C are formed between second reflectors 114A-114C and active regions 108A-108C—rather than first contacts 118A-118C being formed on second reflectors 114A-114C, as shown in
[0091]
[0092] Referring to
[0093] Referring to
[0094] Referring to
[0095] Referring to
[0096] Referring to
[0097] Referring to
[0098] Referring to
[0099] In some embodiments, the annealing process can be performed on back side 104b of substrate 104, instead of performing on the front side of the structure, as shown in
[0100] Referring to
[0101] Referring to
[0102] In some embodiments, operation 1550 may not be performed if first contacts 3318A-3318C are formed between second reflectors 114A-114C and active regions 108A-108C—rather than first contacts 118A-118C being formed on second reflectors 114A-114C, as shown in
[0103] In some embodiments, instead of forming first contacts 118A-118C and second contacts 120A-120C in operation 1550, first contacts 418A-418C can be formed as electrical contacts on second reflectors 114A-114C, and second contacts 420A-420C can be formed as annular-shaped electrical contacts on back side 104b of substrate 104 with openings 2219 aligned with apertures 110A-110C, as shown in
[0104] In some embodiments, in operation 1520, instead of forming capping structures 1730A-1730C, grating structures 322A-322C can be formed by transferring a mold pattern on polymeric material layer 1630 to form the structure of
[0105]
[0106] Referring to
[0107] Referring to
[0108] Referring to
[0109] Referring to
[0110] Referring to
[0111] In some embodiments, instead of forming first contacts 118A-118C and second contacts 120A-120C in operation 2545, first contacts 418A-418C can be formed as electrical contacts on second reflectors 114A-114C and second contacts 420A-420C can be formed as annular-shaped electrical contacts on back side 104b of substrate 104 with openings 2219 aligned with apertures 110A-110C, as shown in
[0112] In some embodiments, in operation 2530, instead of forming capping structures 1730A-1730C, grating structures 422A-422C can formed by transferring a mold pattern on polymeric material layer 1630 to form the structure of
[0113] The foregoing disclosure outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the scope of the present disclosure.