Method using plasma-coupled solar thermal energy and related device
10829837 ยท 2020-11-10
Inventors
Cpc classification
Y02P20/133
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02T50/678
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01J8/10
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/0822
PERFORMING OPERATIONS; TRANSPORTING
B01J2208/00415
PERFORMING OPERATIONS; TRANSPORTING
B01J19/088
PERFORMING OPERATIONS; TRANSPORTING
B01J8/087
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/0809
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/0871
PERFORMING OPERATIONS; TRANSPORTING
B01J2208/00389
PERFORMING OPERATIONS; TRANSPORTING
B01J19/087
PERFORMING OPERATIONS; TRANSPORTING
B01J19/20
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01J8/10
PERFORMING OPERATIONS; TRANSPORTING
C10K3/00
CHEMISTRY; METALLURGY
B01J19/08
PERFORMING OPERATIONS; TRANSPORTING
B01J19/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A microwave thermosolar method and device used in a tubular reactor (110) includes a conveyor for substrates defined as materials thus conveyed. According to this method, a step is provided for circulating an electric current in the conveyor in order to produce heat in this conveyor by Joule effect and optionally to cause, in the substrates, at least some of the following: curing, pyrolyses, gasifications, fusions and chemical reactions including oxidation-reduction reactions, under the action of the electric current.
Claims
1. A microwave thermosolar method implemented in a tubular reactor including a conveyor, the method comprising: conveying substrates in the conveyor, the substrates comprising alumina and at least one material other than alumina; circulating an electric current in the conveyor, in order to produce heat in the conveyor by Joule effect; and fusing the substrates, so that an electrolysis bath is obtained in which electric current is circulating, the electrolysis bath comprising aluminum issued from a reduction of the alumina into aluminum, under action of the electric current circulating in the electrolysis bath.
2. The method according to claim 1, wherein one of the substrates contains aluminum that is fused in the tubular reactor, under action of at least one energy from solar energy, microwave energy, and thermal energy produced by the circulation of said electric current in the substrate conveyor.
3. The method according to claim 1, wherein the conveying comprises conveying said substrates along a helical worm by rotating the helical worm.
4. The method according to claim 1, wherein said method induces, in the substrates, under the action of the electric current, at least one of a curing, pyrolyses, gasifications, fusions, and chemical reactions comprising oxidation-reduction reactions.
5. A method for conveying substrates in a microwave thermosolar device including a tubular reactor including a conveyor, said substrates being defined as materials thus conveyed, the method comprising: conveying said substrates by a system of successive conveyor pallets connected together by one of a cable and a chain, said conveyor pallets being adjusted to an inside diameter of the tubular reactor so that the substrates are trapped between two successive conveyor pallets and are pushed through the tubular reactor in order to traverse the tubular reactor.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The following description is given in relation to
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
(2) Thus various improvement devices for implementing the methods presented above are described below:
(3) In a particular embodiment, the solar/microwave part (F_smo) can be folded in a container such as lifting systems actuated by motors (F1.1) for lifting the solar/microwave reactor to a height or to lower it, and articulated systems and jacks for unfolding and folding the mirrors
(4) The reactor is placed on a support such as a carriage
(5) 1) In one embodiment, the functional unit allowing torrefaction and pyrolysis of the substrate is the solar/microwave furnace reactor (F_smo) comprising one or more pipes
(6) The corrugated structure will for example be included in a flange
(7) In a particular embodiment, the rotation of the mirrors enabling the travel of the sun to be followed, will comprise firstly a gearing system including a circular rack coupled to at least one pinion at each end of the reactor, and secondly rotation bearings, either external
(8) 2) At the entrance and exit of the reactor of the F_smo 110 systems will be disposed enabling the substrate to pass, but not the gases. The gases will enter and emerge from the reactor through one or more wells intended for this purpose. Thus the reactor will be isolated from the atmosphere by a method of loading and unloading the substrates.
(9) 2-1) At the entrance to and respectively the exit from the pipe of the reactor, there will for example be disposed a device 20, comprising two cylinders fitted together, turning in opposite directions, the innermost cylinder will be solid, and provided with a cavity 21 pierced in its bottom with a series of pores 22 opposite to the opening of the cavity 23. The outer cylinder 24, including the inner cylinder, will be provided with an opening 25 of the same size as the opening of the cavity of the inner cylinder 23. The two cylinders will be included in a cylindrical chamber 26 provided with two openings above and below of the same size as the openings of the aforementioned two cylinders, and two series of opposite pores disposed laterally in the equatorial position 27. Each series of pores of the cylindrical chamber will be disposed on an external series of bumps preventing the occlusion of the pores when crossing with the pores disposed on the inner cylinder during the rotation of the various cylinders. The inner and outer cylinders will be provided with a gearing system for example comprising two geared plates 28 making it possible to rotate them in opposite directions, by means for example at least one pinion disposed between the two plates.
(10) In position:
(11) a) the openings of the cylinders are aligned upwards with the opening of the cylindrical chamber, and allows filling of the cavity by the substrate;
(12) b) by turning through /2 in opposite directions the cavity of the inner cylinder is closed off by the outer cylinder while the pores of the bottom of the cavity are positioned facing the opening of the outer cylinder opposite the first series of bumps on the cylindrical chamber. The first series of bumps is connected to a vacuum pump voiding the atmosphere of the cavity (external atmosphere).
(13) c) by continuing the rotations in opposite directions through /2, the two openings of the inner and outer cylinders are aligned on the bottom opening of the cylindrical chamber, enabling the content of the cavity to be poured inside the reactor without contamination of the outside air, the pores of the bottom of the cavity being closed off by the outer cylinder;
(14) d) by continuing the rotation by /2, the pores of the bottom of the cavity align with the opening of the outer cylinder facing the second bump itself connected to a second vacuum making it possible to pump the atmosphere coming from the reactor to the inside of the reactor. Then another cycle recommences. The vacuums are produced by pump or Venturis pumping the atmospheres respectively to the outside and to the inside of the reactor.
(15) The sealing of the cylinders with respect to each other will for example be provided with metal S-shaped seals 29. The cavity of the inner chamber will be connected to the blowing system making it possible to eject the substrates in the low position.
(16) In a particular embodiment, the top cavity of the cylindrical chamber is connected to the bottom outlet of a loading cyclone.
(17) 2.1.1 In a particular embodiment, the loader and/or unloader will comprise two superimposed discs
(18) The movement is broken down into 4 steps.
(19) Step 1
(20) Step 2
(21) Step 3
(22) Step 4
(23) In some embodiments, a conduit or opening of the second top and bottom chamber sector of the discs makes it possible to discharge the substrate arriving in this sector.
(24) 2.1.2 In some embodiments the loader and/or unloader comprises a system of successive palets
(25) 2.2. In a particular embodiment, the device for discharging the substrates at the outlet from the discharger will comprise a system of cyclones. In a particular configuration, the system of cyclones will consist of a discharge cyclone 30 with a dual inlet, longitudinal 31 for the substrates and tangential 32 for the gases. The longitudinal inlet of the cyclone will comprise inclined paddles 33 so as to allow the liquid and substrates to pass, orienting them in the direction of rotation of the vortex that will be caused by the cone of the cyclone. A pipe 34 recovers the gases rising in the central gas column formed in the cyclone and conducts them through the reservoir to the other units. A tapping 35 situated at the end of the reactor pipe recovers the gases circulating in the reactor and leads them to the tangential inlet 32 of the cyclone. Under the action of these gases, a descending vortex will form in the cyclone, entraining the substrates to the bottom outlet of the cyclone while the gases will rise in a central column to the recovery pipe.
(26) 2.3 At the entre of the pipe of the F_smo 110, a worm
(27) 2.4 In an even more preferential embodiment, to allow rotation of a large worm or screw inside the reactor, the worm will comprise sliding and damping shoes 40. The shoes will comprise a sliding shoe preferably made from ceramic 41 but which can be made from metal or any other material providing sliding, a spring and optionally a guide spindle for the spring body 43. These shoes serve both for the sliding by virtue of the ceramic and for suspension by virtue of the spring, thus enabling the worm to turn in the reactor with a minimum amount of friction.
(28) 2.5 In some embodiments, the worm will be tensioned in the reactor at a tension varying from 1 kg to 10 tonnes. The tensioners
(29) 2.6 The part of the worm disposed facing the magnetrons will be bevelled 50 and will optionally have a copper scraper.
(30) 2.7 In a particular embodiment, at least one rotating or optionally rotating joint 51 will be disposed at at least one end of the worm. In a particular embodiment, at each end of the worm joints
(31) 2.8 In some embodiments, at least one bearing 56 at at least one end of the worm guides the rotation of the worm and provides abutment for the tension of the screw through the Belleville washers.
(32) 2.9 In some embodiments, the worm will be in a plurality of parts fitted together by means of dovetails, each part of the worm preferentially being positioned along an axis passing through the cylindrical reactor. In this embodiment, part of the worm will be made from ceramic, in particular the part of the worm in contact with the reactor.
(33) In some embodiments, the elements of the worm are held on each other by means of keys.
(34) 2.10 In some embodiments, the worm is replaced by a system of successive palets
(35) In some embodiments, the worm or cable of the palets will have an electric current pass through it so as to heat the screw or cable and the palets by Joule effect. The device used for the transit of the substrates can then participate in the heating and curing/pyrolysis of the substrates.
(36) 3. In some embodiments, the pipe of the reactor F_smo (110) will be included in a transparent confinement chamber
(37) 4. Outside the pipe and the glass confinement, in the length. one or more cylindroparabolic
(38) 5. Magnetrons
(39) In a preferential embodiment, the microwave source is a magnetron F that will have a waveguide merging with the gas guide forming a mixed guide. The gas guide makes it possible to inject into the reactor the gas coming firstly from the space between the two glass confinement tubes and secondly from the tube or tubes situated under the metal plate vertically in line with the reactor. The angle of installation of the waveguides, and of the gas guide in the mixed guide, as well as the flow of gas coming from the gas guide, will prevent the entrance into the waveguide of the substrate and the gases circulating in the aperture of the F_smo. In a particular embodiment, a porthole made from quartz or alumina or other ceramic transparent to microwaves is disposed in the waveguide before the gas entrance. In some embodiments, the porthole may be replaced by or supplemented with a ceramic tube transparent to microwaves such as zirconium oxide doped with magnesia introduced into the reactor.
(40) 6. The conduits and/or the shaft of the screw or any other part of the reactor will optionally become connected to ultrasound sources in order to prevent the formation of scale at this level. The microwaves cause very rapid heating of the molecules of the substrate, by agitating the water molecules and other polar molecules contained in the substrate. The microwaves may optionally be supplemented by infrared radiation. The heat produced by the microwaves added to the convergence heat of the solar radiation and that accumulated in the circulating gas causes torrefaction and pyrolysis of the substrate. During this pyrolysis, a release of volatile materials containing tar as well as various other inflammable gases occurs. These various gases are recovered by the tapping in the degassing chimneys 35 in order to be injected into a gasification reactor after separation of the gases and synthetic coal in the discharge cyclone. Before they are injected into the gasifier, these gases may be superheated (between 160 C. and 2000 C.) by the addition of microwaves and heat of solar origin.
(41) 7. In some embodiments, the substrate comprises the elements necessary for producing an electrolysis bath for producing aluminium by electrolysis, for example a mixture formed by any combination of NaF, KF, AlF.sub.3, AlCl.sub.3, Na.sub.3AlF.sub.6, NaCl or C, in proportions varying for example from 0 to 50% by mass supplemented by alumina Al.sub.2O.sub.3. The mixture, during its transit in the reactor, will be raised to temperatures above 950 C. by the action of the microwaves and/or solar radiation, so as to obtain a heterogeneous molten salt or a heterogeneous partially molten salt forming an electrolysis bath or medium for reducing alumina into aluminium.
(42) The mixed molten or semi-molten salt will be able to undergo conventional electrolysis such as that described for the reduction of alumina.
(43) In a particular embodiment, the electrolysis will be carried out directly in a part of the furnace. In this particular embodiment, the part of the furnace intended for reducing alumina will comprise a peripheral electrode
(44) In some embodiments, between the negative electrode and the worm or the palets of the conveyor 111, a cylinder made from porous ceramic
(45) In other embodiments, the shaft of the worm 95 of the reactor or the chain or the cable
(46) The substrate circulating in the electrolytic part of the reactor is subjected to an electrical field preferentially between 5V and 200 kV and has an electric current with an intensity preferably between 100 and 100,000 A running through it, which passes between the positive electrode and the negative electrode, so as to have a current density great than 0.1 A/cm.sup.2.
(47) Under the action of the current, the electrolytes in the molten or semi-molten salts react so that at the anode the following reaction occurs
4F+AL.sub.2O.sub.2F.sub.42+C.fwdarw.4e+2AlF.sub.4+CO.sub.2
4F+AL.sub.2O.sub.2F.sub.42+2C.fwdarw.4e+2AlF.sub.4+2CO
(48) whereas at the cathode the following reaction occurs:
ALF.sub.4+3e.fwdarw.Al (liquid)+4F
In other embodiments, the part of the cylindrical reactor for reduction of alumina is in two parts 105a, 105b, which, fitted together, form a cylinder preferably made from ceramic
(49) At the discharge from the reactor the more dense reduced aluminium will be recovered at the bottom outlet of a cyclone while the less dense electrolysis liquid and optionally the carbon injection gases can be recovered through the rising tube of the cyclone.
(50) 8. In some embodiments, the solar/microwave furnace optionally supplemented by the Joule effect of an electric current passing through the conveyor will be used for recycling aluminium from aluminium waste, by means of the fusion of said waste passing through the solar reactor.
LEGENDS FOR ALL THE FIGURES
(51) 1) lifting system actuated by motors 2) articulated system and jacks for unfolding and refolding the mirrors 3) cylindroparabolic solar concentrator mirror 4) pipe of the solar/microwave furnace reactor (F_smo) 5) fitted-on or screwed connecting pieces of a reactor pipe 6) corrugated structure (