RIBBON LIKE FILAMENTS AND SYSTEMS AND METHODS FOR PRODUCING THE SAME
20230045733 · 2023-02-09
Inventors
Cpc classification
D01F8/00
TEXTILES; PAPER
D01D4/06
TEXTILES; PAPER
D10B2331/04
TEXTILES; PAPER
D01D5/253
TEXTILES; PAPER
International classification
D01D4/06
TEXTILES; PAPER
D01D5/253
TEXTILES; PAPER
Abstract
Various implementations include a melt-spun filament that has a radial cross section that has two substantially parallel linear perimetrical sections and first and second curved perimetrical sections. The first curved perimetrical section extends between first ends of the linear perimetrical sections, and the second curved perimetrical section extends between second ends of the linear perimetrical sections. The curved perimetrical sections are convex. According to some embodiments, the curved perimetrical sections are semi-circular or semi-elliptical. A plurality of melt-spun filaments may be included in a bundle of filaments and/or a yarn made with the melt-spun filaments. In addition, a spinneret plate for spinning the melt-spun filaments and a method of making the melt-spun filaments is also provided.
Claims
1.-72. (canceled)
73. A spinneret plate for producing a self-bulking melt-spun filament comprising: at least one capillary comprising: a first section comprising a counterbore with vertical sides; wherein the counterbore comprises a depth of between about 0.010 inches and about 0.025 inches; a second section comprising angled sides of a first angle; a third section comprising vertical sides; a fourth section comprising angled sides of a second angle; wherein a cross-section of the at least one capillary comprises a rectangle; and wherein a rectangular cross-section comprises a width and a height, and wherein a spin slot aspect ratio is the ratio of the width to the height in the counterbore of the capillary.
74. The spinneret plate according to claim 73, wherein the spin slot aspect ratio is selected from the group consisting of about 4:1 or about 6:1.
75. The spinneret plate according to claim 73, wherein the first angle is between 45° and 80°.
76. The spinneret plate according to claim 73, wherein the second angle is between 45° and 80°.
77. The spinneret plate according to claim 73, wherein the first angle is equal to the second angle.
78. A method for producing a melt-spun filament from the capillary according to claim 73 comprising: pumping a polymer melt into the capillary at a first speed to produce a filament having a first filament aspect ratio at the spinneret plate; drawing the filament at a first draw rate from the spinneret plate such that the filament has a second filament aspect ratio at a point further away from the spinneret plate.
79. The melt-spun filament produced from the capillary according to claim 78, wherein the radial cross section is capsule shaped.
80. The melt-spun filament produced from the capillary according to claim 78, wherein the radial cross section is rice shaped.
81. The melt-spun filament produced from the capillary according to claim 78, wherein a plane extending axially through the melt-spun filament intersects the curved perimetrical ends and includes a central axis of the filament, and a line that is tangential to one of the ends of the linear perimetrical sections intersects the plane at an angle of between 0° and 10°.
82. The melt-spun filament produced from the capillary according claim 78, further comprising a core and a sheath disposed around the core, the core being formed from a first material, and the sheath being formed from a second material.
83. The melt-spun filament produced from the capillary according to claim 82, wherein the first material and the second material are selected from the group consisting of polytrimethylene terephthalate (PTT), polyethylene terephthalate (PET), polyamides (PA), Polybutylene terephthalate (PBT), other polyesters and polyolefins, or combinations thereof.
84. A method for producing a self-bulking melt-spun filament comprising: providing a spinneret plate comprising at least one capillary, wherein the capillary comprises: a rectangular opening with a first section comprising a counterbore having substantially vertical sides that are perpendicular to a face of the spinneret plate; a second section adjoining the first section, wherein the second section comprises sides that are angled away from the vertical sides of the first section at a first angle; a third section adjoining the second section, wherein the third section comprises sides that are substantially vertical; a fourth section adjoining the third section, wherein the fourth section comprises sides that are angled away from the vertical sides of the third section at a second angle; pumping a polymer melt into the fourth section of the capillary at a first speed to extrude a filament from the counterbore, wherein the filament has a first filament aspect ratio at the spinneret plate; drawing the filament at a first draw rate from the spinneret plate such that the filament has a second filament aspect ratio at a point further away from the spinneret plate.
85. The melt-spun filament according to claim 84, wherein the radial cross section is capsule shaped.
86. The melt-spun filament according to claim 84, wherein the radial cross section is rice shaped.
87. The melt-spun filament according to claim 84, wherein a plane extending axially through the melt-spun filament intersects the curved perimetrical ends and includes a central axis of the filament; and wherein a line that is tangential to one of the ends of the linear perimetrical sections intersects the plane at an angle of between 0° and 10°.
88. The capillary according to claim 84, wherein the counterbore comprises a depth of between about 0.010 inches and about 0.025 inches.
89. The capillary according to claim 84, wherein the first angle is between 45° and 80°.
90. The capillary according to claim 84, wherein the second angle is between 45° and 80°.
91. The capillary according to claim 84, wherein the first angle is equal to the second angle.
92. The melt-spun filament produced from the capillary according to claim 82, wherein the first material and the second material are selected from the group consisting of polytrimethylene terephthalate (PTT), polyethylene terephthalate (PET), polyamides (PA), Polybutylene terephthalate (PBT), other polyesters and polyolefins, or combinations thereof.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0022] Example features and implementations are disclosed in the accompanying drawings. However, the present disclosure is not limited to the precise arrangements shown, and the drawings are not necessarily drawn to scale.
[0023]
[0024]
[0025]
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[0028]
[0029]
[0030]
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[0034]
DETAILED DESCRIPTION
[0035] Various implementations include a melt-spun filament that has a radial cross section that has two substantially parallel linear perimetrical sections and first and second curved perimetrical sections. The first curved perimetrical section extends between first ends of the linear perimetrical sections, and the second curved perimetrical section extends between second ends of the linear perimetrical sections. The curved perimetrical sections are convex. According to some embodiments, the curved perimetrical sections are semi-circular or semi-elliptical. Various implementations of the melt-spun filament provide a softer hand feel than rectangular shaped filaments, which is similar to the hand feel provided by trilobal and round shaped filaments, but the melt-spun filaments are less prone to breaking (higher tenacity) than trilobal and round shaped filaments, which also reduces waste.
[0036] In some implementations, a bundle of filaments that includes a plurality of the melt-spun filaments is provided. In some implementations, a filament yarn that includes a plurality of the melt-spun filaments is provided. And, in some implementations, a bulked continuous filament yarn that includes a plurality of melt-spun filaments is provided.
[0037] According to some implementations, the melt-spun filament is made by (1) providing a spinneret plate comprising one or more capillaries, each capillary having a rectangular shaped outlet opening; and (2) feeding at least one melted thermoplastic polymer through the capillary.
[0038] For example,
[0039] The curved perimetrical sections have a radius of curvature that is less than any radius of curvature of the linear perimetrical sections. In particular, to the extent that the linear perimetrical sections are curved, the curvature of each linear perimetral section has a radius that is significantly greater than the radius of the curvature of each of the curved perimetral section. For example, a tangent line to the ends of the linear perimetrical sections is between 0° to 10° relative to a plane that extends axially through the melt-spun filament and intersects (e.g., bisects) the curved perimetral sections and includes the central axis of the filament. Due to the expansion of material as it exits the spinneret and the pulling of the filament after it exits the spinneret, the linear perimetrical sections are not perfectly linear. In other words, some curvature with a large radius is expected for these linear perimetral sections.
[0040] According to some embodiments, the filament 10 comprises a thermoplastic material. For example, according to one embodiment, the thermoplastic material is selected from the group consisting of: polytrimethylene terephthalate (PTT), polyethylene terephthalate (PET), polyamides (PA), Polybutylene terephthalate (PBT), and other polyesters and polyolefins. Example polyamides include nylon 6 and nylon 6,6. Example polyolefins include polypropylene (PP) and polyethylene (PE). And, in some embodiments, the first or second material may include a polyolefin and a carbon filler to produce an antistatic yarn. The thermoplastic material resin may be virgin or reclaim grade, according to some embodiments.
[0041] According to some embodiments, a width W.sub.F to height H.sub.F ratio of the radial cross section of the filament 10 is between 3.5:1 and 1.5:1. The width W.sub.F is measured in a direction of the linear perimetrical sections 12, 14 at the widest points of the radial cross section, and the height H.sub.F is measured in a direction perpendicular to the length direction. For example, according to some embodiments, the width W.sub.F to height H.sub.F ratio of the radial cross section is between 3:1 and 2.2:1. In certain embodiments in which the filament 10 is spun through capillaries having a 4:1 width to height ratio (such as shown in
[0042]
[0043] The ratio of the number of filaments per yarn spun into the shape shown in
[0044] In other implementations, the melt-spun filament 10 is converted into a plurality of staple fibers. Staple fibers have shorter lengths, such as 2 to 3 inches long, compared to filaments, which have long continuous lengths. For example, the melt-spun filament may be converted to a plurality of staple fibers by stretch breaking or chopping one or more of such melt-spun filaments. And, in some implementations, a plurality of the staple fibers may be bundled.
[0045] According to some implementations, the filament 10 is made by (1) providing a spinneret plate comprising one or more capillaries, each capillary having a rectangular shaped outlet opening; and (2) feeding at least one melted thermoplastic polymer through the capillary. For example, the spinneret plate may be the spinneret plate 100 shown in
[0046] In other implementations, the spinneret plate may be spinneret plate 200 shown in
[0047]
[0048] According to some embodiments, the melt-spun filament further comprises a core and a sheath disposed around the core. For example,
[0049] According to some embodiments, the melt-spun filament comprises a first material and a second material that are coupled along a plane that includes the axis of the fiber, and the first material and second material have different coefficients of thermal expansion. For example,
[0050] Like the first filament 10, the other filaments 20, 30, 40 are solid. Accordingly, the other filaments 20, 30, 40 do not define void or hollow portions that extend axially through the other filaments 20, 30, 40.
[0051] In another embodiment of the inventions disclosed and taught herein, the capillaries may be configured with a counterbore section below the second angled portion.
[0052]
[0053]
[0054] The counterbore 1055 has sides that are perpendicular to the surface 1010b of the spinneret plate 1010 with a length L.sub.CB. Optimal filaments have been produced using a counterbore 1055 with a length of between about 0.010 inches and about 0.025 inches. Filaments exhibiting the properties disclosed herein may be made with counterbores having longer or shorter lengths as well.
[0055] Various factors contribute to the shape and denier per filament of the filaments, including the melt temperature, the speed of the pump in communication with the extruder, the draw ratio, and the rate at which the filaments are cooled. Altering one or more of these factors can provide the desired shape. For example, if the pump speed is increased but all other factors remain the same, the denier per filament is increased. If the draw ratio is increased and all other factors remain the same, the denier per filament is decreased and the aspect ratio decreases (e.g., from 4:1 to 4:1.5). As another example, if the cooling rate is increased and all other factors remain the same, the cross-sectional shape of the filament is more defined.
[0056] In other implementations, the spinneret plate may be spinneret plate 1110 shown in
[0057]
[0058] The counterbore 1155 has sides that are perpendicular to the surface 1110b of the spinneret plate 1110 with a length L.sub.CB. Optimal filaments have been produced using a counterbore 1155 with a length of between about 0.010 inches and about 0.025 inches. Filaments exhibiting the properties disclosed herein may be made with counterbores having longer or shorter lengths as well.
[0059] Various factors contribute to the shape and denier per filament of the filaments, including the melt temperature, the speed of the pump in communication with the extruder, the draw ratio, and the rate at which the filaments are cooled. Altering one or more of these factors can provide the desired shape. For example, if the pump speed is increased but all other factors remain the same, the denier per filament is increased. If the draw ratio is increased and all other factors remain the same, the denier per filament is decreased and the aspect ratio decreases (e.g., from 6:1 to 6:1.5). As another example, if the cooling rate is increased and all other factors remain the same, the cross-sectional shape of the filament is more defined.
[0060]
[0061] Immediately upon exiting the counterbore 1255, the molten polymer has been observed to swell and bulge outwardly from the centerline of the capillary 1250. The draw down force, represented as F.sub.d in
[0062] Since the pump is responsible for the throughput or velocity of the polymer melt through the capillaries, increasing the depth of the counterbore may be used to cause a greater pressure drop through that capillary and then cause more shear differential across the filament. That is to say that the middle of the polymer melt will travel faster than the edges as it is extruded from the capillary.
[0063] This pressure drop, in turn, will cause different stresses and alignments to form in the polymer melt that may be exploited to cause changes in the resulting bulk of the yarn.
[0064] As the filament 10 is being drawn down, it will have a first filament aspect ratio at a point near the spinneret plate, and a second filament aspect ratio at a point further away from the spinneret plate. That is to say that as the filament will no longer retain an aspect ratio similar to that of the counterbore as it is drawn, but will change to have a different aspect ratio at a point further away from the counterbore of the spinneret plate.
[0065] The titer per fiber or filament (also referred to as “denier per filament”, “denier per fiber” or “dpf”) range using the processes disclosed and taught herein may be between 2 and 5 dpf. Those of ordinary skill in the art and in possession of the teachings and disclosures herein will be able to envision and produce other dpf ranges without departing from the spirit of the inventions disclosed and taught herein.
[0066] The following two tables represent without limitation the characteristics of filaments that may be spun from different capillaries under different influences. Table 1 represents the characteristics of filaments spun from capillaries having a spin slot aspect ratio of 4:1, and Table 2 represents the characteristics of filaments spun from capillaries having a spin slot aspect ratio of 6:1.
TABLE-US-00001 TABLE 1 L.sub.CB F.sub.d Bulk Feel Short Low Low Slick Short Hi Low Slick Long Low Medium Slick Long Hi Medium Slick
TABLE-US-00002 TABLE 2 L.sub.CB F.sub.d Bulk Feel Short Low Medium Soft Short Hi Medium Soft Long Low High Soft Long Hi High Soft
[0067] As may be seen from tables 1 and 2, filaments produced with longer counterbore depths—those near or around 0.025 inches—produce filaments with higher bulk and softer feel than those produced with shorter counterbore depths—those near or around 0.010 inches. Since the pressure may be considered to be a by-product of the throughput, temperature of the polymer, and the capillary design, controlling the pressure may also affect the stress placed upon the polymer to allow for the configuration of the resulting bulk.
[0068] Table 3 represents without limitations a set of exemplary properties of yarns produced using the inventions disclosed and taught herein. Two spinneret plates were connected to a single hanger from an extruder and filaments were produced from a polymer melt extruded through the capillaries. The left spinneret plate was configured with capillaries configured in a 6:1 spin slot aspect ratio, while the right spinneret plate was configured with capillaries configured in a 4:1 spin slot aspect ratio. All other parameters of the pump rate, quench, and draw were the same. Both sets of capillaries had a short length of near 0.010 inches. That is to say that the F.sub.d was “Low”.
TABLE-US-00003 Spinneret Plate Denier FOY Tenacity Elongation % TR Crimp Shrink Left 6:1 1204 0.800 2.900 51.20 8.49-9.40 4.15-4.37 4.53-5.26 Right 4:1 1223 0.725 2.885 48.65 9.38-9.61 5.14-5.15 5.56-5.70
[0069] In general, then, using the inventions disclosed and taught herein, the production of self-bulking yarn may be achieved by extruding polymer melt through a capillary with a high depth of the counterbore, having a 6:1 spin slot aspect ratio with a high melt temperature. The extruded polymer melt may then be processed with a low quench temperature with high quench flow and humidity, along with a minimum required draw ratio with high temperatures on the godets. A low dpf/filament count spinneret may be used to obtain a bulkier fiber that will have greater coverage. Similarly, for a softer feel, a higher filament count spinneret may be used.
[0070] Similarly, using the inventions disclosed and taught herein, the production of a soft yarn may be achieved by extruding polymer melt through a capillary with a 4:1 spin slot aspect ratio with a low depth of the counterbore in a high filament count spinneret. The extruded polymer melt may then be processed with a low quench temperature and with the draw ratios maximized with minimal temperatures on the godets. The resulting yarn will feel slick and soft. To obtain improved coverage by the yarn in the carpet, a deeper counterbore (a “Hi” counterbore such as near or about 0.025 inches) in the spinneret may be configured with all other parameters kept the same. This configuration and processing may cause more twisting on a macro scale and leave the yarn soft with more bulk.
[0071] Various implementations have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the description. Accordingly, other implementations are within the scope of the following claims.
[0072] Disclosed are materials, systems, devices, methods, compositions, and components that can be used for, can be used in conjunction with, can be used in preparation for, or are products of the disclosed methods, systems, and devices. These and other components are disclosed herein, and it is understood that when combinations, subsets, interactions, groups, etc. of these components are disclosed that while specific reference of each various individual and collective combinations and permutations of these components may not be explicitly disclosed, each is specifically contemplated and described herein. For example, if a device is disclosed and discussed every combination and permutation of the device, and the modifications that are possible are specifically contemplated unless specifically indicated to the contrary. Likewise, any subset or combination of these is also specifically contemplated and disclosed. This concept applies to all aspects of this disclosure including, but not limited to, steps in methods using the disclosed systems or devices. Thus, if there are a variety of additional steps that can be performed, it is understood that each of these additional steps can be performed with any specific method steps or combination of method steps of the disclosed methods, and that each such combination or subset of combinations is specifically contemplated and should be considered disclosed.