Epitaxial conversion element, method for producing an epitaxial conversion element, radiation emitting RGB unit and method for producing a radiation emitting RGB unit

10833219 · 2020-11-10

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Abstract

An epitaxial conversion element, a method for producing an epitaxial conversion element, a radiation emitting RGB unit and a method for producing a radiation emitting RGB unit are disclosed. In an embodiment an epitaxial conversion element includes a green converting epitaxial layer configured to convert electromagnetic radiation from a blue spectral range into electromagnetic radiation of a green spectral range and a red converting epitaxial layer configured to convert electromagnetic radiation from the blue spectral range into electromagnetic radiation of a red spectral range, wherein the green converting epitaxial layer and the red converting epitaxial layer are based on a phosphide compound semiconductor material, and wherein the green converting epitaxial layer and the red converting epitaxial layer are in different main extension planes which are parallel to each other.

Claims

1. An epitaxial conversion element comprising: a green converting epitaxial layer configured to convert electromagnetic radiation from a blue spectral range into electromagnetic radiation of a green spectral range; and a red converting epitaxial layer configured to convert electromagnetic radiation from the blue spectral range into electromagnetic radiation of a red spectral range, wherein the green converting epitaxial layer and the red converting epitaxial layer are based on a phosphide compound semiconductor material, and wherein the green converting epitaxial layer and the red converting epitaxial layer are in different main extension planes which are parallel to each other.

2. The epitaxial conversion element according to claim 1, wherein the green converting epitaxial layer and the red converting epitaxial layer are grown epitaxially on a common growth substrate.

3. The epitaxial conversion element according to claim 1, wherein the green converting epitaxial layer and the red converting epitaxial layer have substantially the same crystal lattice.

4. The epitaxial conversion element according to claim 1, wherein the green converting epitaxial layer and the red converting epitaxial layer have substantially the same lattice constant along their main extension planes.

5. The epitaxial conversion element according to claim 1, wherein the epitaxial conversion element is free of compound bonding layers.

6. The epitaxial conversion element according to claim 1, wherein the red converting epitaxial layer is disposed between two barrier layers.

7. The epitaxial conversion element according to claim 1, wherein the green converting epitaxial layer is disposed between two barrier layers.

8. The epitaxial conversion element according to claim 1, further comprising a top layer arranged between the red converting epitaxial layer and a radiation exit surface of the conversion element and/or between the green converting epitaxial layer and the radiation exit surface of the epitaxial conversion element.

9. The epitaxial conversion element according to claim 1, further comprising: a green converting region comprising the green converting epitaxial; and a red converting region comprising the red converting epitaxial layer, wherein the red converting region and the green converting region do not overlap laterally.

10. The epitaxial conversion element according to claim 9, wherein the green converting region and/or the red converting region has a width not greater than wo micrometers.

11. A method for producing the epitaxial conversion element according to claim 1, the method comprising: providing a growth substrate; epitaxially depositing the red converting epitaxial layer based on a phosphide compound semiconductor material; and epitaxially depositing the green converting epitaxial layer based on a phosphide compound semiconductor material.

12. The method according to claim 11, further comprising: structuring the red converting epitaxial layer into a plurality of red converting regions; depositing a first transparent planarization layer on the red converting regions thereby forming a first planar surface; connecting a carrier to the first planar surface; removing the growth substrate; and structuring the green converting epitaxial layer into a plurality of green converting regions.

13. A radiation-emitting RGB unit comprising: an active zone configured to generate electromagnetic radiation of the blue spectral range; and the epitaxial conversion element according to claim 1, wherein the green converting epitaxial layer and the red converting epitaxial layer are configured to convert the electromagnetic radiation of the active zone, and wherein a main extension plane of the active zone is parallel to the main extension planes of the green converting epitaxial layer and the red converting epitaxial layer.

14. The radiation-emitting RGB unit according to claim 13, further comprising a radiation exit surface comprising a red emission region, a green emission region and a blue emission region, wherein a red converted radiation of the red converting epitaxial layer is emitted from the red emission region during operation, wherein a green converted radiation of the green converting epitaxial layer is emitted from the green emission region during the operation, and wherein a blue unconverted radiation of the active zone is emitted from the blue emission region during the operation.

15. The radiation-emitting RGB unit according to claim 14, wherein the blue emission region and/or the green emission region and/or the red emission region has a width which is not greater than 100 micrometers.

16. A method for producing the radiation-emitting RGB unit according to claim 13, the method comprising: providing a growth substrate; epitaxially depositing the red converting epitaxial layer; epitaxial deposition the green converting epitaxial layer; structuring the red converting epitaxial layer into a plurality of red converting regions; depositing a first transparent planarization layer on the red converting regions thereby forming a first planar surface; bonding a radiation emitting epitaxial semiconductor layer sequence having an active zone to the first planar surface; removing the growth substrate; and structuring the green converting epitaxial layer into a plurality of green converting regions.

17. The method according to claim 16, wherein an etch stop layer is disposed between the green converting epitaxial layer and the red converting epitaxial layer.

18. The method according to claim 16, wherein side surfaces of the red converting regions and/or the green converting regions comprise a mirroring layer.

19. The method according to claim 16, further comprising applying a second transparent planarization layer to the green converting regions thereby forming a second planar surface.

20. The method according to claim 16, further comprising separating the radiation-emitting RGB unit into a large number of RGB semiconductor chips.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Further advantageous embodiments and further development of the epitaxial conversion element, the method for producing an epitaxial conversion element, the radiation-emitting RGB unit and the method for producing the radiation-emitting RGB unit result from the embodiments described below in connection with the figures.

(2) FIGS. 1 to 7 show a method for the production of an epitaxial conversion element according to an embodiment;

(3) FIG. 7 also shows a schematic cross-section of an epitaxial conversion element according to an embodiment;

(4) FIG. 8 shows the layer sequence of the epitaxial conversion element according to FIG. 1;

(5) FIG. 9 schematically shows a diagram of the band gaps of the epitaxial semiconductor layer sequence according to the embodiment of FIGS. 1 and 8;

(6) FIGS. 10 to 20 show a method for producing an RGB unit according to an embodiment; and

(7) FIG. 21 shows an RGB unit according to an embodiment.

(8) Same, similar or similar elements are in the figures provided with the same reference signs. The figures and the proportions of the elements depicted in the figures are not to be regarded as true to scale. Rather, individual elements, in particular layer thicknesses, may be exaggeratedly large for better representability and/or better understanding.

DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS

(9) In the method for producing an epitaxial conversion element 1 as shown in the embodiment in FIGS. 1 to 6, a plurality of layers are first formed on a growth substrate 2 as shown in FIG. 1. The growth substrate 2 is presently formed from gallium arsenide or has gallium arsenide. Some layers are grown epitaxially, but not necessarily all of them.

(10) The sequence of layers shown in FIG. 1 shows a roughened or decoupled top layer 3 deposited on growth substrate 2. The top layer 3 is transparent to radiation of a red converting epitaxial layer 4 and a green converting epitaxial layer 5.

(11) A barrier layer 6 is arranged on top layer 3, on which the green converting epitaxial layer 5 is epitaxially deposited. The green converting epitaxial layer 5 is also preferred to convert electromagnetic radiation of the blue spectral range into electromagnetic radiation of the green spectral range.

(12) Barrier layer 6 is also preferably deposited epitaxially on top layer 3. On the green converting epitaxial layer 5 another barrier layer 6 is applied, also preferably epitaxial. The green converting epitaxial layer 5 is thus enclosed between two barrier layers 6, which serve to concentrate electrical charge carriers in the green converting epitaxial layer 5.

(13) The green converting epitaxial layer 5 and the red converting epitaxial layer 4 are arranged in different main extension planars which are parallel to each other.

(14) An etch stop layer 7, preferably based on an arsenide compound semiconductor material such as gallium arsenide, is arranged on the further barrier layer 6.

(15) A further top layer 3 is applied to the etch stop layer 7, which can be provided with decoupling structures or roughened. On top layer 3 there is another barrier layer 6, followed by the red converting epitaxial layer 4. The red converting epitaxial layer 4 is suitable to convert electromagnetic radiation of the blue spectral range into electromagnetic radiation of the red spectral range.

(16) A further barrier layer 6 is arranged on the red converting epitaxial layer 4. The two barrier layers 6 include the red converting epitaxial layer 4 and concentrate the electric charge carriers in the red converting epitaxial layer 4.

(17) The green converting epitaxial layer 5 and the red converting epitaxial layer 4 are both preferably based on or formed from a phosphide compound semiconductor material.

(18) The two top layers 3 are particularly transparent to electromagnetic radiation of the red spectral range and/or the green spectral range.

(19) In a next step schematically shown in FIG. 2, the red converting epitaxial layer 4 and the barrier layers 6 including the red converting epitaxial layer 4 and the second top layer 3 are structured to form a red converting region 8 comprising the red converting epitaxial layer 4. Etching is carried out up to the etch stop layer 7.

(20) In the next step, schematically shown in FIG. 3, a first planarization layer 9 is applied to the red converting regions 8, which fills the recesses created by the etching to form a first planar surface 10. The first planarization layer 9 is transparent for radiation of the blue spectral range and/or the red spectral range and/or the green spectral range.

(21) In a further step, schematically shown in FIG. 4, a carrier 11 is applied to the first planar surface 10 of the first planarization layer 9. Carrier 11 mechanically stabilizes the epitaxial conversion element 1 during the subsequent removal of growth substrate 2.

(22) FIG. 5 schematically shows the method stage after the growth substrate 2 has been removed from the layers.

(23) Now also the green converting epitaxial layer 5 is structured into at least one green converting region 12 (FIG. 6). For example, the structuring of the green converting epitaxial layer 5 into the green converting epitaxial region 12 is also done by etching up to the etch stop layer 7.

(24) The present embodiment of the method for producing an epitaxial conversion element 1 shows only one red converting region 8 and one green converting region 12, respectively, but the method is typically performed at wafer level so that the green converting epitaxial layer 5 and the red converting epitaxial layer 4 are structured into a plurality of green converting regions 12 and red converting regions 8, respectively. For reasons of clarity, this is not shown here.

(25) In a next step, a second planarization layer 13 is applied to the green converting epitaxial regions 12, which in turn creates a second planar surface 14 and fills the recesses created by structuring the green converting epitaxial layer 5. The finished epitaxial conversion element 1 is shown schematically in FIG. 7.

(26) FIG. 8 once again shows the sequence of layers according to FIG. 1, while FIG. 9 opposite shows the corresponding band gaps E.sub.g.

(27) According to FIG. 9, the green converting epitaxial layer 5 has a larger band gap E.sub.g than the red converting epitaxial layer 4, the two top layers 3 have a larger band gap E.sub.g than the two converting layers 4, 5 because they are transparent to the green converted radiation of the green converting epitaxial layer 5 and to the red converted radiation of the red converting epitaxial layer 4, the etch stop layer 7 and the growth substrate 2 have a relatively small band gap E.sub.g.

(28) In the method of producing an RGB unit according to the embodiment given in FIGS. 10 to 20, a growth substrate 2 is provided in a first step (FIG. 10). A green converting epitaxial layer 5 is grown epitaxially on growth substrate 2 (FIG. 11). In the next step, schematically shown in FIG. 12, an etch stop layer 7 is applied to the green converting epitaxial layer 5, also preferably epitaxial. Then a red converting epitaxial layer 4 is fully applied to the etch stop layer 7 (FIG. 13).

(29) The red converting epitaxial layer 4 is structured into red converting regions 8, for example, by etching. The etching method is stopped by the etch stop layer 7 (FIG. 14).

(30) The side surfaces of the red converting regions 8 are provided with a reflective layer 15. The reflective layer 15, for example, is made of a metallic material or of a dielectric material. For example, the reflective layer 15 can be deposited by sputtering or thermal evaporation (FIG. 15).

(31) In the next step, schematically shown in FIG. 16, a first planarization layer 9 is applied to the red converting regions 8 to fill the recesses created by etching between the red converting regions 8. The first planarization layer 9 forms a first planar surface 10.

(32) As schematically shown in FIG. 17, an epitaxial semiconductor layer sequence 16 with an active zone 17 is applied to the first planar surface 10 of the first planarization layer 9. The active zone 17 is preferably suitable for emitting electromagnetic radiation from the blue spectral range, which is converted into green light by the green converting regions 12 and into red light by the red converting regions 8. The epitaxial semiconductor layer sequence 16 with the active zone 17 is applied to a carrier element 18.

(33) In a next step, schematically shown in FIG. 18, the growth substrate 2 of the green converting epitaxial layer 5 and the red converting epitaxial layer 4 is removed. In this way, the green converting epitaxial layer 5 is freely accessible from outside and can be structured, as schematically shown in FIG. 19, into green converting regions 12, for example, also by etching, wherein the etch stop layer 7 stops the etching method.

(34) The side surfaces of the green converting regions 12 are also provided with a reflective layer 15. The recesses between the green converting regions 12 are then filled with a second planarization layer 13.

(35) Finally, the various RGB units are separated along dividing lines 19 (FIG. 20). RGB units may be single semiconductor chips, each comprising only individual RGB pixels.

(36) The RGB unit according to the embodiment of FIG. 21 has a green converting region 12 that includes a green converting epitaxial layer 5. Sides of the green converting region 12 are provided with a reflective layer 15. Further, according to FIG. 21, the RGB unit comprises a red converting region 8 comprising a red converting epitaxial layer 4, the side faces of which are also provided with a reflective layer 15.

(37) The green converting region 12 and the red converting region 8 are arranged next to each other according to the embodiment of FIG. 21 and do not overlap laterally. Furthermore, the green converting region 12 and the red converting region 8 are arranged in different main extension planars, which are arranged parallel to each other.

(38) In addition, the RGB unit includes an epitaxial semiconductor layer sequence 16 with an active zone 17 as shown in the embodiment in FIG. 21. The active zone 17 is suitable for generating electromagnetic radiation from the blue spectral range. The epitaxial semiconductor layer sequence 16 also contains a carrier element 18, which mechanically stabilizes the RGB unit.

(39) The red converting region 8 is provided to convert blue light of the active zone 17 into red light, preferably completely. The green converting region 12 is also provided to convert blue light of the active zone 17 into green light, also preferably completely.

(40) The RGB unit shown in FIG. 21 has a radiation exit surface 20 comprising a red emission region 21, a green emission region 22 and a blue emission region 23. The red emission region 21 is subordinate to the red converting region 8 in the direction of radiation. The red converted radiation of the red converting region 8 is emitted from the red emission region 21.

(41) Furthermore, the radiation exit surface 20 of the RGB unit comprises the green emission region 22, which is arranged downstream of the green converting region 12 in the radiation direction and is emitted by the green converted radiation of the green converting region 12.

(42) The blue emission region 23 of the radiation exit surface 20 of the RGB unit according to FIG. 21 emits blue unconverted radiation of the active zone 17.

(43) The three emission regions 21, 22, 23 are arranged laterally next to each other and do not overlap.

(44) The invention is not limited by the description using the embodiments to these. Rather, the invention includes any new feature and any combination of features, which in particular includes any combination of features in the patent claims, even if that feature or combination itself is not explicitly mentioned in the patent claims or embodiments.