Enhanced efficiency of LED structure with n-doped quantum barriers
11870006 ยท 2024-01-09
Assignee
Inventors
- Jian Yin (Waterloo, CA)
- Dayan Ban (Waterloo, CA)
- Ehsanollah Fathi (Waterloo, CA)
- Gholamreza Chaji (Waterloo, CA)
Cpc classification
H01L33/30
ELECTRICITY
H01L33/06
ELECTRICITY
H01L33/025
ELECTRICITY
International classification
H01L33/06
ELECTRICITY
H01L33/00
ELECTRICITY
H01L33/14
ELECTRICITY
H01L33/30
ELECTRICITY
Abstract
The present invention provides light-emitting devices with improved quantum efficiency. The light emitting diode structure comprising: a p-doped layer an n-doped layer; and a multiple quantum well structure sandwiched between the p-doped layer and n-doped layer, wherein the multiple quantum well structure comprising a quantum well disposed between n-doped barrier layers.
Claims
1. A method to reduce ratio of a surface area to a volume in quantum-wells, the method comprising: providing an n-doped layer, 55 m2 microLEDs with a single quantum well structure, and a p-doped layer, wherein the single quantum well structure includes a quantum well layer disposed between n-doped barrier layers; achieving a 128% IQE improvement at 20 A/cm.sup.2 having growth substrate; having an n-type layer formed on the growth substrate; having single quantum well structure active zone grown on the n-type layer to generate radiation; having an electron blocking layer; and a p-type layer.
2. The method of claim 1, the method further comprising: having a microLED with the n-doped layer, a quantum well layer disposed between two n-doped barriers, and a p-doped layer.
3. The method in claim 2, wherein the quantum well comprises one of: GaAs, InGaN, InGaAs, AlGaN or InGaAsP.
4. The method of claim 2, wherein the barrier layers comprise one of: AlGaAs, GaN, AlGaAs, AlGaN or InP.
5. The method of claim 1, wherein the method reduces a leakage of an optoelectronic device.
6. The method in claim 2, the method further comprising a uniform composition of indium in the single quantum well structure.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The foregoing and other advantages of the disclosure will become apparent upon reading the following detailed description and upon reference to the drawings.
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(12) Use of the same reference numbers in different figures indicates similar or identical elements.
(13) While the present disclosure is susceptible to various modifications and alternative forms, specific embodiments or implementations have been shown by way of example in the drawings and will be described in detail herein. It should be understood, however, that the disclosure is not intended to be limited to the particular forms disclosed. Rather, the disclosure covers all modifications, equivalents, and alternatives falling within the spirit of the invention as defined by the appended claims.
DETAILED DESCRIPTION
(14) Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
(15) As used in the specification and claims, the singular forms a, an and the include plural references unless the context clearly dictates otherwise.
(16) The term comprising as used herein will be understood to mean that the list following is non-exhaustive and may or may not include any other additional suitable items, for example one or more further feature(s), component(s) and/or element(s) as appropriate,
(17) The terms device and micro device are used herein interchangeably. It would be clear to one skill in the art that the embodiments described here are independent of the device size.
(18) In this disclosure, InGaN/GaN based LEDs are used as an example, However, the simulations result may applicable to other LED structures based on different material systems, such as GaAsP based LEDs, InGaAsP based LEDs, InGaAs based LEDs, or GaAs based LEDs. The multiple quantum well structure may comprise quantum well and barrier layers. The quantum well may comprise one of: GaAs, InGaN, InGaAs, AlGaN and InGaAsP and the barrier layers may comprises one of: AlGaAs, GaN, AlGaAs, AlGaN and InP.
(19) This disclosure provides a design of microLED structure using a single quantum well disposed between n-doped barrier layers to improve the efficiency performance, contrary to LEDs with regular sizes (i.e., greater than 100 m) in which the barrier layers are typically p-doped to improve device efficiency performance.
(20) According to one aspect of the invention, an optimized design for 55 m.sup.2 microLEDs with n-doped barrier layers and a single quantum well shows more than 100% efficiency improvement at a current density of 20 A/cm.sup.2 compared to a conventional intrinsic multiple quantum well based design.
(21) In conventional quantum well structures, a surface recombination velocity in GaN and InGaN is typically around 110.sup.2 cm/s to 110.sup.5 cm/s and the surface recombination area is around 1 m from the semiconductor surface.
(22) According to another aspect of the invention, Apsys software is employed to simulate GaN/InGaN based microLEDs by setting a surface recombination range of 1 m and surface recombination velocity of 310.sup.4 cm/s.
(23) In one case, temperature-dependent measurements for the 5050 m.sup.2 microLEDs are set to check the reliability of the simulation results.
(24) Conventional p-i-n Structure with p-Doped Quantum Well Barrier Layers
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(26) The electron blocking layer 108 can be deposited on the MQW structure 120. In one case, the electron blocking layer may comprise p-type doped AlGaN. Then, a p-type GaN layer may be deposited on the p-type AlGaN. Further, a p-type metal contact 112 such as Pd/Au, Pt or Ni/Au is formed on the p-type GaN layer. Also, the substrate (e.g., sapphire) is an insulator, and the n-type GaN layer 104 is exposed to make contact to this layer. This step is usually done using a dry-etch process to expose the n-type GaN layer and then deposit the appropriate metal contacts (e.g., n-type metal contact 106).
(27) The conventional p-doped barrier layers are well suited for GaN/InGaN LEDs with a regular size (>100 m in dimension) to improve device efficiency performance.
(28) However, when the size of microLEDs shrink down to a few micrometers (e.g., 55 m.sup.2), the surface recombination starts to dominate the efficiency performance of GaN/InGaN p-doped barriers layers.
(29) LED Structure with n-Doped Quantum Well Barrier Layers
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(31) Here, the MQW structure 120 may comprise a single quantum well 222 disposed between n-doped barrier layers 224. In one example, the quantum well 222 may comprise InGaN and the barrier layers 224 may comprise n-doped GaN. However, the simulations result may applicable to other LED structures based on different material systems, such as GaAsP based LEDs, InGaAsP based LEDs, InGaAs based LEDs, or GaAs based LEDs. The quantum well may comprise one of: GaAs, InGaN, InGaAs, AlGaN and InGaAsP and the barrier layers may comprises one of: AlGaAs, GaN, AlGaAs, AlGaN and InP.
(32) According to one aspect of the invention, compared to the MQW structure shown in
(33) Experimental and Simulation Results Analysis of GaN/InGaN Light-Emitting Diodes with p-Doped Barrier Layers
(34) Here, InGaN/GaN based LEDs are used as an example, However, the simulations result may applicable to other LEDs based on different material systems.
(35) By setting the surface recombination range and the surface recombination velocity, the current-voltage curve and device quantum efficiency of a 5050 m.sup.2 GaN/InGaN microLED were simulated at different temperatures, which are in good agreement with experimental results.
(36) Simulations of the internal quantum efficiency of the LIED structure of
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(39) In one case, to verify the simulation, temperature-dependent measurement by experiment and simulation can be done.
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(41) This increase in EQE occurs because low temperatures suppress the non-radiative recombination in the active region of the LED. However, when the temperature furtherly decreases below 120K, the EQE strongly decreases. The first reason for a decrease in efficiency at low temperatures is mainly due to the fluctuation in the quantum wells. The electroluminescence spectrum of InGaN/GaN LEDs first shifts to blue and then shifts to red between 300K to 5K. The energy peak position difference can be up to 40 meV. The imbalanced spatial distribution of indium (In) also reduces the density of radiative recombination centers in quantum wells. The quantum wells tend to cluster in a two to three nanometer region, with less radiative recombination centers in other regions. Some injected carriers overflow and reduce carrier injection efficiency, and even lower temperatures can aggravate this problem.
(42) The second reason that InGaN/GaN-based LEDs exhibit poor performance in low temperature situations is the high activation energy or presence of Mg in GaN. Due to the high activation energy of the acceptors of GaN, the hole concentration dramatically decreases, and the recombination zone shifts from the active region to the p-type GaN region at low temperature, which leads to lower efficiency.
(43) The differences between experimental and simulation results in
(44) Therefore, a more optimized LED design that can improve efficiency performance is needed.
(45) Further, the simulation results can be discussed as follows. Theoretically, the internal quantum efficiency (IQE) of GaN/InGaN LEDs can be described by a simple model equation:
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where .sub.inj is the injection current efficiency, N is the carrier density in quantum wells, and A, B, C, are the Shockley-Read-Hall (SRH) nonradiative recombination coefficient, the radiative coefficient, and the Auger coefficient, respectively. The peak efficiency .sub.peak can be inferred when d.sub.IQE/dN=0, and the carrier density at peak efficiency can be obtained as N.sub.peak={square root over (AC)} using equation (1).
(47) For microLEDs that are just a kw micrometers, the surface recombination overwhelms the auger recombination and dominates the nonradiative recombination. This means that the N.sub.peak shifts to a very high value and crosses the regular current operating range of an LED (i.e., greater than 100 A/cm.sup.2). This phenomenon illustrates that GaN/InGaN microLEDs with a smaller dimension no longer suffer from efficiency droop, but instead efficiency slowly rises with the injection current.
(48) On the other hand, by neglecting the auger term, equation (1) with a low injection level can be simplified to:
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(50) As seen in equation (2), increasing the carrier density N in quantum wells improves .sub.IQE. In one case, doping the barrier layers of an MQW active region can increase the carrier density in quantum wells. The additional electrons or holes compensate the carriers of the microLEDs for radiative recombination lost in current leakage due to nonradiative surface recombination.
(51) Accordingly, p-doped barrier layers are commonly applied to alleviate the efficiency droop problem of GaN/InGaN LEDs caused by the low hole injection issues in GaN/InGaN LEDs.
(52) Simulation and Experimental Analysis of GaN/InGaN Micro Light-Emitting Diodes with n-Doped Quantum Well Barriers
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(54) Here, as an example, simulated IQE results of LEDs with different dimensions (i.e., 100100 m.sup.2, 5050 m.sup.2, 1010 m.sup.2, and 55 m.sup.2) and barrier layers with different doping profiles (i.e., intrinsic, p-doped at 110.sup.17 cm.sup.3, and n-doped at 110.sup.17 cm.sup.3) at room temperature are shown. These results show that the IQE value significantly deteriorates as the device size shrinks to 55 m.sup.2, and is strongly affected by the doping profile.
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(58) Here, the Shockley-Read-Hall (SRH) recombination mechanism can be analyzed. The SRH recombination rate is given through the SRH formula:
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where .sub.p,n is the SRH lifetime and f.sub.n,.sub.p is the trap occupation probabilities.
(60) With the same doping concentration, the SRH recombination rates at small injection levels in a GaN/InGaN LED with p-doped or n-doped barrier layers are:
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(62) where the trap occupation probabilities f.sub.n in equation (4) and 1f.sub.p in equation (5) probably equal each other.
(63) The proportional magnitude between .sub.p and .sub.n can be considered as the proportional magnitude between the hole and electron lifetime, .sub.p0 and .sub.n0, respectively. In GaN .sub.p0 is much larger than .sub.n0. Therefore, the SRH recombination rate R.sup.n.sub.SRH in a device with n-doped barrier layers is much smaller than the SRH recombination rate R.sup.p.sub.SRH in a device with p-doped barrier layers.
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(65) Although n-doped barrier layers can improve the efficiency of GaN/InGaN LEDs, n-doped barrier layers can aggravate the low hole injection problem and push the recombination zone close to the p-type GaN region.
(66) Therefore, a very high doping concentration of n-doped barrier layers has a very strong efficiency droop problem and weakens the efficiency performance.
(67) According to one aspect, revising the doping concentration in n-doped barrier layers shows the best performance of the simulated 55 m.sup.2 microLEDs by balancing the low holes injection and high nonradiative SRH recombination rate problems.
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(70) The energy band diagram of the LED structure with p-doped barrier layers has been shown in
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(72) From the energy band diagrams discussed above, the n-doped barrier layers surpasses the current leakage factor and improve efficiency performance.
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(74) According to one embodiment, a light emitting diode structure may be provided. The light emitting diode structure may comprising a p-doped layer, an n-doped layer, and an active zone between the p-doped layer and n-doped layer, the active zone comprising a multiple quantum well structure, wherein the multiple quantum well structure comprising a quantum well disposed between n-doped barrier layers.
(75) According to another embodiment, the quantum well may comprise one of: GaAs, InGaN, InGaAs, AlGaN and InGaAsP and the barrier layers may comprises one of AlGaAs, GaN, AlGaAs, AlGaN and InP. The n-doped barrier layers has a flat conduction band and reduced current leakage from n-doped layer to p doped layer.
(76) According to yet another embodiment, each of the barrier layers may be doped with a dopant concentration ranging from undoped to 110.sup.18 cm.sup.3. Each of the barrier layers may be doped with a dopant concentration of 510.sup.17 cm.sup.3. The barrier layers may have a current density in a range of 0 to 50 A/cm.sup.2. The barrier layers may have a current density of 20 A/cm.sup.2.
(77) According to some embodiments, the light emitting diode structure may further comprising: a substrate, wherein the n-type doped layer is deposited on the substrate and the multiple quantum well structure is grown over the n-type doped layer; and an electron blocking layer deposited on the multiple quantum well structure, wherein the p-type doped layer is deposited on the electron blocking layer.
(78) According to one embodiment, the light emitting diode structure may further comprising: a p-type contact and an n-type contact deposited on the light emitting diode structure. The n-doped layer comprises an n-type GaN layer. The p-doped layer comprises a p-type GaN layer.
(79) According to yet another embodiment, a light emitting diode structure may be provided. The light emitting diode structure may comprising a substrate, an n-doped layer deposited on the substrate, an active zone grown over the n-doped layer, the active zone comprising a multiple quantum well structure, wherein the multiple quantum well structure comprising a quantum well disposed between n-doped barrier layers, an electron blocking layer deposited on the active zone; and a p-doped layer deposited on the electron blocking layer.
(80) According to some embodiments, the multiple quantum well structure comprises one of: GaAs/AlGaAs, InG InaN/GaN, InGaAs/AlGaAs, AlGaN/AlGaN and InGaAsP/InP.
(81) According to one embodiment, a method of manufacturing a light emitting diode structure may be provided. The method may comprising providing a substrate, forming an n-doped layer on the substrate; and forming a multiple quantum well structure over the n-doped layer, wherein the multiple quantum well structure comprising a quantum well disposed between n-doped harrier layers.
(82) According to another embodiment, the method may further comprising forming an electron blocking layer on the multiple quantum well structure; and forming a p-type doped layer on the electron blocking layer.
(83) According to yet another embodiment, the substrate may comprises a sapphire substrate. Each of the barrier layers may be doped with a dopant concentration ranging from undoped to 11018 cm3. each of the barrier layers may be doped with a dopant concentration of 51017 cm3. The barrier layers may have a current density in a range of 0 to 50 A/cm2. The barrier layers may have a current density of 20 A/cm2.
(84) In summary, an optimized design for 55 m.sup.2 microLEDs with n-doped barrier layers and a single quantum well shows an efficiency improvement of 128% at a current density of 20 A/cm.sup.2 as compared to a conventional design with intrinsic MQW active regions.
(85) The foregoing description of one or more embodiments of the invention has been presented for illustration and description purposes. It is not intended to be exhaustive or to limit the invention to the precise form disclosed. Many modifications and variations are possible in light of the teaching herein. The scope of the invention is not intended to be limited by this detailed description, but rather by the appended claims.