Rotary Batch Preheater
20230040599 · 2023-02-09
Inventors
Cpc classification
F28D2021/0024
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02P40/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F27D2013/007
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D7/1669
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F27D13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28F5/06
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D13/00
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
International classification
C03B3/02
CHEMISTRY; METALLURGY
F28D11/04
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Rotary heat-exchanger for glass batch and/or cullet, comprising a stationary casing having a gas inlet and outlet, and an interior region between the gas inlet and outlet; a chamber positioned in the casing rotatable with respect to the casing and configured to receive batch material or a mixture with cullet; at least one heat exchange tube in the casing in fluid communication with the gas inlet and outlet; a feeder in communication with the chamber and comprising a feeder housing configured to discharge the batch material or mixture of batch material and cullet into the chamber along an infeed length and in contact with the at least one tube; wherein the infeed length is a length effective to heat the batch or mixture with cullet material up to at least 100° C. in the infeed length. A method of preheating glass batch is also disclosed.
Claims
1. A rotary heat-exchanger, comprising: a. a stationary casing having a gas inlet, a gas outlet spaced from said inlet, and an interior region between said gas inlet and said gas outlet; b. a chamber positioned in said stationary casing, said chamber being rotatable with respect to said stationary casing and configured to receive batch material or a mixture of batch and cullet material; c. at least one heat exchange tube in said chamber in fluid communication with said gas inlet and said gas outlet, said at least one heat exchange tube having a first end and a second end spaced from said first end; d. a first tube plate attached to said first end of said at least one tube and a second tube plate attached to said second end of said at least one tube, and an outlet attached to said second tube plate and in communication with said chamber for discharging said batch material or mixture of batch and cullet material; e. a feeder in communication with said chamber, said feeder comprising a feeder housing configured to discharge said batch material or mixture of batch material and cullet into said chamber along an infeed length and in contact with said at least one tube; wherein said infeed length is a length effective to heat said batch or mixture of batch and cullet material up to at least 100° C. in said infeed length.
2. The rotary heat-exchanger of claim 1, further comprising an annular gap between said chamber and said stationary casing that is in fluid communication with said gas inlet and said gas outlet.
3. The rotary heat-exchanger of claim 1, wherein said feeder comprises a screw auger.
4. The rotary heat-exchanger of claim 1, wherein said feeder housing has a slot through which said batch material or mixture of batch material and cullet is discharged and distributed over said infeed length.
5. The rotary heat-exchanger of claim 1, wherein chamber has a total length between said first and second tube plates, and wherein said infeed length is at least ¼ of said total length.
6. The rotary heat-exchanger of claim 1, wherein said feeder comprises a driving force for dispersing said batch material or mixture of batch material and cullet into said chamber along said infeed length.
7. The rotary-heat exchanger of claim 1, wherein said driving force comprises a source of compressed air.
8. A method of preheating a batch or a mixture of batch and cullet, said batch or mixture comprising soda-lime glass comprising soda ash, said method comprising: introducing exhaust gas from a glass melting furnace into a rotary heat exchanger comprising at least one heat exchange tube, a stationary casing having a gas inlet in fluid communication with a source of said exhaust gas, a gas outlet spaced from said gas inlet, and an interior region between said gas inlet and said gas outlet, and a chamber in said interior region having a batch infeed length; causing said exhaust gas to flow through said at least one heat exchange tube; introducing said batch or mixture into said chamber along said infeed length of said chamber and rotating said chamber with respect to said stationary casing to allow said batch or mixture to contact said at least one heat exchange tube to transfer heat from said exhaust gas flowing through said at least one heat exchange tube to said batch or mixture to preheat said batch or mixture, wherein said infeed length is effective to allow said batch or mixture to reach a temperature of at least 100° C. in said infeed length; and discharging the preheated batch or mixture from said chamber.
9. The method of claim 8, wherein said infeed length is effective to form sodium carbonate monohydrate from said soda ash.
10. The method of claim 8, wherein said batch or mixture is introduced into said chamber through a slot in a feeder housing that distributes said batch or mixture over said batch infeed length.
11. The method of claim 8, wherein said batch or mixture is introduced into said chamber with a driving force.
12. The method of claim 11, wherein said driving force comprises a source of compressed air.
13. The method of claim 8, further comprising introducing said preheated batch or mixture to a glass melting furnace.
14. The method of claim 8, wherein said exhaust gas is introduced into a plurality of heat exchange tubes of said rotary heat exchanger, and wherein the rotation of said chamber allows said batch or mixture to contact said plurality of heat exchange tubes to transfer heat from said exhaust gas flowing through said plurality of heat exchange tubes to said batch or mixture to preheat said batch or mixture.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0094] The above and other aspects of the embodiments disclosed herein will now be described in further detail, by way of example only, with reference to the accompanying drawings, in which:
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DETAILED DESCRIPTION
[0108] Embodiments disclosed herein concern themselves with the manufacture of soda-lime glass, the most common glass type manufactured. At a glass factory, a variety of raw materials are mixed and then melted in the furnace. The principal ingredients in the manufacture of soda-lime glass are silica sand (SiO.sub.2), limestone (calcium carbonate, CaCO.sub.3), and soda ash (sodium carbonate, Na.sub.2CO.sub.3). In addition, a variety of minor ingredients can be added to promote special properties, including sodium sulfate (Na.sub.2SO.sub.4), carbon (C), gypsum (CaSO.sub.4), aluminum oxide (Al.sub.2O.sub.3), selenium (Se), cerium, cobalt oxide, and others.
[0109] Most glass manufacturing operations assure that batch includes about 3-4% water when introduced to the furnace. If not naturally occurring as a contaminant in the raw materials, glass manufacturing operations often will add water to the batch. This is desirable to reduce dusting during material handling and to prevent segregation of the various batch constituents during handling and charging of the furnace.
[0110] As previously mentioned, a major problem with use of batch preheaters in the glass industry is formation of large agglomerates of batch inside the preheater. It has been discovered that these agglomerates are formed because of the heating of the combination of liquid water with soda ash in the preheater.
[0111] Soda ash will typically comprise 15% to 18% of the total batch mass, with ranges as wide as 12% to 20%. Soda ash is water soluble, hygroscopic, and will form a variety of hydrated forms when contacted with water. When soda ash is mixed with the water some of the soda ash dissolves into the liquid water. If batch with dissolved soda ash is subsequently heated and dried, the dissolved soda ash will leave a solid residue that will act as a cement to agglomerate the various mixture constituents together. This is the cause of agglomeration problems in the prior art batch preheaters.
[0112] When sodium carbonate anhydrous (SCA) is contacted with water, various hydrates can be formed, specifically sodium carbonate monohydrate (SCM), Na.sub.2CO.sub.3.H.sub.2O, sodium carbonate heptahydrate (SCH), Na.sub.2CO.sub.3.7H.sub.2O, and sodium carbonate decahydrate (SCD), Na.sub.2CO.sub.3.10H.sub.2O. When initially contacted with water at room temperature, SCA will dissolve into the water to its saturation concentration of about 32 g/100 ml. This dissolution is exothermic and heats batch material, normally to temperature above 40° C.
[0113] When subsequently heated, as in a batch and cullet preheater, the water will be evaporated and leave behind the SCA solute as a residue. This residue will act as a binder to adhere the grains of the batch material together and form an agglomerate. These agglomerates will clog the preheater device, preventing flow of the batch material and rendering the device inoperable. Formation of such agglomerates is a natural result of the transition of wet batch to dry batch upon heating.
[0114] The other main batch ingredients, silica sand and limestone, are not water soluble. As a result, when they are mixed with water and then heated, the water will evaporate but will not contribute to the residue of dissolved material.
[0115] Embodiments disclosed herein take advantage of several features regarding soda ash/water physicochemical properties, including some or all of the following: [0116] 1) Soda ash readily dissolves into water. Saturation concentration is between 31 and 34.5 g/100 ml depending upon temperature. The dissolution process is exothermic. [0117] 2) When the solution of soda ash and water is cooled to temperature below 32° C., Sodium Carbonate Decahydrate will be formed as a solid substance. [0118] 3) When water with dissolved soda ash is evaporated, the solute residue consists of sodium carbonate monohydrate if the temperature is greater than 35.4° C. [0119] 4) Sodium carbonate is hygroscopic. When anhydrous sodium carbonate is exposed to air temperature above 34.5° C. and with relative humidity greater than 72%, water vapor will be reacted with the sodium carbonate to form sodium carbonate monohydrate. This process is exothermic. [0120] 5) Sodium carbonate monohydrate (SCM) is a stable solid between temperatures of 34.5° C. and 109° C. [0121] 6) SCM thermally decomposes to sodium carbonate and water vapor at temperature above 109° C. The water does not go through a liquid phase. This process is endothermic. [0122] 7) SCM contains 85.48% Na.sub.2CO.sub.3 and 14.52% H.sub.2O by weight.
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[0124] As discovered by Slade (U.S. Pat. No. 3,545,988) dry batch which has been treated by exposure to atmospheres with high humidity will transform SCA into SCM as a coating on the silica sand grains. The resulting treated batch exhibits substantially less dust generation during handling processes and in the furnace than untreated batch.
[0125] Another discovery made by the present inventor is that batch which has been treated as described above exhibits more rapid melting in the glass furnace than untreated batch. It is postulated that the SCM coating on the silica sand grains improves the rate of fluxing action for melting of the silica. Soda ash melts at lower temperature than silica, and molten soda ash will serve as flux to melt the silica at lower temperature than pure silica will melt.
[0126] A preferred embodiment is now described with reference to
[0127] An embodiment of a rotating structure, drum, or chamber 4 alone is depicted in
[0128] Returning to
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[0130] The end 82 of screw housing 29 is typically left open or partially open so that any batch 5 carried by auger 10 that is not pressed through slot 30 is discharged out of the open end of the housing, as shown by element 83.
[0131] As additional batch 5 is fed into the rotating structure 4, the level of batch 5 rises until it spills at 35 over into the outlet cylinder 9. It travels along the bottom of cylinder 9 until it drops at 16 off the end of the cylinder 9. In steady state, the amount of batch 5 exiting at 16 the rotating structure 4 will equal the amount 3 of batch 5 fed into the rotating structure 4.
[0132] The rotating structure 4 and stationary casing 88 can be operated with a horizontal longitudinal axis. Alternatively, the axis may be inclined to horizontal so that gravity will facilitate the flow of batch through the device. In practice the incline angle can vary from 0° to 10° from horizontal.
[0133] In operation, as wet batch at initial temperature 20° C. (e.g., ambient temperature) is heated, the heat input first provides for sensible heating of the wet batch, up to temperature 100° C. For batch with 3% water, the sensible heat required is 68 kJ/kg of batch. After the wet batch is heated to 100° C., additional heat input is used for the latent heat of water evaporation. Again, for batch with 3% water, the latent heat required is 68 kJ/kg of batch.
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[0135] For the example here we specify performance of the machine with batch (with 3% water) infeed rate of 1000 kg/h. The temperature profile of the batch material as it travels through the rotating structure shell is depicted in
[0136] If the batch material is wet the individual grains of batch will adhere to each other and form clumps inside the device. These clumps will not release from the tubes and instead remain attached to the tubes during operation. Then upon further heating and drying, the clumps would form cakes (hard deposits) on the tubes and prevent efficient heat transfer from the hot gases into the batch.
[0137] The preferred embodiment per the present disclosure is shown in
[0138] To summarize and generalize, if the amount of heat transferred into the batch in the infeed zone 65 exceeds that required to heat batch and water to temperature 51 above 100° C. and to evaporate all the water in the batch, the batch in the infeed zone 65 will be dry and at a temperature above 100° C. Generally, this will result if the infeed length is greater than the length of the wet zone plus the evaporation zone in the corresponding machine with material infeed according to prior art.
[0139] Referring again to
[0140] The interior atmosphere 13 of the rotating structure shell 4 becomes filled with water vapor evaporated from wet batch as described above. Some air may infiltrate into the shell 4 but the resulting interior atmosphere 13 will in general have high relative humidity (e.g., higher than 72%). If this atmosphere 13 has relative humidity greater than 72% then water vapor 38 will react with the SCA in batch 32 in the infeed zone 65 to form SCM. The reaction is exothermic and provides additional heat to the batch, aiding in the desired function to keep all batch in the infeed zone 65 warm and dry. Depending on the balance between amounts of SC and water in the batch, most if not all the liquid water can be converted to SCM in the device and all the SCA can be converted to SCM. As described earlier, this recrystallization of SCA to SCM has two significant benefits to the glass furnace process: [0141] 1. Subsequent handling of the batch will exhibit significantly reduced dust generation. [0142] 2. Subsequent melting of the batch will require shorter melting time and reduced melting energy.
[0143] As the batch travels further downstream in the device, its temperature increases as shown at 54 in
[0144] An alternate embodiment is depicted in
[0145] With prior art as depicted in
[0146] Dry batch exhibits a free-flowing characteristic, much like sand in an hourglass. It can flow through structures easily so long as the gap is wider than the piece of batch itself. With the embodiment described herein, there are no “wet zones”. As a result, the spacing between the tubes can be much less without the aforementioned problem with agglomerate formation between the tubes. For 50 mm diameter tubes the spacing between tubes can be as low as 50 mm. This results in 100 mm between centers of the tubes.
[0147] The amount of heat transferred from the hot gases to the batch and/or cullet is directly proportional to the amount of heat transfer area provided in the device, in this case the surface area of the tubes. With the 50 mm spacing enabled by the embodiment described herein, 4 times the number of tubes can be provided in the rotating structure, compared to the number of tubes that could be provided using prior art. Thus 4 times the heat transfer surface is provided in the same size device as prior art. In practice this manifests itself as higher batch temperature out of the device, a smaller and less expensive device, or a combination of the two.
[0148] When cullet is included with batch in the device, the tube spacing must be larger than the largest size piece of cullet. Cullet crushers can sometimes be provided to achieve the optimum size cullet for the device. A typical cullet size specification for a conventional modern crusher is 40 mm maximum size. Such cullet could be handled in the embodiment described herein with 50 mm tube spacing.
[0149] Additionally, the design of the embodiment described here with no “wet zones” will have lower maintenance requirements, as most maintenance is associated with cleaning and removing of accumulated agglomerates inside the device. Experience with the embodiment described herein is that the tubes are maintained in a “bare metal” condition.
EXAMPLE
[0150] Typical machine operation is described below.
[0151] A rotary heat exchanger with rotating chamber of diameter 2100 mm and length of 3650 mm is fitted with 204 tubes. Tubes are 60 mm diameter. The stationary casing is 2150 mm inner diameter so as to provide a gap of 25 mm between the rotating chamber and the stationary casing. Such a device presents 142 square meters of heat transfer area associated with the tubes. The rotary heat exchanger is inclined at an angle of 3° to the horizontal to facilitate batch movement. The chamber rotates at 5 rotations per minute.
[0152] 9000 kg/h of wet batch (with 3% moisture) at temperature 20° C. is fed into the chamber by a cantilevered screw feeder. The cantilevered screw feeder has a 1500 mm long slot hole cut in its bottom to provide an infeed length of 1500 mm, comprising 41% of the rotating chamber length. Batch infeed is uniformly distributed along the infeed length.
[0153] Hot furnace exhaust gases at 550° C. are introduced to the heat exchanger inlet and are cooled to 350° C. at the gas outlet. After steady state is reached, 9000 kg/h of batch exits the heat exchanger at temperature of 370° C. Visual observation confirms that there are no “wet zones” within the heat exchanger and no clumps or agglomerates are formed. The heat transfer rate calculates to be 41 W/m.sup.2-° K based on the tube surface area.
[0154] The same size device built with rotating chamber according to prior art would include 52 tubes. Wet batch is fed into the rotating chamber at one end. This design presents 36 square meters of heat transfer area associated with the tubes. Such device would manifest a “wet zone” comprising about 60% of the length of the chamber. In this wet zone, clumps would form and stick inside the chamber and after a short time the machine would have to be shut down. The agglomerates would block the infeed end of the rotating chamber and prevent additional infeed of wet batch. Even if it could avoid clump formation, the device would only heat the cullet/batch mix to 175° C. at the same heat transfer rate of 41 W/m.sup.2-° K.