Countercurrent heat exchanger/reactor
10823510 ยท 2020-11-03
Assignee
Inventors
Cpc classification
B01J19/0093
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/00835
PERFORMING OPERATIONS; TRANSPORTING
F28F9/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D7/1607
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D7/1653
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J2219/2462
PERFORMING OPERATIONS; TRANSPORTING
F28D7/1684
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J8/087
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/00788
PERFORMING OPERATIONS; TRANSPORTING
B01J2219/00849
PERFORMING OPERATIONS; TRANSPORTING
F28F2260/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J2219/0086
PERFORMING OPERATIONS; TRANSPORTING
International classification
F28D7/02
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
F28D7/16
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01J19/00
PERFORMING OPERATIONS; TRANSPORTING
B01J19/24
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Counter-flow heat exchanged is constructed with plenums at either end that separate the opposing fluids, the channels of which are arrayed in a checkerboard patterns, such that any given channel is surrounded by channels of opposing streams on four sideslaterally on both sides and vertically above and below.
Claims
1. A device including channels arranged for countercurrent flow comprising: a bundle of channels comprising a first plurality of channels and a second plurality of channels configured to flow fluids counter-currently in opposite directions whereby opposing streams of fluid are arranged in a checkerboard pattern, such that for any given channel there exist alongside, in four directions, laterally on both sides, above and below, channels containing the opposite fluid; wherein the second plurality of channels confines one of the opposing streams through a plenum area at either end of the bundle, and extends into a cavity through which fluid enters or exits the device by second flowstream ports in a wall of the cavity; and wherein the second plurality of channels that penetrates the plenum area may be altered in size or shape, or both size and shape, so as to ensure free space completely around the second plurality of channels, such that fluid is free to flow between the second plurality of channels to or from first flowstream ports.
2. The device of claim 1 wherein the areal density of the bundle of channels is greater than 400 m.sup.2/m.sup.3.
3. The device of claim 1 wherein a heat transfer coefficient is enhanced by means of structural changes in walls of the individual channels, leading to increased turbulence in the flowing stream.
4. The device of claim 1 wherein a cross-sectional shape of individual channels in the first plurality of channels is a hollow polygon of no more than four sides, while a cross-sectional shape of the second plurality of channels takes the form of any shape and size, including the voids created between the walls of the first plurality of channels.
5. The device of claim 1 wherein the checkerboard pattern is formed by alternating layers of sheets and rows of tubes, said tubes of which may be round, ovate or polygonal in cross section and separated laterally by void spaces, while sheets positioned above and below these rows separate them vertically, such that alternating layers of tubes are staggered.
6. The device of claim 1 wherein a manifold at one or both ends is formed by means of obstructing axial flow of a first set of complementary channels in half-checkerboard pattern and redirecting it in the transverse direction via channels that pass diagonally between the channels of a second set of complementary channels in half-checkerboard pattern, such that flow from the first set converges to side ports alongside the ends of the channel bundle.
7. A method of heat transfer between a first fluid stream and a second fluid stream in a countercurrent single pass heat exchanger, the method comprising: flowing the first fluid stream and the second fluid stream in a bundle of channels such that the first and second fluid streams flow countercurrently to each other to exchange heat within an interior region of the bundle along a longitudinal axis of the bundle in four directions with respect to an individual channel without mixing the first and second fluid streams, the four directions comprising above the individual channel, below the individual channel, and along at least a portion of each lateral side of the individual channel; collecting the first fluid stream in a first fluid receiving member the second fluid stream being confined within a plurality of channels extending through a plenum area of the first fluid receiving member to separate the first and second fluid streams, wherein the plurality of channels may be altered in size or shape, or both size and shape, so as to ensure free space completely around the plurality of channels such that fluid is free to flow between the plurality of channels to or from a flowstream port; and collecting the second fluid stream in a second fluid receiving member.
8. The method of claim 7 further comprising: increasing flow turbulence of the first fluid stream such that a heat transfer coefficient of the first flow stream is modified to a value which is within one order of magnitude of a heat transfer coefficient value of the second fluid stream.
9. The method of claim 7, wherein a chemical reaction occurs in the first fluid stream and the second fluid stream either absorbs energy therefrom or provides thermal energy to the first fluid stream.
Description
BRIEF DESCRIPTION OF THE FIGURES
(1) Embodiments of the present invention will now be described, by way of example only, with reference to the accompanying drawings for the purpose of illustrating the embodiments, and not for purposes of limiting the invention, wherein:
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DETAILED DESCRIPTION OF THE INVENTION
(12) An illustration of an exemplary heat exchanger, heat exchanger 10, of the present invention is shown in
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(14) A discriminating feature of this heat exchanger design is that every channel for each set of half checkerboard receives its own fluid that does not mix with the flow from an adjacent channel. In conventional shell-and-tube heat exchangers, one or more horizontal baffles may serve to delineate separate compartments of shell-side flowusually for the purpose of reversing flow of the shell-side between compartmentsbut not for the purpose of ensuring single-pass axial counter-current flow.
(15) Below are definitions of terms used herein to describe the invention:
(16) Checkerboarda pattern in which zones of opposite characteristics, such as fluid properties, exist side-by-side in four directionslaterally on both sides, above and belowin the same way as the colors of a checkerboard game table are arrayed.
(17) Half-checkerboardjust one of the two complementary patterns that make up the full checkerboard pattern.
(18) Channel bundlea collection of channels, arrayed in a checkerboard pattern.
(19) Headera zone within which the opposing fluids are distributed separately to the channels of one half-checkerboard pattern or the other. It is composed of two distinct spaces that are impervious to each other.
(20) Separator platea wall, penetrable only by a set of channels dedicated to one of the two half-checkerboard patterns. It is analogous to the tube sheet of conventional shell-and-tube heat-exchanger designs.
(21) Areal densitythe ratio of total internal surface area of channels of the smaller cross-sectional perimeter of the two channel patterns, to the total outside volume dimension of the channel bundle, expressed as square meters per cubic meters.
(22) Plenuma space that is open to more than one channel. It can be used as a distribution point for fluid entering or exiting channels. For purposes of this disclosure, the plenum is the space directly adjacent to the channel bundle that distributes fluid that enters or exits the heat exchange transverse to a longitudinal axis of the channel bundle.
(23) As noted above
(24) In particular, Sect. A-A of
(25) The termination of channel bundle 1 occurs at the terminal plane 4, shown as Sect. B-B in
(26) In the above embodiments of heat exchanger 10, flow paths of streams 14 and 16 have been described as either entering and exiting the exchanger through one of ports 6 or 7. For example, stream 14 has been described as entering the heat exchanger device through port 6 in end 10B (see
(27) Various configurations of channel bundles that fall within the scope and definition of a checkerboard pattern are described in
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(29) The contiguous channels 32 need not have the same cross-sectional area; one set of channels can be smaller than the other set of channels.
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(31) For example, stream 16 can be directed through round or ovate tubes 44 (acting as channels) that may be welded to thin sheets 40 above and below, forming a sandwich of tubes 44 held between metal sheets 40. The spaces 42 between the tubes 44 can then be used to convey the other stream 14 counter-currently. In this case, void spaces 42 between tubes 44 would look something like an hourglass. The relative area of tube cross-section versus that of the hourglass cross-section is variable according to the pitch, or distance between tubes. The basic pattern of the checkerboard is retained in that each channel exists in proximity to channels of opposing flow, exchanging heat in four directions, laterally on both sides, above and below.
(32) In an exemplary embodiment of the sheet-separated channel configuration 38, each stream, 14 and 16, would enter via a side port 6 and exit via an axial port 7 at the other end, or vice-versa. This configuration may improve pressure drop, depending on conditions of temperature, pressure and viscosity. The alternative is to have the streams 14 and 16 enter and exit via the same type of collector, be it located on the sides to handle fluid that flows transversely through a header 2, or axially at the end caps 3 of the heat exchanger 10.
(33) In the configuration shown in
(34) Referring to
(35) In any of the configurations described, the present invention 10 can also be used to facilitate chemical reaction in at least one of the opposing streams 14, 16 together with simultaneous heat transfer between two streams 14, 16 in countercurrent flow, such that one of the opposing streams provides energy to the other stream. An example of such a reaction is the endothermic syngas process for producing carbon monoxide and hydrogen from methane and water. In one embodiment, a feedstock mixture would be fed to one complementary set of half-checkerboard channels (e.g., 12,
(36) A heat exchanger 10 according to this disclosure can be manufactured to areal densities of greater than 400 m.sup.2/m.sup.3. Depending of the form applied, areal density can reach up to 2,000 m.sup.2/m.sup.3 and possibly higher. Such a heat exchanger exhibits superior performance over conventional shell-and-tube heat exchanger in terms of pressure drop. For the shell side of a conventional shell-and-tube heat exchanger especially, pressure drop increases rapidly as the channel size decreases. Table 1 provides data calculated for a hypothetical heat exchanger designed in accordance with an embodiment of the present invention: that is, for a hypothetical microchannel heat exchanger providing single-pass countercurrent flow and having a bundle of channels in which the channels are arranged to form the checkerboard pattern with opposing flows that are kept separate. Table 1 describes a hypothetical cases of a microchannel heater exchanger according to the present disclosure and a conventional shell-and-tube heat exchanger, both being of equal outer dimension and flow conditions. The microchannel countercurrent heat exchanger, longitudinally baffled at each row, serves as a baseline case for comparison with transversely baffled shell-and-tube heat exchangers of varying tube diameters (see Table 2 below). These cases exemplify heat recuperation with opposing streams of carbon dioxide-one stream hotter than the other and at different pressure, but both at the same flow rate. The tube outside diameter of this base-case microchannel heat exchanger is 1.07 mm. The envelope is large enough to contain a bundle of 40,000 such tubes.
(37) Table 2 compares the pressure drop of the longitudinally baffled microchannel heat exchanger of fixed tubing size (1-mm diameter) with the transversely baffled shell and tube heat exchange of varying tube sizes from 20 mm to as narrow as 1 mm in outside diameter. Because the outer dimension of the tube bundled remains fixed according to Table 1, the tube count for the shell-and-tube case decreases as the tube outside diameter increases. At about the 12-mm-OD tube size (approximately -inch), the shell-side pressure drop of the conventional heat exchanger is equal to the pressure drop at the shell-side of the hypothetical microchannel device presented in Table 1. While the pressure drop between the two exchangers may be equivalent, the areal density of the exchanger in accordance to the present disclosure and provided in Table 1, is over 5 times greater (compare 1,493 m.sup.2/m.sup.3 to 289 m.sup.2/m.sup.3). At the 1-mm size, the transversely baffled shell and tube heat exchanger (having 5 baffles) has a pressure drop that is 18 times greater than the exchanger described in Table 1 and in accordance with an embodiment of the present disclosure. (Note however, that the areal densities between the two different exchangers is substantially equivalent.) For a given shell dimension, the areal density increases as tube OD decreases. Thus as a general rule, heat exchanger 10 according to this disclosure operates with less pressure drop at areal densities of 400 m.sup.2/m.sup.3 or greater.
(38) It is also the case that the heat duty capability of conventional shell-and-tube heat exchangers cannot match counter-current microchannel heat exchangers 10 according to this disclosure unless the areal density is greater than 400 m.sup.2/m.sup.3 (see Table 3). Looking at it another way, a microchannel heater exchanger 10 according to this disclosure can achieve a high degree of heat duty in a compact envelope without the high pressure drop that would result from a conventional shell-and-tube design. As can be seen in Table 3, the conventional shell-and-tube heat exchanger (with 5 baffles) does not achieve equivalent heat duty performance as the microchannel heat exchanger unless the tubes are less than 4 mm in outside diameter, but at this size the shell-side pressure drop is much higher than that of the longitudinally baffled design. Therefore, conventional shell-and-tube design exchangers (i.e., including one or more transverse baffles) can not provide similar or equivalent heat duty performance while maintaining an acceptable pressure drop.
(39) TABLE-US-00001 TABLE 1 Baseline specification: Longitudinally baffled microchannel heat exchanger Tube bundle OD 0.33 meters Tube bundle length 1.5 meters Tube OD 1.07 Millimeter Tube count 40,000 Areal density 1,493 m.sup.2/m.sup.3 Heat duty Carbon dioxide (both sides) Flow rate 15 kg/s (both sides) Heat duty 2,783 kW Tube side Inlet 200.0 C. 285.0 Bar Outlet 336.0 C. 284.8 Bar Tube side pressure drop: 0.2 Bar Shell side Inlet 450.0 C. 115.0 Bar Outlet 292.1 C. 114.7 Bar Shell side pressure drop: 0.3 Bar
(40) TABLE-US-00002 TABLE 2 Comparative performance: Pressure drop 40,000-tube Baseline horizontally baffled microchannel HX (A) versus Transversely baffled shell-and-tube HX (B) of varying tube size HX B: Shell side Tube side Tube Areal Press. Times Press. Times OD Tube density drop, baseline drop, Baseline mm count m.sup.2/m.sup.3 bar microHX bar microHX 1 41,660 1,500 5.38 17.93 0.57 2.85 2 10,420 750 2.36 7.87 0.27 1.35 3 4,630 500 1.46 4.87 0.18 0.90 4 2,610 376 1.04 3.47 0.13 0.65 5 1,670 301 0.80 2.67 0.11 0.55 6 1,160 251 0.65 2.17 0.10 0.50 7 860 217 0.55 1.83 0.08 0.40 8 660 190 0.47 1.57 0.08 0.40 9 520 168 0.41 1.37 0.07 0.35 10 417 150 0.37 1.23 0.07 0.35 11 344 136 0.33 1.10 0.06 0.30 12 289 125 0.30 1.00 0.06 0.30 13 246 115 0.27 0.90 0.06 0.30 14 213 107 0.25 0.83 0.06 0.30 15 185 100 0.23 0.77 0.05 0.25 16 163 94 0.22 0.73 0.05 0.25 17 144 88 0.20 0.67 0.05 0.25 18 129 84 0.19 0.63 0.05 0.25 19 115 79 0.18 0.60 0.05 0.25 20 104 75 0.17 0.57 0.05 0.25 A base line of under 1.00 (e.g., see above lines) denotes comparative underperformance by transversely baffled shell-and tube heat exchanger
(41) TABLE-US-00003 TABLE 3 Comparative performance: Heat exchange duty 40,000-tube Baseline longitudinally baffled microchannel HX (A) versus Transversely baffled shell-and-tube HX (B) of varying tube size HX B: Tube Areal OD Tube density Heat duty, Times baseline mm count m.sup.2/m.sup.3 kW microHX 1 41660 1,500 2,787 1.00 2 10420 750 2,786 1.00 3 4630 500 2,766 0.99 4 2610 376 2,693 0.97 5 1670 301 2,569 0.92 6 1160 251 2,418 0.87 7 860 217 2,263 0.81 8 660 190 2,108 0.76 9 520 168 1,959 0.70 10 417 150 1,815 0.65 11 344 136 1,688 0.61 12 289 125 1,574 0.57 13 246 115 1,470 0.53 14 213 107 1,379 0.50 15 185 100 1,292 0.46 16 163 94 1,216 0.44 17 144 88 1,144 0.41 18 129 84 1,083 0.39 19 115 79 1,020 0.37 20 104 75 998 0.36 Area below the line denotes comparative under-performance by transversely baffled heat exchanger
Example 1
(42) A heat exchanger as shown in
(43) TABLE-US-00004 TABLE 4 Heat duty: Tests with water 25 25 channels, 1 1 6.57 outer dimensions Heat Power Flowrate Inlet Outlet duty density Case Stream [GPM] [F.] [F.] [kW] MW/m.sup.3 A1 Hot Side 1.08 91.4 73.2 2.9 26.8 Cold Side 1.08 60.8 79.1 2.88 B1 Hot Side 0.48 124.4 85.9 2.71 25.1 Cold Side 0.48 64.4 102.7 2.7 C1 Hot Side 0.9 96.1 74.4 2.86 26.6 Cold Side 0.9 60.1 81.8 2.86 D1 Hot Side 0.67 110.7 79.3 3.09 28.6 Cold Side 0.67 60.3 91.6 3.08 E1 Hot Side 0.29 180.4 98 3.5 32.4 Cold Side 0.29 62.4 144.1 3.47 F1 Hot Side 0.38 148.4 93.8 3.04 28.1 Cold Side 0.38 66.7 120.9 3.02
Example 2
(44) A stainless steel microchannel heat exchanger constructed in accordance with the present disclosure, and having an areal density of 1,351 m2/m3 in a bundle volume of 65.7 cubic inches, weighing 8.5 lbs., was tested under the conditions described in Table 5. Power density for these cases is in the range of 10 to 11 MW/m.sup.3.
(45) TABLE-US-00005 TABLE 5 Heat duty: Tests with carbon dioxide 32 20 channels, 1.04 2.155 29.43 outer dimensions Heat Power Flowrate Inlet Outlet duty density Case Stream [GPM] [F.] [F.] [kW] MW/m.sup.3 A2 Hot Side 3.45 175.6 97.0 10.8 10.1 Cold Side 2.22 77.8 112.9 11.1 B2 Hot Side 3.37 178.9 97.3 10.9 10.0 Cold Side 2.19 79.7 115.4 10.7 C2 Hot Side 6.87 167.4 101.5 12.1 11.2 Cold Side 2.23 83.3 142.5 12.1
(46) While the disclosure has been described in detail and with reference to specific embodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope of the embodiments. Thus, it is intended that the present disclosure cover the modifications and variations of this disclosure provided they come within the scope of the appended claims and their equivalents.