Hydrogen purging device and method for fuel cell system

Abstract

A hydrogen purging device for a fuel cell system includes a humidifier that humidifies dry air supplied from an air blower, using moist air discharged from a cathode of a stack and supplies the humidified air to the cathode. A water trap and a hydrogen recirculation blower are sequentially connected to an outlet of an anode, wherein a hydrogen outlet of the water trap and an inlet of the humidifier are connected by a cathode-hydrogen purging line for purging hydrogen to the cathode so that the hydrogen discharged from the anode of the fuel stack is purged to the cathode during idling or during normal driving.

Claims

1. A hydrogen purging method comprising: a first step of purging hydrogen from an anode of a fuel cell stack; a second step of supplying the purged hydrogen to an inlet of a humidifier; and a third step of passing the purged hydrogen supplied to the inlet of the humidifier through the humidifier with air and dispersing the purged hydrogen to a cathode of the fuel cell stack, wherein the purged hydrogen passes through a cathode-side hydrogen purging line, connected between a hydrogen outlet of a water trap and the inlet of the humidifier, to the cathode of the fuel cell stack in accordance with the first to third steps when an idling begins, and hydrogen purging to the cathode is stopped in accordance with the first to third steps when a cell voltage drops to or below a reference voltage, wherein the hydrogen purging to the cathode according to the first to third steps is performed when an amount of charge of cells of the fuel cell stack is at or above a predetermined amount during a normal driving of a fuel cell vehicle so as to prevent an exposure of internal components of the fuel cell stack to a predetermined high cell potential, and wherein the hydrogen purging to the cathode is stopped when voltage differences of the cells are at or above a predetermined level.

2. The method of claim 1, wherein the first to third steps are periodically performed during the idling or during the normal driving of the fuel cell vehicle.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) The above and other features of the present disclosure will now be described in detail with reference to certain exemplary embodiments thereof illustrated by the accompanying drawings which are given hereinbelow by way of illustration only, and thus are not limitative of the present disclosure.

(2) FIG. 1 is a diagram illustrating a configuration of a hydrogen purging device for a fuel cell system of the related art.

(3) FIG. 2 is a diagram schematically illustrating a method of dropping cell voltage during idling in the related art.

(4) FIG. 3 is a diagram illustrating a configuration of a hydrogen purging device for a fuel cell system according to the present disclosure.

(5) FIG. 4 is a flowchart illustrating a hydrogen purging method for a fuel cell system according to the present disclosure.

(6) FIG. 5 is a diagram schematically illustrating idling where hydrogen purging for a fuel cell system according to the present disclosure is performed.

(7) FIG. 6 is a graph comparing cell voltage drop ratios according to operation cycles which are measured in an operation that uses a hydrogen purging method for a fuel cell system according to the present disclosure and during ordinary operation.

(8) It should be understood that the appended drawings are not necessarily to scale, presenting a somewhat simplified representation of various preferred features illustrative of the basic principles of the disclosure. The specific design features of the present disclosure as disclosed herein, including, for example, specific dimensions, orientations, locations, and shapes will be determined in part by the particular intended application and use environment.

(9) In the figures, reference numbers refer to the same or equivalent parts of the present disclosure throughout the several figures of the drawing.

DETAILED DESCRIPTION

(10) Hereinafter reference will now be made in detail to various embodiments of the present disclosure, examples of which are illustrated in the accompanying drawings and described below. While the disclosure will be described in conjunction with exemplary embodiments, it will be understood that present description is not intended to limit the disclosure to those exemplary embodiments. On the contrary, the disclosure is intended to cover not only the exemplary embodiments, but also various alternatives, modifications, equivalents, and other embodiments, which may be included within the spirit and scope of the disclosure as defined by the appended claims.

(11) Hereinafter, exemplary embodiments of the present disclosure will be described more fully with reference to the accompanying drawings for those skilled in the art to implement the present disclosure.

(12) Referring to FIG. 3, an air supply system 30 for supplying air to a fuel cell stack 10 includes an air blower 31 supplying external air to a humidifier 32, and a humidifier 32 humidifying dry air supplied from the air blower 31 with moist air discharged from a cathode of the stack 10 and supplying the humidified air to the cathode.

(13) A fuel supply system 20 supplying hydrogen to the fuel cell stack 10 includes a water trap 21 and a hydrogen recirculation blower 22 sequentially connected to the outlet of an anode in order to recirculate non-reacted hydrogen purged at the anode back to the anode, in addition to supplying new hydrogen fuel to the anode.

(14) According to the present disclosure, a hydrogen outlet of the water trap 21 and an inlet (an inlet through which air flows into the humidifier 32 from the air blower 31) of the humidifier 32 are connected by a cathode-side hydrogen purging line 40 for purging hydrogen to the cathode so that hydrogen discharged from the anode of the fuel cell stack can be purged to the cathode during idling or normal driving. Idling refers to when the vehicle is on but stationary, and normal driving refers to a vehicle moving without stopping.

(15) A solenoid type valve 42 is disposed in the cathode-side hydrogen purging line 40 to purge the hydrogen to the cathode or to stop the hydrogen from being purged to the cathode when the cell voltage drops to or below a reference voltage.

(16) A hydrogen purging method of the present disclosure based on a configuration is described hereafter with reference to FIGS. 3 and 4.

(17) When a fuel cell vehicle equipped with a fuel cell system idles, such as while stopped, for example, waiting at a traffic signal in a city while driving normally, the hydrogen purging method of the present disclosure is performed.

(18) The hydrogen purging method of the present disclosure includes a first step of purging hydrogen from an anode of a fuel cell stack, a second step of supplying the purged hydrogen to an inlet of a humidifier, and a third step of passing the supplied hydrogen to the inlet of the humidifier through the humidifier with air and dispersing the hydrogen to an anode of the fuel cell stack.

(19) In the first step, as the hydrogen is purged from the anode, the hydrogen is discharged with water, in which the water is held in an internal space of the water trap 21 and the hydrogen passes through the internal space of the water trap 21.

(20) In the second step, the purged hydrogen passing through the water trap 21 is supplied to the inlet of the humidifier 32 along the cathode-side hydrogen purging line 40, and the valve 42 in the hydrogen purging line 40 is opened to allow the hydrogen purge.

(21) In the third step, the hydrogen supplied to the inlet of the humidifier 32, that is, the inlet into which dry air flows from the air blower 31, passes through the humidifier 32 with the water from the air blower 31, and is purged to the cathode of the fuel cell stack 10.

(22) The hydrogen purged to the cathode of the fuel cell stack during idling causes the voltage potential of the cells of the fuel cell stack to drop while producing water by reacting with air at the cathode.

(23) That is, the hydrogen purged to the cathode produces water by reacting with some of the air supplied to the cathode to generate electricity in the fuel cell stack, thus as the amount of air decreases, the voltage potential of the cells may temporarily drop.

(24) Referring to FIG. 5, as a test example of the present disclosure, a test that operates a fuel cell system including a fuel cell stack, such as a cell proton exchange membrane fuel cell (PEMFC) stack, in an actual driving mode was conducted for a total operation time of 600 cycles (1 cycle: 1 hr) while purging hydrogen to a cathode for about 10 minutes during idling.

(25) The test results show that cell voltage drops from 0.945 V to 0.821 V during idling while the hydrogen is purged to the cathode.

(26) Therefore, it is possible to reduce a corrosion due to exposure of internal components, such as, an electrolyte membrane, a catalyst layer, etc., of the fuel cell to high potential because of the voltage drop of the cells during idling, thus improving durability of the fuel cell.

(27) As described above, since the hydrogen purged at the anode is purged to the cathode to drop the voltage without being discharged to the outside, the exposure of the internal components, such as, the electrolyte membrane, the catalyst layer, etc., to high voltage potential is prevented due to the voltage drop of the fuel cell. Therefore, it is possible to improve the durability of the fuel cell, and thereby, satisfy the safety rules for hydrogen exhaust concentration since the hydrogen is purged to the cathode.

(28) Further, since the cell voltage is reduced by the hydrogen purging to the cathode in accordance with the first to third steps, and the operation state of the fuel cell may become abnormal when the cell voltage drops to or below a reference voltage, purging the hydrogen to the cathode is stopped when the voltage of the fuel cell is reduced to or below the reference voltage. The valve 42 in the cathode-hydrogen purging line 40 is controlled to close and stop hydrogen from being purged to the cathode.

(29) The hydrogen purging method of the present disclosure is also used at a certain amount of charge of the fuel cells in restarting of normal driving after a period of idling, in addition to during idling.

(30) That is, the hydrogen purging method according to the first to third steps is performed even when the amount of charge of the cells is at or above a predetermined amount while driving normally, thus minimizing the exposure of the internal components of a fuel cell to high cell potential and stopping hydrogen purged to a cathode when the voltage differences of cells are at or above a predetermined level.

(31) As another test example of the present disclosure, a test of durability of a fuel cell by the hydrogen purging method of the present disclosure was conducted as follows, as compared with the related art. Subject of test: 20 cell proton exchange membrane fuel cell (PEMFC) stack Test equipment: Small breadboard

(32) For reference, when a fuel cell system is installed in a laboratory, it is called a breadboard. Operating conditions: Operation temperature: 58 C. Air fuel stoichiometric ratio: 2.2 Air humidification type: Membrane humidifier Hydrogen supply system operation type: Hydrogen recirculation Cumulative operation time: 600 cycles (1 cycle=1 hr)

(33) Hydrogen was discharged as an ordinary operation, to a cathode without purging it on the basis of the operating conditions. A fuel cell system was operated while purging the hydrogen to a cathode in accordance with the hydrogen purging method of the present disclosure, and then a deterioration ratio of cells and a cell voltage drop ratio were measured.

(34) As a result of measuring, the deterioration ratio (@0.6 A/cm.sup.2) was 2.99% in purging of hydrogen to the cathode and 6.59% in the ordinary operation, and the cell voltage drop ratio (@0.6 A/cm.sup.2) was 25.7 V/hr in purging of hydrogen to a cathode and 74 V/hr in the ordinary operation. Therefore, it is possible to reduce the cell voltage drop ratio about three times for the same operation cycle.

(35) It has been known that the higher the operation cycle of a fuel cell, the greater the decrease in durability of the fuel cell, and the voltage of the entire cell stack drops. However, according to the present disclosure, it is possible to reduce the voltage drop ratio of the cell about three times in the same cycle operation, as compared with the ordinary operation of the related art, therefore it is possible to increase the durability of a fuel cell in the operation cycle of a fuel cell.

(36) Although embodiments of the present disclosure were described in detail above, the scope of the present disclosure is not limited thereto, and various changes and modifications from the spirit of the present disclosure defined in the following claims by those skilled in the art are also included in the scope of the present disclosure.

(37) The disclosure has been described in detail with reference to the exemplary embodiments thereof. However, it will be appreciated by those skilled in the art that changes may be made in these embodiments without departing from the principles and spirit of the disclosure, the scope of which is defined in the appended claims and their equivalents.