SEPARATOR ASSEMBLY FOR FUEL CELL AND FUEL CELL STACK INCLUDING SAME
20200343565 ยท 2020-10-29
Inventors
Cpc classification
H01M8/0256
ELECTRICITY
Y02E60/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01M8/0258
ELECTRICITY
International classification
Abstract
A separator assembly for a fuel cell is configured such that separators made of metal materials having different thermal expansion coefficients are joined together and includes: a first separator having a first buffer portion formed by depressing at least one point on a surface of the first separator; and a second separator integrated with the first separator by joining, and having a second buffer portion that is formed by depressing a surface of the second separator such that the second buffer portion is spaced apart from the first buffer portion and surrounds the first buffer portion.
Claims
1. A separator assembly for a fuel cell, the separator assembly being configured such that separators made of metal materials having different thermal expansion coefficients are joined together, the separator assembly comprising: a first separator including a first buffer portion formed by depressing at least one point on a surface of the first separator; and a second separator integrated with the first separator by joining, and including a second buffer portion that is formed by depressing a surface of the second separator such that the second buffer portion is spaced apart from the first buffer portion and surrounds the first buffer portion.
2. The separator assembly of claim 1, wherein the first separator has a larger thermal expansion coefficient than the second separator.
3. The separator assembly of claim 1, wherein each of the first separator and the second separator includes multiple manifolds provided at locations corresponding to each other and through which reactive gas and coolant are introduced and discharged, a welding spot where the first separator and the second separator are welded together is provided at a predetermined point in each of edge regions of the first separator and the second separator, and each of the first buffer portion and the second buffer portion is provided in a region between the manifolds and the welding spot.
4. The separator assembly of claim 1, wherein a width (w1) of the first buffer portion is smaller than a width (w2) of the second buffer portion.
5. The separator assembly of claim 4, wherein the width (w1) of the first buffer portion and the width (w2) of the second buffer portion satisfies the following equation:
w2w1>x1x2, wherein x1 denotes an amount of expansion of the first separator in response to temperature, and x2 denotes an amount of expansion of the second separator in response to temperature.
6. The separator assembly of claim 1, wherein a depth (h1) of the first buffer portion is smaller than a depth (h2) of the second buffer portion.
7. The separator assembly of claim 1, wherein the first buffer portion and the second buffer portion are provided in a dot shape.
8. The separator assembly of claim 7, wherein the second buffer portion is provided in a shape of one dot, and the first buffer portion is provided in a shape of at least one dot.
9. The separator assembly of claim 1, wherein the first buffer portion and the second buffer portion are provided in a line shape.
10. A fuel cell stack provided by stacking multiple unit cells in which each of the unit cells includes a membrane electrode assembly, a pair of gas diffusion layers, a first separator, and a second separator, comprising: the first and second separators facing each other in adjacent unit cells are integrated by joining, the first separator includes a first buffer portion formed by depressing at least one point on a surface of the first separator, and the second separator includes a second buffer portion formed by depressing a surface of the second separator such that the second buffer portion is spaced apart from the first buffer portion and surrounds the first buffer portion.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0036] The above and other objectives, features and other advantages of the present disclosure will be more clearly understood from the following detailed description when taken in conjunction with the accompanying drawings, in which:
[0037]
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[0039]
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[0042]
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[0044]
DETAILED DESCRIPTION OF THE DISCLOSURE
[0045] It is understood that the term vehicle or vehicular or other similar term as used herein is inclusive of motor vehicles in general such as passenger automobiles including sports utility vehicles (SUV), buses, trucks, various commercial vehicles, watercraft including a variety of boats and ships, aircraft, and the like, and includes hybrid vehicles, electric vehicles, plug-in hybrid electric vehicles, hydrogen-powered vehicles and other alternative fuel vehicles (e.g. fuels derived from resources other than petroleum). As referred to herein, a hybrid vehicle is a vehicle that has two or more sources of power, for example both gasoline-powered and electric-powered vehicles.
[0046] The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the disclosure. As used herein, the singular forms a, an and the are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms comprises and/or comprising, when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. As used herein, the term and/or includes any and all combinations of one or more of the associated listed items. Throughout the specification, unless explicitly described to the contrary, the word comprise and variations such as comprises or comprising will be understood to imply the inclusion of stated elements but not the exclusion of any other elements. In addition, the terms unit, -er, -of, and module described in the specification mean units for processing at least one function and operation, and can be implemented by hardware components or software components and combinations thereof.
[0047] Further, the control logic of the present disclosure may be embodied as non-transitory computer readable media on a computer readable medium containing executable program instructions executed by a processor, controller or the like. Examples of computer readable media include, but are not limited to, ROM, RAM, compact disc (CD)-ROMs, magnetic tapes, floppy disks, flash drives, smart cards and optical data storage devices. The computer readable medium can also be distributed in network coupled computer systems so that the computer readable media is stored and executed in a distributed fashion, e.g., by a telematics server or a Controller Area Network (CAN).
[0048] Hereinbelow, exemplary embodiments of the present disclosure will be described in detail with reference to the accompanying drawings. However, it should be understood that the embodiments of the present disclosure may be changed to a variety of embodiments and the scope and spirit of the present disclosure are not limited to the embodiment described hereinbelow. The embodiments of the present disclosure described hereinbelow are provided for allowing those skilled in the art to more clearly comprehend the present disclosure. Throughout the drawings, the same reference numerals will refer to the same or like parts.
[0049] A fuel cell stack according to an embodiment of the present disclosure is to improve the airtightness by improving the shape and airtightness structure of separators while maintaining the structure of a fuel cell stack according to the related art shown in
[0050] Therefore, a fuel cell stack according to an embodiment of the present disclosure is formed by stacking multiple unit cells to be connected in series as shown in
[0051] In the present disclosure, when the separator assembly is made of metal materials having different thermal expansion coefficients, positions thereof are not specified as the anode separator and the cathode separator depending on the thermal expansion coefficients.
[0052] Therefore, in the following description, a separator having a relatively larger thermal expansion coefficient is referred to as a first separator, and a separator having a relatively smaller thermal expansion coefficient is referred to as a second separator in the pair of separators constituting the separator assembly.
[0053] The separator assembly will be described in detail.
[0054] As shown in
[0055] The first separator 110 has a reaction surface 114 provided at the center thereof in which an MEA is disposed, and multiple inlet manifolds 112 and multiple outlet manifolds 113 that are provided at opposite side of the reaction surface 114, respectively. In order to seal the reaction surface 114, the inlet manifolds 112, and the outlet manifolds 113, a gasket 40 is used to surround a region where the reaction surface 114, the inlet manifolds 112, and the outlet manifolds 113 are provided.
[0056] Further, similar to the first separator 110, the second separator 120 also has a reaction surface 124 provided at the center thereof in which an MEA is disposed, and multiple inlet manifolds 122 and multiple outlet manifolds 123 that are provided at opposite side of the reaction surface 124, respectively. In order to seal the reaction surface 124, the inlet manifolds 122, and the outlet manifolds 123, a gasket 40 is used to surround a region where the reaction surface 124, the inlet manifolds 122, and the outlet manifolds 123 are provided.
[0057] The positions of the reaction surface 114, the inlet manifolds 112, and the outlet manifolds 113 of the first separator 110 respectively correspond to the positions of the reaction surface 124, the inlet manifolds 122, and the outlet manifolds 123 of the second separator 120.
[0058] Further, a welding spot W where the first separator 110 and the second separator 120 are joined together is provided at a predetermined point in each of edge regions of the first separator 110 and the second separator 120. The first separator 110 and the second separator 120 are integrally joined together at the welding spots W.
[0059] Meanwhile, the first separator 110 has a first buffer portion 111 that is formed by depressing at least one point on the surface of the first separator so as to absorb deformation of the first separator 110 upon expansion and contraction due to thermal changes.
[0060] Further, the second separator 120 also has a second buffer portion 121 that is formed by depressing at least one point on the surface of the second separator so as to absorb deformation of the second separator 120 upon expansion and contraction due to thermal changes. As shown in
[0061] Therefore, when the first separator 110 and the second separator 120 are deformed in response to temperature changes, such deformation of the first and second separators 110 and 120 is absorbed by the first and second buffer portions 111 and 121.
[0062] The first and second separators 110 and 120 are configured such that positions of the welding spots W and the gaskets 40 are fixed. Due to this, when the first separator 110 and the second separator 120 are deformed in response to temperature changes, the first and second separators having different thermal expansion coefficients may differ from each other in amount of deformation in a region between the gasket 40 surrounding the inlet manifolds 112 and 122 and an inlet-side welding spot W and in a region between the gasket 140 surrounding the outlet manifolds 113 and 123 and am outlet-side welding spot W, and thus the separators may undergo undesired bending deformation. In order to prevent this, it is preferable that the first buffer portion 111 and the second buffer portion 121 are provided in a region between the inlet manifolds 112 and 122 and the inlet-side welding spot W and in a region between the outlet manifolds 113 and 123 and the outlet-side welding spot W, respectively.
[0063] Meanwhile, due to the fact that the first separator 110 and second separator 120 differ from each other in amount of deformation in response to temperature changes, the first buffer portion 111 and the second buffer portion 121 may be formed to have different sizes such that a difference in the amount of deformation is compensated.
[0064] For example, as shown in
[0065] Therefore, when the first separator 110 and the second separator 120 expand and contract in response to temperature changes, deformation of the first buffer portion 111 is allowed inside the second buffer portion 121. This makes it possible to prevent undesired bending deformation of the first separator 110 and the second separator 120.
[0066] In particular, it is preferable that the relationship between the width w1 of the first buffer portion 111 and the width w2 of the second buffer portion 121 satisfies the following Equation 1.
w2w1>x1x2 Equation 1
[0067] Herein, x1 denotes the amount of expansion of the first separator 110 in response to temperature, and x2 denotes the amount of expansion of the second separator 120 in response to temperature.
[0068] For example, when a difference in thermal expansion coefficient between the first separator 110 and the second separator 120 is 1.6 times, and when x1 within an operating temperature range of a fuel cell is 16 mm, x2 is 10 mm. Therefore, the width w2 of the second buffer portion 121 has to be at least equal to or greater than 6 mm larger than the width w1 of the first buffer portion 111 such that even when the first separator 110 and the second separator 120 are deformed in response to temperature changes, the first buffer portion 111 and the second buffer portion 121 can absorb such deformation without interfering with each other.
[0069] Meanwhile,
[0070] In this state, when a low temperature environment having a temperature lower than the room temperature is created, the first separator 110 and the second separator 120 contract. The first separator 110 having a relatively larger thermal expansion coefficient is larger in amount of contraction than the second separator 120. Therefore, even when the amount of contraction of the first buffer portion 111 contracted inward of the first separator 110 is larger than the amount of contraction of the second buffer portion 121 in the low temperature environment as shown in
[0071] Further, when a high temperature environment having a temperature higher than the room temperature is created, the first separator 110 and the second separator 120 expand. The first separator 110 having a relatively larger thermal expansion coefficient is larger in amount of expansion than the second separator 120. Therefore, even when the amount of expansion of the first buffer portion 111 expanded outward of the first separator 110 is larger than the amount expansion of the second buffer portion 121 in the high temperature environment as shown in
[0072] Meanwhile, the first buffer portion and the second buffer portion may be implemented in various shapes.
[0073] As shown in
[0074] Further,
[0075] Meanwhile,
[0076]
[0077] Further, similar to the first separator 310, the second separator 320 also includes a reaction surface 324, multiple inlet manifolds 322, and multiple outlet manifolds 323, and a gasket 40 is provided.
[0078] Further, a welding spot W where the first separator 310 and the second separator 320 are joined together is provided at a predetermined point in each of edge regions of the first separator 310 and the second separator 320. The first separator 310 and the second separator 320 are integrally joined together at the welding spots W.
[0079] In particular, the first separator 310 and the second separator 320 has an aspect ratio of 1:1.
[0080] The first separator 310 has a first buffer portion 311, and the second separator 320 has a second buffer portion 321. The first buffer portion 311 and the second buffer portion 312 may be provided at locations and shapes corresponding to the locations and shapes of the first buffer portion 111 and the second buffer portion 121 of the above-described embodiment.
[0081]
[0082] Further, similar to the first separator 410, the second separator 420 also includes a reaction surface 424, multiple inlet manifolds 422, and multiple outlet manifolds 423, and a gasket 40 is provided.
[0083] Further, a welding spot W where the first separator 410 and the second separator 420 are joined together is provided at a predetermined point in each of edge regions of the first separator 410 and the second separator 420. The first separator 410 and the second separator 420 are integrally joined together at the welding spots W. In consideration of the structure in that the inlet manifolds 412 and 422 and the outlet manifolds 413 and 423 are provided at four sides of the reaction surfaces 414 and 424, a welding spot W is provided at each side of the reaction surfaces 414 and 424.
[0084] The first separator 410 has a first buffer portion 411, and the second separator 420 has a second buffer portion 421. The first buffer portion 411 and the second buffer portion 421 are provided between the inlet manifolds 412 and 422 and the outlet manifolds 413 and 423, which are provided at four sides of the reaction surfaces 414 and 424, and the respective welding spots W. The first buffer portion 411 and the second buffer portion 421 may be formed in shapes corresponding to the shapes of the first buffer portion 111 and the second buffer portion 121 of the above-described embodiment, respectively.
[0085] Meanwhile,
[0086] Further, similar to the first separator 510, the second separator 520 also includes a reaction surface 524, multiple inlet manifolds 522, and multiple outlet manifolds 523, and a gasket 40 is provided.
[0087] Further, a welding spot W where the first separator 510 and the second separator 520 are joined together is provided at a predetermined point in each of edge regions of the first separator 510 and the second separator 520. The first separator 510 and the second separator 520 are integrally joined together at the welding spots W.
[0088] The first separator 510 has a first buffer portion 511, and the second separator 520 has a second buffer portion 521.
[0089] However, in this embodiment, the first buffer portion 511 and the second buffer portion 521 are provided in a line shape. It is preferable that the first buffer portion 511 and the second buffer portion 521 have widths and depths corresponding to the widths and depths of the above-described embodiments.
[0090] Meanwhile, the first buffer portion 511 and the second buffer portion 521 provided in a line shape are provided between the multiple inlet manifolds 512 and 522 and an inlet-side welding spot W and between the multiple manifolds 513 and 523 and an outlet-side welding spot W, respectively.
[0091] Meanwhile, in the present disclosure, the thicknesses of the first and second separators according to various embodiments are the same. However, the present disclosure is not limited thereto, and the thicknesses of the first and second separators may be different from each other. In this case, the first separator has to be larger in amount of thermal deformation than the second separator.
[0092] Although the exemplary embodiments of the present disclosure have been described for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the disclosure as disclosed in the accompanying claims.