Devices and methods for measuring light

Abstract

The invention features devices and methods for collecting and measuring light from external light sources. In general, the devices of the invention feature a light diffusing element, e.g., as a component of a light collector, connected by a light conducting conduit, e.g., a fiber optic cable, to a light measuring device, e.g., a spectrometer. This light diffusing element allows, e.g., for substantially uniform light diffusion across its surface and thus accurate measurements, while permitting the total footprint of the device to remain relatively small and portable. This light diffusing element also allows flexibility in scaling of the device to permit use in a wide range of applications.

Claims

1. A device comprising a light diffusing element comprising an element comprising a top portion, a bottom portion, and a side portion, wherein the top portion comprises an aperture, the bottom portion comprises an inner surface that is substantially hemispherical, and the side portion comprises an inner surface that is substantially cylindrical, and wherein the side portion is connected to the top portion and the bottom portion.

2. The device of claim 1, further comprising an outlet port in the side portion, wherein the outlet port is substantially parallel to the top portion and is adjacent to the bottom portion.

3. The device of claim 1, further comprising a light measuring component.

4. The device of claim 1, further comprising an external shell housing the light diffusing element.

5. The device of claim 1, wherein the light diffusing element allows for substantially uniform light diffusion across the inner surfaces.

6. The device of claim 1, wherein the inner surfaces comprise polytetrafluoroethylene, barium sulfate, or polyoxymethylene.

7. The device of claim 1, wherein the top portion further comprises an aperture having a diameter substantially equivalent to or smaller than the diameter of the substantially cylindrical inner surface of the side portion.

8. The device of claim 1, further comprising a screen covering the aperture.

9. The device of claim 8, wherein the screen comprises polytetrafluoroethylene, barium sulfate, or polyoxymethylene.

10. The device of claim 8, wherein the screen comprises a transparent or translucent material.

11. The device of claim 8, wherein the screen is coated with a translucent Lambertian coating.

12. The device of claim 1, wherein the height of the substantially cylindrical inner surface of the side portion is between 1 mm and 50 mm.

13. A method for measuring light, comprising directing light generated by a light source into the light diffusing element of the device of claim 1, wherein a. light entering the light diffusing element diffuses within the light diffusing element; b. a portion of the light diffused within the light diffusing element exits the light diffusing element is detected by a light measuring component.

14. The method of claim 13, wherein the light measuring component measures visible light, infrared light, or UV light.

15. The method of claim 13, wherein the light source is a dental light curing unit.

16. The method of claim 13, wherein the light measuring component determines power, irradiance, or maximum exposure time.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a schematic diagram of a light collector.

(2) FIG. 2A is a schematic diagram of the front view of a light collector. Units are in millimeters.

(3) FIG. 2B is a schematic diagram of the top view of a light collector. Units are in millimeters.

(4) FIG. 2C is a schematic diagram of the cross-sectional view of a light collector showing the light diffusing element. Units are in millimeters. In some embodiments, the connection point of the light conducting conduit does not scale with the other dimensions of the light collector if made bigger.

(5) FIG. 3 is a schematic diagram of a light collector, light conducting conduit, and spectrometer. Also depicted are an aperture screen, an optional filter, and a USB cable capable of connecting, e.g., to a laptop.

(6) FIG. 4 is a schematic diagram of a connecting element. Units are in millimeters.

(7) FIG. 5A is a schematic diagram of a top view of the top portion of a light diffusing element.

(8) FIG. 5B is a schematic diagram of a side view of the top portion of a light diffusing element.

(9) FIGS. 6A-C are schematic diagrams of a spectrometer, including a high density USB port, an SMA connector, and a fiber optic stub.

(10) FIGS. 7A, 7B, and 7C are schematic diagrams of front, top, and side views, respectively, of a spectrometer connected to a light collector via a light conducting conduit. Units are in millimeters.

(11) FIG. 8 is a schematic diagram depicting a side view, of the external housing and its interior with a light collector and spectrometer installed.

(12) FIG. 9 is a graph showing a comparison of power and power variation between three different light collecting devices, measured using a STS spectrometer.

(13) FIG. 10 is a graph showing transmission spectra of interference (TS600, TS575, TS500, and D1) and color (BG1 & BG12) filters measured by an Ocean Optics USB4000 spectrometer through an Ocean Optics FOIS-1 Fiber Optic Integrating Sphere.

(14) FIG. 11 is a set of graphs displaying data of weighted blue light irradiance as a function of distance from a LCU for the palatal and facial geometries. The graph on the right displays least-square fitted lines of the data.

(15) FIG. 12 is a graph showing the weighted power for all shields and using QTH, PAC, or LED light curing units as light sources.

(16) FIG. 13 is a graph showing the blue light hazard function for retinal photochemical damage at different wavelengths of light.

(17) FIGS. 14A-D are a set of graphs showing spectral radiation flux of four different light sources of different powers (Light 1, Light 2, Light 3, and Light 4, respectively) measured using a light collector (device of the invention) or an integrating sphere (Labsphere, Inc., 6 in.). Two different spectrometers were used as indicated (USBUSB4000 and STSSTS vis, both from Ocean Optics).

(18) FIG. 15A-15C are a set of schematic diagrams of a spectrometer. Units are in millimeters.

(19) FIG. 16A is a schematic diagram of side view of a fully assembled device of the invention showing the relative position of the various parts of the device. Units are in inches.

(20) FIG. 16B is a schematic diagram of top view of a fully assembled device of the invention showing the relative position of the various parts of the device. Units are in inches.

(21) FIGS. 17A-17L are schematic diagrams of a device of the invention including a light diffusing element housed in an external housing without an external shell. FIG. 17A shows various views of the external housing. FIG. 17B shows various cross-sectional and exploded views of the external housing, light diffusing element, and light measuring component. FIG. 17C shows a cross-sectional view of the fastening of the top and bottom of the external housing (not to scale). FIG. 17D shows the light diffusing element, light conducting conduit, and light measuring component placed in the bottom of the external housing. FIG. 17E shows various views of the bottom of the external housing. FIG. 17F shows various views of the top of the external housing. FIG. 17G shows various views of a rubber gasket for moisture protection around a USB port. FIG. 17H shows various views of a spacer that provides an optional distance aid between the light diffusing element and the light conducting conduit. FIG. 17I shows various views of the light diffusing element. FIG. 17J shows various views of the light conducting conduit. FIG. 17K shows various views of an exemplary light measuring component. FIG. 17L shows various views of the screen. Units are in millimeters.

DETAILED DESCRIPTION

(22) The invention features devices and methods for collecting and measuring light from external light sources. In general, the devices of the invention feature a light diffusing element, e.g., as part of a light collector, connected by a light conducting conduit, e.g., a fiber optic cable, to a light measuring component, e.g., a spectrometer. The light diffusing element allows for substantially uniform light diffusion across its surface and accurate measurements, while permitting the total footprint of the device to remain relatively small and portable. The light diffusing element also allows flexibility in scaling of the device to permit use in a wide range of applications.

(23) The devices of the invention may be employed in different configurations. In the simplest configuration, the device includes a light diffusing element that includes top portion (3) that includes screen (5) and an optional aperture (4); bottom portion (6), which includes bottom portion inner surface (7) that is substantially hemispherical; and side portion (8), which includes side portion inner surface (9) that is substantially cylindrical. Side portion (8) further includes outlet port (10). The light diffusing element may or may not be enclosed within an external shell (2) to form a light collector. An exemplary light diffusing element in a light collector is shown in FIGS. 1 and 2A-2C.

(24) Referring to FIG. 1, the diameter of aperture (4), dimension (A), may be equivalent to or smaller than the diameter of bottom portion inner surface (7), distance (B). Dimensions (A) and/or (B) may vary, e.g., between 4 mm and 500 mm, e.g., between 10 mm and 15 mm, between 8 mm and 30 mm, between 4 mm and 30 mm, between 20 mm and 25 mm, or between 30 mm and 300 mm. In some embodiments, dimensions (A) and/or (B) are about 15 mm. In some embodiments, dimensions (A) and/or (B) are, e.g., 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 35, 40, 45, 50, 60, 70, 80, 90, 100, 110, 120, 130, 140, 150, 160, 170, 180, 190, 200, 210, 220, 230, 240, 250, 260, 270, 280, 290, or 300 mm, or may be between any two of these values. In some embodiments, dimension A is, e.g., 100%, 95%, 90%, 85%, 80%, 75%, 70%, 65%, 60%, 55%, 50%, or less than 50% of dimension B.

(25) The distance between a plane tangent to the base of bottom portion inner surface (7) and the bottom of outlet port (10), dimension (C), may be about half of dimension (B), or 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, or 70% of dimension (B), or may be between any two of these values. The distance between bottom portion inner surface (7) and the internal wall of external shell (2), and/or the distance between side portion inner surface (9) and the internal wall of external shell (2), dimension (D), may vary in accordance with the material and application of the device. In some embodiments, dimension (D) is sufficient to prevent light from penetrating through light diffusing element (1) and interacting with the internal surface of external shell (2), e.g., by the thickness of the material used to manufacture the side and bottom portions. Dimension (D) may be between 1 mm and 100 mm, e.g., 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, or 100 mm, or may be between any two of these values. In some embodiments, dimension (D) is about 3 mm or greater. The distance from the bottom of screen (5) to the top of outlet port (10), dimension (Y), may be between 1 mm and 100 mm, e.g., 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, or 100 mm, or may be between any two of these values. In some embodiments, dimension (Y) may be between 10% and 300% of dimension (C), e.g., 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, 100%, 110%, 120%, 130%, 140%, 150%, 160%, 170%, 180%, 190%, 200%, 225%, 250%, 275%, or 300% of C, or may be between any two of these values. In some embodiments, dimension (Y) is about 50%, 100%, or 200% of dimension (C).

(26) The geometrical configuration of light diffusing element (1) permits accurate measurement and collection of light independent of the angle at which the light enters the element and/or device.

(27) The side, bottom, and top portions may be manufactured from any suitable material, e.g., polytetrafluoroethylene (e.g., Teflon@ or Spectralon from Labsphere Inc.), polyoxymethylene (e.g., Delrin), barium sulfate (e.g., 6080 White Reflectance Coating from Labsphere Inc.) or other Lambertian coating (e.g., Spectraflect or Duraflect from Labsphere Inc.). These portions may also include other materials, e.g., plastic, ceramic, glass, or metal, on which Lambertian materials are layered or coated. When the top portion includes an aperture, the portions of the top not including the screen may be made from any material suitable to hold the screen, e.g., plastic, ceramic, glass, or metal.

(28) The exterior shape of optional external shell (2) may be substantially cubical, cylindrical, pyramidal, or a rectangular solid. The internal surface and cavity shape of external shell (2) may vary according to the external shape of the light diffusing element, e.g., it may conform to the exterior shape.

(29) In the descriptions that follow, in some instances, numbered elements not shown in a referenced figure are shown in one or more preceding figures.

(30) Referring to FIGS. 2A-2C, a front view, a top view, and a cross-sectional view, showing the light diffusing element and external shell in the light collector are shown. This shell may include external shell inner surface (21), external shell outer surface (22), and cavity (23) to fit a connection element. External shell (2) may be made of any solid material, e.g., plastic, ceramic, glass, or metal. Outlet port (10) passes through both the external surface of the light diffusing element and side portion inner surface (9) of the light diffusing chamber defined by bottom portion inner surface (7) and side portion inner surface (9). Outlet port (10) may be located adjacent to cavity (23) of external shell (2) so as to create a channel from the inner surface of the light diffusing chamber to the outer surface of the external shell.

(31) In other embodiments, the light diffusing element is connected to a light measuring device by a light conducting conduit. This device may or may not be enclosed in an external housing (34). The device may also include connectors to external processors or computers as are known in the art, e.g., USB and Ethernet. Alternatively, the device may include hardware for wireless transmission of data. The device may also include a processor or computer within it to analyze data and/or provide an indicator. When an external housing is employed, the light diffusing element may or may not be enclosed in an external shell (2).

(32) Referring to FIG. 3, light collector (31), which includes light diffusing element (1) enclosed in external shell (2), is connected to light measuring element (32), e.g., a spectrometer, via light conducting conduit (33). At the top of light collector (31) are screen (5) and optional filter (35). USB cable (36) optionally connects spectrometer (32) to an external computer, e.g., a laptop.

(33) The surface of screen (5), e.g., the material of the surface or a coating applied to the surface, is white, translucent, and Lambertian, e.g., made from or coated with polytetrafluoroethylene (e.g., Teflon@ or SpectraIon from Labsphere Inc.), polyoxymethylene (e.g., Delrin), barium sulfate (e.g., 6080 White Reflectance Coating from Labsphere Inc.) or other Lambertian coating (e.g., Spectraflect or Duraflect from Labsphere Inc.). Screen (5) is located above the side and bottom portions of light diffusing element (1) of light collector (31). When the top includes an aperture (4), the screen may be sized to cover at least aperture (4) of light diffusing element (1). The length of screen (5) may be equal to or greater than the diameter of the substantially hemispherical bottom portion. In some embodiments, the device may include a filter, e.g., glass (such as alkali-aluminosilicate sheet toughened glass (Gorilla glass)), neutral density filter, blue band filter, or a filter that filters wavelengths of at least 500 nm. Filter (35) may be located in the top portion of light diffusing element (1) above or below aperture screen (5). In certain embodiments, the filter acts as a physical barrier to protect the screen from damage. When an aperture (4) is present in the top portion, it may include one or more tiered recesses into which the screen (5) and any filter (35) rest. The tiered recesses provide physical support for the perimeter of the screen and filter. Alternative ways of attaching a screen and/or filter are known. For example, the screen may be part of a component that screws or clamps to the side and bottom portions. The screen may also be a sheet of material that is compressed against the side portion, e.g., by an external housing as shown in FIGS. 17A-17L.

(34) Referring to FIGS. 5A and 5B, FIG. 5A is a top view of top portion (3) of light diffusing element (1), and FIG. 5B is a side view of top portion (3) of light diffusing element (1). Top portion (3) includes graduated diameters and/or widths, with the base being the largest in diameter and/or width and the top level being the smallest in diameter. In certain embodiments, screen (5) and/or filter (35) are attached, e.g., affixed or screwed, to top portion (3) of light diffusing element (1). If filter (35) is used, it may be attached above or below screen (5) in top portion (3). The top portion may be attached to the rest of the device, e.g., via threads (e.g., as shown in FIGS. 5A and 5B).

(35) Light conducting conduit (33) may be, e.g., a fiber optic cable or liquid light conduit. Light conducting conduit (33) may be attached to light diffusing element (1) and/or external shell (2) so that light conducting conduit (33) is disposed substantially parallel to screen (5) or aperture (4) while the opening of light conducting conduit (33) is substantially perpendicular to screen (5) or aperture (4). Light conducting conduit (33) may be between 1 mm and 500 mm in length, e.g., 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 25, 30, 35, 40, 45, 50, 75, 100, 125, 150, 175, 200, 250, 300, 350, 400, 450, or 500 mm, or may be between any two of these values. The inner diameter of light conducting conduit (33) may be between, 50 m and 10,000 m, e.g., 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 125, 150, 200, 250, 500, 1,000, 2,000, 3000, 4,000, 5,000, 6,000, 7,000, 8,000, 9,000, or 10,000 m, or may be between any two of these values. The inner diameter of light conducting conduit (33) may be selected to optimize the acceptance angle for a given application and materials. Referring to FIG. 4, the acceptance angle, .sub.max, for a fiber optic cable, e.g., a step-index multimode fiber, is calculated by the indices of refraction as follows:
NA=n sin .sub.max={square root over (n.sub.f.sup.2n.sub.c.sup.2)}
Where n is the refractive index of the medium light is traveling before entering the fiber; n.sub.f is the refractive index of the fiber core; and n.sub.c is the refractive index of the cladding.

(36) Referring to FIG. 4, side views of a connection element, e.g., an SMA connection element, are shown. The external diameter of the connection element may be substantially equivalent to the diameter of outlet port (10) of light diffusing element (1). In some embodiments, the external diameter of the connection element and the diameter of outlet port (10) are within 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, or 10% of one another. The connection element may be made out of any solid material, e.g., plastic, ceramic, glass, or metal.

(37) The light measuring element may be any device capable of analyzing the spectral components and/or intensity of light and encoding the information in an electronic signal, e.g., a spectrometer, a light meter, a photometer, a photodiode, a photomultiplier tube, a CCD array, a CMOS sensor, or a photovoltaic device. Spectral information may be obtained by using of appropriate filters or a diffracting or refracting element such as a grating or prism. Referring to FIGS. 6A-6C, devices of the invention may employ spectrometer (32) having slit ranges, e.g., between 1 m and 1,500 m, e.g., between 10 m and 1,000 m, between 100 m and 500 m, between 300 m and 400 m, and between 360 nm and 540 nm, e.g., 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 150, 200, 250, 300, 350, 400, 500, 600, 700, 800, 900, or 1,000 m, or between any two of these values. Spectrometer (32) may be capable of measuring UV light, visible light, and/or infrared light. FIGS. 6B and 6C include a connector, e.g., an SMA connector, so as to facilitate connection between spectrometer (32) and light conducting conduit (33). Any connector that facilitates this connection may be used. In some embodiments of the invention, spectrometer (32) may be replaced with any light measuring component. Exemplary spectrometers are described herein, e.g., as shown in FIGS. 15A-15C.

(38) FIGS. 7A-7C show a light collector connected to a spectrometer, which may be placed in external housing (34). In these embodiments, a window (37) is aligned over aperture (4) and/or screen (5) of light collector (31) so as to permit light to pass through external housing (34) directly into light diffusing element (1). FIG. 8 schematically shows an exemplary assembled device.

(39) In certain embodiments, external housing (34) may also include a port (38) in proximity to spectrometer (32) so as to allow an external processor, e.g., a computer such as a laptop computer, to connect with spectrometer (32). In these embodiments, a cable, e.g., USB cable (36), may pass through external housing (34). In still other embodiments, spectrometer (32) and/or the assembled device may further include a processor and/or display capable of and/or programmed to analyze and display the data obtained by spectrometer (32) and/or light measuring component and/or an indicator related to this data. This internal processor and/or display may generate an indicator and/or store the data.

(40) An exemplary device is shown in FIGS. 17A-17L. In this device, the light diffusing element is enclosed in an external housing without an external shell (FIGS. 17A, B, and D). The light diffusing element (FIG. 17I) is connected to a light conducting conduit (FIG. 17J) which is also connected to a light measuring component, a spectrometer as depicted (FIG. 17K). The light conducting conduit includes SMA connectors. As shown in section G of FIG. 17B and section D-D of FIG. 17F, the external housing has tiered recesses around the window to accommodate a filter (35), e.g., protective glass, and the screen (5). FIG. 21G shows a gasket that can be used to seal around a data port, e.g., mini USB, to seal the external housing from moisture. FIG. 21H shows a spacer used to ensure that the light conducting conduit is inserted into the light diffusing element at the correct depth.

(41) Calibration and Methods of Use

(42) The devices of the invention may be calibrated before use. This calibration may include transmitting a light beam (e.g., visible light, or infrared light, or UV light) from a calibrated lamp, e.g., a NIST certified lamp, into light diffusing element (1). The light source can be one that is capable of curing dental resin. A portion of this light is transmitted along light conducting conduit (33) into the light measuring component, e.g., spectrometer (32), that measure properties of the light and may then generate an indicator, and/or an additional communication step may occur where the data is communicated to an external processor (e.g., a computer) for analysis and/or indicator display. This indicator may be power, irradiance, or maximum exposure time. This indicator value is then compared against the anticipated indicator value for the calibrated light source. A correction factor may then be applied to the software and/or programming within the processor to generate an accurate light measurement. Alternatively, the value obtained by the devices of the invention may be compared to those obtained by an integrating sphere, and a correction factor applied accordingly.

(43) In some embodiments, the devices of the invention may be used to test the properties, e.g., transmitted spectral power, transmitted light power, transmitted light intensity, and/or maximum safe exposure time, of light through a light blocking material (e.g., a shield or pair of glasses that protect against ocular damage from light generated by dental resin curing tools). Specifically, this light may be generated from a LCU. Filters, e.g., blue filters, neutral density, or short wave length, may optionally be used as appropriate to the light source. The safety material, e.g., safety glasses and/or shields, can be placed over the light diffusing element. The light may then be directed through the material into the light diffusing element for a duration and/or from a distance representative of the normal use of the light source. Other parameters may be used as required by the application, and, as discussed above, the device may be calibrated to each set of parameters if required. The light then diffuses within the light diffusing chamber, and a portion of the light exits the chamber through the port and is transmitted along the light conducting conduit to a light measuring component, where properties of the light are measured. This device then may analyze the data and render the required indicator and/or the data from measuring the properties of the light are communicated to an external processor for analysis and/or indicator display. This method is further discussed below in Example 1.

(44) In still other embodiments, the devices of the invention may be used with other light generating sources and methods, e.g., those described in U.S. Pub. Nos. 2012-0171745, 2012-0172478, and 2012-0196122, each of which is hereby incorporated by reference in its entirety.

EXAMPLES

(45) The following examples are intended to illustrate the invention. They are not meant to limit the invention in any way.

Example 1

(46) Background: Improperly polymerized dental resin materials have reduced mechanical, hardness, and structural integrity, which lead to reduced longevity, high replacement costs, and potential exposure to toxic unpolymerized materials. For instance, the average life of resin-based fillings is six years. A key aspect of light curing is that the dentist must watch at all times the restoration of the tooth. A high power 1 Watt) LCU cures the resin. Because the greatest ocular hazard to blue-light occurs at approximately 440 nm (which is close to the peak wavelength of many light emitting diode curing lights), the dentist must wear blueblocking glasses or shields to protect both his or her own eyes and the patient's eyes from the blue light and prevent retinal damage. The maximum daily exposure from a high power curing unit with an output of 1.56 W/cm.sup.2 is only about 6 seconds when the dentist's eyes are 30 cm away from tooth.

(47) Dental resin materials generally consist of light sensitive monomers that polymerize when properly initiated by light in a narrow range of the visible blue spectrum. Most lights units emit intense blue light in the 400-500 nm wavelength range with radiant power that can be in excess of 1 Watt. However, the spectral emissions are different between brands of LCUs, with some also emitting in the ultraviolet-A (UVA) range (320-400 nm). The ISO 10650-1 standard for halogen curing lights limits the irradiance in the 190 nm to 385 nm region to no more than 200 mW/cm.sup.2, but there is no upper irradiance limit in the 400 to 500 nm range, and some units can deliver in excess of 10 W/cm.sup.2, which can result in adverse health effects, especially ocular damage.

(48) FIG. 13 shows the blue light hazard function for retinal photochemical damage (American Conference of Government Industrial Hygienists; TLVs and BEIs based on the Documentation of the Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices; 2008, pp 146-154). The function is greater than 0.1 in the spectral range from 400 nm to 500 nm. The greatest ocular hazard to blue-light occurs at approximately 440 nm (which is close to the peak wavelength of many light emitting diode curing lights). Blue light transmits through the ocular media and is absorbed by the retina; at chronic low levels of exposure, the blue light amplifies retinal aging and degeneration by causing photochemical injury to the retinal-pigmented epithelium and choroid. Clinical manifestations of retinal damage include acute photoretinitis or, in severe cases, premature age-related macular degeneration.

(49) Experimental Methods:

(50) A device of the invention, as shown in FIGS. 2A-2C and FIGS. 16A-16B, was tested. This device included a light collector connected to a spectrometer and encased within an external housing. The spectrometer used was an STS-VIS spectrometer that is optimized in the visible region with a slit width of 200 m and a fiberoptic cable with a core diameter of 400 m and a length of 10 cm. Protective eyewear/shields were placed over the window of the external housing. An LCU, in particular a dental curing wand, was held approximately 30 cm away from the protective eyewear/shield. The inner surfaces of the light diffusing element were made of polytetrafluoroethylene (Teflon).

(51) LabVIEW was used as an exemplary programming language to collect the spectra measured by the device and to calculate the maximum exposure time. Inputs for data collection and analysis include integration time, LCU type (PAC, QTH, or LED) and distance between the operator and the tooth. A dark spectrum was measured first with the LCU off, and then the transmitted spectrum with the LCU on was measured. The raw and blue-weighted spectra were used to verify that the data collection has been carried out correctly and to provide a visual guide on the signal to noise ratio in the spectra.

(52) Results:

(53) FIG. 9 displays a comparison between different light collecting devices that were measured using a STS spectrometer. The radiant source was an LED based Allegro light curing unit. Both the Cosine Corrector (Ocean Optics) and the Light Collector of the present invention had a 1 mm thick polytetrafluoroethylene (Teflon) piece covering their apertures. The Integrating Sphere refers to the Ocean Optics FOIS-1 Fiber Optic Integrating Sphere (Ocean Optics, 3 in.). An ideal device has the highest power and smallest power variation across LCU position from aperture center, as well as lowest cost. The smallest power variation was key for this application.

(54) During testing, it was noted that when an LCU was shining through blue blocker glasses or shields, fluorescence with wavelengths greater than 500 nm was emitted from the glasses or shields. This fluorescence entered and scattered within the spectrometer, resulting in a spurious signal in the spectral range below 500 nm. This spurious signal interfered with the weakly transmitted blue light. A blue band pass filter was necessary to attenuate the fluorescence.

(55) FIG. 10 depicts transmission spectra of interference (TS600, TS575, TS500, and D1) and color (BG1 & BG12) filters measured by an Ocean Optics USB4000 spectrometer through an Ocean Optics FOIS-1 Fiber Optic Integrating Sphere (Ocean Optics, 3 in.). The reference light source is an incandescent light bulb (60 W; 120V). The ideal filter allows 100% of the light within the blue region and 0% within the yellow region. In the present Example, the results indicate that the color BG1 filter is optimal for this application.

(56) FIG. 11 displays data of weighted blue light irradiance as a function of distance from an LCU for the palatal and facial geometries. The data were obtained from the literature (Evaluation of ocular hazards from 4 types of curing lights, Labrie D, Moe J, Price R B, Young M E, Felix C M. J. Can. Dent. Assoc. 2011; 77:b116) under typical clinical conditions. These data were used to evaluate the total weighted power as a function of distance for the two geometries. As shown in FIG. 11 (right), the data were least-square fitted by straight lines. The equations are shown below:
WI=WP.Math.c.Math.d.sup.B,
and C=10.sup.A.

(57) WI is the weighted irradiance in units of W/cm.sup.2, WP is the weighted power in units of W calculated from the spectral radiant power transmitted through the glasses and shields and measured by the prototype device, d is the distance between the eyes and the LCU in units of cm, and A and B are two parameters given in Table 1.

(58) TABLE-US-00001 TABLE 1 Palatal Facial Constant LED QTH PAC LED QTH PAC A 0.53602 0.77749 0.48787 1.30516 1.34564 1.3718 B 1.78566 1.80626 2.0141 1.858965 1.9413 1.78902
The maximum acceptable exposure time, t.sub.max, may be determined as follows:

(59) $t_{\max }=\frac{E_{\mathrm{limit}}}{\mathrm{WI}}$
where E.sub.limit is equal to 10000 J/cm.sup.2.
Evaluation of the Effectiveness of Blueblocker Protective Glasses/Shields Against Ocular Light Induced Hazards

(60) Table 2 shows a list of seven shields and eight blue-blocker glasses together with two glasses (A1 and A2) used in the glass blowing industry.

(61) TABLE-US-00002 TABLE 2 ABBREVIATION MODEL NAME LENS MFG# MANUFACTURER S1 Pinnacle Vision Saver 4575 TotalCare Corporation.sup.1 S2 Round Orange Blockers Inc. w/ Kerr Kerr Corporation.sup.1 Sybron Command S3 Cure-Shield 9006166 Premier Dental Products.sup.2 S4 Shield VLC Angulate 089-4550 Patterson Dental Supply.sup.3 S5 Swiss Master Light DT-072 EMS.sup.4 S6 Protective light shield 20816 Kerr Corporation.sup.1 S7 Orange Shields (Large) 5600011 Patterson Dental Supply.sup.3 G1 Light protection DZ-011 EMS.sup.4 goggles G2 Genesis XC?.sup.7 Orange (2-1.7 U 1 ?.sup.7 Ultraden/uvex?.sup.7 FT K N CE/3111) G3 Filter Argon/KTP- 60 (Orange) ?.sup.7 NoIR.sup.5 EN207 G4 Ultra-spec 1000(140 mm Orange ?.sup.7 Uvex.sup.6 Z87) G5 super fit PC amber/UV 2- 9178.385 Uvex.sup.6 1.2 G6 Ultra-spec 2000 (130-150 mm SCT-Orange S0360X Uvex.sup.6 Z87.1) G7 skyper SCT-Orange S1933X Uvex.sup.6 G8 Style #21 - Large Flip- #60 #21 #60 NoIR.sup.5 up Clip-ons A1 Astrospec OTG 3001 Shade 3.0 Infradura S2508 Uvex.sup.6 A2 Astrospec OTG 3001 Shade 5.0 Infradura S2509 Uvex.sup.6 .sup.11717 West Collins, Orange, CA 92867 (totalcareprotects.com/kerrdental.com) .sup.21710 Romano Drive, Plymouth Meeting, PA 19462, U.S.A. (premusa.com) .sup.31205 Henri Bourassa Blvd., W. Montreal, Quebec, Canada, H3M 3E6 (pattersondental.ca) .sup.4Ch. de la Vuarpillire 31, 1260 Nyon, Switzerland (ems-company.com) .sup.56155 Pontiac Trail, South Lyon, MI 48178 (noir-medical.com/noirlaser.com) .sup.6UVEX ARBEITSSCHUTZ GmbH, Wrzburger Str. 181-189, 90766 Frth (uvex.com) .sup.7The question marks indicate insufficient information was available to fully describe the glasses/shields.

(62) FIG. 12 illustrates the weighted power for all shields and glasses (Table 2) tested in this Example, with QTH, PAC, and LED light curing units as light sources. The highest weighted power of 5 mW was collected using a PAC LCU and S1 shield, while the lowest power of 0.2 W was collected using a LED LCU and S6 shield. These measurements provide evidence of the dynamic range and sensitivity available with the device.

(63) Conclusion:

(64) The device and methods tested and described in the present Example were highly effective in functioning as a means to evaluate the effectiveness of protective eyewear/shields using the light curing units found in dental clinics.

Example 2

(65) Experimental Objective:

(66) To demonstrate that a device of the invention (light collector) accurately measures spectral radiant flux, of four different light sources, as compared to a commercially available integrating sphere (Labsphere Inc., 6 in.).

(67) Experimental Method:

(68) Equal amounts of light from four different light sources were introduced into either a device of the invention (as shown in FIGS. 2A-2C and FIGS. 7A-7C) or an integrating sphere (Labsphere Inc., 6 in.). Spectral radiance flux across 360 nm-540 nm wavelengths was measured and recorded for each light source.

(69) Results:

(70) The device of the invention collected and measured data accurately, from each light source, as compared to a commercially available integrating sphere (Labsphere Inc., 6 in.). Data for total spectral radiant flux measurements from each of the light sources, using the device of the invention or the integrating sphere (Labsphere Inc., 6 in.) are provided in Table 3 and in FIGS. 14A-14D.

(71) TABLE-US-00003 TABLE 3 Total Spectral Radiant Flux Measurement Light 1 Light 2 Light 3 Light 4 Device Spectrometer (mW) (mW) (mW) (mW) Integrating Sphere USB4000 287 740 1189 699 (IS) Integrating Sphere STS 288 731 1204 689 (IS) Light Collector (LC) USB4000 291 734 1210 694 Light Collector (LC) STS 298 739 1238 714 Mean 291 736 1210 699 S.D 5 4 21 11 Variance (%) 1.7% 0.6% 1.7% 1.5% Light 1: Smartlite IQ (Denstply Caulk); Light 2: Elipar S10 (3M ESPE); Light 3: D1 (DXM); Light 4: Bluephase Style (Ivoclar Vivadent)

(72) Conclusion:

(73) The device of the invention accurately measured spectral radiant flux, and these measurements are comparable to those made by a commercially available integrating sphere (Labsphere Inc., 6 in.).

(74) All publications and patents cited in this specification are incorporated herein by reference as if each individual publication or patent were specifically and individually indicated to be incorporated by reference. Although the foregoing invention has been described in some detail by way of illustration and example for purposes of clarity of understanding, it will be readily apparent to those of ordinary skill in the art in light of the teachings of this invention that certain changes and modifications may be made thereto without departing from the spirit or scope of the appended claims.