Volatile composition dispenser
11554192 · 2023-01-17
Assignee
Inventors
- Kumaresh Govindan Radhakrishnan (Singapore, SG)
- Rahul Vyas (Singapore, SG)
- Thinh Nguyen Ha (Cincinnati, OH, US)
- Stefano Deflorian (Trento, IT)
Cpc classification
International classification
Abstract
A volatile composition dispenser including a container having a bottom wall and side walls extending circumferentially around the bottom wall to define a reservoir and a perfume composition contained in the container. The side walls have a circumferential inner edge defining a reservoir opening. A reservoir opening plane extends across the reservoir opening and intersects the circumferential inner edge. There is a first depth and a second depth between the bottom wall and the reservoir opening plane, wherein D1 is longer than D2.
Claims
1. A volatile composition dispenser comprising: (a) a container having a bottom wall and side walls extending circumferentially around the bottom wall to define a reservoir, wherein the side walls have a circumferential inner edge defining a reservoir opening; (b) a reservoir opening plane extending across the reservoir opening and intersecting the circumferential inner edge; (c) a perfume composition contained in the reservoir; (d) a headspace between the reservoir opening plane and the contained perfume composition; (e) a vapor impermeable substrate attached to the dispenser across the reservoir opening plane; (f) a center longitudinal axis (Yc) of the reservoir opening plane, wherein the center longitudinal axis (Yc) extends along a length (L) of the reservoir opening plane between first and second circumferential inner edges and extending through a centroid of the reservoir opening plane; (g) wherein a first depth (D1) and a second depth (D2) between the bottom wall and the reservoir opening plane is measured orthogonal to the center longitudinal axis, wherein the first depth (D1) is measured ⅕ of the length (L), and the second depth (D2) is measured ⅘ of the length (L), wherein the first depth (D1) is longer than the second depth (D2).
2. The dispenser according to claim 1, wherein a third depth (D3) between the bottom wall and the reservoir opening plane is measured orthogonal to the center longitudinal axis (Yc) and ⅗ of the length (L) such that the third depth (D3) is less than the first depth (D1) and greater than the second depth (D2) to define a sloped profile of the bottom wall.
3. The dispenser according to claim 1, wherein a third depth (D3) between the bottom wall and the reservoir opening plane is measured orthogonal to the center longitudinal axis (Yc) and ⅗ of the length (L) such that the third depth (D3) is greater than the second depth (D2).
4. The dispenser according to claim 1, further comprising: (h) a center latitudinal axis X extending along a width of the reservoir opening plane between opposing circumferential inner edges and through the centroid, C forming a 90-degree angle with the center longitudinal axis; (i) a left longitudinal axis parallel to the center longitudinal axis between opposing circumferential inner edges, wherein the left longitudinal axis is located ⅖ of the width of the center latitudinal axis X from a third circumferential inner edge; (j) wherein a fourth depth between the bottom wall and the reservoir opening plane is measured orthogonal to the left longitudinal axis and ⅕ of the length of the left longitudinal axis from the first circumferential inner edge, and a fifth depth between the bottom wall and the reservoir opening plane is measured orthogonal to the left longitudinal axis and ⅘ of the length of the left longitudinal axis from the first circumferential inner edge, wherein D4 is longer than D5.
5. The dispenser (1) according to claim 1, further comprising: (h) a center latitudinal axis X extending along a width of the reservoir opening plane between opposing circumferential inner edges and through the centroid, C forming a 90-degree angle with the center longitudinal axis; (i) a right longitudinal axis parallel to the center longitudinal axis between opposing circumferential inner edges, wherein the right longitudinal axis is located ⅖ of the width from a fourth inner circumferential edge; (j) wherein a sixth depth between the bottom wall and the reservoir opening plane is measured orthogonal to the right longitudinal axis and ⅕ of the length of the right longitudinal axis from the first circumferential inner edge, and a seventh depth between the bottom wall and the reservoir opening plane is measured orthogonal to the right longitudinal axis and ⅘ of the length of the right longitudinal axis from the first circumferential inner edge, wherein D6 is longer than D7.
6. The dispenser according to claim 1, wherein the perfume composition comprises a total perfume fill volume (V.sub.FILL) of 75%, of a total internal reservoir volume of the reservoir (V.sub.r), wherein the headspace comprises a headspace volume of at least 25%, of the total internal reservoir volume (V.sub.r).
7. The dispenser according to claim 6, wherein the surface area of the reservoir opening plane comprises a first surface area, SA.sub.1 and a second surface area, SA.sub.2, wherein SA.sub.1 is ⅕ of the length from the first circumferential inner edge to define a reservoir deep region and SA.sub.2 is ⅘ of the length from the first circumferential inner edge to define a reservoir shallow region relative to the reservoir deep region, wherein SA1<SA2, wherein the head space volume comprises a first head space volume, V.sub.H1, wherein V.sub.H1 is defined as V.sub.H1=Total internal reservoir volume V.sub.r−Volume of the perfume composition in the reservoir shallow region; wherein V.sub.H1 is less than or equal to a Volume of the perfume composition in the deep reservoir region; wherein the total perfume fill volume, V.sub.FILL is defined as total perfume fill volume=Volume of the perfume composition in the reservoir shallow region+Volume of the perfume composition in the reservoir shallow region; preferably, V.sub.H1 is at least 1 ml, more preferably V.sub.H1 is from 1 ml to 3 ml.
8. The dispenser according to claim 1, comprising a total perfume fill volume (V.sub.FILL) of from about 2 ml to 50 ml.
9. The dispenser according to claim 1, wherein the side walls include a first side wall and a second side wall opposing each other, wherein the first side wall is proximal to said first circumferential inner edge and the second side wall is proximal to a second circumferential inner edge, wherein the center longitudinal axis (Yc) intersects the first circumferential inner edge and the second circumferential inner edge wherein a height of the first side wall is measured orthogonal to an intersection of the center longitudinal axis and the first inner circumferential edge and a height of the second side wall is measured orthogonal to an intersection of the center longitudinal axis and the second inner circumferential edge, wherein the height of the first side wall is longer than the height of the second side wall.
10. The dispenser according to claim 1, further comprising a porous membrane attached to the dispenser across the reservoir opening such that the vapor impermeable substrate is a rupturable vapor impermeable substrate disposed between the porous membrane and the reservoir opening.
11. The dispenser according to claim 1, wherein the perfume composition comprises a viscosity of from about 1.0 cP to less than about 25 cP, at 25 degrees Celsius, wherein the perfume composition comprises at least one volatile aldehyde selected from the group consisting of: (E)-3-phenylprop-2-enal, benzaldehyde, 4-propan-2-ylbenzaldehyde, 4-methoxybenzaldehyde, (2E,6Z)-nona-2,6-dienal, (E)-hex-2-enal, (2E,6Z)-dodeca-2,6-dienal, non-2-enal, 2,4,6-trimethylcyclohex-3-ene-1-carbaldehyde; 3,5,6-trimethylcyclohex-3-ene-1-carbaldehyde, 3-(6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)-2,2-dimethylpropanal, nonanal, (E)-dec-4-enal, 2,6-dimethylhept-5-enal, (Z)-non-6-enal, 7-methoxy-3,7-dimethyloctanal, 3-(4-methylcyclohex-3-en-1-yl)butanal, 3,7-dimethyloct-6-enal, 2-methyldecanal, 2,4-dimethylcyclohex-3-ene-1-carbaldehyde, undec-10-enal, 4,8-dimethyldeca-4,9-dienal, octanal, undecanal, decanal, undec-9-enal, 6-methoxy-2,6-dimethylheptanal, 3-(6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)propanal, 4,7-Methanoindan-1-carboxaldehyde and mixtures thereof.
12. The dispenser according to claim 1, wherein the perfume composition comprises a total perfume fill volume (V.sub.FILL) of 70% of a total internal reservoir volume of the reservoir (V.sub.r), and wherein the headspace comprises a headspace volume of at least 30% of the total internal reservoir volume (V.sub.r).
13. The dispenser according to claim 1, wherein the perfume composition comprises a total perfume fill volume (V.sub.FILL) 65% of a total internal reservoir volume of the reservoir (V.sub.r), and wherein the headspace comprises a headspace volume of at least 35% of the total internal reservoir volume (V.sub.r).
14. The dispenser according to claim 1, wherein the perfume composition comprises a total perfume fill volume (V.sub.FILL) of 60% of a total internal reservoir volume of the reservoir (V.sub.r), and wherein the headspace comprises a headspace volume of at least 40% of the total internal reservoir volume (V.sub.r).
15. The dispenser according to claim 1, comprising a total perfume fill volume (V.sub.FILL) of from about 4 ml to 30 ml.
16. The dispenser according to claim 1, comprising a total perfume fill volume (V.sub.FILL) of from about 6 ml to 20 ml.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(16) The present invention relates to a volatile composition dispenser (hereinafter “dispenser”) with splash control design features and method of manufacturing a volatile composition dispenser. Specifically, the dispenser comprises a reservoir for receiving a perfume composition. The dispenser comprises a container having a bottom wall and side walls extending from the bottom wall to create the reservoir. The side walls have a circumferential inner edge defining a reservoir opening and a reservoir opening plane extends across the reservoir opening and intersects the circumferential inner edge. The reservoir opening plane has a center longitudinal axis extending along a length of the reservoir opening plane between opposing circumferential inner edges and extending through a centroid of the reservoir opening plane. A first depth (D1) and a second depth (D2) between the bottom wall and the reservoir opening plane is measured orthogonal to the longitudinal axis. D1 is measured ⅕ of the length from a first circumferential inner edge and D2 is measured ⅘ of the length from the first circumferential inner edge. D1 is longer than D2 to define an asymmetric profile of the bottom wall, thereby enabling control of perfume splash from the reservoir during transport of the container in the method of manufacturing the dispenser.
(17) In the following description, the dispenser described is a consumer product, such as an air freshener, for evaporating a perfume composition in spaces to deliver a variety of benefits such as freshening, malodor removal or scenting of air in spaces such as rooms in household and commercial establishments, or enclosed spaces such as a vehicle passenger compartment space. However, it is contemplated that the dispenser may be configured for use in a variety of applications to deliver volatile materials to the atmosphere and the dispenser may include but is not limited to consumer products, such as, for example air freshening products. Further, the container described has a reservoir opening having a substantially elliptical shape. However, it is contemplated that the container may be configured in a variety of geometrical shapes including but not limited to squares, rectangles, polygons, circles, or the like.
(18) Prior to describing the present invention in detail, the following terms are defined for clarity. Terms not defined should be given their ordinary meaning as understood by a skilled person in the relevant art.
(19) “Horizontal orientation” as used herein, refers to a position of a volatile composition dispenser according to the present invention wherein the membrane is facing the environment in an upward or downward position.
(20) “Membrane” as used herein, refers to a semi-permeable material which allows some components of matter to pass through but stops other components. Of the components that pass through, the membrane moderates the permeation of components i.e. some components permeate faster than other components. Such components may include molecules, ions or particles.
(21) “Microporous membrane” as used herein, refers to a material having a network of pores.
(22) “Vertical orientation” as used herein, refers to a position of a volatile composition dispenser according to the present invention wherein the membrane is facing the environment in a forward facing position or in a rear facing position.
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(24) The container 10 may be made of a substantially vapor impermeable material designed to resist diffusion of a vapor phase of the volatile composition 12. For example, the container 10 may be made of metal, glass, ceramic, porcelain, tile and plastic including but not limited to thermoplastics and other known materials suitable for thermoforming, injection molding and blow molding.
(25) A membrane 13 may be disposed within the container 10 and arranged to be in fluid communication with the perfume composition 12. The dispenser 1 may further include a vapor impermeable substrate 14 adjacent to the membrane 13 wherein the vapor impermeable substrate 14 is configured to prevent release of the perfume composition 12 before use.
(26) Referring to
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(28) Referring to
(29) Referring to
(30) Further, the side walls 22 include a first side wall 221 proximal to the first circumferential inner edge 241 and a second side wall 222 opposing the first side wall 221. The first side wall 221 is longer than the second side wall 222. As shown in
(31) Further, as shown in
(32) A technical effect of the geometry of the container 10 is to provide a reservoir with varying depths, and preferably with side walls of different lengths for containing the perfume composition which minimizes or prevents perfume splash in a method of manufacturing a volatile composition dispenser 1.
(33) To explain the way the container 10 works to prevent splash according to the present invention, it is helpful to understand how forces acting on the perfume composition 12 is generated during movement of the container 10 in a horizontal direction such as when the container 10 is conveyed on a conveyor belt in manufacturing.
(34) In
(35) Without wishing to be bound by theory, a technical effect of having D1 longer than D2 enables a head space 17 sufficient for minimizing splash when the container containing the perfume composition is moved after filling and stopped at the next station for subsequent process steps in a method of manufacturing a volatile composition dispenser according to the present invention.
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(37) The perfume composition 12 may be dispensed up to a level to define a head space 17 between the perfume surface level 16 and the reservoir opening plane 27. A total perfume fill volume, V.sub.FILL of the perfume composition 12 may be 75%, preferably 70%, more preferably 65%, yet more preferably 60% of a total internal reservoir volume, V.sub.r of the reservoir 11. The total internal reservoir volume, V.sub.r is defined as
(38) V.sub.r=Surface Area (S.A.) of the reservoir opening plane multiplied by an Average Depth (Avg. D.) of the reservoir.
(39) The head space 17 comprises a headspace volume of at least 25%, preferably at least 30%, more preferably at least 35%, even more preferably at least 40% of the total internal reservoir volume, V.sub.r. An advantage of having the minimum headspace volume in the above described percentages is that it enables the conveyor belt to be operated at a maximum line speed to increase production output of the dispensers 1 and minimizing perfume splash. The surface area (S.A.) of the reservoir opening plane 27 depends on a geometry or shape of the reservoir opening plane 27. For example, referring to
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(42) The conveyor belt 32 may be operated at a line speed of greater than or equal to 14 cycles per minute, preferably 14 to 20 cycles per minute, more preferably 16 to 20 cycles per minute, yet more preferably 18 to 20 cycles per minute. An effect of operating the conveyor belt at a line speed of 20 cycles per minute is that it enables an increased production output relative to a lower line speed which will require addition of new lines to achieve the same increased production out, thereby enabling a savings in capital investments.
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(44) Referring to
(45) Further, the head space volume comprises a first head space volume, V.sub.H1, wherein V.sub.H1 is defined as
(46) V.sub.H1=Total internal reservoir volume V.sub.r−Volume of the perfume composition in the reservoir shallow region;
(47) wherein V.sub.H1 is less than or equal to a Volume of the perfume composition V.sub.2 in the deep reservoir region;
(48) wherein the total perfume fill volume, V.sub.FILL is defined as
(49) total perfume fill volume=Volume of the perfume composition in the reservoir shallow region+Volume of the perfume composition in the reservoir shallow region.
(50) Preferably, V.sub.H1 is at least 1 ml, more preferably V.sub.H1 is from 1 ml to 3 ml.
(51) Specifically, referring to
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(55) The dispenser 1 of the present invention can be configured for use in a variety of applications to deliver a perfume composition 12 to the atmosphere as long as the perfume composition 12 can vaporize from the membrane 13 into the air.
(56) Accordingly, the specific physical properties of the membrane 13 may be chosen based on the specific desired use of the dispenser 1, designed to be activated by peeling off the vapor impermeable substrate 14 or by rupturing the vapor impermeable substrate 14. Membranes and vapor impermeable substrates designed to be releasably attached are known and will not be further described. Examples of suitable physical parameters of the membrane 13 and the vapor impermeable substrate 14 suitable for a dispenser 1 designed to be activated by rupturing the vapor impermeable substrate 14 will be described hereinafter in the description.
(57) The membrane 13 may be a microporous membrane and comprise an average pore size of about 0.01 to about 1 microns, about 0.01 to about 0.06 microns, from about 0.01 to about 0.05 microns, about 0.01 to about 0.04 microns, about 0.01 to about 0.03 microns, about 0.02 to about 0.04 microns, or about 0.02 microns. Further, the membrane 12 may be filled with any suitable filler and plasticizer known in the art. Fillers may include finely divided silica, clays, zeolites, carbonates, charcoals, and mixtures thereof. An example of a filled membrane is an ultra-high molecular weight polyethylene (UHMWPE) membrane filled with silica, such as those described in U.S. Pat. No. 7,498,369. Although any suitable fill material and weight percentage may be used, typical fill percentages for silica, may be between about 50% to about 80%, about 60% to about 80%, about 70% to about 80%, or about 70% to about 75% of the total weight of the membrane. Examples of suitable membrane thicknesses include, but are not limited to between about 0.01 mm to about 1 mm, between about 0.1 mm to 0.4 mm, about 0.15 mm to about 0.35 mm, or about 0.25 mm. Still further, an evaporative surface area of the membrane 12 may be about 2 cm.sup.2 to about 100 cm.sup.2, about 2 cm2 to about 25 cm.sup.2, about 10 cm.sup.2 to about 50 cm.sup.2, about 10 cm.sup.2 to about 45 cm.sup.2, about 10 cm.sup.2 to about 35 cm.sup.2, about 15 cm.sup.2 to about 40 cm.sup.2, about 15 cm.sup.2 to about 35 cm.sup.2, about 20 cm.sup.2 to about 35 cm.sup.2, about 30 cm.sup.2 to about 35 cm.sup.2, about 35 cm.sup.2.
(58) The vapor impermeable substrate 14 may be made of any material that can be ruptured with a pre-determined applied force, with or without the presence of an element, such as rupture element, to aid in such rupture. The planar surface may further comprise a circumferential outer edge opposing said circumferential inner edge, to define a planar surface area therein between, wherein the planar surface area is configured for attaching the vapor impermeable substrate.
(59) In embodiments where the vapor impermeable substrate 14 is intended to contain the volatile composition when the dispenser 1 is not in use, the vapor impermeable substrate 14 may be made from any suitable barrier material that reduces or prevents evaporation of the perfume composition 12. Such materials may be impermeable to vapors and liquids. Suitable barrier materials for the vapor impermeable substrate 14 include, but are not limited to coated or uncoated films, such as polymeric films, webs, foils, and composite materials such as foil/polymeric film laminates. An example of a foil that may be used as a barrier material is a micron aluminum foil including a nitrocellulose protective lacquer, a polyurethane primer, and a 15 g/m2 polyethylene coating (Lidfoil 118-0092), available from Alcan Packaging. Suitable polymeric films include, but are not limited to, polyethylene terephtalate (PET) films, acrylonitrile copolymer barrier films such as, for example, those sold under the tradename Barex® by INOES, ethylene vinyl alcohol films, and combinations thereof. It is also contemplated that coated barrier films may be utilized as the vapor impermeable substrate 14. Such coated barrier films include, but are not limited to, metallized PET, metalized polypropylene, silica or alumina coated film.
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PERFUME COMPOSITION
(62) The dispenser 1 of the present invention may comprise an air freshening composition, wherein the air freshening composition comprise up to 100%, about 4% to about 100%, about 15% to about 100%, about 65% to 86%, of the perfume composition 12 by weight of the air freshening composition.
(63) The perfume composition 12 may comprise a viscosity of from about 1.0 cP to less than about 25 cP, preferably about 1.0 cP to less than about 20 cP, at 25 degrees Celsius.
(64) The perfume composition 12 may comprise a mixture of carbonyl containing compounds. The mixture of carbonyl containing compounds may be present in an amount of from about equal to or greater than 0.01% to about less than or equal to 100%, in an amount from about 0.01% to 50%, from about 1% to 40%, from about 4% to 25%, from about less than or equal to 5% to equal to or less than 25% by weight of the perfume composition. An effect of having less than 25% by weight of the carbonyl containing compounds is to enable formulation space for adding optional ingredients described hereinafter such as perfume raw materials to provide a hedonic experience.
(65) The vapor pressure of the volatile carbonyl containing compounds may be greater than or equal to 0.025 torr, about 0.025 torr to about 30 torr, measured at 25 degrees Celsius. The vapor pressure of individual volatile carbonyl containing compounds can be calculated using the Advanced Chemistry Development Labs (“ACD”) (Toronto, Canada) VP computational model, version 14.02 providing vapor pressure (VP) values at 25 degrees Celsius expressed in unit of torr. The volatile carbonyl containing compound may be selected from the group consisting of: volatile aldehydes, ketones and mixtures thereof. Exemplary volatile aldehydes and ketones are listed in the following description and are named according to the method of naming organic chemical compounds as recommended by the International Union of Pure and Applied Chemistry (IUPAC).
(66) The carbonyl containing compound may comprise volatile aldehydes. Aldehydes that are partially volatile may be considered a volatile aldehyde as used herein. Exemplary volatile aldehydes which may be used include, but are not limited to, aldehydes as shown in Table 1 below. The carbonyl containing compound may also comprise ketones. Exemplary ketones which may be used in the volatile material include, but are not limited to ketones shown in Table 2 below.
(67) TABLE-US-00001 TABLE 1 Vapor Pressure (torr) CAS IUPAC Name @ 25 degrees Celsius 04-55-2 (E)-3-phenylprop-2-enal 0.080 100-52-7 Benzaldehyde 0.13 122-03-2 4-propan-2-ylbenzaldehyde 0.031 123-11-5 4-methoxybenzaldehyde 0.021 557-48-2 (2E,6Z)-nona-2,6-dienal 0.18 6728-26-3 (E)-hex-2-enal 10.66 5392-40-5 (2E)-3,7-dimethylocta-2,6-dienal 0.13 2363-89-5 (E)-oct-2-enal 0.99 21662-13-5 (2E,6Z)-dodeca-2,6-dienal 0.004 2463-53-8 non-2-enal 0.21 1335-66-6 2,4,6-trimethylcyclohex-3- 2.64 ene-1-carbaldehyde; 3,5,6- trimethylcyclohex-3-ene-1- carbaldehyde 33885-52-8 3-(6,6-dimethyl-4- 0.028 bicyclo[3.1.1]hept-3-enyl)- 2,2-dimethylpropanal 124-19-6 Nonanal 0.37 65405-70-1 (E)-dec-4-enal 0.35 106-72-9 2,6-dimethylhept-5-enal 0.48 2277-19-2 (Z)-non-6-enal 0.22 3613-30-7 7-methoxy-3,7-dimethyloctanal 0.040 6784-13-0 3-(4-methylcyclohex-3-en- 0.11 1-yl)butanal 106-23-0 3,7-dimethyloct-6-enal 0.14 19009-56-4 2-methyldecanal 0.053 68039-49-6 2,4-dimethylcyclohex-3-ene-1- 0.73 carbaldehyde 112-45-8 undec-10-enal 0.019 71077-31-1 4,8-dimethyldeca-4,9-dienal 0.019 124-13-0 Octanal 1.14 112-44-7 Undecanal 0.037 112-31-2 Decanal 0.12 143-14-6 undec-9-enal 0.011 62439-41-2 6-methoxy-2,6-dimethylheptanal 0.130 33885-51-7 3-(6,6-dimethyl-4- 0.039 bicyclo[3.1.1]hept-3-enyl)propanal
(68) TABLE-US-00002 TABLE 2 Vapor Pressure (VP), CAS IUPAC Name torr @ 25° C. 1125-21-9 2,6,6-trimethylcyclohex-2-ene-1,4-dione 0.158 10373-78-1 4,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione 0.0817 1193-79-9 1-(5-methylfuran-2-yl)ethanone 0.301 765-70-8 3-methylcyclopentane-1,2-dione 0.978 98-86-2 1-phenylethanone 0.299 600-14-6 pentane-2,3-dione 26.416 4077-47-8 4-methoxy-2,5-dimethylfuran-3-one 0.103 3658-77-3 4-hydroxy-2,5-dimethylfuran-3-one 0.032 1196-01-6 (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-en-4-one 0.0773 18309-32-5 (1R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-en-4-one 0.0773 78-59-1 3,5,5-trimethylcyclohex-2-en-1-one 0.15 2758-18-1 3-methylcyclopent-2-en-1-one 2.741 2244-16-8 (5S)-2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one 0.0656 6485-40-1 (5R)-2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one 0.0656 141-79-7 4-methylpent-3-en-2-one 8.757 99-49-0 2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one 0.0656 1072-83-9 1-(1H-pyrrol-2-yl)ethanone 0.11 89-82-7 (5R)-5-methyl-2-propan-2-ylidenecyclohexan-1-one 0.0934 2550-26-7 4-phenylbutan-2-one 0.0557 2308-18-1 3-methylbutyl 3-oxobutanoate 0.167 513-86-0 3-hydroxybutan-2-one 1.92 81786-73-4 (Z)-3,4,5,6,6-pentamethylhept-3-en-2-one 0.0275 4906-24-5 3-oxobutan-2-yl acetate 2.069 105-45-3 methyl 3-oxobutanoate 1.543 141-97-9 ethyl 3-oxobutanoate 0.89 5524-05-0 (2R,5R)-2-methyl-5-prop-1-en-2-ylcyclohexan-1-one 0.107 7764-50-3 2-methyl-5-prop-1-en-2-ylcyclohexan-1-one 0.107 5948-04-9 (2S,5S)-2-methyl-5-prop-1-en-2-ylcyclohexan-1-one 0.107 55739-89-4 2-ethyl-4,4-dimethylcyclohexan-1-one 0.25 25304-14-7 1-(3,3-dimethylcyclohexyl)ethanone 0.287 36977-92-1 (2S,5S)-5-methyl-2-propan-2-ylcyclohexan-1-one 0.256 89-80-5 (2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-one 0.256 65443-14-3 2,2,5-trimethyl-5-pentylcyclopentan-1-one 0.0261 873-94-9 3,3,5-trimethylcyclohexan-1-one 0.582 4884-24-6 2-cyclopentylcyclopentan-1-one 0.0588 546-80-5 (1S,4R,5R)-4-methyl-1-propan-2- 0.323 ylbicyclo[3.1.0]hexan-3-one 16587-71-6 4-(2-methylbutan-2-yl)cyclohexan-1-one 0.0649 76-22-2 4,7,7-trimethylbicyclo[2.2.1]heptan-3-one 0.225 110-93-0 6-methylhept-5-en-2-one 1.277 111-13-7 octan-2-one 1.725 7787-20-4 (1S,4R)-2,2,4-trimethylbicyclo[2.2.1]heptan-3-one 0.463 110-43-0 heptan-2-one 4.732 1195-79-5 2,2,4-trimethylbicyclo[2.2.1]heptan-3-one 0.463 541-85-5 5-methylheptan-3-one 2.444 106-68-3 octan-3-one 1.504
(69) Table 3 shows a mixture of volatile aldehydes suitable for use in the dispenser 1 of the present invention, the mixture is referred to herein as Accord A.
(70) TABLE-US-00003 TABLE 3 Accord A Weight % by weight of the VP (torr) CAS No. Material Name Volatile Material @ 25° C. 6728-26-3 (E)-hex-2-enal 1 to 4 10.66 1335-66-6 2,4,6-trimethylcyclohex-3- 4 to 8 2.64 ene-1-carbaldehyde; 3,5,6- trimethylcyclohex-3-ene-1- carbaldehyde 124-13-0 octanal 7 to 12 1.14 68039-49-6 2,4-dimethylcyclohex-3- 10 to 20 0.73 ene-1-carbaldehyde 106-72-9 2,6-dimethylhept-5-enal 10 to 20 0.48 2277-19-2 (Z)-non-6-enal 0.1 to 0.3 0.22 557-48-2 (2E,6Z)-nona-2,6-dienal 0.3 to 1.0 0.18 100-52-7 benzaldehyde 8 to 13 0.13 5392-40-5 (2E)-3,7-dimethylocta-2,6- 7 to 12 0.13 dienal 112-31-2 decanal 10 to 20 0.12 30772-79-3 4,7-Methanoindan-1- 10 to 20 0.05 carboxaldehyde Total by weight of the 100% Volatile Material
(71) Table 4 shows a further mixture of volatile aldehydes suitable for use in the dispenser of the present invention, the mixture is referred to herein as Accord B.
(72) TABLE-US-00004 TABLE 4 Accord B Wt % by weight of the VP (torr) CAS Material Name Volatile Material @ 25° C. 6728-26-3 (E)-hex-2-enal 0.5 to 2.0 10.66 124-13-0 octanal 3 to 10 1.14 110-41-8 2-methylundecanal 1 to 5 0.015 100-52-7 benzaldehyde 10 to 20 0.13 106-72-9 2,6-dimethylhept-5-enal 3 to 8 0.48 68039-49-6 2,4-dimethylcyclohex-3- 9 to 15 0.73 ene-1-carbaldehyde 124-19-6 nonanal 1 to 3 0.37 1335-66-6 2,5,6-trimethylcyclohex-3- 5 to 10 2.64 ene-1-carbaldehyde 557-48-2 (2E,6Z)-nona-2,6-dienal 0.2 to 1.2 0.182 112-31-2 decanal 7 to 15 0.12 5392-40-5 (E)-3,7-dimethylocta-2,6- 10 to 20 0.13 dienal 112-45-8 undec-10-enal 1 to 5 0.019 112-54-9 dodecanal 1 to 6 0.007 123-11-5 4-methoxybenzaldehyde 10 to 20 0.021 Total by weight of the 100% Volatile Material
(73) The following examples are intended to more fully illustrate the present invention and are not to be construed as limitations of the present invention since many variations thereof are possible without departing from the scope of the present invention. All parts, percentages and ratios used herein are expressed as percent weight unless otherwise specified.
EXAMPLES
(74) Test equipment/materials and test dispenser samples are first described under Materials, then the Test Method is provided, and lastly results are discussed. Data is provided demonstrating the dispensers of the present invention having improved splash control and achieves a desired vertical fill height. Equipment and materials used in the Test Method described hereinafter are listed in Table 5 below. The perfume compositions provided in the inventive and comparative samples are prepared using conventional methods.
MATERIALS
(75) TABLE-US-00005 TABLE 5 Equipment/Materials Equipment/ Materials Technical Specifications Conveyor Belt Monolab Main Automatic Machine Manufacturer: Monolab Model: MB961XL Serial Number: B2.09.009 Perfume Technical Specifications are not disclosed by the Filling manufacturer. Filling station comprising a nozzle Station in fluid communication with a tank containing a perfume composition Perfume Perfume composition having a viscosity of from Composition 1.0 cp to less than 25 cp at 25 degrees Celsius. for Perfume Filing Station Comparative Conventional Dispenser with configuration based on Sample #1 FIG. 9 with perfume composition having a viscosity of from 1.0 cp to less than 25 cp at 25 degrees Celsius. Comparative Conventional Dispenser with configuration based on Sample #2 FIG. 9 with perfume composition having a viscosity of from 1.0 cp to less than 25 cp at 25 degrees Celsius. Inventive Inventive Dispenser with configuration based on Sample #3 FIG. 5A with perfume composition having a viscosity of from 1.0 cp to less than 25 cp at 25 degrees Celsius.
TEST METHOD
(76) Perfume Fill Performance Test Method
(77) This test method is to determine a maximum line speed for containers containing perfume composition and having different head space volumes or head space gap between the perfume surface level and the reservoir opening plane. The test method is performed under the following test conditions: at an average temperature of 20° C. to 25° C. The steps for performing the test are illustrated in
EXAMPLE
(78) Comparative Samples #1, #2 and Inventive Sample #3 of Table 5 are evaluated according to the Perfume Fill Performance Test Method described hereinbefore under Test Method.
(79) Table 6 shows a correlation between the head space 17 in the dispenser 1 and a maximum line speed without perfume splash (cycles/minute) to achieve a desired vertical level in the perfume composition 12.
(80) TABLE-US-00006 TABLE 6 Total Total Perfume Maximum Vertical visual internal Total Fill Colume as a line speed Height reservoir Perfume % of a total Total (cycles/ (Perfume Fill volume of Fill interanl reservoir Head minute) with Level in a Vertical the Volume volume of the Space no splash Orientation of the Example reservoir, V (ml) reservoir, V.sub.r Volume detected Dispenser Comparative 10.5 ml 6.5 ml 60% 4 ml 20 39.7 mm Sample #1 Comparative 10.5 ml 7.2 ml 70% 3.3 ml 17 >42.4 mm Sample #2 Inventive 10.5 ml 6.5 ml 60% 4 ml 20 >42.4 mm Sample #3
(81) As shown in Table 6, the results of Inventive Sample #3 demonstrate that having a configuration of the container 10 in the Inventive Sample #3 and enables an optimum total head space volume of 4 ml to prevent splash and achieves a vertical visual height of greater than or equal to 42.4 mm when Inventive Sample #3 is placed in a vertical orientation. Further, the production of Inventive Sample #3 is achieved at a maximum speed of 20 cycles/minute to optimize production output. The results of Comparative Sample #1 show a lower vertical visual height of 39.7 mm compared to Inventive Sample #3 even with the same perfume fill volume of 6.5 ml and the same head space volume of 4 ml. On the other hand, the results of Comparative Sample #2 show the same vertical visual height of 42.4 mm, but the line speed is reduced to 17 cycles per minute in order to prevent splash.
(82) The overall results show that having a container 10 of the present invention having a first depth (D1) and a second depth (D2) between the bottom wall 20 and the reservoir opening plane 27 wherein D1 is longer than D2 helps prevent perfume splash and achieves a desired vertical visual height requirement than a configuration without D1 and D2, despite maintaining all other conditions such as demonstrated in Comparative Sample #1. Therefore, a container having D1 and D2 as described hereinbefore may be used to prevent the effect of splash in manufacturing while achieving high production output of dispensers which meet the visual vertical height requirements.
(83) The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
(84) Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
(85) While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.