Electroluminescent display device and method of fabricating same

10811626 ยท 2020-10-20

Assignee

Inventors

Cpc classification

International classification

Abstract

An electroluminescent display device and a fabricating method thereof are provided. The device has a TFT layer, a first functional layer, an electroluminescent layer, a second functional layer, and a functional bar disposed sequentially. The device uses Seebeck effect of constituent material of p-type Bi.sub.2Te.sub.3 of the functional bar to absorb heat of the TFT layer for converting the heat into electric energy, thereby effectively reducing heat of the TFT layer, reducing aging of circuit and organic material, and improving life of the electroluminescent display device. A work function of p-type Bi.sub.2Te.sub.3 material of the functional bar is 5.3 eV. An electroluminescent material has a HOMO energy level ranging from 5 to 6 eV. Under a driving of a thermoelectromotive force, majority carriers (holes) in the constituent material of p-type Bi.sub.2Te.sub.3, are injected into the electroluminescent layer to improve a carrier concentration therein, thereby improving emission luminance of the electroluminescent display device.

Claims

1. An electroluminescent display device, comprising: a TFT layer; a first functional layer disposed on the TFT layer; an electroluminescent layer disposed on the first functional layer; a functional bar disposed in the first functional layer and the electroluminescent layer, wherein the functional bar consists of a p-type Bi.sub.2Te.sub.3 material; and a second functional layer disposed on the electroluminescent layer, wherein the electroluminescent layer consists of an electroluminescent material, the electroluminescent material has a HOMO energy level ranging from 5 to 6 eV, and a work function of the p-type Bi.sub.2Te.sub.3 material of the functional bar is 5.3 eV.

2. The electroluminescent display device according to claim 1, wherein the second functional layer comprises: an electron transporting layer disposed on the electroluminescent layer; an electron injection layer disposed on the electron transporting layer; and a metal cathode disposed on the electron injection layer.

3. The electroluminescent display device according to claim 1, wherein a number of the functional bar is two or more than two, wherein the functional bars form an array and are uniformly disposed in the first functional layer and the electroluminescent layer.

4. The electroluminescent display device according to claim 1, wherein a top portion of the functional bar extends upwardly to a location of 0.4-0.6 times of a thickness of the electroluminescent layer.

5. The electroluminescent display device according to claim 1, wherein the first functional layer comprises: a ITO anode disposed on the TFT layer; a hole injection layer disposed on the ITO anode; and a hole transporting layer disposed on the hole injection layer.

6. The electroluminescent display device according to claim 5, wherein a bottom portion of the functional bar contacts with a surface of the ITO anode.

Description

DESCRIPTION OF DRAWINGS

(1) The disclosure is further explained below in conjunction with the drawings and embodiments.

(2) FIG. 1 is a schematic structural diagram of an electroluminescent display device according to an embodiment of the present disclosure,

(3) FIG. 2 is a schematic diagram of the electroluminescent display device shown in FIG. 1, which relates to a Seebeck effect and a hole injection of a functional bar.

(4) FIG. 3 is a flow chart of fabricating an electroluminescence display device.

(5) Components in the figure are identified as follows:

(6) TABLE-US-00001 1: TFT layer 3: electroluminescent layer 5: functional bar 21: ITO anode 22: hole injection layer 23: hole transporting layer 41: electron transporting layer 42: electron injection layer 43: metal cathode 51: hole

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

(7) The following description of the embodiments with reference to the appended drawings is used for illustrating specific embodiments which may be used for carrying out the present disclosure. The directional terms described by the present disclosure, such as upper, lower, front, back, left, right, top, bottom, etc., are only directions by referring to the accompanying drawings. Thus, the used directional terms are used to describe and understand the present disclosure, but the present disclosure is not limited.

(8) As shown in FIG. 1, an electroluminescent display device includes a TFT layer 1, a first functional layer, an electroluminescent layer 3, a second functional layer, and a functional bar 5 disposed sequentially. The first functional layer is disposed on the TFT layer 1. The electroluminescent layer 3 is disposed on the first functional layer. The second functional layer is disposed on the electroluminescent layer 3.

(9) The first functional layer comprises a ITO anode 21, a hole injection layer 22, and a hole transporting layer 23. The ITO anode 21 is disposed on the TFT layer 1. The hole injection layer 22 is disposed on the ITO anode 21. The hole transporting layer 23 is disposed on the hole injection layer 22. The ITO anode 21 consists of indium tin oxide (ITO), and the ITO anode 2 made of ITO has good light transmittance. The hole transporting layer 23 controls transporting of holes, thereby controlling the recombination of the holes with electrons in the electroluminescent layer 3, so as to improve a luminous efficiency.

(10) The electroluminescent layer 3 consists of an electroluminescent material, and the electroluminescent material has a HOMO energy level ranging from 5 to 6 eV, wherein the electroluminescent layer 3 can be fabricated by one of vapor deposition, printing, homogeneous deposition, and gas phase synthesis, but is not limited thereto.

(11) The second functional layer comprises an electron transporting layer 41, an electron injection layer 42, and a metal cathode 43. The electron transporting layer 41 is disposed on the electroluminescent layer 3. The electron injection layer 42 is disposed on the electron transporting layer 41. The metal cathode 43 is disposed on the electron injection layer 42. The electron transport layer 41 controls transporting of electrons, thereby controlling recombination of electrons with holes in the electroluminescent layer 3, thereby improving the luminous efficiency.

(12) The functional bar 5 consists of a p-type Bi.sub.2Te.sub.3 material, and a work function of the p-type Bi.sub.2Te.sub.3 material is 5.3 eV. A bottom portion of the functional bar 5 is disposed in the first functional layer, and a top portion of the functional bar 5 extends upwardly into an interior of the electroluminescent layer 3. Specifically, a bottom portion of the functional bar 5 contacts with a surface of the ITO anode 21. The top portion of the functional bar 5 extends upwardly to a location of 0.4-0.6 times of a thickness of the electroluminescent layer 3. Preferably, the top portion of the functional bar 5 extends upwardly to a location of 0.5 times of the thickness of the electroluminescent layer 3, but is not limited thereto. This allows carrier holes 51 inside the functional bar 5 to enter the electroluminescent layer 3 more uniformly, and the luminous efficiency is more effectively improved.

(13) A number of the functional bar 5 is plural, and the functional bars 5 form an array uniformly disposed inside the first functional layer and the electroluminescent layer 3. The more the number of functional bars, the more heat absorbed by the functional bar 5 under the Seebeck effect, thereby more effectively reducing aging of a circuit and an organic material, and improving a life of the electroluminescent display device. The specific quantity can be determined according to actual needs and is not limited.

(14) In operation, as shown in FIG. 2, the TFT layer is energized and heated, and heat is transferred up to the electroluminescent layer 3, thereby forming a temperature difference between the TFT layer and the electroluminescent layer 3. The functional bar 5 generates a Seebeck effect under temperature stimulation, and then begins to absorb high temperature heat and convert the absorbed heat into electrical energy.

(15) In one aspect, this heat absorption and electrical energy conversion reduce temperature and thus reduce the aging of the circuit and the organic material, and improves the life of the electroluminescent display device. In another aspect, it forms a thermoelectromotive force between the TFT layer 1 and the electroluminescent layer 3. Due to a driving of the thermoelectromotive force, the holes 51 in the functional rod 5 are also moved from a high temperature end to a low temperature end, and injected into the electroluminescent layer 3, thereby increasing a carrier concentration in the electroluminescent layer 3, so as to improve luminance of AMOLED.

(16) Further, the P-type Bi.sub.2Te.sub.3 material of the functional bar 5 has a work function of 5.3 eV, and the electroluminescent material used in the electroluminescent layer 3 has a HOMO energy level of 5-6 eV. Both the work functions match each other to ensure that carrier holes 51 inside the functional bar 5 can be injected into the electroluminescent layer 3. When the HOMO level of the electroluminescent material is greater than 6 eV, the holes 51 inside the functional bar 5 cannot be injected into the electroluminescent layer 3. When the HOMO level of the electroluminescent material is less than 5 eV, the holes 51 inside the functional bar 5 are also incapable of being injected into the electroluminescent layer 3.

(17) An electroluminescent display device relating to the present disclosure has a functional bar consisting of a p-type Bi.sub.2Te.sub.3 material. In one aspect, the device uses Seebeck effect of the functional bar to absorb heat of the TFT layer for converting the heat into electric energy, thereby effectively reducing heat of the TFT layer, reducing aging of circuit and organic material, and improving life of the electroluminescent display device. In another aspect, a work function of p-type Bi.sub.2Te.sub.3 material of the functional bar is 5.3 eV. An electroluminescent material has a HOMO energy level ranging from 5 to 6 eV. Under a driving of a thermoelectromotive force, majority carriers (holes) in a constituent material of p-type Bi.sub.2Te.sub.3 also are injected into the electroluminescent layer to improve a carrier concentration in the electroluminescent layer, so as to improve emission luminance of the electroluminescent display device.

(18) As shown in FIG. 3, a method of fabricating an electroluminescent display device, comprising: a step S1 of providing a TFT layer 1; a step S2 of disposing a first functional layer on the TFT layer 1; a step S3 of disposing an electroluminescent layer 3 on the first functional layer; a step S4 of disposing a porous alumina film (AAO) as a template on the first functional layer, depositing a p-type Bi.sub.2Te.sub.3 material between the template and the electroluminescent layer 3 by using a chemical deposition method or a physical vapor deposition method, and removing the template by etching, so as to finally obtain a functional bar 5 with a standardized shape and size; and a step S5 of disposing a second functional layer on the electroluminescent layer 3.

(19) The above are only the preferred embodiments of the present disclosure, and are not intended to limit the present disclosure. Any modifications, equivalents, and improvements made within the spirit and scope of the present disclosure are included in the scope of the present disclosure.