METHOD OF MAKING A COLD FORMABLE HIGH STRENGTH STEEL STRIP AND STEEL STRIP

Abstract

A method of manufacturing steel strip including the steps of: casting molten steel into slabs; reheating the slabs at 1150° C. or more for 1 hour or more; hot rolling the steel into a strip, preferably with an average F1 slab entry temperature above 1000° C.; coiling the hot rolled steel strip; batch annealing the steel strip: at an intercritical temperature (i.e. between Ac1 and Ac3), preferably below 700° C.; in non-oxidising and non-nitrogenated atmosphere; total annealing time at least 5 hours, preferably at least 10 hours to get Mn enrichment in austenite such that Mn content is at least 1.25 times bulk Mn content of the steel and C enrichment such that C content is at least 1.2 times bulk C content of the steel; cooling the steel after batch annealing in air, forced air or water quench.

Claims

1. A method of manufacturing a cold rolled and annealed steel strip, composition of the steel being in wt. %: C: 0.05-0.3; Mn: 3.0-12.0; Al: 0.03-3.0; optionally one or more further alloying elements: Si: less than 1.5; Cr: less than 2.0; V: less than 0.1; Nb: less than 0.1; Ti: less than 0.1; Mo: less than 0.5 inevitable impurities and the remainder being Fe; the method comprising the steps of: casting the molten steel into a slab; reheating the slab and holding it at a temperature of 1150° C. or more for a time of 1 hour or more; hot rolling the steel into a strip, coiling the hot rolled steel strip; pickling the steel strip; intermediate-batch-annealing the coiled steel at a temperature lower than 650° C. for longer than 24 hours to achieve at least 60 vol. % ferrite after cooling to room temperature; cold rolling the steel into a cold rolled steel strip and coiling it; batch annealing the coiled steel strip: at an intercritical temperature between Ac1 and Ac3 which is below 700° C.; in a non-oxidising and non-nitrogenated atmosphere; the total annealing time for which the strip is kept at said intercritical temperature being at least 5 hours in order to get Mn enrichment in austenite which is such that the Mn content is at least 1.25 times the bulk Mn content of the steel and C enrichment such that the C content is at least 1.2 times the bulk C content of the steel; cooling the steel after batch annealing in air, in forced air or by water quench.

2. A method of manufacturing a hot rolled and annealed steel strip, composition of the steel being in wt. %: C: 0.05-0.3; Mn: 3.0-12.0; Al: 0.03-3.0; optionally one or more further alloying elements: Si: less than 1.5; Cr: less than 2.0; V: less than 0.1 ; Nb: less than 0.1 ; Ti: less than 0.1; Mo: less than 0.5 inevitable impurities and the remainder being Fe; the method comprising the steps of: casting the molten steel into a slab; reheating the slab at a temperature of 1150° C. or more, for a time of 1 hour or more; hot rolling the steel into a strip coiling the hot rolled steel strip; pickling the steel strip; batch annealing the coiled steel strip: at an intercritical temperature between Ac1 and Ac3 which is below 700° C.; in a non-oxidising and non-nitrogenated atmosphere; the total annealing time for which the strip is kept at said intercritical temperature being at least 5 hours in order to get Mn enrichment in austenite such that the Mn content is at least 1.25 times the bulk Mn content of the steel and C enrichment such that the C content is at least 1.2 times the bulk C content of the steel; cooling the steel after batch annealing in air, in forced air or by water quench.

3. The method according to claim 1 wherein reheating the slab is at a temperature of 1200° C. or more.

4. The method according to claim 1 wherein reheating the slab is at a temperature of 1250° C. or more.

5. The method according to claim 1 wherein batch annealing the coiled steel strip takes place at an intercritical temperature below 660° C.

6. The method according to claim 1 wherein the resulting strip is coated with any metallic coating applied by hot dip galvanising, galvannealing, electro-galvanising, aluminising or any other method such as PVD, CVD.

7. The method according to claim 1, wherein the resulting steel strip undergoes skin pass rolling.

8. The method according to claim 7,wherein the skin pass rolling takes place with a thickness reduction of 5 % or less.

9. A steel strip obtainable by a method according to claim 1 wherein the steel strip has a steel composition being in wt. %: C:0.05-0.3; Mn: 3.0-12.0; Al:0.03-3.0; optionally one or more further alloying elements: Si:less than 1.5; Cr:less than 2.0; V:less than 0.1; Nb:less than 0.1; Ti:less than 0.1; Mo:less than 0.5 inevitable impurities; and the remainder being Fe; wherein the steel strip has a retained austenite composition that has a Mn content that is at least 1.4 times the Mn content of the steel composition as well as a C content that is at least 2.3 times the C content of the steel composition, in order to obtain metastable retained austenite to give the steel a high strain hardening exponent of at least 0.3 measured after yield point elongation for a strain range of 7 % in a quasi-static tensile test, wherein the microstructure after final batch annealing comprises in vol. %: ferrite: 30 - 70 %; retained austenite: 20 - 65 %; martensite: <20 %, including 0 vol. %.

10. Steel strip according to claim 9 wherein the size of the ferrite grains is 0.2-2 .Math.m.

11. Steel strip according to claim 9 wherein the length/width ratio of the ferrite grains is 3 or smaller.

12. Steel strip according to claim 9 having a yield point elongation of a maximum of 10 % engineering strain measured from its engineering stress-strain curve.

13. Steel strip according to claim 9 having a yield strength of 600 MPa or more and an ultimate tensile strength of 800 MPa or more and a total elongation (A80) of 20 % or more.

14. The steel strip according to claim 9 having a very high formability characterized by an individual direction stretching strain in biaxial stretching condition of 10 % or more, a VDA bending angle at 1.0 mm thickness of 100o or more and a hole expansion capacity of 20 % or more.

15. The method according to claim 1, wherein the inevitable impurities have S:less than 20 ppm; P: less than 0.04.

16. The method according to claim 2, wherein the inevitable impurities have S:less than 20 ppm; P: less than 0.04.

17. The steel strip according to claim 8, wherein the inevitable impurities have S: less than 20 ppm; P: less than 0.04.

18. The method according to claim 1, wherein the hot rolling of the steel into the strip has an average F1 slab entry temperature of above 1000° C.

19. The method according to claim 1, wherein the total annealing time for which the strip is kept at said intercritical temperature being at least 10 hours.

Description