Co-extrusion of periodically modulated structures

Abstract

A structure at least one stripe of material having a length, wherein a first stripe has a varying width along the length.

Claims

1. A structure, comprising: a first longitudinal stripe of a first material containing at least one electrochemically active material on a surface, the first stripe having borders with a first continuous, periodic sinusoidal pattern of wider and narrower portions about a centerline of the first stripe, wherein the centerline is between the borders; and a second longitudinal stripe of a second material adjacent to, and in contact with, the first stripe, the second stripe having borders with a second continuous, periodic sinusoidal pattern of wider and narrower portions about a centerline of the second stripe complementary to the first pattern, wherein the centerline is between the borders.

2. The structure of claim 1, wherein the first material and the second material are a same material.

3. The structure of claim 1, wherein the first material and the second material are different materials.

4. The structure of clam 1, further comprising a third material.

5. The structure of claim 1, wherein the second material is a non-active material.

6. The structure of claim 1, wherein the first material is electrically conductive.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 shows a prior art two dimensional structure.

(2) FIG. 2 shows a prior art two dimensional structure after removal of a sacrificial material.

(3) FIG. 3 shows a three dimensional structure formed in a method according to the prior art.

(4) FIG. 4 shows an embodiment of a near-three dimensional structure of material having varying widths.

(5) FIG. 5 shows an embodiment of a near-three dimensional structure of two materials having complementary patterns of varying widths.

(6) FIG. 6 shows an embodiment of a near-three dimensional structure of three materials.

(7) FIG. 7 shows an embodiment of a system for modulating pressures in an extrusion head.

(8) FIG. 8 shows a graph of paste pressures in an extrusion head.

DETAILED DESCRIPTION OF THE EMBODIMENTS

(9) FIG. 1 shows a two-dimensional structure in accordance with the prior art. It is two-dimensional in that it has at least two stripes of materials. In extrusion, the simplest structures resulting from one circular or rectangular slot in an extrusion head is generally considered to be one-dimensional (1D). The next level of complexity would encompass 2D structures, resulting from extrusion heads that have multiple slots, such as 10 shown in FIG. 1. The same material 14 may be simultaneously extruded from different slots of the same or different forms, or multiple materials such as 12 and 14 could be co-extruded from multiple slots. In some structures, the second material 12 may be sacrificed to form gaps in the structure, where after removal the second material of the structure would then become air, as shown in FIG. 2.

(10) A further level of complexity would be to achieve 3D structures such as 20, typically with multiple passes of the extrusion head to form layers of extruded materials such as 24 and 26. True 3D structures could include hidden features such as voids, overhangs, re-entrant features, etc., typically not achievable using a single pass of an extrusion head. However, it is possible to achieve near-3D structures, having higher complexity than simple stripes or runs of multiple materials from a single pass extrusion head.

(11) The embodiments here may be referred to as near-3D or 2.5D structures. The features of the resulting stripes of materials are more complex than simple stripes of materials, having varying widths along their lengths. This may be accomplished by varying the pressure used to extrude the materials over time. FIG. 4 shows an embodiment or a representation of such a near-3D structure 30. The extrudate stripes 34 have varying width along their length, referred to here as periodically modulated stripes. The stripes may be extruded from a single material 34 from an extrusion head. The varying width may have a periodic pattern as shown, but the varying width may also have a non-periodic, or randomized, pattern. However, the use of a periodic pattern of the first extrudate allows for some variations.

(12) FIG. 5 shows a near-3D structure having extrudate stripes of periodically varying widths. The first extrudate 34 has a first pattern of varying widths. The second extrudate 36 has a complementary second pattern where the wide portions and narrow portions of the second pattern match up to the narrow portions and wide portions of the first pattern. The two patterns are accomplished by periodically modulating the pump differently over time for each pattern. The modulation of the flow of materials over time allows the formation of the patterns.

(13) The two materials may consist of any material that can be extruded through the extrusion head. Typically, the materials are pastes. The materials remain separate from each other. The materials may be a mixture of other materials, but for the purposes of this discussion, when they exit the print head as extrudates they are each one material. Similarly, the two extrudates remain separate from each other, even though they may be extruded together. Some mixing may occur at the material boundaries, but the integrity of each is substantially maintained. One should note that the examples here discuss two materials, but more than two materials may be used.

(14) FIG. 6 shows an example of a near-three dimensional structure having more than two materials. The extrudates 34 and 36 have another extrudate 38 in the structure. The materials are modulated with respect to time as before, but the extrudates 34 and 38 would be modulated in phase with each other to form the patterns that complement the pattern of extrudate 36. For example, the extrudates may form the pattern of extrudate 34, extrudate 36, extrudate 38, extrudate 36, extrudate 34, etc.

(15) The pastes may contain materials which would form electrically conductive or electrochemically active structures, as examples. Electrochemically active materials may be used in electrode structures that make up part of batteries. Non-active materials may be used as filler and then sacrificed. If non-active, or sacrificial, material is used, then once the non-active material is removed, such as be drying, sintering, etc., it can be replaced with another material; but in the instance where no other material is subsequently introduced, then gaps would remain, where the second material would be air.

(16) If for example one of the materials is electrochemically active, a simple model assuming sinusoidal modulation has shown that the resulting structure has approximately 21% greater periphery while having about 10% less average distance between the centerline of an extruded stripe and the nearest border, compared to a conventional linear extruded structure. This increase in surface area, and decrease in the average distance between the interior and border, could for example enhance functional material reaction rates or utilization. Even such a small improvement could be economically significant in a cost-sensitive business such as battery manufacturing.

(17) To vary the widths along the length of the features, the dispensing system uses a pump to create a pressure that then forces the paste out of the extrusion head. One embodiment uses a spool valve to modulate the flow from the pump. Spool valves typically consist of a cylinder housed in a case. The case contains a system of valves that connect to a reservoir and pump on one side. The spools in the valve slide or rotate in the system in response to fluid flow levels to either open or block channels. The fluid from the reservoir flows through the open channels. Typically, spool valves have a controller device that actuates the valve to rotate the spools into the necessary position. FIG. 6 shows an example of this type of system.

(18) In FIG. 7, the motor/pump 40 would connect to the reservoir of material or reservoirs of materials. The controller 46 may control the pump/motor and/or the valve 42. The fluid then flows out of the extrusion head 44 in response to the pressure. In one embodiment, a pressure modulation cycle of 18 milliseconds (msec) is used.

(19) FIG. 8 shows graphical representations of downstream paste pressure responses for rapid partial strokes. Paste #1 is a functional paste in this embodiment, and #2 is a sacrificial paste. Curve 50 is the pressure of paste #1, and curve 52 is for paste #2.

(20) Another embodiment may employ a rotary motor to drive a cam, which in turn would drive a piston. Another piston embodiment may use a linear, moving-coil actuator that would require a mechanical linkage to produce enough force to push on the high pressure paste.

(21) Other variations and modifications exist. The embodiments up to this point have assumed that the materials reside adjacent to each other laterally. It is also possible that the materials can be stacked vertically. Further, the vertical thickness of the materials may be of any thickness. Typically, the thickness may be approximately 10 microns or greater.

(22) It will be appreciated that several of the above-disclosed and other features and functions, or alternatives thereof, may be desirably combined into many other different systems or applications. Also that various presently unforeseen or unanticipated alternatives, modifications, variations, or improvements therein may be subsequently made by those skilled in the art which are also intended to be encompassed by the following claims.