Flat soft magnetic powder and production method therefor

Abstract

Provided is a flaky soft magnetic powder composed of an FeSiAl alloy containing Si: 5.5 to 10.5 mass %, Al: 4.5 to 8.0 mass %, and Fe and incidental impurities: balance, wherein the flaky powder exhibits a ratio (D.sub.50/TD) of 35 to 92 where D.sub.50 represents the average particle size (m) of the powder and TD represents the tap density (Mg/m.sup.3) of the powder, and the flaky powder exhibits a coercive force of 239 to 479 A/m as measured under application of a magnetic field in an in-plane direction of the flaky powder. The flaky soft magnetic powder exhibits superior sheet formability and has high magnetic permeability.

Claims

1. A flaky soft magnetic powder comprising an FeSiAl alloy containing Si: 5.5 to 10.5 mass %, Al: 5.5 to 8.0 mass %, and Fe and incidental impurities: balance, wherein the flaky powder exhibits a ratio (D.sub.50/TD) of 40 to 92 where D.sub.50 represents the average particle size (m) of the powder and TD represents the tap density (Mg/m.sup.3) of the powder, and the flaky powder exhibits a coercive force of 239 to 479 A/m as measured under application of a magnetic field in an in-plane direction of the flaky powder.

2. The flaky soft magnetic powder according to claim 1, wherein the coercive force as measured under application of a magnetic field in a thickness direction of the flaky powder is 2 to 4.5 times the coercive force as measured under application of a magnetic field in an in-plane direction of the flaky powder.

3. The flaky soft magnetic powder according to claim 1, wherein the flaky powder exhibits a half width of the strongest XRD peak (2=442) of 0.3 to 0.6.

4. A method of producing the flaky soft magnetic powder according to claim 1, the method comprising the steps of: preparing a raw material powder by any process selected from water atomization, gas atomization, disk atomization, and grinding after melt-alloying; flattening the raw material powder; and heat-treating the flattened powder at 200 to 500 C. under vacuum or in an argon or nitrogen atmosphere.

5. The flaky soft magnetic powder according to claim 1, wherein the flaky powder exhibits a ratio (D.sub.50/TD) of 55 to 92.

Description

DESCRIPTION OF EMBODIMENTS

(1) Flaky Soft Magnetic Powder

(2) The flaky soft magnetic powder of the present invention is composed of an FeSiAl alloy containing Si, Al, and Fe and incidental impurities (balance). The Si content is preferably 5.5 to 10.5 mass %, more preferably 6.5 to 9.5 mass %. An Si content of less than 5.5 mass % leads to a very high magnetocrystalline anisotropy constant, resulting in reduced magnetic permeability of the magnetic sheet. An Si content exceeding 10.5 mass % leads to a very high hardness of particles of the powder. This excessively promotes the miniaturization of crystal grains during the flattening of the powder, resulting in an increase in the coercive force of the powder and thus a reduction in the magnetic permeability of the magnetic sheet. The Al content is preferably 4.5 to 8.0 mass %, more preferably 5.5 to 7.0 mass %. An Al content of less than 4.5 mass % leads to a very high magnetocrystalline anisotropy constant, resulting in reduced magnetic permeability of the magnetic sheet. An Al content exceeding 8.0 mass % leads to a very low saturation magnetic flux density of the flaky powder, resulting in reduced magnetic permeability of the magnetic sheet.

(3) The flaky soft magnetic powder has an average particle size D.sub.50 of preferably 35 to 55 m, more preferably 40 to 50 m. An average particle size D.sub.50 of 35 m or more leads to a high aspect ratio of the flaky powder. This prevents a reduction in real part of magnetic permeability and further improves the magnetic permeability of the magnetic sheet. An average particle size D.sub.50 of 55 m or less can prevent impairment of the formability of the magnetic sheet. In particular, the average particle size is preferably 55 m or less in view of the performance and production cost of the magnetic sheet. If the average particle size is 55 m or less, the resultant magnetic sheet has small surface irregularities; i.e., no special treatment is required for preventing the surface irregularities.

(4) The flaky soft magnetic powder has a tap density TD of preferably 0.6 to 1.0 Mg/m.sup.3, more preferably 0.7 to 0.9 Mg/m.sup.3. The tap density tends to monotonically decrease with the progress of the process. A tap density of 0.6 Mg/m.sup.3 or more leads to shortening of the period of the flattening step, resulting in reduced production cost, and also prevents a decrease in average particles size and an increase in coercive force. A tap density of 1.0 Mg/m.sup.3 or less leads to prevention of an excessive increase in average particle size. Thus, the filling ratio of the flaky powder increases in the magnetic sheet, and the magnetic permeability of the magnetic sheet is further improved. The flaky soft magnetic powder produced under the aforementioned conditions exhibits superior sheet formability and high magnetic permeability.

(5) In the flaky soft magnetic powder of the present invention, the ratio of the average particle size D.sub.50 (m) to the tap density TD (Mg/m.sup.3) (i.e., D.sub.50/TD) is preferably 35 to 92, more preferably 35 to 80, most preferably 40 to 60. A ratio D.sub.50/TD of less than 35 leads to low aspect ratio of the flaky powder and low filling ratio of the powder in the magnetic sheet, resulting in reduced magnetic permeability of the magnetic sheet. A ratio D.sub.50/TD exceeding 92 leads to high aspect ratio of the flaky powder and high filling ratio of the powder in the magnetic sheet, which may result in poor formability of the magnetic sheet.

(6) The flaky soft magnetic powder exhibits a coercive force Hc of preferably 239 to 479 A/m, more preferably 319 to 439 A/m as measured under application of a magnetic field in an in-plane direction of the flaky powder. A coercive force Hc of less than 239 A/m leads to a large imaginary part of complex magnetic permeability (=-j) in a low frequency band, resulting in increased energy loss. A coercive force Hc exceeding 479 A/m leads to a small real part of complex magnetic permeability (=-j), resulting in poor antenna performance.

(7) The coercive force of the flaky soft magnetic powder as measured under application of a magnetic field in a thickness direction of the flaky powder is preferably 2 to 4.5 times, more preferably 2 to 3.5 times, still more preferably 2 to 3 times, the coercive force of the flaky soft magnetic powder as measured under application of a magnetic field in an in-plane direction of the flaky powder. If the ratio of the coercive force in the thickness direction to that in the in-plane direction is 2 or more, the magnetic permeability further increases, whereas if the ratio is 4.5 or less, the sheet formability, which may be impaired by surface protrusions, is maintained.

(8) The flaky soft magnetic powder exhibits a half width of the strongest XRD peak (2=442 of preferably 0.3 to 0.6, more preferably 0.4 to 0.5. A half width of 0.3 or more indicates prevention of a reduction in coercive force Hc caused by excessive heat-treatment. This results in a small imaginary part of complex magnetic permeability (=-j) and reduced energy loss. A half width of 0.6 or less indicates sufficient recovery of lattice defects generated in the powder flattened with an attritor. This results in a large real part and satisfactory antenna performance.

(9) Method of Producing Flaky Soft Magnetic Powder

(10) The method of producing the flaky soft magnetic powder of the present invention involves a step of preparing soft magnetic alloy powder (raw material powder) by, for example, atomization; a step of flattening the raw material powder; and a step of heat-treating the flattened powder under vacuum or in an inert gas atmosphere.

(11) (1) Step of Preparing Raw Material Powder

(12) The flaky soft magnetic powder of the present invention can be prepared by flattening of soft magnetic alloy powder. The soft magnetic alloy powder preferably has high saturation magnetization. In general, an FeSiAl alloy is superior in coercive force and saturation magnetization.

(13) The soft magnetic alloy powder is prepared by any process selected from atomization (e.g., water atomization, gas atomization, or disk atomization) and grinding after melt-alloying. The soft magnetic alloy powder preferably has a low oxygen content. Thus, the soft magnetic alloy powder is preferably prepared by gas atomization, more preferably prepared by use of an inert gas. Although disk atomization can provide the soft magnetic alloy powder without causing any problem, gas atomization is more preferred from the viewpoint of mass productivity.

(14) The flaky powder of the present invention is readily produced by water atomization, gas atomization, disk atomization and/or grinding after melt-alloying. The powder prepared by atomization, which has a substantially spherical shape, is more readily flattened than ground by an attritor treatment. The powder prepared by grinding has a particle size smaller than that of the powder prepared by atomization, and thus barely forms protrusions on the surface of the magnetic sheet.

(15) The soft magnetic alloy powder may have any particle size. The soft magnetic alloy powder may be subjected to classification for adjustment of the average particle size after flattening, removal of particles having high oxygen content, or other productive purposes.

(16) (2) Flattening Step

(17) The soft magnetic alloy powder is then flattened. The powder may be flattened by any known technique using an attritor, a ball mill, a vibration mill or the like. Particularly preferred is an attritor, which has a relatively high ability to flatten the powder. In the case of dry flattening, an inert gas is preferably used. In the case of wet flattening, an organic solvent is preferably used. The organic solvent may be of any type.

(18) The organic solvent is added in an amount of preferably 100 parts by mass or more, more preferably 200 parts by mass or more, relative to 100 parts by mass of the soft magnetic alloy powder. The maximum amount of the organic solvent may be any value. The amount of the organic solvent may be appropriately adjusted in consideration of the balance between productivity and the intended size and shape of the flaky powder. The water content of the organic solvent is preferably 0.002 parts by mass or less relative to 100 parts by mass of the organic solvent for a reduction in the oxygen content of the flaky powder. The organic solvent may be used in combination with a flattening aid. The amount of the flattening aid is preferably 5 parts by mass or less relative to 100 parts by mass of the soft magnetic alloy powder for preventing oxidation.

(19) (3) Heat-Treatment Step

(20) The flattened soft magnetic powder is then heat-treated. The apparatus for heat-treatment may be of any type. The heat-treatment temperature is preferably 200 C. to 500 C., more preferably 350 to 450 C. The heat-treatment performed within such a temperature range can produce flaky soft magnetic powder having reduced coercive force and high magnetic permeability. The heat-treatment is performed for recovering lattice defects generated in the powder flattened with an attritor and reducing the coercive force of the powder. Thus, a temperature lower than 200 C. is insufficient for the heat-treatment. In contrast, the heat-treatment at a temperature exceeding 500 C. may cause sintering of a certain composition of materials, and the resultant coarse lumps may form numerous protrusions on the surface of the sheet. The flattened powder may be heat-treated for any period of time. The heat-treatment period is appropriately determined in consideration of the productivity or the amount of the powder to be treated. The heat-treatment period is preferably within five hours for maintaining the productivity.

(21) The heat-treatment step is preferably performed under vacuum or in an inert gas atmosphere for preventing oxidation. The heat-treatment may be performed in a nitrogen atmosphere in view of surface treatment of the powder. The heat-treatment in a nitrogen atmosphere, however, may cause an increase in coercive force, resulting in magnetic permeability lower than that in the case of heat-treatment under vacuum.

(22) The heat-treatment under vacuum or in an argon or nitrogen atmosphere repairs lattice defects generated in the powder flattened with an attritor to recover the magnetic permeability. The heat-treatment in air causes oxidation and fails to produce the powder of the present invention. Thus, the heat-treatment needs to be performed under vacuum or an inert gas atmosphere. The heat-treatment in a nitrogen atmosphere can form a nitride coating to provide the powder with high surface resistance. The use of the powder can reduce the occurrence of eddy currents and can improve the performance of an antenna for 10 MHz or thereabouts (e.g., an antenna for RFID).

(23) The flaky soft magnetic powder of the present invention satisfies the aforementioned ratio of the average particle size D.sub.50 to the tap density TD (D.sub.50/TD) and the aforementioned coercive force as measured under application of a magnetic field in an in-plane direction of the flaky powder. In some cases, surface-treated flaky powder is desired for improving the insulation of the sheet formed from the powder. Thus, a surface treatment step may optionally be added before, during, or after the heat-treatment step. For example, the heat-treatment may be performed in an atmosphere containing a small amount of active gas for surface treatment of the powder.

(24) The flaky powder may be subjected to a traditional surface treatment using a cyan coupling agent for improving the corrosion resistance of the powder or the dispersibility of the powder in rubber. A magnetic sheet can be produced from the flaky powder by any traditional process. For example, the flaky powder is mixed with a solution of chlorinated polyethylene in toluene, the mixture is applied to a substrate and then dried, and the resultant product is compressed with any press or roll, to produce a magnetic sheet.

EXAMPLES

(25) The present invention will now be described in more detail by way of examples.

(26) (1) Preparation of Flaky Soft Magnetic Powder

(27) Powder having a predetermined composition was prepared by any process selected from water atomization, gas atomization, disk atomization, and grinding after melt-alloying, and then subjected to classification, to prepare raw material powder having a particle size of 150 m or less. In the gas atomization process, an alloy was melted in an alumina crucible, the molten alloy was discharged through a nozzle (diameter: 5 mm) disposed below the crucible, and high-pressure argon gas was sprayed to the molten alloy. In the disk atomization process, an alloy was melted in an alumina crucible, the molten alloy was discharged through a nozzle (diameter: 1 to 5 mm) disposed below the crucible, and the molten alloy was dropped onto a disk rotating at a high rate. The rotation rate of the disk was adjusted to 40,000 rpm to 60,000 rpm. The molten alloy was quenched and solidified by the disk to prepare powder.

(28) The resultant raw material powder was then flattened with an attritor. In the flattening process with an attritor, SUJ2 balls (diameter: 4.8 mm) were placed in an agitation vessel, the raw material powder and industrial ethanol were added to the agitation vessel, and an agitation blade was rotated at 300 rpm. The industrial ethanol was added in an amount of 200 to 500 parts by mass relative to 100 parts by mass of the raw material powder. No flattening aid was used, or a flattening aid was added in an amount of 1 to 5 parts by mass relative to 100 parts by mass of the raw material powder. The flattened powder and the industrial ethanol were removed from the agitation vessel and transferred to a stainless steel dish, followed by drying at 80 C. for 24 hours. The flattened powder was heat-treated under vacuum or in an argon or nitrogen atmosphere at 200 to 500 C. for two hours, to produce a flaky soft magnetic powder. The flaky soft magnetic powder was evaluated for the properties described below. Tables 1 and 2 illustrate detailed conditions for preparation of the flaky powder.

(29) (2) Evaluation of Flaky Soft Magnetic Powder

(30) The resultant flaky powder was evaluated for average particle size, tap density, coercive force, and magnetic permeability. The average particle size and the true density were determined by laser diffractometry and the gas replacement method, respectively. For evaluation of the tap density, the flaky powder (about 20 g) was placed in a cylinder (volume: 100 cm.sup.3), and the filling density was determined under the following conditions (drop height: 10 mm, tapping: 200 times). For determination of the coercive force, the flaky powder was placed in a cylindrical resin container having a diameter of 6 mm and a height of 8 mm, and was subjected to the measurement under magnetization in a height direction and a diametrical direction of the container. Since the thickness direction of the flaky powder corresponds to the height direction of the cylindrical container, the coercive force of the flaky powder in a thickness direction is determined under magnetization in the height direction of the container, and the coercive force of the flaky powder in an in-plane direction is determined under magnetization in the diametrical direction of the container. The coercive force was determined under application of a magnetic field of 144 kA/m.

(31) (3) Preparation and Evaluation of Magnetic Sheet

(32) Chlorinated polyethylene was dissolved in toluene, and the flaky powder was dispersed in the solution. The resultant dispersion was applied to a polyester resin (coating thickness: about 100 m) and dried at ambient temperature and humidity, followed by pressing at 130 C. and 15 MPa, to prepare a magnetic sheet having dimensions of 150 mm by 150 mm by 50 m (thickness). The volumetric filling ratio of the flaky powder in the magnetic sheet was about 50%. The magnetic sheet was then cut into a toroidal piece having an outer diameter of 7 mm and an inner diameter of 3 mm. The impedance of the piece was measured with an impedance meter at room temperature and 13.56 MHz. The magnetic permeability (real part of complex magnetic permeability: , imaginary part of complex magnetic permeability: ) was calculated on the basis of the measured impedance.

(33) The present invention should not be limited to the above-described examples. The results of evaluation are illustrated in Tables 1 and 2.

(34) TABLE-US-00001 TABLE 1 Ratio of average particle size Raw material Preparation Rotation Heat- Average D.sub.50 to Aspect powder of rate treatment Heat- particle tap ratio composition raw material of attritor Attrition temperature treatment size density TD: of flaky No (mass %) powder (rpm) time (h) ( C.) atmosphere D.sub.50 (m) D.sub.50 /TD powder 1 Fe9.5Si5.5Al GA 450 3 300 Ar 30 20 2 2 Fe9.5Si5.5Al GA 450 5 300 Ar 32 26 4 3 Fe9.5Si5.5Al GA 450 10 300 Ar 36 33 5 4 Fe9.5Si5.5Al GA 450 12 300 Ar 41 40 9 5 Fe9.5Si5.5Al GA 450 15 300 Ar 46 57 15 6 Fe9.5Si5.5Al GA 450 20 300 Ar 53 88 29 7 Fe9.5Si6.0Al GA 450 3 300 Ar 35 22 3 8 Fe9.5Si6.0Al GA 450 5 300 Ar 41 28 5 9 Fe9.5Si6.0Al GA 450 10 300 Ar 45 30 8 10 Fe9.5Si6.0Al GA 450 12 300 Ar 46 43 11 11 Fe9.5Si6.0Al GA 450 15 300 Ar 51 55 20 12 Fe9.5Si6.0Al GA 450 22 300 Ar 55 90 31 13 Fe9.5Si6.5Al GA 450 3 400 Ar 36 18 3 14 Fe9.5Si6.5Al GA 450 5 400 Ar 40 30 6 15 Fe9.5Si6.5Al GA 450 10 400 Ar 47 45 10 16 Fe9.5Si6.5Al GA 450 12 400 Ar 50 43 11 17 Fe9.5Si6.5Al GA 450 15 400 Ar 55 59 15 18 Fe9.5Si6.5Al GA 450 22 400 Ar 57 95 28 19 Fe6.5Si6.0Al GA 300 15 100 Vacuum 31 60 11 20 Fe6.5Si6.0Al GA 300 15 200 Vacuum 35 55 18 21 Fe6.5Si6.0Al GA 300 15 300 Vacuum 44 58 30 22 Fe6.5Si6.0Al GA 300 15 400 Vacuum 33 54 12 23 Fe6.5Si6.0Al GA 300 15 500 Vacuum 41 57 15 24 Fe6.5Si6.0Al GA 300 15 600 Vacuum 45 60 27 25 Fe6.5Si6.0Al GA 300 15 800 Vacuum 35 62 15 26 Fe6.5Si6.0Al GA 300 15 400 N.sub.2 39 58 19 27 Fe5.5Si6.0Al GA 300 15 400 Vacuum 47 54 23 28 Fe10.5Si7.0Al GA 300 15 400 Vacuum 40 54 13 29 Fe6.5Si4.5Al GA 300 15 400 N.sub.2 50 55 19 30 Fe6.5Si8.0Al GA 300 15 400 N.sub.2 55 60 23 Ratio of coercive force Real Imaginary in thickness part of part of Ratio of Thickness Coercive direction complex complex complex of force to coercive Half width of magnetic magnetic magnetic flaky Oxygen Nitrogen in in-plane force in strongest permeability permeability permeability powder content content direction in-plane XRD peak of of sheet of sheet No (m) (mass %) (ppm) (A/m) direction (2 = 44 2) sheet () () tan (/) 1 18 0.06 15 240 1.25 0.30 65 12 0.185 2 6.2 0.11 20 260 1.54 0.35 92 20 0.217 3 4.5 0.12 19 290 1.85 0.36 108 25 0.231 4 3.1 0.15 20 320 2.00 0.38 115 18 0.157 5 2.5 0.22 22 365 2.70 0.42 112 20 0.179 6 1.5 0.37 38 405 2.23 0.45 100 22 0.220 7 16 0.05 18 142 1.15 0.28 85 23 0.271 8 5.9 0.09 21 158 1.38 0.32 120 21 0.175 9 4.7 0.11 22 185 2.49 0.37 128 19 0.148 10 2.9 0.12 21 210 2.50 0.40 145 32 0.221 11 2.5 0.2 25 250 3.70 0.41 132 18 0.136 12 1.3 0.34 40 283 2.42 0.39 102 8 0.076 13 9 0.05 14 140 0.85 0.30 70 15 0.214 14 5.8 0.12 18 155 1.90 0.32 102 20 0.196 15 3.4 0.15 20 195 1.84 0.34 110 22 0.200 16 2.1 0.14 23 208 2.70 0.40 140 28 0.200 17 1.9 0.24 27 260 4.50 0.38 142 13 0.092 18 1.4 0.35 39 370 2.00 0.35 113 24 0.212 19 3.4 0.30 25 209 1.20 0.71 66 12 0.182 20 2.2 0.31 28 250 2.10 0.50 120 14 0.117 21 1.5 0.24 24 245 2.50 0.40 110 13 0.118 22 3.2 0.26 25 242 3.0 0.38 108 11 0.102 23 2.5 0.28 26 217 2.4 0.36 110 17 0.155 24 1.5 0.29 28 198 2.1 0.24 120 19 0.158 25 2 0.27 28 200 2.4 0.14 140 22 0.157 26 2.2 0.31 5000 229 1.80 0.35 124 18 0.145 27 2.1 0.57 31 440 2.10 0.32 90 12 0.133 28 2.3 0.32 29 286 2.41 0.27 120 11 0.092 29 2.2 0.33 6400 310 2.4 0.35 110 14 0.127 30 2.1 0.62 35 500 3.0 0.33 97 13 0.134 Note 1) GA: gas atomization Note 2) DA: disk atomization Note 3) WA: water atomization Note 4) Underlined numerals fall outside the scope of the present invention

(35) TABLE-US-00002 TABLE 2 Ratio of average particle size Raw material Preparation Rotation Heat- Average D.sub.50 to Aspect powder of rate treatment Heat- particle tap ratio composition raw material of attritor Attrition temperature treatment size density TD: of flaky No (mass %) powder (rpm) time (h) ( C.) atmosphere D.sub.50 (m) D.sub.50 /TD powder 31 Fe3Si GA 450 15 400 Ar 47 30 32 32 Fe3Si GA 450 20 400 Ar 40 32 30 33 Fe6Si GA 450 15 400 Ar 44 35 36 34 Fe6Si GA 450 20 400 Ar 40 37 38 35 Fe10Si GA 450 15 400 Ar 43 33 33 36 Fe10Si GA 450 20 400 Ar 40 35 35 37 Fe10Si2Cr GA 450 10 400 Ar 55 52 28 38 Fe10Si2Cr DA 300 10 400 Vacuum 53 50 30 39 Fe10Si2Cr WA 180 10 400 Air 57 57 22 40 Fe10Si5Cr GA 450 10 300 Ar 52 60 31 41 Fe10Si5Cr DA 300 10 300 Vacuum 55 58 25 42 Fe10Si5Cr WA 180 10 300 Air 56 58 32 43 Fe4.5Si3.5Al GA 450 15 400 Ar 35 55 30 44 Fe4.5Si9.0Al GA 450 15 400 Vacuum 40 52 28 45 Fe11.5Si3.5Al GA 450 15 400 Ar 28 60 25 46 Fe11.5Si9.0Al GA 450 15 400 Vacuum 30 58 30 Ratio of coercive force Real Imaginary in thickness part of part of Ratio of Thickness Coercive direction complex complex complex of force to coercive Half width of magnetic magnetic magnetic flaky Oxygen Nitrogen in in-plane force in strongest permeability permeability permeability powder content content direction in-plane XRD peak of of sheet of sheet No (m) (mass %) (ppm) (A/m) direction (2 = 44 2) sheet () () tan (/) 31 1.9 0.32 25 1100 1.90 0.41 120 20 0.167 32 1.3 0.41 22 1200 1.50 0.36 105 21 0.200 33 1.5 0.35 23 1450 1.30 0.40 123 25 0.203 34 1.6 0.44 19 1400 1.50 0.44 120 23 0.192 35 0.9 0.34 24 1600 1.44 0.36 125 22 0.176 36 1.2 0.39 25 1650 1.30 0.39 130 27 0.208 37 2.4 0.15 20 280 3.4 0.35 130 24 0.185 38 2 0.12 17 300 3.4 0.38 135 30 0.222 39 1.8 0.72 30 310 2.5 0.38 124 24 0.194 40 2.4 0.17 15 300 2.7 0.41 110 17 0.155 41 2.3 0.15 17 350 2.8 0.44 128 18 0.141 42 1.8 0.59 37 400 2.9 0.48 130 15 0.115 43 2.1 0.14 30 950 1.8 0.44 70 15 0.214 44 2.3 0.16 35 1080 2.0 0.50 94 22 0.234 45 1.8 0.15 36 1050 2.0 0.47 95 25 0.263 46 1.7 0.17 34 1540 1.8 0.51 85 18 0.212 Note 1) GA: gas atomization Note 2) DA: disk atomization Note 3) WA: water atomization Note 4) Underlined numerals fall outside the scope of the present invention

(36) As illustrated in Tables 1 and 2, Nos. 4 to 6, 11, 12, 17, 20 to 22, and 27 to 29 correspond to Examples of the present invention, and Nos. 1 to 3, 7 to 10, 13 to 16, 18, 19, 23 to 26, and 31 to 46 correspond to Comparative Examples.

(37) With reference to Tables 1 and 2, in Comparative Example Nos. 1 and 2, the average particle size D.sub.50 is small, and the aspect ratio of the flaky powder is low, resulting in low magnetic permeability of the magnetic sheet. In addition, the ratio of the average particle size D.sub.50 to the tap density TD is low, and the ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example No. 3, the ratio of the average particle size D.sub.50 to the tap density TD is low, and the ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability.

(38) In Comparative Example No. 7, the ratio of the average particle size D.sub.50 to the tap density TD is low, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In addition, the half width of the strongest XRD peak (2=442) is less than 0.3, which indicates excessive heat-treatment of the flattened powder. This results in very low coercive force Hc. Thus, the imaginary part of complex magnetic permeability is large, and energy loss increases.

(39) In Comparative Example No. 8 (similar to the case of No. 7), the ratio of the average particle size D.sub.50 to the tap density TD is low, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example No. 9, the ratio of the average particle size D.sub.50 to the tap density TD is low, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. In Comparative Example 10, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss.

(40) In Comparative Example Nos. 13 and 14, the ratio of the average particle size D.sub.50 to the tap density TD is low, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example No. 15, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example No. 16, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss.

(41) In Comparative Example No. 18, the ratio of the average particle size D.sub.50 to the tap density TD is high, and the average particle size D.sub.50 is large, probably resulting in poor formability of the magnetic sheet. In Comparative Example No. 19, the average particle size D.sub.50 is small, and thus the aspect ratio of the flaky powder is low, resulting in low magnetic permeability during formation of the magnetic sheet. The coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In addition, the half width of the strongest XRD peak (2=442) exceeds 0.6, which indicates insufficient recovery of lattice defects generated in the powder flattened with an attritor. This results in a small imaginary part and unsatisfactory performance of an antenna.

(42) In Comparative Example No. 23, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. In Comparative Example No. 24, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. In addition, the half width of the strongest XRD peak (2=442) is less than 0.3, which indicates excessive heat-treatment of the flattened powder. This results in very low coercive force Hc. Thus, the imaginary part of complex magnetic permeability is large, and energy loss increases.

(43) In Comparative Example No. 25 (similar to the case of No. 24), the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. In addition, the half width of the strongest XRD peak (2=442) is less than 0.3, which indicates excessive heat-treatment of the flattened powder. This results in very low coercive force Hc. Thus, the imaginary part of complex magnetic permeability is large, and energy loss increases.

(44) In Comparative Example No. 26, the coercive force in the in-plane direction is low, and thus the imaginary part of complex magnetic permeability is large in a low-frequency band, resulting in increased energy loss. The ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example Nos. 31, 32, and 35, the ratio of the average particle size D.sub.50 to the tap density TD is low, the coercive force Hc in the in-plane direction exceeds 479 A/m, and thus the real part of complex magnetic permeability is small, resulting in poor performance of an antenna. In addition, the ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. In Comparative Example Nos. 33, 34, and 36, the coercive force Hc in the in-plane direction exceeds 479 A/m, and thus the real part of complex magnetic permeability is small, resulting in poor performance of an antenna. In addition, the ratio of the coercive force in the thickness direction to that in the in-plane direction is less than 2, resulting in low magnetic permeability. Comparative Example Nos. 37 to 42 correspond to the case of comparison between different FeSiCr alloys. Comparative Example Nos. 43 and 44 correspond to the case of low Si content and low and high Al contents. In each of Comparative Example Nos. 43 and 44, the magnetic permeability of the resultant magnetic sheet is low. Comparative Example Nos. 45 and 46 correspond to the case of high Si content and low and high Al contents. In each of Comparative Example Nos. 45 and 46, the magnetic permeability of the resultant magnetic sheet is low. In contrast, satisfactory effects are achieved in the flaky powders of Example Nos. 4 to 6, 11, 12, 17, 20 to 22, and 27 to 29, which satisfy the conditions of the present invention.

(45) As described above, the real part of magnetic permeability is large and the imaginary part of magnetic permeability is small at 10 MHz or thereabouts (e.g., for RFID) if the ratio of the average particle size D.sub.50 to the tap density TD (D.sub.50/TD) is 35 to 92 and the coercive force as measured under application of a magnetic field in the in-plane direction is 239 to 479 A/m. If the coercive force in the thickness direction is 2 to 4.5 times that in the in-plane direction, sufficiently high complex magnetic permeability is achieved, and the formation of protrusions is reduced on the surface of the magnetic sheet. In the case where the half width of the strongest XRD peak (2=442) is 0.3 to 0.6, superior effects (e.g., high complex magnetic permeability) are obtained.