A COATED STEEL SUBSTRATE

Abstract

A coated steel substrate including a coating including nanographite having a lateral size between 1 and 60 m and a binder, wherein the steel substrate has the following compositions in weight percent: 0.31C1.2%, 0.1Si1.7%, 0.7Mn3.0%, P0.01%, S0.1%, Cr0.5%, Ni0.5%, Mo0.1%, and on a purely optional basis, one or more elements such as Nb0.05%, B0.003%, Ti0.06%, Cu0.1%, Co0.1%, N0.01%, V0.05%, the remainder of the composition being made of iron and inevitable impurities resulting from the elaboration; and a method for the manufacture of the coated steel substrate.

Claims

1-24. (canceled)

25: A coated steel substrate comprising: a steel substrate; a coating including nanographite flakes having a lateral size between 1 and 60 m; and a binder, wherein the steel substrate has a composition in weight percent as follows: 0.31C1.2%, 0.1Si1.7%, 0.7Mn3.0%, P0.01%, S0.1%, Cr0.5%, Ni0.5%, Mo0.1%, and on a purely optional basis, at least one of the following: Nb0.050%, B0.003%, Ti0.06%, Cu0.1%, Co0.1%, N0.01%, V0.05%, a remainder of the composition being made of iron and inevitable impurities resulting from processing.

26: The coated steel substrate as recited in claim 25 wherein the lateral size of the nanoparticles is between 20 and 55 m.

27: The coated steel substrate as recited in claim 26 wherein the lateral size of the nanoparticles is between 30 and 55 m.

28: The coated steel substrate as recited in claim 25 wherein a thickness of the coating is between 10 and 250 m.

29: The coated steel substrate as recited in claim 25 wherein the steel substrate is a slab, a billet or a bloom.

30: The coated steel substrate as recited in claim 25 wherein the binder is sodium silicate or the binder includes aluminum sulfate and an additive being alumina.

31: The coated steel substrate as recited in claim 25 wherein the coating further comprises an organometallic compound.

32: The coated steel substrate as recited in claim 31 wherein the organometallic compound includes Dipropylene glycol monomethyl ether (CH.sub.3OC.sub.3H.sub.6OC.sub.3H.sub.6OH), 1,2-Ethanediol (HOCH.sub.2CH.sub.2OH) and 2-ethylhexanoic acid, manganese salt (C.sub.8H.sub.16MnO.sub.2).

33: A method for the manufacture of the coated steel substrate as recited in claim 25, the method comprising the successive following steps: providing the steel substrate; and depositing an aqueous mixture on the steel substrate to form the coating.

34: The method as recited in claim 33 further comprising drying of the coating.

35: The method as recited in claim 33 wherein the depositing is performed by spin coating, spray coating, dip coating or brush coating.

36: The method as recited in claim 33 wherein the aqueous mixture includes from 1 to 60 g/L of nanographite and from 150 to 250 g/L of binder.

37: The method as recited in claim 33 wherein the aqueous mixture includes nanographite with above 95% by weight of C.

38: The method as recited in claim 37 wherein the aqueous mixture includes an amount of C equal or above to 99% by weight.

39: The method as recited in claim 33 wherein a ratio in weight of nanographite with respect to binder is below or equal to 0.3.

40: The method as recited in claim 33 wherein the aqueous mixture includes an organometallic compound.

41: The method as recited in claim 40 wherein a concentration of the organometallic compound is equal or below to 0.12 wt. %.

42: The method as recited in claim 34 wherein the drying is performed at a temperature between 50 and 150 C.

43: The method as recited in claim 34 wherein the drying is performed at room temperature.

44: The method as recited in claim 34 wherein the drying is performed with hot air.

45: The method as recited in claim 34 wherein the drying is performed for 5 to 60 minutes.

46: A method for manufacture of a hot rolled steel product, the method comprising the following successive steps: providing the coated steel substrate as recited in claim 25; reheating the coated steel substrate in a reheating furnace at a temperature between 750 and 1300 C.; descaling of the reheated coated steel sheet; and hot-rolling the descaled steel product.

47: The method as recited in claim 46 wherein the reheating is performed at a temperature between 800 and 1300 C.

48: The method as recited in claim 46 wherein the descaling is performed using water under pressure or the descaling is performed mechanically.

49: The method as recited in claim 46 wherein the descaling is performed using the water under pressure, the pressure being between 100 and 150 bars.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0025] To illustrate the invention, various embodiments and trials of non-limiting examples will be described, particularly with reference to the following Figure:

[0026] FIG. 1 illustrates an example of coated steel substrate according to the present invention.

[0027] FIG. 2 illustrates an example of a nanographite coating over a steel substrate according to the present invention.

[0028] Other characteristics and advantages of the invention will become apparent from the following detailed description of the invention.

DETAILED DESCRIPTION

[0029] The invention relates to a coated steel substrate comprising a coating comprising nanographite having a lateral size between 1 and 60 m and a binder, wherein the steel substrate has the following compositions in weight percent: [0030] 0.31C1.2%, [0031] 0.1Si1.7%, [0032] 0.7Mn3.0%, [0033] P0.01%, [0034] S0.1%, [0035] Cr0.5%, [0036] Ni0.5%, [0037] Mo0.1%, [0038] and on a purely optional basis, one or more elements such as [0039] Nb0.05%, [0040] B0.003%, [0041] Ti0.06%, [0042] Cu0.1%, [0043] Co0.1%, [0044] N0.01%, [0045] V0.05%, [0046] the remainder of the composition being made of iron and inevitable impurities resulting from the elaboration.

[0047] Without willing to be bound by any theory, it seems that a coating comprising nanographite having a lateral size between 1 and 60 m and a binder on a steel substrate having the above specific steel composition reduces the decarburization during the reheating of the coated steel substrate. The inventors have found that not only the steel composition but also the nature of coating plays an important role on the reduction or the elimination of steel decarburization during the heating treatment.

[0048] Indeed, it seems that there is a competition between oxidation and decarburization kinetics during the reheating. For the above specific steel substrate (5), the formation of iron of the steel into scale reduces the decarburized layer. Additionally, as illustrated in FIG. 1, it is believed that in the coating (1) nanographite flakes (2) having the specific lateral size are well dispersed into the binder (3) forming a tortuous path (4) allowing a carburization of the decarburized areas. Indeed, it seems that there is a carbon restoration due to the presence of nanographite having the specific lateral size into the coating.

[0049] Regarding the chemical composition of the steel, preferably, the C amount is between 0.31 and 1.0% by weight.

[0050] Preferably, the Mn amount is between 0.9 and 2.5% and preferably between 1.1 and 2.0% by weight.

[0051] Advantageously, the amount of Cr is below or equal to 0.3% by weight.

[0052] Preferably, the amount of Ni is below or equal to 0.1% by weight.

[0053] Advantageously, the amount of Mo is below or equal to 0.1%.

[0054] FIG. 2 illustrates an example of nanographite flake according to the present invention. In this example, the lateral size means the highest length of the nanoplatelet through the X axis and the thickness means the height of the nanoplatelet through the Z axis. The width of the nanoplatelet is illustrated through the Y axis.

[0055] Preferably, the lateral size of the nanoparticles is between 20 and 55 m and more preferably between 30 and 55 m.

[0056] Preferably, the thickness of the coating is between 10 and 250 m. For example, the thickness of the coating is between 10 and 100 m or between 100 and 250 m.

[0057] Advantageously, the steel substrate is a slab, a billet or a bloom.

[0058] Preferably, the binder is sodium silicate or the binder includes aluminum sulfate and an additive being alumina. In this case, without willing to be bound by any theory, it seems that the coating according to the present invention better adheres on the steel substrate so that the steel substrate is even more protected.

[0059] Thus, the risk of coating cracks and coating detachment, exposing the steel substrate to decarburization, is further prevented.

[0060] Preferably, the coating further comprises an organometallic compound. For example, the organometallic compound includes Dipropylene glycol monomethyl ether (CH.sub.3OC.sub.3H.sub.6OC.sub.3H.sub.6OH), 1,2-Ethanediol (HOCH.sub.2CH.sub.2OH) and 2-ethylhexanoic acid, manganese salt (C.sub.8H.sub.16MnO.sub.2). Indeed, without willing to be bound by any theory, it is believed that the organometallic compound allows for a fast curing of the coating avoiding a drying step at high temperature.

[0061] The invention also relates to a method for the manufacture of the coated steel substrate according to the present invention, comprising the successive following steps: [0062] A. The provision of a steel substrate having the above steel composition, [0063] B. The coating deposition using an aqueous mixture to form the coating and [0064] C. Optionally, the drying of the coated steel substrate obtained in step B).

[0065] Preferably, in step B), the deposition of the coating is performed by spin coating, spray coating, dip coating or brush coating.

[0066] Advantageously, in step B), the aqueous mixture comprises from 1 to 60 g/L of nanographite and from 150 to 250 g/L of binder. More preferably, the aqueous mixture comprises from 1 to 35 g/L of nanographite.

[0067] Preferably, in step B), wherein the aqueous mixture comprises nanographite comprising above 95% and advantageously 99% by weight of C.

[0068] Advantageously, in step B), the ratio in weight of nanographite with respect to binder is below or equal to 0.3.

[0069] Preferably, in step B), the aqueous mixture comprises an organometallic compound. More preferably, the concentration of the organometallic compound is equal or below to 0.12 wt. %. Indeed, without willing to be bound by any theory, it is believed that this concentration allows for an optimized coating without any curing or with a curing at room temperature.

[0070] In a preferred embodiment, the coating is dried in a step C). Without willing to be bound by any theory, it is believed that the drying step allows for an improvement of the coating adhesion. Indeed, since water evaporates, the binder becomes tackier and more viscous leading to a hardened condition. In a preferred embodiment, in step C), the drying is performed at room temperature or a temperature between 50 and 150 C. and preferably between 80 and 120 C.

[0071] In another preferred embodiment, no drying step is performed.

[0072] Preferably, in step C), when a drying is applied, the drying step is performed with hot air.

[0073] Advantageously, in step C), when a drying is applied, the drying is performed during 5 to 60 minutes and for example, between 15 and 45 minutes.

[0074] The invention also relates to a method for manufacture of a Hot rolled steel product comprising the following successive steps: [0075] I. The provision of the coated steel substrate according to the present invention, [0076] II. The reheating of the coated steel substrate in a reheating furnace at a temperature between 750 and 1300 C., [0077] III. The descaling of the reheated coated steel sheet obtained in step II) and [0078] IV. The hot-rolling of the descaled steel product.

[0079] Preferably, in step I), the reheating is performed at a temperature between 800 and 1300 C., more preferably between 900 and 1300 C. and advantageously between 1100 and 1300 C.

[0080] Advantageously, in step II), the descaling is performed using water under pressure. For example, the water pressure is between 100 and 150 bars. In another embodiment, the descaling is performed mechanically, for example, by scratching or brushing the scale layer.

[0081] With the method according to the present invention, a hot rolled steel product wherein the surface is mainly not decarburized is obtained.

[0082] For example, after the hot-rolling, the hot product can be coiled, cold-rolled, annealed in an annealing furnace and also coated with a metallic coating.

[0083] Finally, the invention relates to the use of a hot rolled steel product obtainable from the method according to the present invention for the manufacture of a part of an automotive vehicle, a rail, a wire or a spring.

[0084] The invention will now be explained in trials carried out for information only.

[0085] They are not limiting.

EXAMPLES

[0086] In Examples, steels substrates having the following steel composition in weight percent were used:

TABLE-US-00001 Steel C Mn Si Cu Cr Ti V Mo Ni 1 0.39 0.673 1.593 0.011 0.036 0.003 0.002 0.001 0.014 2 0.798 1.310 0.446 0.014 0.097 0.0014 0.0026 0.0018 0.016 3 0.901 0.309 0.244 0.017 0.215 0.002 0.002 0.001 0.019

[0087] Trial 1 was casted in the form of slab and Trials 2 and 3 were casted in the form of bloom.

Example 1: Decarburization Test

[0088] For some Trials, steels were coated by spraying an aqueous mixture comprising 30 g/L of nanographite having a lateral size between 35-50 m, a binder being Na.sub.2SiO.sub.3 (sodium silicate) and optionally an organometallic compound being DriCAT onto the steel. Then, optionally, the coating was dried at room temperature or during 30 minutes at 100 C.

[0089] Then, uncoated steels and coated steels were reheated at 1250 C. After the reheating, the trials were analyzed by optical microscopy (OM). 0 means that almost no decarburized areas are present at the trial surface, i.e. almost no decarburization happened, during the reheating and 1 means that a lot of decarburized areas are present at the surface of the trial.

The results are in the following Table 1:

TABLE-US-00002 Reheating step Curing after coating temperature Trials Steels Coating deposition ( C.) time decarburization 1* 1 Aqueous 30 min at 100 C. 1250 3 h 0 mixture 2* 1 Aqueous 30 min at 100 C. 1250 6 h 0 mixture 3 1 1250 3 h 1 4* 2 Aqueous 30 min at 100 C. 1250 2 h 0 mixture 5* 2 Aqueous 30 min at 100 C. 1250 6 h 0 mixture 6* 2 Aqueous No curing 1250 6 h 0 mixture including DriCAT 7* 2 Aqueous Room temperature 1250 6 h 0 mixture including DriCAT 8 2 1250 2 h 1 9* 2 Aqueous 30 min at 100 C. 1250 3 h 0 mixture 10 2 1250 3 h 1 11 3 Aqueous 30 min at 100 C. 1250 3 h 1 mixture 12 3 1250 3 h 1 *according to the present invention.

[0090] For Trials according to the present invention, a very low amount of carbon was removed at the trial surface. On the contrary, for comparative Trials, a lot of decarburized areas were present allowing a change in the microstructure and therefore mechanical properties. Indeed, in the areas where there is a lot of carbon depletion, i.e. decarburized areas, ferrite is formed instead of pearlite.

Example 2: Microhardness Test

[0091] In this case, after the reheating at 1250 C., some Trials were quenched in water to form martensite and the microhardness evolution from the hot steel product surface to a depth of 1500 m was determined by microhardness measurements. Indeed, when martensite is formed, the carbon content of the martensite is directly proportional to the amount of carbon in the microstructure. Therefore, the higher the microhardness is, the higher the carbon content is.

The results are in the following Table 2:

TABLE-US-00003 Reheating step Microhardness (HV) Trials Steels Coating temperature ( C.) time 100 (m) 500 (m) 1000 (m) 1500 (m) 4* 2 Aqueous 1250 2 h 840 840 840 840 mixture 8 2 1250 2 h 280 420 600 700 9* 2 Aqueous 1250 3 h 820 840 900 900 mixture 10 2 1250 3 h 380 640 820 900 *according to the present invention.

[0092] The microhardness of Trials 4 and 9 clearly show that the decarburization was significantly reduced with the coated steel substrate according to the present invention compared to Trials 8 and 10.