Air purification device and process
10792611 ยท 2020-10-06
Assignee
Inventors
Cpc classification
B01D2259/80
PERFORMING OPERATIONS; TRANSPORTING
B01D2257/404
PERFORMING OPERATIONS; TRANSPORTING
B01D53/323
PERFORMING OPERATIONS; TRANSPORTING
B01D53/885
PERFORMING OPERATIONS; TRANSPORTING
B01D2257/708
PERFORMING OPERATIONS; TRANSPORTING
International classification
B01D50/00
PERFORMING OPERATIONS; TRANSPORTING
B01D53/32
PERFORMING OPERATIONS; TRANSPORTING
B01D53/02
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A device and a process used to purify air from pollutants are disclosed. The device has at least one empty body defining a chamber intended to receive an air flow to be purified and having at least one inlet hole for the air, and at least one outlet hole for the air. The chamber has an electric field generator, at least one photocatalyst, intended to be excited by a luminous radiation, implementing a photocatalysis process, at least one luminous radiation source intended to excite the photocatalyst, and at least one adsorbing material. The electric field generator, the at least one photocatalyst and the at least one adsorbing material are disposed in the chamber in such manner to cooperate.
Claims
1. An apparatus for purifying air from pollutants, the apparatus comprising: at least one empty body defining a chamber adapted to receive an air flow to be purified, the at least one empty body having at least one inlet hole and at least one outlet hole for the air flow, the chamber comprising: an electric field generator internal of the chamber; a luminous radiation source internal of the chamber; a photocatalyst adapted to be excited by luminous radiation from said luminous radiation source so as to cause photocatalysis; a plurality of walls formed of an absorbent material, each of said plurality of walls lying on a plane, wherein said electric field generator and said photocatalyst and said plurality of walls are cooperative with each other internal of the chamber, wherein said plurality of walls are disposed radially around said photocatalyst such that the planes of said plurality of walls converge toward said photocatalyst, said plurality of walls defining a plurality of spaces within the chamber, the at least one inlet hole and the at least one outlet hole being arranged such that the air flow enters the chamber in correspondence to the convergence of the planes of said plurality of walls and passes through the plurality of plurality of spaces and passes outward of the at least one empty body through the at least one outlet hole.
2. The apparatus of claim 1, wherein said photocatalyst comprises a composite material having a photocatalytic material applied on at least a portion of an adsorbing material of said photocatalyst.
3. The apparatus of claim 1, wherein said photocatalyst is disposed on at least one conductive element.
4. The apparatus of claim 1, wherein said electric field generator comprises a first electrode and a second electrode, said photocatalyst being disposed on at least one of the first and second electrodes.
5. The apparatus of claim 1, wherein at least a portion of said plurality of walls comprises activated carbon.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1) Additional features and advantages of the present invention will be more evident from the following description, which has a merely illustrative, not limiting purpose, with reference to the following diagrammatic drawings, wherein:
(2)
(3)
(4)
(5)
EMBODIMENTS OF THE INVENTION
(6)
(7) Said device 1 is formed of an empty body 70 that defines a chamber 60 (see for example
(8) According to an embodiment of the present invention, the empty body of the device comprises a horizontal upper side (that is to say a wall) 70a and a horizontal lower side 70b parallel to the horizontal upper side. The empty body also comprises a lateral side 70c, for example in the case of an empty body having a substantially cylindrical shape, or can comprise more than one lateral side to form an empty prismatic body. The at least one lateral side (wall) is substantially perpendicular to the two horizontal sides, and suitable for connecting said horizontal upper and lower sides. According to a possible embodiment, such as the one shown for example in the attached figures, the empty body 70 is shaped as a parallelepiped having two parallel upper and lower sides (walls) 70a, 70b and four lateral sides (walls) 70c.
(9) Specifically, according to the embodiment shown in the figures, the empty body 70 comprises four lateral walls 70c that extend between the two upper and lower walls 70a, 70b with square shape.
(10) As mentioned above, the shape of the empty body 70 of the device is not limited to this embodiment. In fact, other shapes of the empty body 70 are possible, for example, a prismatic and a cylindrical shape, on condition that a chamber is formed inside the empty body, preferably a single chamber intended to receive the air flow to be purified.
(11) As illustrated in detail below, one of the two horizontal sides, such as for example the upper side 70a, is provided with at least one inlet hole 40, preferably a plurality of inlet holes that let the air to be purified in.
(12) According to a preferred embodiment of the present invention, such an upper side is provided with a fan 41, or similar means for forcedly introducing air inside the empty body, which is preferably positioned inside the chamber, and more preferably inside the chamber in correspondence of the inlet holes of the air. Therefore, air can be introduced in the device thanks to the fan, which generates an incoming air flow.
(13) Specifically, as shown in
(14) According to a preferred embodiment, at least one lateral side (wall), preferably all lateral sides, of the empty body of the device have at least one outlet hole 50, preferably a plurality of outlet holes that let the air out.
(15) In view of the above, the air is introduced in the device according to an incoming air flow, which is substantially perpendicular to the two upper and lower sides 70a, 70b, and comes out of the device through the outlet holes 50, from the lateral walls 70c, according to one or more outgoing flows; said outgoing flows being substantially perpendicular, preferably perpendicular and radial, with respect to the incoming flow.
(16) Means for generating an electric field 20, a photocatalyst 10, a luminous radiation source 11 and an adsorbing material 11 are provided inside the device 1.
(17) In particular, according to the embodiment of
(18) Although not shown in the figures, the device comprises a suitable power supply to supply the necessary voltage to the metal wire.
(19) According to the embodiment shown in
(20)
(21) As mentioned above, according to a possible embodiment, the device comprises a conductive material. For example, the photocatalyst 10 may comprise a composite material with conductive properties.
(22) It must be noted that a photocatalyst material can be applied on the conductive material (for example graphite) and/or on an adsorbing material.
(23) According to a possible embodiment, the photocatalyst 10 comprising a composite material with photocatalytic, adsorbing and conductive properties (diagrammatically indicated in the figures with reference 10a) can correspond to the collecting electrode for the electrofiltration process.
(24) As known, although not shown in the attached figures, also the collecting electrode is suitably connected to the power supply that provides the necessary voltage to generate a potential difference between the two (discharge and collecting) electrodes. According to other embodiments, if the photocatalyst has no conductive properties, the composite material with adsorbing and photocatalytic properties can be positioned on an electrode, for example a plate of metallic material acting as electrode.
(25) An adsorbing material 30 can be seen in the embodiment of
(26) Specifically, such an adsorbing material 30 is disposed radially with respect to the axis that perpendicularly intercepts the two horizontal upper and lower sides of the device 1; according to the embodiment shown in
(27) Such a plurality of walls (filters) of adsorbing material 30 defines a plurality of spaces 31 inside the chamber of the device 1, which are intended to convey the air flow between the walls of adsorbing material 30. Then the air flow comes out of the device 1 passing through the outlet holes 50 provided on the lateral walls 70c of the empty body 70 of the device 1. According to a possible embodiment, as shown in the attached figures, the walls (filters) of adsorbing material are disposed in such manner to be perpendicular to the upper and lower sides (walls) 70a, 70b.
(28) According to the embodiment of
(29) As illustrated above, the air to be purified is extracted with a fan 41 from the space and is introduced in the device 1 from suitable inlet holes 40 obtained on the side (wall) 70a of the empty body 70 of the device 1 whereon the fan 41 is provided.
(30) The air flow is conveyed towards the photocatalyst, and in particular towards the adsorbing, photocatalytic and conductive material 10a, which is subject both to the electric field generated by the metal wire 20a (whereon an electric potential is applied), and to the UV light coming from the UV lamp UV 11a.
(31) As mentioned above, according to a possible embodiment, the adsorbing, photocatalytic and conductive material 10a corresponds to the collecting electrode of an electrofilter (whose discharge electrode is the metal wire 20a).
(32) In this way, the electric field generated by the electrodes (i.e. in this case the metal wire 20a and the adsorbing, photocatalytic and conductive material 10a) induces the collection of pollutants on the adsorbing, photocatalytic and conductive material 10a. The presence of the electrofilter generates ozone and increments the removal of the pollutants. The photocatalysis process by the adsorbing, photocatalytic and conductive material 10a, which is activated by means of a UV lamp 11a, oxides the pollutants (moreover, titanium dioxide (TiO2) also reduces the presence of the ozone), partially regenerating the adsorbing, photocatalytic and conductive material 10a.
(33) The adsorbing material 30, disposed radially to the adsorbing, photocatalytic and conductive material 10a, holds and confines the primary and secondary pollutants inside the device 1. Outlet holes 50 are provided on the lateral walls of the empty body 70 to let the purified air out.
(34)
(35)
(36) As mentioned above, the incoming air flow 42 is generated by extracting the air with a fan 41 from the space and is introduced in the chamber 60 from suitable inlet holes 40 obtained on the side 70a of the empty body 70 of the device 1 whereon the fan 41 is provided.
(37) With reference to
(38)
(39) For the sake of clarity,
(40)
(41) In such an embodiment, the air flow that is purified inside the device 1 comes out from the device with an orthogonal and radial direction with respect to the incoming direction.
(42)
(43) Also
(44) The same figure also shows the fan 41 and the inlet holes 40 to introduce the air inside the chamber 60 of the device 1.
(45) The chamber 60 contains the UVA lamp 11a with relevant support means 12, the plate of adsorbing, photocatalytic and conductive material 10a (of which only small portions are visible in
(46) A plurality of walls of adsorbing material 30 is disposed radially with respect to the direction of the incoming air flow 42, not shown in
(47) As shown in
(48) According to the embodiment of the device 1 of the invention, as shown in
(49) In conclusion, in the device 1 and in the process according to the present invention, a fan 41 or similar means for forcedly introducing the air inside the device generates an air flow that is introduced in the chamber 60 defined by the empty body 70 of the device through the inlet holes 40.
(50) The air flow reaches the photocatalyst and in particular the adsorbing, photocatalytic and conductive material 10a. In such a case, the adsorbing, photocatalytic and conductive material corresponds to the collecting electrode of an electrofilter, so that the electric field induces the collection of pollutants on said adsorbing, photocatalytic and conductive material and on the walls of adsorbing material.
(51) As mentioned earlier, the discharge electrode of the electrofilter is, for instance, a metal wire 20.
(52) The presence of the electrofilter generates ozone and increments the elimination of pollutants. The photocatalysis process by the photocatalyst, which is activated by means of a suitable luminous source, for example, a UV lamp 11a, oxides the pollutants, at least partially regenerating the adsorbing, photocatalytic and conductive material, and the walls (filters) of adsorbing material (for example composed of active carbon).
(53) Preferably, the adsorbing, photocatalytic and conductive material 10a reduces the presence of the ozone generated by the action of the electric field. The adsorbing material 30, for example of the active carbon walls, encloses the primary pollutants (the pollutants that are introduced directly in the space because of the process that produced them) and the secondary pollutants (that is to say by-products of the reactions that take place on the primary pollutants) inside the device.
(54)
(55) The three blocks, which are indicated as ESP, Photocatalyst and Adsorbing Material, diagrammatically indicate the three purification techniques used simultaneously according to the invention, that is to say the electrostatic precipitation (ESP block), the photocatalysis (Photocatalyst) and the adsorption (Adsorbing Material).
(56) The continuous lines indicate the effects of the single techniques, whereas the broken lines represent the connections created between the effects of the different techniques, diagrammatically showing how each of the electrostatic precipitation (ESP), the photocatalysis (Photocatalyst) and the adsorption (Adsorbing Material) has some effects that synergistically interact with the effects of the other techniques.
(57) For example, in
(58) The effects of photocatalysis (Photocatalyst) are summarized in: oxidation of pollutants and destruction of the ozone.
(59) The effects of the third technique, that is to say adsorption (Adsorbing Material), are summarized in: adsorption of the pollutants and adsorption of the ozone.
(60) As shown in the diagram, the capacity of the adsorbing material to adsorb pollutants is incremented by the effects of the electric field used in the electrostatic precipitation. The electric field generates ozone inside the air treated with the electrostatic precipitation (electrofiltration) that is simultaneously destroyed by the photocatalytic action of the photocatalyst and/or adsorbed by the adsorbing material. It must be noted that the photocatalytic action can be also implemented at the level of the ozone already adsorbed by the adsorbing material.
(61) The interactions indicated in the diagram of
(62) For example, the additional effects of the application of an electric field to the photocatalysis (specifically heterogeneous photocatalysis) are: increased efficiency of the catalytic process, generation of activated chemical species, and their confinement inside the device of the invention thanks to the adsorbing properties, which are in turn increased by the synergies between the processes.
(63) Moreover, the association of the photocatalysis (in particular heterogeneous photocatalysis) and of an electric field induced on a solid adsorbing material generates an interaction with a higher adsorbing capacity of the material, regenerating the adsorbing material thanks to the oxidation of the pollutants that are present at adsorbing material level caused by the photocatalysis.