Method of fabricating a turbine engine part

Abstract

A method of fabricating a turbine engine part, the method including fabricating an ingot out of ceramic material of eutectic composition by performing the Czochralski process including putting a seed of the ingot that is to be obtained into contact with a molten bath of a mixture of eutectic composition in order to initiate the formation of the ingot on the seed, the mixture including at least two ceramic compounds; drawing the ingot from the molten bath while imposing on the ingot that is being formed a drawing speed less than or equal to 10 mm/h together with rotation at a speed of rotation less than or equal to 50 rpm; and machining the ingot as fabricated in this way in order to obtain the turbine engine part.

Claims

1. A method of fabricating a turbine engine part, the method comprising: fabricating an ingot out of ceramic material of eutectic composition by performing the Czochralski process comprising the following steps: putting a seed of the ingot that is to be obtained into contact with a molten bath of a mixture of eutectic composition in order to initiate the formation of the ingot on the seed, said mixture comprising at least two ceramic compounds; drawing the ingot from the molten bath while imposing on the ingot that is being formed a drawing speed less than or equal to 10 mm/h together with rotation at a speed of rotation less than or equal to 50 rpm; and machining the ingot as fabricated in this way in order to obtain the turbine engine part, wherein the ingot is drawn from the molten bath along a drawing axis, and wherein a temperature gradient less than or equal to 50 C./mm is maintained in the ingot along the drawing axis, at least in the vicinity of a surface of the molten bath.

2. A method according to claim 1, wherein the eutectic mixture includes alumina.

3. A method according to claim 1, wherein the eutectic mixture includes zirconia.

4. A method according to claim 1, wherein the eutectic mixture includes at least: a rare earth oxide, an aluminum and rare earth garnet RE.sub.3Al.sub.5O.sub.12, or a perovskite REAlO.sub.3, where RE designates a rare earth element.

5. A method according to claim 1, wherein the eutectic mixture is selected from the following mixtures: Al.sub.2O.sub.3ZrO.sub.2, Al.sub.2O.sub.3-YAG, RE.sub.3Al.sub.5O.sub.12Al.sub.2O.sub.3 where RE is a rare element, Al.sub.2O.sub.3RE.sub.3Al.sub.5O.sub.12ZrO.sub.2, and Al.sub.2O.sub.3-YAG-ZrO.sub.2.

6. A method according to claim 1, wherein the ingot being formed is subjected to a drawing speed lying in the range 1 mm/h to 5 mm/h.

7. A method according to claim 1, wherein the ingot being formed is subjected to a speed of rotation lying in the range 1 rpm to 30 rpm.

8. A method according to claim 1, wherein the fabricated part is a turbine engine blade or vane.

9. A method according to claim 1, wherein the fabricated part is a ring sector.

10. A method according to claim 1, wherein the fabricated part is a nozzle.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) Other characteristics and advantages of the invention appear from the following description of particular implementations of the invention, given as nonlimiting examples, and with reference to the accompanying drawings, in which:

(2) FIG. 1 is a flowchart showing the steps performed for fabricating a turbine machine part by a method of the invention;

(3) FIGS. 2A to 2D are diagrams showing an ingot of ceramic material of eutectic composition being drawn in the context of a method of the invention;

(4) FIG. 3 shows the formation of such an ingot in greater detail; and

(5) FIGS. 4 and 5 are photographs of ingots obtained by performing a Czochralski process in the context of a method of the invention.

DETAILED DESCRIPTION OF IMPLEMENTATIONS

(6) FIG. 1 shows two steps. The first step 10 of a method of the invention consists in fabricating an ingot of ceramic material of eutectic composition by performing the Czochralski process. During this step, particular values are used for drawing speed and speed of rotation, in particular in order to control the microstructure of the resulting ingot. The ingot is then machined during a second step 15 in order to form the turbine engine part.

(7) The first step 10 is described below with reference to FIGS. 2A to 2D and 3.

(8) The first step performs a Czochralski process during which a seed 20 of the ceramic material of eutectic composition that is to be obtained is initially put into contact with a molten bath 22 present in a crucible 24 (see FIG. 2A). The seed 20 and the molten bath 22 present the same chemical composition. This chemical composition corresponds to the composition of the ingot that is to be formed. The seed 20 is a little colder than the molten bath 22 (so as to present a temperature gradient at the solid/liquid interface), thereby initiating crystallization of the ingot 26 of the seed 20 when the seed is put into contact with the molten bath 22 (see FIG. 2B). The molten bath 22 solidifies on the seed 20 while keeping the same crystal organization as that of the seed 20 (epitaxy). The drawing of the ingot shown in FIGS. 2B, 2C, and 2D is performed by imposing a nonzero drawing speed on the ingot 26 that is being formed, which speed is less than or equal to 10 mm/h, while also rotating it at a nonzero speed that is less than or equal to 50 rpm. This drawing speed and speed of rotation make it possible to obtain the desired microstructure for the ingot. After drawing, a solid ingot 28 is obtained that is to be machined in order to obtain the turbine engine part. The resulting ingot 28 may be cylindrical in shape, as shown, or in a variant it may be conical in shape. The diameter (greatest transverse dimension) of the resulting ingot 28 may be greater than or equal to 100 mm, for example. The diameter of the resulting ingot 28 can be modified by varying the size of the crucible 24. Also, it is possible to refill the molten bath 22 while drawing the ingot. This serves advantageously to increase the length of the ingot 28 that is drawn. The ingot 28 can be formed without any mold or die, unlike the Bridgman process or the EFG process.

(9) FIG. 3 shows in greater detail the drawing of the ingot by the Czochralski process. The seed 20 is initially put into contact with the molten bath 22 situated in a crucible 24 made of molybdenum, platinum, or iridium, for example. The crucible 24 is placed on a support tray 30. The material for the crucible 24 is selected so as to have a crucible 24 that withstands the high temperatures involved and that does not react with the molten bath 22. During its formation, the ingot is not in contact with the crucible 24 and so there is no need for it to be unmolded. The bath 22 is maintained in the molten state by being heated by a heater device 38, specifically a coil 38 performing heating by induction. In a variant, it would be possible to use resistive heating.

(10) The seed 20 is present on a seed carrier 21, itself connected to a rod 23. The rod 23 is connected to an automatic mover device (not shown) configured to draw the rod 23 along the axis X in the direction T while simultaneously rotating the rod about its axis (rotary movement referenced R in FIG. 3). These movements of the rod 23 are transmitted to the ingot 26 that is being formed, so it is thus drawn along the direction T and simultaneously it is caused to rotate while it is being drawn.

(11) During the drawing, the crucible 24 and also the ingot 26 that is being formed are present in an inside volume V defined by a thermally insulating wall 32. As shown, the wall 32 may present one or more heat screens 34 on its inside surface. The thermally insulating wall 32 and the heat screens 34 serve to control the temperature of the molten bath 22 and of the ingot 26 that is being formed. In particular, at least in the vicinity of the surface S of the molten bath 22, it is possible to maintain a temperature gradient along the drawing axis X in the ingot 26 that is being formed that is less than or equal to 50 C. per millimeter ( C./mm), e.g. less than or equal to 10 C./mm. Such values for the temperature gradient may be maintained over a distance of not less than 40 millimeters (mm), or indeed 50 mm, from the surface S of the bath 22. In particular, it is possible to maintain such values for the temperature gradient over a distance lying in the range 40 mm to 50 mm from the surface S of the molten bath 22. Furthermore, a cooling circuit (not shown) is present around the insulating wall 32 and the heater device 38. By way of example, it is possible to use water as the cooling liquid. It comes within the general competence of the person skilled in the art to adjust the heating, the nature of the thermal insulation 32 and 34, and the cooling to be implemented in order to obtain the above-described values for the temperature gradient.

(12) As mentioned above, the ingot is formed by being drawn from a molten bath 22 of a eutectic mixture comprising at least two different ceramic compounds. By way of example, each of these ceramic compounds may be an oxide, but it would not go beyond the ambit of the invention for that not to be so, as mentioned above. The eutectic mixture may thus be: a eutectic mixture of ceramic oxides; or a eutectic mixture of ceramic carbides; or indeed a eutectic mixture of ceramic nitrides.

(13) During the drawing step, the ingot 26 that is being formed is subjected to a constant drawing speed along the direction T that is less than or equal to 10 mm/h, together with rotary motion R about the axis X at a constant speed of rotation that is less than or equal to 50 rpm. In the example shown, the direction T and the axis X are perpendicular to the surface S of the molten bath 22. The rod 23 is moved along the direction T and is simultaneously rotated about the axis X during the drawing step. Such values for the drawing speed and the speed of rotation make it possible to obtain steady crystallization conditions and thus to obtain the microstructure desired for the part being fabricated, in particular by limiting any unwanted germination that might give rise to defects degrading mechanical performance.

(14) The atmosphere in the inside volume V may be an atmosphere that is inert (argon, dinitrogen). The pressure in the inside volume V may be less than or equal to atmospheric pressure (1 bar). By way of example, it is possible to use an inert gas flow rate of about 1 liter per hour (L/h) through the inside volume, which rate may nevertheless be modified as a function of the nature of the material to be obtained.

(15) As mentioned above, the molten bath 22 may be refilled progressively while the ingot is being drawn so as to obtain an ingot of greater length, thereby making it possible in continuous manner to fabricate ingots that are relatively long.

(16) The resulting crystallized ingot 28 is then machined in order to obtain the final part with the desired shape. By way of example, the machining may be performed using diamond tools. As mentioned above, using the above-described values for drawing speed and speed of rotation serves to concentrate defects in the microstructure at the periphery of the ingot 28, thus enabling them to be eliminated during the machining step. The invention thus makes it possible in relatively simple manner to obtain turbine engine hot parts made out of single-crystal or multi-crystal ceramic material of eutectic composition. Parts fabricated in this way have a microstructure that is controlled, giving them the desired mechanical properties.

Example

(17) Fabricating an Ingot of Al.sub.2O.sub.3-YAG-ZrO.sub.2 of Eutectic Composition

(18) Use was made of an iridium crucible having the following dimensions: diameter 60 mm, height 60 mm, and thickness 1.5 mm. The crucible contained a ternary composition comprising Al.sub.2O.sub.3, Y.sub.2O.sub.3, and ZrO.sub.2.

(19) The composition was prepared by mixing the various ingredients in the following proportions: Al.sub.2O.sub.3 65 molar percent (mol %), Y.sub.2O.sub.3 16 mol %, and ZrO.sub.2 19 mol % followed by high-temperature sintering in order to obtain the following eutectic mixture Al.sub.2O.sub.3-YAG-ZrO.sub.2.

(20) The eutectic mixture obtained in that way was melted by induction heating in order to form the molten bath in the crucible. During the drawing, the crucible 24 was present in the inside volume as defined by a thermally insulating wall provided with a screen.

(21) A seed 20 having the same composition as the molten bath was put into contact with the bath in order to initiate crystallization of the ingot. The molten bath was maintained at a temperature close to 1750 C. during the drawing, and the drawing was carried out in an atmosphere of argon. The seed 20, together with the ingot being formed thereon, were then drawn vertically while imposing a drawing speed of 2 mm/h and a speed of rotation of 2 rpm. A cylindrical ingot 28 was obtained presenting a diameter of about 30 mm and a length of about 60 mm (FIG. 4). The ingot 28 as fabricated in that way was white in color and did not present any visible microscopic defects. X-ray diffraction analysis at ambient temperature (20 C.) revealed the existence of the three phases in the ingot 28: Al.sub.2O.sub.3, YAG, and ZrO.sub.2.

(22) That test was reproduced several times in order to confirm that it is reproducible. FIG. 5 shows the ingot 28 obtained after reiterating that test.

(23) The expression lying in the range . . . to . . . should be understood as including the bounds.