Photonic circuit for measuring a sample
10794825 ยท 2020-10-06
Assignee
Inventors
Cpc classification
G01N2021/458
PHYSICS
International classification
Abstract
A method and system for measuring a sample property (X) by means of photonic circuit (10). The photonic circuit (10) comprises at least two photonic sensors (11, 12) configured to modulate the light according to respective output signals (S1,S2) with periodically recurring signal values (V1, V2). The photonic sensors (11, 12) comprise a low range sensor (11) with a relatively low range or high sensitivity for measuring a change (X) of the sample property (X) and a high range sensor (12) with a relatively high range or low sensitivity to measure the change (X) of the sample property (X). The sample property (X) is calculated by combining the output signals (S1, S2) of the sensors (11, 12). Particularly, the second output signal (S2) of the high range sensor (12) is used to distinguish between recurring signal values (V1) in the first output signal (S1) of the low range sensor (11).
Claims
1. A method for measuring a sample property by a photonic circuit, the method comprising applying an input light into the photonic circuit and measuring an output light out of the photonic circuit; wherein the photonic circuit comprises an at least two photonic sensors configured to interferometrically modulate the output light with respect to the input light according to a respective output signal; wherein a respective signal values of the respective output signals periodically recur as a function of a wavelength of the input light according, to a respective wavelength interval; wherein a wavelength at which the recurring respective signal values occur, shifts according to a respective wavelength shift as a function of change in the sample property to be measured by a corresponding change of effective refractive index for light through at least a portion of the at least two photonic sensors; wherein a relative range of a respective photonic sensor for the sample property is defined by a respective quotient of the respective wavelength interval over the respective wavelength shift for a change in the sample property; wherein the at least two photonic sensors comprise a low range sensor providing a first output signal and a high range sensor providing a second output signal wherein the high range sensor has a higher relative range for the sample property than the low range sensor; wherein the sample property is calculated by combining the output signals of the at least two photonic sensors, wherein the second output signal of the high range sensor is used, to distinguish between recurring signal values in the first output signal of the low range sensor; and wherein the at least two photonic sensors comprise a combination of a multi-path interferometer and a ring resonator, wherein the multi-path interferometer forms the high range sensor and the ring resonator forms the low range sensor.
2. The method according to claim 1, wherein the photonic sensors are calibrated to identify, by measurement of the second output signal, a mode number of a recurring signal value in the first output signal.
3. The method according to claim 1, wherein an actual wavelength or an actual shift of wavelength of the recurring signal value in a particular number mode is calculated by measuring one wavelength at which the recurring signal value occurs in a measured wavelength range of the first output signal and adding an integer number times the wavelength interval of the low range sensor, wherein the integer number is based on the second output signal.
4. The method according claim 1, wherein the sample property is calculated based on a difference of the output signal compared to a reference property.
5. The method according to claim 1, wherein the sample property is calculated based on a wavelength shift of an identifiable signal value in the output signals compared to a reference sample property.
6. The method according to claim 1, wherein the sample property rapidly changes between subsequent measurements such that a wavelength of the recurrences in the first output signal shift more than half the wavelength interval of the low range sensor, wherein the high range sensor is sufficiently insensitive to the changing sample property such that a change in a mode number of recurrences in the first output signal can be identified.
7. The method according to claim 1, wherein the respective wavelength interval is determined by at least one of the group consisting of: a respective dimension of a waveguide forming the photonic sensor, and an effective wavelength of light traversing the waveguide.
8. The method according to claim 1, wherein the wavelength interval of the high range sensor is larger than a wavelength of the input light.
9. The method according to claim 1, wherein the photonic sensors comprise two or more ring resonators with equal path length, and wherein a first ring resonator is made less sensitive to the sample property than another ring resonator of the two or more ring resonators.
10. The method according to claim 1, wherein the photonic sensors comprise multiple low range sensors working together with one high range sensor, and wherein the high range sensor is used to calculate a respective mode number of a recurring signal in each one of the multiple low range sensors.
11. The method according to claim 1, wherein the at least two photonic sensors are configured to modulate an intensity of the output light with respect to the input light depending on the wavelength.
12. The method according to claim 1, wherein the respective quotient indicating the relative range of the high range sensor for the sample property is higher than the respective quotient indicating the relative range of the low range sensor for the sample property by at least a factor ten.
13. A non-transitory computer readable medium comprising computer-executable instructions that, when executed on a computer, cause the execution of a method comprising: measuring a sample property by means of a photonic circuit by applying an input light into the photonic circuit and measuring an output light out of the photonic circuit; wherein the photonic circuit comprises an at least two photonic sensors configured to interferometrically modulate the output light with respect to the input light according to a respective output signal; wherein a respective signal values of the respective output signals periodically recur as a function of a wavelength of the intuit light according to a respective wavelength interval; wherein a wavelength at which the recurring respective signal values occur, shifts according to a respective wavelength shift as a function of change in the sample property to be measured by a corresponding change of effective refractive index for light through at least a portion of the at least two photonic sensors; wherein a relative range of a respective photonic sensor for the sample property is defined by a respective quotient of the respective wavelength interval over the respective wavelength shift for a change in the sample property; wherein the at least two photonic sensors comprise a low range sensor providing a first output signal and a high range sensor providing a second output signal, wherein the high range sensor has a higher relative range for the sample property than the low range sensor; wherein the sample property is calculated by combining the output signals of the at least two photonic sensors, wherein the second output signal of the high range sensor is used to distinguish between recurring signal values in the first output signal of the low range sensor; wherein the at least two photonic sensors comprise a combination of a multi-path interferometer and a ring resonator, wherein the multi-path interferometer forms the high range sensor and the ring resonator forms the low range sensor.
14. A system for measuring a sample property by a photonic circuit, the system comprising: an optical interrogator configured to apply input light into the photonic circuit and measure output light out of the photonic circuit; the photonic circuit comprising an at least two photonic sensors; wherein the at least two photonic, sensors are configured to interferometrically modulate the output light with respect to the input light according to a respective output signal; wherein a respective signal values of the respective output signals periodically recur as a function of a wavelength of the input light according to a respective wavelength interval; wherein a wavelength at which the recurring, respective signal values occur, shifts according to a respective wavelength shift as a function of change in the sample property to be measured by a corresponding change of effective refractive index for light through at least a portion of the photonic sensors; wherein a relative range of a respective photonic sensor for the sample property is defined by a respective quotient of the respective wavelength interval over the respective wavelength shift for a change in the sample property; wherein the at least two photonic sensors comprise a low range sensor providing a first output signal and a high range sensor providing a second output signal, wherein the high range sensor has a higher relative range for the sample property than the low range sensor; and a controller configured to calculate the sample property by combining the output signals of the at least two photonic sensors, wherein the second output signal of the high range sensor is used to distinguish between recurring signal values in the first output signal of the low range sensor; wherein the at least two photonic sensors comprise a combination of a multi-path interferometer and a ring resonator, wherein the multi-path interferometer forms the high range sensor and the ring resonator forms the low range sensor.
Description
BRIEF DESCRIPTION OF DRAWINGS
(1) These and other features, aspects, and advantages of the apparatus, systems and methods of the present disclosure will become better understood from the following description, appended claims, and accompanying drawing wherein:
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DESCRIPTION OF EMBODIMENTS
(9) Terminology used for describing particular embodiments is not intended to be limiting of the invention. As used herein, the singular forms a, an and the are intended to include the plural forms as well, unless the context clearly indicates otherwise. The term and/or includes any and all combinations of one or more of the associated listed items. It will be understood that the terms comprises and/or comprising specify the presence of stated features but do not preclude the presence or addition of one or more other features. It will be further understood that when a particular step of a method is referred to as subsequent to another step, it can directly follow said other step or one or more intermediate steps may be carried out before carrying out the particular step, unless specified otherwise. Likewise it will be understood that when a connection between structures or components is described, this connection may be established directly or through intermediate structures or components unless specified otherwise.
(10) The invention is described more fully hereinafter with reference to the accompanying drawings, in which embodiments of the invention are shown. In the drawings, the absolute and relative sizes of systems, components, layers, and regions may be exaggerated for clarity. Embodiments may be described with reference to schematic and/or cross-section illustrations of possibly idealized embodiments and intermediate structures of the invention. In the description and drawings, like numbers refer to like elements throughout. Relative terms as well as derivatives thereof should be construed to refer to the orientation as then described or as shown in the drawing under discussion. These relative terms are for convenience of description and do not require that the system be constructed or operated in a particular orientation unless stated otherwise.
(11)
(12) Without being bound by theory, the principle on which photonic sensors typically rely are changes of the effective refractive index n.sub.eff of the waveguide mode due to changes in the sample property X to be measured. The changes of the sample property can manifest in corresponding changes of its ambient refractive index n.sub.ambient, which can influence the effective refractive index n.sub.eff of the waveguide mode index e.g. via evanescent field interaction. This can be written as
(13)
where the partial derivative may depend on parameters such as the wavelength and waveguide geometry.
(14) For example, in a ring resonator such as shown in
(15)
in which m is an integer called the mode number, e.g. the number of times the effective wavelength fits in the waveguide. At these resonant wavelengths, the sensor transmission shows a sharp minimum or maximum at these resonance wavelengths, as shown in the plot of the signal S1 versus wavelength . Taking dispersion into account, the shift in resonant wavelengths as a result of a change in n.sub.ambient may be calculated as:
(16)
where n.sub.g is the group index and the n.sub.eff is given by the equation above. Changes in the sample property X can be obtained from changes in the index n.sub.eff which are obtained by measuring consecutive wavelength sweeps and identifying the shifts of the resonance wavelengths in these sweeps.
(17) In the example of
(18)
where L stands for either the sensing window length or arm length difference for equal and unequal arms lengths, respectively. As is clear from this equation, the phase sensitivity scales with L allowing for a tunable high or low sensitivity, corresponding to a low or high range, respectively. As opposed to a conventional 22 MZI, the 33 MZI combines both arms with a 33 coupler resulting in three outputs that have a mutual 120 degrees phase difference. This can have advantages in readout.
(19) Typically, input light Li with an input wavelength .sub.i is coupled into the photonic circuit, e.g. using a Vertical Grating Couplers (VGC) or other type coupler. Output light Lo may similarly be coupled out of the circuit. The output light Lo may comprise as respective signal S.sub.1 or S.sub.2 which may depend on the interaction between the sensor and the sample property X.
(20) For a ring resonator such as shown in
(21) For an MZI such as shown in
(22) In the example of
(23)
where P.sub.n is the output power at output n, P.sub.0 is the total input power, V the fringe visibility, the phase difference and n=1, 2, 3 the path number. The equation contains three unknowns (P.sub.0, V and ), and three values P.sub.n so that each unknown can be solved for. Using the equation and assuming normalized signals, the obtained expression for can be calculated by:
(24)
As opposed to the commonly applied 2-port interferometer, the phase calculation is not sensitive to power or visibility variations. Moreover, the 2-port implementation has zero sensitivity and ambiguous reading when the phase equals an integer times pi, which is not the case for the 3-port implementation.
(25) An important parameter of a photonic sensor with periodic response such as the ring resonator is the free spectral range (FSR) which is the spacing in wavelength between resonances, e.g. written as
(26)
The spacing depends on the wavelength A but this may be negligible at higher mode numbers. Alternatively, the reciprocal wavelength 1/ can be used, in which case the FSR is wavelength independent, and is given by:
(27)
(28) Conventionally, the experimental conditions using ring resonators are kept such that successive spectra do not shift by more than half an FSR, because in that case the actual shift may not be unambiguously determined. A similar problem may occur for other photonic sensors having periodic response such as the MZI. In the latter case, a phase shift of more than 2 may be ambiguous. For example, the observed shift can be the actual shift plus or minus an integer times the FSR. These and other problems may be alleviated using a combination of different sensitivity sensors as described in the following.
(29)
(30) In the embodiment of
(31) In the embodiment of
(32) Typically, a period or wavelength interval between recurring signals is determined by a respective dimension of a waveguide forming the photonic sensor 11,12 and/or an effective wavelength of light traversing the waveguide. For example, the wavelength interval between different recurrences or modes of a ring resonator can be determined by the circumference or path length L.sub.R of the waveguide forming a ring. Resonances typically occur at effective wavelengths .sub.eff fitting an integer times into the ring path length L.sub.R. For example, the wavelength interval between different recurrences or modes in an interferometer such as the MZI can be determined by the path length difference L between arms of the interferometer. The same phase difference of light traveling the different arms typically occurs when the effective wavelength .sub.eff fits an integer times into the path length difference L. The effective wavelengths .sub.eff can e.g. be varied by sweeping the wavelength .sub.i of the input light Li and/or by changes of the effective refractive index n.sub.eff in the waveguide. In some embodiments, the input light Li comprises a spectrum of multiple wavelengths measured simultaneously e.g. by a spectrometer.
(33) In some embodiments, the path length difference L is relatively small, e.g. comparable to or smaller than the effective wavelength .sub.eff or input wavelength .sub.i. In this way a very low sensitivity or very high range sensor 12 can be formed wherein recurrences are far apart, e.g. sufficiently far to uniquely identify a mode number based on a particular phase difference in the second output signal S.sub.2. Alternatively, both paths can be the same length, e.g. wherein the effective refractive index n.sub.eff along one path has a different sensitivity to the sample property X than the other path. For example, one path can be shielded. Preferably, the shielding comprises a cover material with a thickness larger than a penetration depth of an evanescent field between the waveguide and sample. In some embodiments, the wavelength interval of the high range sensor 12 may be larger than a wavelength i of the input light Li to uniquely determine the mode number of the low range sensor 11 or provide an absolute (low sensitivity or high range) measurement of the sample property X.
(34) In some embodiments, as shown in
(35) In a preferred embodiment, as shown in
(36) In some embodiments, a single input port Pi is used for coupling light into both the high and high range sensors. For example, in
(37) In some embodiments (not shown), the photonic sensors comprise multiple low range or high sensitivity sensors working together with one high range or low sensitivity sensor. For example, the high range sensor is used to calculate the mode number of a recurring signal in each of the low range sensors. The low range sensor need not all have the same sensitivity or range. In some embodiments a combination of two, three, four, or more sensors is used, wherein different sensors can have different ranges and/or sensitivities. For example, one multi-path interferometer, preferably an MZI employing at least one 33 MMI, may act as a high range sensor to distinguish recurring signal values in a plurality of low range ring resonators, having the same or different sensitivities. Because of the small size of the ring resonators compared to the multi-path interferometer, the combination may provide a large number of sensors on a relatively small foot print while distinguishing recurring signal values of the ring resonators.
(38) One embodiment for measuring a sample property X by means of photonic circuit 10 comprises applying input light Li into the photonic circuit 10 and measuring output light Lo out of the photonic circuit 10. Typically, the photonic sensors 11,12 are configured to modulate an intensity of the output light Lo with respect to the input light Li depending on the wavelength .sub.i. Alternatively, or in addition, depending on the optical circuit also other properties of the light may be modulated such as wavelength or polarization. As described herein, the photonic circuit 10 comprises at least two photonic sensors 11,12 configured to modulate the output light Lo with respect to the input light Li according to a respective output signal S.sub.1,S.sub.2.
(39)
(40) In sensors having periodic responses S.sub.1, S.sub.2 as shown in
(41) As described herein, two or more photonic sensors may be combined, each having at least some sensitivity to the same sample property X but to a different degree. Preferably, the sensors 11,12 are relatively close together, e.g. within a distance of ten millimeter, one millimeter, hundred micrometer, or less. In a preferred embodiment, the sensors comprise a high range sensor 12 for measuring changes X of the sample property X over a relatively high range. The high range sensor 12 may complement a low range sensor 11 having a relatively low range for measuring the same changes X of the sample property X, typically with a relatively high sensitivity.
(42) In some embodiments, the sensitivity of the low range sensor 11 is relatively high and the sensitivity of the high range sensor 12 is relatively low. For example, as shown in
(43) In some embodiments, such as
(44) Typically, the low range sensor, as described herein, is a high-sensitivity sensor having a periodic response to the change of the sample property. This may cause (realistic) sample property changes to result in sensor response changes larger than the periodicity. In some embodiments, the low range sensor, as described herein, is a relatively low or reduced-sensitivity sensor, which may or may not have a periodic response to the change of the sample property, such that the sample property changes result in non-ambiguous sensor response changes.
(45) Generally, the unambiguous range of a respective periodic photonic sensor can be described by
(46)
where is the sensor periodicity, and S is the sensor transfer function efficiency. For a ring resonator, S=d/dX with d the wavelength shift of a resonance induced by a sample property change dX. For an MZI, S=d/dX, with d is the phase shift induced by a sample property change dX.
(47) Preferably, the quotient .sub.2/S.sub.2 of the high range sensor 12 is more than the quotient .sub.1/S.sub.1 of the low range sensor 11, e.g. by factor two, four, ten, twenty, or more.
(48) For example, in an MZI, the sensitivity X (the smallest detectable sample property change) can be described using X=p/S=(/).Math.X.sub.max=(/2).Math.X.sub.max. The phase sensitivity is typically determined by the read-out hardware and/or software and the signal-to-noise ratio, and typically independent of the MZI design parameters such as the Free Spectral Range. Consequently, a good sensitivity (small X) is in this case associated with a small unambiguous range X.sub.max,
(49) For example, in a ring resonator, the sensitivity can be described using X=(/).Math.X.sub.max, where the wavelength sensitivity is again typically determined by the read-out hardware and/or software and the signal-to-noise ratio. The sensitivity scales with the periodicity , which is a ring resonator design parameter, so that a considerable unambiguous range X.sub.max can be obtained even at a small X. In some embodiments, it is envisaged to increase X.sub.max at small X beyond what is possible in practice by increasing the Free Spectral Range . For example, a large value for is obtained at a small ring circumference, which can be limited by the minimum waveguide bending radius at which waveguide losses are acceptable.
(50) As described herein, the sample property X is calculated by combining the output signals S.sub.1,S.sub.2 of the at least two photonic sensors 11,12. In particular, the second output signal S.sub.2 of the high range sensor 12 can be used to distinguish between recurring signal values V.sub.1 in the first output signal S.sub.1 of the low range sensor 11. For example, as illustrated at the bottom of
(51) In some embodiments, the photonic sensors 11,12 are calibrated to identify, by measurement of the second output signal S.sub.2, a mode number m.sub.a1, m.sub.a, m.sub.a1 of a recurring signal value V.sub.1 in the first output signal S.sub.1. In the embodiments, as shown in
(52) In some embodiments, as shown in
(53) In some embodiments, as shown in
(54) In one embodiment, the sample property X is calculated based on a difference of the output signal S.sub.1,S.sub.2 compared to a reference property X[0]. For example, a current sample property X[t] is calculated based on a difference between a current set of output signals S.sub.1,S.sub.2 corresponding to the current sample property X and a reference set of output signals S.sub.1,S.sub.2 corresponding to a reference sample property X[0]. Typically, the sample property X is measured as a function of time t. For example, the reference set of output signals S.sub.1,S.sub.2 are the output signals of the sample property X measured at a previous time t=0. For example, differences in the output signals are correlated to differences in the refractive index n0,nt at different times and corresponding differences of the sample property X as a function of time t. In one embodiment, the sample property X is calculated based on a wavelength shift .sub.1, .sub.2 of an identifiable signal value V.sub.1,V.sub.2 in the output signals S.sub.1,S.sub.2 compared to the reference sample property X[0]. For example, the identifiable signal value V.sub.1,V.sub.2 comprises a lowest signal value of a resonance peak or a particular phase of the output signal S.sub.1,S.sub.2.
(55) In some embodiments, the sample property X rapidly changes between subsequent measurements X[0],X[t] such that a wavelength .sub.res of the recurrences in the first output signal S.sub.1 shift more than half the wavelength interval .sub.1 of the low range sensor 11. For example, relatively large changes of refractive index may occur over a short time when the photonic circuit 10 is put in a different medium, e.g. different media to be measured or from air into a liquid medium. Preferably, the high range sensor 12 is sufficiently insensitive to the changing sample property X such that a change in mode number M of a recurrences in the first output signal S.sub.1 can be identified.
(56) Preferably, comparative measurements X[0],X[t] of the second output signal S.sub.2 are kept within range of the second wavelength interval .sub.2 of the high range sensor 12, more preferably less than half the second wavelength interval .sub.2. For example, in
(57)
(58) In the embodiment shown, the system 100 comprises an optical interrogator 21,22 configured to apply input light Li into the photonic circuit 10 and measure output light Lo out of the photonic circuit 10. As described herein, the photonic circuit 10 comprising two or more photonic sensors. The photonic sensors are configured to modulate the output light Lo with respect to the input light Li according to a respective output signal S.sub.1,S.sub.2. Respective signal values of the respective output signals S.sub.1,S.sub.2 periodically recur as a function of a wavelength .sub.i of the input light Li according to a respective wavelength interval .sub.1,.sub.2. A wavelength or phase at which the recurring signal values V.sub.1,V.sub.2 occur, shifts according to a respective wavelength shift as a function of change X in the sample property X to be measured. The photonic circuit 10 comprises at least a low range sensor 11 having relatively low range to the change X of the sample property X and a high range sensor 12 having relatively high range to the change X of the sample property X.
(59) The system 100 may comprise a controller 30 to perform operational acts in accordance with the methods as described herein. In one embodiment, the controller 30 is configured or programmed to calculate the sample property X by combining the output signals S.sub.1,S.sub.2 of the at least two photonic sensors 11,12. Particularly, the second output signal S.sub.2 of the high range sensor 12 is used to distinguish between recurring signal values in the first output signal S.sub.1 of the low range sensor 11.
(60) In one embodiment, the system 100 comprises a light source 21 configured to direct the input light Li into the photonic circuit 10. In another or further embodiment, the system 100 comprises a light sensor 22 configured to measure the output light Lo from the photonic circuit 10. In some embodiments, the system 100 comprises a wavelength control unit 31 configured to set a wavelength of the input light Li.
(61) In the embodiment shown, the controller 30 comprises signal processors 32-38 to determine the sample property from the signals S1,S2. While the processors are illustrated as separate blocks, some or all of their functionality can be integrated or combined. As shown, the signal processor 32 is configured to process the first output signal S.sub.1 for determining a perceived wavelength .sub.res,t of a recurring signal value, e.g. resonance dip. The signal processor 33 is configured to calculate a perceived wavelength shift .sub.resM.Math..sub.1 based on the perceived wavelength .sub.res,t and a reference wavelength .sub.res,0. The signal processor 34 is configured to process the second output signal S.sub.2 for determining the second signal value V.sub.2 e.g. phase t. The signal processor 35 is configured to calculate a mode number M based on the second output signal S.sub.2 e.g. by comparing the phase .sub.t to a reference .sub.0. The signal processor 36 configured to calculate an actual wavelength shift .sub.res based on the perceived wavelength shift .sub.resM.Math..sub.1 in the first output signal S.sub.1 and the mode number M based on the second output signal S.sub.2. The signal processor 37 is configured to calculate a change X in the sample property X based on the actual wavelength shift .sub.res and e.g. a calibration constant Cx, function, or lookup table. The signal processor 38 is configured to calculate the sample property X[t] based on a reference value X[0] and the change X.
(62) The signal processors or other parts of the system may be implemented in hardware or software. In one aspect, the present disclosure may be embodied as a non-transitory computer readable medium comprising software instructions that when executed on a computer, cause the execution of a method as described herein
(63) For the purpose of clarity and a concise description, features are described herein as part of the same or separate embodiments, however, it will be appreciated that the scope of the invention may include embodiments having combinations of all or some of the features described. For example, while embodiments were shown for specific sensors and signals, also alternative ways may be envisaged by those skilled in the art having the benefit of the present disclosure for achieving a similar function and result. E.g. different photonic circuits may be combined or some of their components split up into one or more alternative components. The various elements of the embodiments as discussed and shown offer certain advantages, such as combining measurements from two sensors using the low range sensor for accurate measurement and the high range sensor for disambiguation of its periodic dependence. Of course, it is to be appreciated that any one of the above embodiments or processes may be combined with one or more other embodiments or processes to provide even further improvements in finding and matching designs and advantages. It is appreciated that this disclosure offers particular advantages to enable the use of high sensitive periodic sensors for tracking rapidly changing experimental conditions or even to perform an absolute measurement of the refractive index without reference by uniquely identifying mode numbers.
(64) In interpreting the appended claims, it should be understood that the word comprising does not exclude the presence of other elements or acts than those listed in a given claim; the word a or an preceding an element does not exclude the presence of a plurality of such elements; any reference signs in the claims do not limit their scope; several means may be represented by the same or different item(s) or implemented structure or function; any of the disclosed devices or portions thereof may be combined together or separated into further portions unless specifically stated otherwise. Where one claim refers to another claim, this may indicate synergetic advantage achieved by the combination of their respective features. But the mere fact that certain measures are recited in mutually different claims does not indicate that a combination of these measures cannot also be used to advantage. The present embodiments may thus include all working combinations of the claims wherein each claim can in principle refer to any preceding claim unless clearly excluded by context.