Systems and methods for providing fluid lighteners while reducing downhole emulsifications

Abstract

Various embodiments provide methods and systems for providing fluid lighteners for use in downhole wells. The fluid lighteners may include one or more viscosifiers, one or more aphron generators, and a location-specific non-emulsifying surfactant.

Claims

1. A method of treating servicing mud used in downhole drillout and cleanout operations at a well site after a reservoir stimulation process has been completed where the servicing mud is circulated between above-ground equipment and a cased wellbore having a maximum allowable downhole pressure gradient, the method comprising: determining surfactant requirements needed to reduce downhole emulsifications by analyzing samples of fluids produced at the well site or fluids having similar characteristics thereto; creating a fluid lightener to add to a servicing fluid that maintains a fluid weight of the servicing fluid that does not overcome the maximum allowable downhole pressure gradient, the creating comprising: providing an aqueous base fluid at the well site; adding a viscosifier to the base fluid to achieve low shear rate viscosity; adding an aphron generator to the viscosified base fluid and agitating to generate aphrons in the viscosified base fluid; and adding a non-emulsifying surfactant to the viscosified base fluid to reduce the risk of downhole emulsions; injecting the fluid lightener into the servicing fluid to reduce a fluid density of the servicing fluid for cleaning the cased wellbore while simultaneously reducing downhole emulsifications of oil and water.

2. The method of claim 1 wherein the viscosifier is xanthan gum.

3. The method of claim 1 wherein the aphron generator contains ethylene glycol monobutyl ether.

4. The method of claim 1 wherein after the agitating the viscosified base fluid is 10-15% aphrons by volume.

5. The method of claim 1 wherein the non-emulsifying surfactant contains diethanolamine.

6. The method of claim 1 wherein the non-emulsifying surfactant contains methanol and isopropyl alcohol.

7. A method of treating servicing mud used in downhole drillout and cleanout operations at a well site after a reservoir stimulation process has been completed where the servicing mud is circulated between above-ground equipment and a cased wellbore having a maximum allowable downhole pressure gradient, the method comprising: determining surfactant requirements to reduce downhole emulsifications by analyzing samples of fluids produced at a well site or a well site having similar characteristics; creating a fluid lightener to add to a servicing fluid that maintains a fluid weight of the servicing fluid that does not overcome the maximum allowable downhole pressure gradient, the creating comprising: providing an aqueous base fluid at the well site; adding a viscosifier to the base fluid to achieve low shear rate viscosity; adding an aphron generator to the viscosified base fluid and agitating to generate aphrons in the viscosified base fluid; adding a first non-emulsifying surfactant to the viscosified base fluid; and adding a second non-emulsifying surfactant to the viscosified base fluid if required to reduce downhole emulsifications; injecting the fluid lightener into the servicing fluid to reduce a fluid density of the servicing fluid for cleaning the cased wellbore while simultaneously reducing downhole emulsification of oil and water; and adding a breaker to the servicing fluid.

8. The method of claim 7 wherein the viscosifier is xanthan gum added to the base fluid at a ratio of 0.3-0.7 lb/bbl.

9. The method of claim 7 wherein the viscosifier added to the base fluid increases the viscosity of the base fluid to approximately 50,000 cPs.

10. The method of claim 7 wherein the aphron generator is a fluid added to the viscosified base fluid at a ratio of approximately 4-10 gal/100 bbl and comprising at least 15% ethylene glycol monobutyl ether, at least 10% methanol, and at least 5% isopropyl alcohol.

11. The method of claim 7 wherein after the agitating the viscosified base fluid is 10-15% aphrons by volume.

12. The method of claim 7 wherein the first non-emulsifying surfactant contains diethanolamine.

13. The method of claim 7 wherein the first non-emulsifying surfactant is diethanolamine added to the to the viscosified base fluid at a ratio of approximately 2-10 gal/100 bbl.

14. The method of claim 7 wherein the second non-emulsifying surfactant contains methanol and isopropyl alcohol.

15. A method of treating servicing mud used in downhole drillout and cleanout operations at a well site after a reservoir stimulation process has been completed where the servicing mud is circulating between above-ground equipment and a cased wellbore having a maximum allowable downhole pressure gradient, the method comprising: obtaining samples of fluids produced at a well site or a well site having similar characteristics; determining surfactant requirements to reduce downhole emulsifications by analyzing the samples; providing a first non-emulsifying surfactant and a second non-emulsifying surfactant; creating a fluid lightener comprising an aqueous base fluid, a viscosifier, and an aphron generator; adding either the first non-emulsifying surfactant or the second non-emulsifying surfactant to the fluid lightener based at least in part on the determined surfactant requirements; and adding the fluid lightener to well servicing mud being used to drillout plugs disposed in the wellbore in a subterranean formation, the fluid lightener configured to maintain a fluid weight of the well servicing mud that does not overcome the maximum allowable downhole pressure gradient while simultaneously reducing downhole emulsification of oil and water.

16. The method of claim 15 wherein the viscosifier is xanthan gum.

17. The method of claim 15 wherein the aphron generator contains ethylene glycol monobutyl ether.

18. The method of claim 15 and further comprising agitating the aqueous base fluid, viscosifier, and aphron generator to generate 10-15% aphrons by volume.

19. The method of claim 15 wherein the first non-emulsifying surfactant contains diethanolamine.

20. The method of claim 15 wherein the second non-emulsifying surfactant contains methanol and isopropyl alcohol.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) A more complete understanding of the method and apparatus of the present invention may be obtained by reference to the following Detailed Description when taken in conjunction with the accompanying Drawings wherein:

(2) FIG. 1 is a flowchart of a method according to an exemplary embodiment;

(3) FIG. 2 is a flowchart of a method according to an exemplary embodiment; and

(4) FIGS. 3A-3C are examples of testing downhole fluids.

DETAILED DESCRIPTION

(5) The present invention is directed towards systems and methods for providing fluid lighteners and, more particularly, to systems and methods for providing fluid lighteners for downhole operations.

(6) In some embodiments, the fluid lighteners may be utilized where reservoir stimulation processes, including, for example, hydraulic fracturing, have been completed and where a servicing fluid will be introduced inside a cased hole where the removal of frac plugs, sand, and/or bi-products of prior drilling and completion servicing operations may be necessary to enhance the ultimate production of oil and gas. In some embodiments, the servicing fluid may reduce the occurrence and/or severity of downhole emulsifications in the reservoir and/or reservoir damage from losses of the circulating servicing fluid to the reservoir. In some embodiments, the servicing fluid may maintain a fluid weight that does not overcome the maximum allowable downhole pressure gradient. In some embodiments, a well drillout and cleanout fluid is provided comprising a base liquid, a first type of a surfactant, a second type of surfactant, a solvent, and other additives. In some embodiments, the drillout and cleanout fluid may comprise an aqueous liquid having a water-soluble polymer hydrated therein and a surfactant. In some embodiments, the base liquid may be fresh water, saturated brine, cut brine, re-processed produced water, Potassium Chloride (KCl), Calcium Chloride (CaCl), and/or produced water.

(7) The term surfactant, as used herein, refers to compounds having an amphiphilic structure which gives them a specific affinity for oil/water-type and water/oil-type interfaces which helps the compounds to reduce the free energy of these interfaces and to stabilize the dispersed phase of a microemulsion. The term surfactant encompasses cationic surfactants, anionic surfactants, amphoteric surfactants, nonionic surfactants, zwitterionic surfactants, and mixtures thereof. In some embodiments, the surfactant is a nonionic surfactant, which generally do not contain any charges. Amphoteric surfactants generally have both positive and negative charges, however, the net charge of the surfactant can be positive, negative, or neutral, depending on the pH of the solution. Anionic surfactants generally possess a net negative charge. Cationic surfactants generally possess a net positive charge. The term surface energy, as used herein, refers to the extent of disruption of intermolecular bonds that occur when the surface is created (e.g., the energy excess associated with the surface as compared to the bulk). Generally, surface energy is also referred to as surface tension (e.g., for liquid-gas interfaces) or interfacial tension (e.g., for liquid-liquid interfaces). Surfactants generally orient themselves across the interface to minimize the extent of disruption of intermolecular bonds (i.e., lower the surface energy). Typically, a surfactant at an interface between polar and non-polar phases orient themselves at the interface such that the difference in polarity is minimized.

(8) In some embodiments, the first and/or second surfactant may be a blend of anionic and non-ionic surfactants and co-surfactants in an aqueous solution that provide low-shear-rate viscosity (LSRV) and encapsulate air in the fluid creating micro-bubbles. In some embodiments, the first surfactant may be a viscosifier, such as, for example, Xanthan gum, commonly referred to as XC. Depending on the chemical properties of the base fluid and/or the wellbore fluid, the viscosifier may be a dried XC or may be a liquid XC. For example, in embodiments needing less and/or slower hydration, a dried XC may be utilized. In some embodiments, the XC may be a dried material suspended in oil. In some embodiments, the second surfactant may be an aphron generator comprising ethylene glycol monobutyl ether (EGMBE) (e.g., 15-20%); methanol (e.g., 10-30%); and isopropyl alcohol (e.g., 5-10%) may be added to generate aphrons with conventional mixing and surface equipment rigs. Once the base fluid has been built to a minimum LSRV of, for example, 50,000 cPs, the aphron generator may be added through the mud hopper. The air, shear, and pressure drop associated with mixing through the hopper may be used to create a 10-15% volume of aphrons in the base fluid. The concentration of aphron-generating surfactant required is generally less than the critical micelle concentration (CMC) of the surfactant or surfactant mixture. An indication of the volume of aphrons generated can be obtained by determining the density reduction which occurs upon generating the aphrons in the fluid. Foaming of the fluid, which is undesirable, can occur if the concentration of aphron-generating surfactant is excessive. Typically, the concentration of surfactant can be increased as the LSRV increases. Thus, the concentration of aphron-generating surfactant is the amount required to generate sufficient aphrons to give the density reduction desired but insufficient to create a long-lasting foam on the surface of the fluid.

(9) In some embodiments, a de-emulsifying surfactant may be used in conjunction with the aphron generator on clean outs to help eliminate emulsion between the water and oil and between the aphron-containing fluid and the oil. In some embodiments, one or more de-emulsifying surfactants may be added to a sample of production fluid and tested at temperatures approximating downhole temperatures to determine which de-emulsifying surfactant(s) should be added to the base fluid. In some embodiments, the de-emulsifying surfactant may include a solvent, a co-solvent, or a mutual solvent, which, when combined with other additives, may enhances the shell structure of micro-bubbles to reduce permeability of the shell. In some embodiments, the solvent may be selected from the group comprising: short chain alcohols, methanol, ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, dipropylene glycol monomethyl ether, triethylene glycol, ethylene glycol monobutyl ether (EGMBE), tetrahydrofuran, dioxane, dimethylformamide, and dimethylsulfoxide.

(10) In some embodiments, the de-emulsifying surfactant may include diethanolamine, which may include compounds such as Cocamide, which is derived in part from coconut oil. Cocamide is the structural basis of many surfactants. Common are ethanolamines (cocamide MEA, cocamide DEA), betaine compounds (cocamidopropyl betaine), and hydroxysultaines (cocamidopropyl hydroxysultaine). Cocamide DEA, or cocamide diethanolamine, is a diethanolamide made by reacting the mixture of fatty acids from coconut oils with diethanolamine. It is a viscous liquid and is used as a foaming agent in products like shampoos and hand soaps, and in other products as an emulsifying agent. Cocamide is a mixture of amides manufactured from the fatty acids obtained from coconut oil.

(11) The alcohol, or combination of alcohols, may serve as a coupling agent between the solvent and the surfactant and aid in the stabilization of the aphron-containing fluid. In some embodiments, the alcohol is selected from primary, secondary, and tertiary alcohols having between 1 and 20 carbon atoms. Non-limiting examples of alcohols include methanol, ethanol, isopropanol, n-propanol, n-butanol, i-butanol, sec-butanol, iso-butanol, and t-butanol. In some embodiments, the alcohol is ethanol or isopropanol. In some embodiments, the alcohol is isopropanol. In some embodiments, the de-emulsifying surfactant may include an alcohol blend of methanol and iso-propyl alcohol which have low grade surfactant properties, but also act as solvents in many fluid additives. In some embodiments, it may include a linear alcohol ethoxylate surfactant. Alcohol ethoxylates (AE) and alcohol ethoxysulfates (AES) are surfactants found in products such as laundry detergents, surface cleaners, cosmetics, agricultural products, textiles, and paint. Alcohol ethoxylate based surfactants are non-ionic. Examples synthesized on an industrial scale include octyl phenol ethoxylate, polysorbate 80 and poloxamers. Ethoxylation is commonly used to increase water solubility. They often feature both lipophilic tails and relatively polar headgroups. AES generally are linear alcohols, which could be mixtures of entirely linear alkyl chains or of both linear and mono-branched alkyl chains. An example of these is sodium laureth sulfate a foaming agent in shampoos and liquid soaps, as well as industrial detergents.

(12) In accordance with the embodiment shown in FIG. 1, the method (100) of using a fluid lightener may begin at step 102 and proceed to a testing phase (104), an initial build phase (106), a maintenance phase (110), and a sweeps phase (112). During the testing phase (104), samples of fluids produced from the stimulated wellbore are analyzed to determine, among other things, water type and surfactant requirements to reduce downhole emulsifications during the application of the servicing fluid. In embodiments where the servicing fluid is needed prior to production, for example in an initial drillout phase, samples of fluids may be taken from nearby wellbores having the same or similar characteristics, for example from the same formation.

(13) Referring now to FIGS. 3A-3D, samples of fluids at various points in an embodiment of a method for testing and analyzing fluid samples are shown. In various embodiments, the testing process begins by obtaining samples of produced oil from the well head (or a nearby well head), produced water from the well head (or a nearby well head), and preparing a fluid lightener with and/or without a non-emulsifying surfactant. In the embodiment shown in FIG. 3A, the samples may be used to prepare four mixtures using various combinations of the samples. For example, Mix 1 (1A) may be formed from a mixture of the produced water (or fresh/brine water, if produced water is unavailable) and the fluid lightener, such as, for example, an aphron-containing fluid lightener, with and/or without a non-emulsifying surfactant. In various embodiments, equal parts of the produced water and fluid lightener may be mixed together, such as, for example, 50 mL of water and 50 mL of fluid lightener with non-emulsifying surfactant. Mix 2 (2A) may be the same as Mix 1 with the addition of produced oil. In the embodiment shown, equal parts of each component have been added to Mix 2 (e.g., 50 mL of water, 50 mL of fluid lightener with non-emulsifying surfactant, and 50 mL of oil). In some embodiments, Mix 2 may be formed by combing the produced oil and the produced water with the fluid lightener without the non-emulsifying surfactant. Mix 3 (3A) may be formed by combining the fluid lightener with non-emulsifying surfactant with the sample of produced oil. In some embodiments, Mix 3 may be formed by combing the produced oil and the fluid lightener without the non-emulsifying surfactant. In the embodiment shown, equal parts of each have been added to Mix 3 (e.g., 50 mL of oil and 50 mL of fluid lightener). Mix 4 (4A) is formed by combining the produced oil with the produced water. In the embodiment shown, equal parts of oil and water have been added (e.g., 50 mL of oil and 50 mL of water). In some tests, more or less of each component may be added, the ratios of each component may be varied, the volumes of each component may be varied, some components may be left out and/or other components may be added. For example, in some embodiments, a first non-emulsifying surfactant may be added to the fluid lightener used in one or more tests and/or one or more mixtures, a second non-emulsifying surfactant may be added to the fluid lightener used in one or more tests and/or one or more mixtures, or the fluid lightener used in one or more tests and/or one or more mixtures may not include a non-emulsifying surfactant.

(14) Next, the mixtures may be vigorously agitated. As part of the testing, in some embodiments, the mixtures may be tested at or near the downhole temperature in order to obtain results approximating downhole conditions. In some embodiments, the mixtures may be observed immediately after agitation and/or heating or may be placed in a roller oven and heated (e.g., 160° F.) and rolled to simulate downhole conditions, and observed at various time intervals (e.g., immediately and again at 1 hr, 4 hrs, 12 hrs, 24 hrs, etc.) for emulsion breaking in the mixtures. After agitations, all four mixtures may contain emulsions and/or be in suspension. As can be seen in FIG. 3B, after a first time interval, for example, of heating and rolling, Mix 1 (1B) and Mix 3 (3B) remain thoroughly mixed, while Mix 2 (2B) and Mix 4 (4B) have begun to separate. In particular, in Mix 2, the emulsion has separated into three layers, with the oil layer on top, the water+fluid lightener layer on bottom, and an emulsion in a middle layer. In Mix 4, the emulsion has begun to separate into an oil layer on top and a water layer on bottom, but some oil remains in the bottom layer and some water remains in the top layer.

(15) As can be seen in FIG. 3C, after additional time has passed, Mix 1 (1C) and Mix 3 (3C) remain thoroughly mixed, while Mix 2 (2C) and Mix 4 (4C) have almost completely separated. In particular, in Mix 2, the emulsion has separated into an oil layer on top and a water+fluid lightener and non-emulsifying surfactant layer on bottom. In Mix 4, the emulsion has separated into an oil layer on top and a water layer on bottom. Although FIGS. 3A-3C show exemplary test results, many different results at different times and in different orders may be observed depending on the characteristics of the oil, water, fluid lightener, and/or non-emulsifying surfactant used. For example, in some embodiments, the emulsion of Mix 3 may separate out before, at the same time, or after the emulsions of Mix 2 and/or Mix 4 break. In some embodiments, Mix 4 (oil+water) may be utilized as a reference sample. Although not shown in the figures, in some embodiments, sand and other sediment and debris may settle out from the samples during the testing process. Based on the observations made during the testing phase, a combination of chemicals and/or surfactants can be optimized for the wellbore where the samples were taken (or a nearby wellbore). For example, if the emulsions break quickly (for example, of Mixes 2 and/or 3 as compared to the reference sample (Mix 4)), a non-emulsifying surfactant may not be needed or less of the non-emulsifying surfactant may be needed. As another example, if the emulsions break slowly (for example, as compared to the reference sample), a non-emulsifying surfactant may be needed, more of the non-emulsifying surfactant may be needed, or a different non-emulsifying surfactant may be needed. As another example, if a first non-emulsifying surfactant causes the emulsions to break faster than a second non-emulsifying surfactant, it may be desirable to use the first non-emulsifying surfactant. The testing may include inspecting for the presence of emulsions and determining the chemical and rheological properties of the fluid. In various embodiments, the properties tested may include weight (lb/gal); funnel viscosity (sec/qt); plastic velocity (cP); yield point (lb/100 ft.sup.2); gel strength (10 sec/10 min) (lb/100 ft.sup.2); mud gradient (psi/ft); API filtrate (mL/30 min); LCM (lb/bbl) (in/out); cake thickness (API/HTHP); solids (% by vol uncorrected); oil content (% by vol); water content (% by vol); sand content (% by volume); pH (whole mud/filtrate); alkalinity (Pm); Chlorides (mg/L); total hardness (mg/L); Iron, PPM (mg/L); low gravity solids (% by vol); low gravity solids (lb/bbl); and/or other measurements.

(16) Referring again to FIG. 1, during the initial build phase (106), one or more of the base fluid, preservatives, a pH control, polymers, surfactants, specialty chemicals, a fluid lightener, and/or lubricants may be added in a mixing process that exposes the ingredients to atmospheric pressure for the purpose of creating aphrons (i.e., an air and water emulsion). Referring now to FIG. 2, a fluid lightening method (200) is provided. At a beginning step (202), a base fluid is added to a mixing pit. In some embodiments, the base fluid may be fresh water. In a preferred embodiment, the base fluid does not include a friction reducer and may be a low chloride solution. In other embodiments, the base fluid may be brine. Next, a viscosifier is added to the base fluid (204). Next, an aphron generator is added to the mixture (206) and the mixture is agitated to stimulate the formation of microbubbles, for example, the mixture may be agitated for less than 5 minutes, between 5 and 30 minutes, or more than 30 minutes. Next, the aphron containing fluid is transferred to a supply tank (210) and a non-emulsifying surfactant is added (212) to strengthen the wall coat of the aphron bubbles. In some embodiments, the non-emulsifying surfactant may be added before the fluid is transferred to the supply tank. In various embodiments, a lower grade XC may be added to strengthen the bubble carrier. Next, the solution is added to the production mud (214) and the aphron-containing mud is circulated downhole.

(17) Referring back to FIG. 1, once the mud is circulating downhole, the maintenance phase (110) begins. During the maintenance phase, the fluid characteristics and properties achieved as a result of the chemicals added to the base fluid during the initial build phase (106) are monitored (108) and adjusted as needed due to, for example, variability of downhole conditions. Referring again to FIG. 2, when the aphron-containing mud returns to the surface, it is filtered (216), such as with a shaker, and a sample of the filtered fluid is taken at various intervals and tested (218). Depending on the test results, additional fluid from the supply barrel may be added to the mud and/or the rate of fluid addition may be increased or decreased, or additional chemicals may be added (220).

(18) Referring back to FIG. 1, during the sweeps phase (112), in addition to increasing, decreasing, and/or changing the amounts of chemicals previously added (e.g., during the initial build phase) and/or adding other chemicals to perform a sweep by changing the fluid profile. If, for example, production decreases, a sweep may be needed. Flow regimes are characterized by the relative amount of swirling or chaotic motion as the fluid moves along the pipe. Downhole fluid may have, in general, different flow regimes, such as laminar flow and turbulent flow. In between each zone, there is a transition zone where the flow regimes are changing. Laminar flow, which generally exists at the low shear rates encountered in the annulus, is the uniform movement of fluid elements parallel to the walls of the flow channel. A laminar regime flows smoothly with instabilities being dampened by the viscosity. Laminar flow usually occurs at a low flow velocity and it is best understood by considering mud as being layers of fluid flow. The velocity of the mud farthest away from any surface is moving the fastest and the velocity of a layer adjacent a surface moves slower. For the laminar flow, the flow has a predictable pattern, and the shear rate is a function of the shear stress of the fluid. Turbulent flow is an erratic, nonlinear flow of a fluid, caused by high velocity and low viscosity. Fluid moving in a turbulent flow region is subject to random local fluctuations in both the direction of flow and fluid velocity. During operations, it is often desirable to maintain laminar flow. The viscosity describes the measure of a fluid's resistance to flow. The flow of liquid through a pipe is resisted by viscous shear stresses within the liquid and the turbulence that occurs along the internal walls of the pipe which is created by the roughness of the pipe material. This resistance is usually known as pipe friction and is measured in feet head of the fluid, thus the term “head loss” is also used to express the resistance to flow. Simply stated, the less viscous the fluid, the greater its ease of movement through the pipe.

(19) In the sweeps phase (112), an operator displaces the lateral with a breaker by, for example, increasing or decreasing the viscosity of at least a portion of the circulating fluid to cause a transition from laminar flow to turbulent flow. In some embodiments, fresh water (or other fluid having a low viscosity relative to the fluid in circulation) may be added to the circulating fluid to lower the viscosity and create turbulent flow to sweep or scour the downhole surfaces. In some embodiments, a breaker, such as Ammonium Persulfate, may be added to the circulating fluid to “eat” the XC to change the viscosity and create the turbulent sweep. In other embodiments, turbulent flow may be created by adding additional viscosifier to the circulating fluid. In some embodiments, the amount of modified fluid needed may be, for example, less than 10 bbl, between 10-15 bbl, or more than 15 bbl, and may vary depending on various fluid and downhole characteristics in order to cause a transition from laminar flow to turbulent flow. In some embodiments, a dye may be added to the modified fluid to provide a visual indicator when the modified fluid has returned to the surface.

(20) Returning now to FIG. 2, in various embodiments, a base fluid is first modified with a viscosifier (204) to provide sufficient polymer loading. The viscosifier is added prior to the aphron-generating fluid lightener (206) to help maintain the integrity of the bubbles created by the fluid lightening additive in order to maintain the air and water emulsion while the servicing fluid is circulated to assist in cleaning the hole. The aphron generator creates microbubbles to lighten the fluid and the microbubbles are protected and enabled by first viscosifying the base fluid. In various embodiments, the viscosifier may provide sufficient protection of the aphron microbubbles to allow continued recirculation downhole. The aphrons are non-coalescing and recirculatable so that density reduction may be accomplished without expensive air or gas injection. In other embodiments, a surfactant may be added (212) after the aphron generator is added to the viscosified fluid in order to enhance the microbubbles and help lower friction pressure by reducing surface tension. In some embodiments, the surfactant may be a non-emulsifying surfactant to reduce the occurrence or severity of the downhole emulsion of oil and water while the servicing fluid is being circulated. The servicing fluid is then able to successfully circulate through the wellbore and clean the wellbore without overcoming the downhole pressure gradient and while simultaneously reducing downhole emulsification of oil and water. In one embodiment, the fluid lightener may include the following chemicals added to the base fluid:

(21) TABLE-US-00001 Generic Chemical Name Units Viscosifier Xanthan Gum 0.25-2.5 lb/bbl Surfactant Anionic Surfactant 0.25-20 gal/100 bbl Aphron Generator EGMBE 1-20 gal/100 bbl Preservative Methyl Alcohol 1-5 gal/100 bbl Biocide Gluteraldehyde 1-15 gal/100 bbl Colored Dye Marker Colored Dye 1-128 oz/100 bbl Non-Emulsifying Surfactant Diethanolamine .25-20 gal/100 bbl

(22) In other embodiments, the concentrations and amounts may be varied according to the following chart:

(23) TABLE-US-00002 Generic Chemical Name Units Viscosifier Xanthan Gum 0.3-1.5 lb/bbl Surfactant Anionic Surfactant 1.5-2 gal/100 bbl Aphron Generator EGMBE 4-10 gal/100 bbl Preservative Methyl Alcohol 1-2.5 gal/100 bbl Colored Dye Marker Colored Dye 5-7 oz/100 bbl Non-Emulsifying Surfactant Diethanolamine 2.0-10.0 gal/100 bbl Biocide Gluteraldehyde 1-5 gal/100 bbl

(24) In some embodiments, additional chemicals may be added to the base fluid depending on the needs of the well. For example, a water-based mud anti-foamer specifically formulated for use in aphron-containing water-based fluids may be necessary to treat surface foams without removing the aphrons from the system. These chemicals may include the following:

(25) TABLE-US-00003 Generic Chemical Name Units Shale Stabilizer Potassium Chloride 2000-35000 ppm Torque Reduction CoPolymer Beads 0.2-5 lb/bbl Oxidizing Agent (breaker) Ammonium Persulfate 0.1-10 lb/1000 gal Defoamer Defoamer 0.1-0.5% by volume pH Control CaOH— 7-10.5 pH Metal Binder Iron Fix 2-10 gal/100 bbl Corrosion Inhibitor Phosphate Ester 1-10 gal/100 bbl Remove Sulfites from Triazine 1-10 gal/100 bbl System

(26) In other embodiments, the concentrations and amounts may be varied according to the following chart:

(27) TABLE-US-00004 Generic Chemical Name Units Shale Stabilizer Potassium Chloride 2000-35000 ppm Torque Reduction CoPolymer Beads 0.25-2 lb/bbl Oxidizing Agent Ammonium Persulfate 2-3 lb/1000 gal Defoamer Defoamer 0.1-0.2% by volume pH Control CaOH— 8-10 pH Metal Binder Iron Fix 6-7 gal/100 bbl Corrosion Inhibitor Phosphate Ester 3-6 gal/100 bbl Remove Sulfites from Triazine 1-3 gal/100 bbl System

(28) In some embodiments, alternative chemicals may be added to the base fluid depending on the needs of the well and the availability and cost of the chemicals. These chemicals may include the following:

(29) TABLE-US-00005 Generic Chemical Name Units Shale Stabilizer Non-ionic Polymer 0.1-10 gal/100 bbl Torque Reduction Lubricant w/or w/o Beads 0.25-5% by vol. Oxidizing Agent Sodium Hypochlorite or as needed Peroxide pH Control NaOH 7-10.5 pH pH Control & Reduce Na.sub.2CO.sub.3 7-10.5 pH Hardness pH Control & KOH 7-10.5 pH Potassium Source Corrosion Inhibitor Filming Amine 1-10 gal/100 bbl

(30) In other embodiments, the concentrations and amounts may be varied according to the following chart:

(31) TABLE-US-00006 Generic Chemical Name Units Shale Stabilizer Non-ionic Polymer 0.25-5 gal/100 bbl Torque Reduction Lubricant w/or w/o Beads 0.25-2% by vol. Oxidizing Agent Sodium Hypochlorite or as needed Peroxide pH Control NaOH 8-10 pH pH Control & Reduce Na.sub.2CO.sub.3 8-10 pH Hardness pH Control & KOH 8-10 pH Potassium Source Corrosion Inhibitor Filming Amine 2-4 gal/100 bbl

(32) In some embodiments, alternative chemicals may be added to the base fluid depending on the needs of the well and the availability and cost of the chemicals. These chemicals may include the following:

(33) TABLE-US-00007 Generic Chemical Name Units Viscosifier and Friction PHPA 0.1-10 gal/100 bbl Reducer Stabilizer, Friction Polymerized 0.25-10% by vol. Reducer, Enhancer Carbohydrate Shale Stabilizer KCl Substitute (Choline 0.25-3 gal/1000 gal Chloride) Shale Stabilizer Potassium Acetate 2000-5000 ppm Shale Stabilizer Potassium Carbonate 2000-5000 ppm Hole Stabilizer and Hole Stabilizer/ 0.2-5 lb/bbl Viscosifier Viscosifier

(34) In other embodiments, the concentrations and amounts may be varied according to the following chart:

(35) TABLE-US-00008 Generic Chemical Name Units Viscosifier and Friction PHPA 0.25-10 gal/100 bbl Reducer Stabilizer, Friction Polymerized 0.25-3% by vol. Reducer, Enhancer Carbohydrate Shale Stabilizer KCl Substitute (Choline 0.5-1 gal/1000 gal Chloride) Shale Stabilizer Potassium Acetate 2000-3000 ppm Shale Stabilizer Potassium Carbonate 2000-3000 ppm Hole Stabilizer and Hole Stabilizer/ 0.25-2 lb/bbl Viscosifier Viscosifier

(36) The base aqueous fluid in which the low shear rate modifying polymer is hydrated may be any aqueous liquid which is compatible with the polymer. Thus, the base liquid may be fresh water, produced water, and/or a brine containing soluble salts such as sodium chloride, potassium chloride, calcium chloride, sodium bromide, potassium bromide, calcium bromide, zinc bromide, sodium formate, potassium formate, cesium formate, and the like. The brine may contain one or more soluble salts at any desired concentration up to saturation. The fluids comprise a liquid, a viscosifier which imparts a low shear rate viscosity to the fluids of at least 10,000 centipoise, an aphron-generating surfactant, and aphrons. Stable aphron-containing fluids are obtained by increasing the low shear rate viscosity (LSRV) of the fluid to at least 10,000 centipoise, preferably at least 20,000 centipoise, and most preferably to at least 50,000 centipoise. Since the stability of the aphrons is enhanced as the LSRV increases, a LSRV of over a hundred thousand centipoise may be desired. The aphrons are obtained by incorporating (1) an aphron-generating surfactant into the fluid and thereafter generating the aphrons in the fluid or (2) generating the aphrons in a liquid compatible with the fluid and mixing the aphron-containing fluid with the fluid.

(37) The polymer used to build the base fluid and maintain the fluid while re-circulating should preferably be able to achieve the characteristics of LSRV while also protecting the microbubbles without interfering in the reduction of downhole emulsification of water and oil. The polymers useful in the LSRV fluids may comprise any water-soluble polymer which increases the LSRV of the fluid to produce a fluid exhibiting a high yield stress, shear thinning behavior and does not interfere in the reduction of downhole emulsifications of oil and water while also protecting the microbubbles created by the addition at the appropriate time of the aphron generator and atmospheric pressure. Particularly useful are biopolymers produced by the action of bacteria, fungi, or other microorganisms on a suitable substrate. Exemplary biopolymers are the polysaccharides produced by the action of Xanthomonas compestris bacteria which are known as xanthan gums. See, for example, U.S. Pat. Nos. 4,299,825 and 4,758,356, each incorporated herein by reference. Other biopolymers useful in the fluids are the so-called welan gums produced by fermentation with a microorganism of the genus Alcaligenes, Gellan gums, schleroglucan polysaccharides produced by fungi of the genus Sclerotium, and succinoglycan biopolymer. The viscosifying agent in some embodiments may be chosen from the group of carbohydrates such as polysaccharides, cellulosic derivatives, guar or guar derivatives, Xanthan, carrageenan, starch polymers, gums, polyacrylamides, polyacrylates, betaine-based surfactants, viscoelastic surfactants, and/or natural or synthetic clays.

(38) The concentration of the polymer to increase the LSRV of the fluid can be determined by testing. The concentration will be an amount sufficient to impart to the fluid the desired LSRV. In various embodiments, the viscosifier may be Horizon Mud's Master Vis, Tex-Xan, and/or Liquid XC. Generally the fluids will contain a concentration from less than or about 0.25 lb/bbl to about 2.5 lb/bbl or more and preferably from about 0.3 lb/bbl to about 1.5 lb/bbl. In some embodiments, the fluid may include copolymer beads such as Mud Masters' Master Fine Beads and/or Master Coarse Beads. The beads may be on the order of 160-900 microns and have a specific gravity of approximately 1.13 to create a ball-bearing effect inside a cased hole to reduce metal-to-metal friction and break capillary forces.

(39) The water based borehole fluids generally may contain materials well known in the art to provide various characteristics or properties to the fluid. Thus the fluids may contain one or more viscosifiers or suspending agents in addition to the polysaccharide, weighting agents, corrosion inhibitors, soluble salts, biocides, fungicides, seepage loss control additives, bridging agents, deflocculants, lubricity additives, shale control additives, and other additives as desired. In some embodiments, the viscosifier may be Mud Masters' Master Clear Seal-5 and/or Master Clear Seal-5 Plus. The viscosifier may be a pulverized powdery inhibitor/lubricant comprising a blend of polymers, starches, and clays, having a specific gravity of 0.66 to 0.75. The viscosifier may help lower API/HPHT fluid loss, decrease wall cake thickness, retard water hydration on clay, extrude into a formation, and act as a deforming sealer. In some embodiments, a fluid additive may include hydrolyzed glucose syrup, such as is described in U.S. Pat. No. 7,745,378, to Rayborn, Sr., entitled Drilling Fluid Additive Containing Corn Syrup Solids, which is hereby incorporated by reference.

(40) The borehole fluids may contain one or more materials which function as encapsulating or fluid loss control additives to further restrict the entry of liquid from the fluid to the contacted shale. Representative materials known in the art include partially solubilized starch, gelatinized starch, starch derivatives, cellulose derivatives, humic acid salts (lignite salts), lignosulfonates, gums, synthetic water soluble polymers, and mixtures thereof.

(41) The fluids should have a pH in the range from about 7.0 to about 10.5, preferably from 8 to about 10. The pH can be obtained as is well known in the art by the addition of acids and/or bases to the fluid, such as potassium hydroxide, potassium carbonate, sodium hydroxide, sodium carbonate, calcium hydroxide, and mixtures thereof and other bases commonly known in the industry.

(42) Various embodiments of the present invention relate to the preparation and use of aphrons during the wellbore drillout and cleanout phases of hydrocarbon production from subterranean reservoirs. Unlike prior drillout and cleanout fluids, the aphrons described herein are stabilized microbubbles that are formed by the combination of solvent-surfactant blends with an appropriate water-based carrier fluid. In general, surfactants adjust surface tension and can be categorized as emulsifying surfactants and non-emulsifying surfactants. When used in rheology up to LSRV, the surfactants useful to create the aphron microbubbles should be compatible with the other chemicals present in the fluid. An aphron is a uniquely structured microbubble created by combining surfactants and polymers in a fluid. Unlike a conventional foam bubble, each aphron is made up of a core, which is often spherical of an internal phase, usually liquid or gas, encapsulated in a thin shell, which prevents leakage of air from the core, provides a barrier against coalescence with adjacent aphrons, and allows the aphron to survive downhole pressures. Typically, the outer surfactant layer is generally hydrophilic, making the aphrons compatible with surrounding water-based fluids.

(43) In the case of the aphron-containing well cleanout fluids, the aphrons may be generated at the surface before being circulated downhole. One way of creating aphron microbubbles is by exposing the base fluid to air at the surface (i.e., at ambient pressure) and agitating the fluid using conventional fluid-mixing equipment to create an air-water emulsion. The surfactant in the fluid is incorporated to achieve the desired concentration of aphrons and produce the surface tension to contain the aphrons as they are formed. The aphrons when first generated contain a wide size distribution ranging from about 25 μm up to about 200 μm in diameter. To successfully complete the generation, the aphrons should be stabilized in the fluid. This may be achieved by using, for example a high yield stress, shear thinning polymer. This type of polymer may act as a viscosifier as well as a stabilizer.

(44) In some embodiments, a well drillout fluid may comprise water, an aphron generator, and a combination of one or more other surfactants, solvents, and/or other additives (e.g., acid). With respect to the solubilizing agent, e.g. the solvent, particularly an organic solvent, non-restrictive examples are alcohols (e.g. methanol, ethanol, isopropanol, butanol, and the like), glycols (e.g. propylene glycol (MPG), dipropylene glycol (DPG), tripropylene glycol (TPG), ethylene glycol (MEG), diethylene glycol (DEG), and the like), glycol ethers (e.g. ethylene glycol monomethyl ether (EGMME)), ethylene glycol monoethyl ether (EGMEE), ethylene glycol monopropyl ether (EGMPE), ethylene glycol monobutyl ether (EGMBE), ethylene glycol monomethyl ether acetate (EGMMEA), ethylene glycol monoethyl ether acetate (EGMEEA acetate) and the like) and alkyl esters (e.g. methyl formate, ethyl formate, methyl acetate, ethyl acetate, butyl acetate, methyl propionate, ethyl propionate, ethyl butyrate, methyl benzoate, ethyl benzoate, methylethyl benzoate, and the like), and combinations thereof.

(45) A solvent is a chemical additive that is soluble in oil and water and may be used to prevent or break up emulsions. A mutual solvent is a chemical additive that is soluble in oil, water, acids (often HCl-based), and other well treatment fluids. Mutual solvents are used to stabilize various oil-water emulsions. Mutual solvents remove organic films leaving them water-wet, thus the risk of emulsions may be reduced. A mutual solvent may be ethylene glycol monobutyl ether, generally known as EGBE or EGMBE. In some embodiments, the aphron-generating surfactant may include EGBE, Methanol, Isopropyl Alcohol, and/or other chemicals or equivalents or derivatives thereof. EGBE is an effective coalescent that improves film integrity. Although some embodiments utilize EGBE, other embodiments may use other solvents, other glycol ether solvent, or other chemicals having low surface tension, miscible with water and other organic liquids, and/or are readily biodegradable.

(46) Aphron formation can be achieved along several routes. In one embodiment, aphrons are obtained by including a mixture of surfactants as aphron-generating agents into a solution containing a viscosifier. Suitable surfactants may be anionic, cationic, amphoteric, or nonionic in nature, or their mixtures. Preferably, the molar ratio is higher than 3 to 1. More preferably, it is higher than 5:1 and most preferably, it is higher than 10:1. Suitable surfactant mixtures may be mixtures of surfactants which are soluble in the described solutions. However, surfactant mixtures may also contain one or more (co-)surfactants which are insoluble in the described solutions.

(47) In some embodiments, the surfactant may be Diethanolamine. Diethanolamine, often abbreviated as DEA or DEOA, is an organic viscous liquid. Diethanolamine is polyfunctional, being a secondary amine and a diol. Like other organic amines, diethanolamine acts as a weak base and is soluble in water. Amides prepared from DEA are often also hydrophilic. DEA is used as a surfactant and a corrosion inhibitor. In various embodiments, the non-emulsifying surfactants used should be compatible with the polymers and surfactants utilized, should not prevent a fluid from achieving LSRV, should yield in form and function to the specific chemistry of each wellbore as determined by the testing process before the base fluid is built, and should not interfere with cleaning of the hole during the re-circulating process.

(48) Increases in vapor pressure due to pressure drops, temperature increases, and cavitation are common in downhole conditions. In various embodiments, the risk of cavitation may be reduced by slowing the rate of addition of the solution down. In various embodiments, a self-priming transfer pump may be utilized to avoid foam out of the pump. In addition, the solution may be pulled from a bottom of the supply tank to maintain the lowest possible head.

(49) In some embodiments, aphrons large enough to be seen without magnification can be observed in the fluid as it flows from the borehole into the surface holding tanks (“pits”) before being recirculated. In some embodiments, the fluid may be passed through a screen before being recirculated. After the fluid passes through the screen or shaker, a sample of the fluid may be taken and run through a centrifuge to remove solid particulate. The sample may then be tested for weight (lbs per gal), viscosity, sand content, and other properties. In addition, the rate of bbls in versus the bbls out may be monitored to detect fluid loss downhole. Upon being recirculated downhole, additional aphrons may be generated provided the concentration of the surfactant is sufficient. It may be desirable to add additional surfactant to the fluid either continuously or intermittently until the desired quantity of aphron microbubbles is produced. In various embodiments, the LSRV mud containing aphrons may be stored and reused at subsequent wellbores.

(50) The quantity of aphrons in the fluid often depends on the density required. Generally, the fluid will contain less than 15% by volume of aphrons. Thus, the density of the circulating fluid can be monitored on the surface and additional surfactant added as necessary to maintain the desired density, if the density is too high, and weight material may be added if the density is too low. The quantity of aphrons in the fluid can be determined by adding a known quantity of a defoamer or other chemical to destabilize the surfactant-containing shells surrounding the aphrons. Measurement of the change in volume of the fluid will indicate the volume % of aphrons in the fluid. In some embodiments, Mud Masters' Z-Foam Out may be used as the defoamer.

(51) If desired, the aphrons can be generated on the surface using the procedures and equipment set forth in the following U.S. patents, incorporated herein by reference: Sebba U.S. Pat. No. 3,900,420 and Michelsen U.S. Pat. No. 5,314,644. The well servicing fluid containing the aphrons can then be continuously circulated through the borehole. The so-called water-soluble polymer present in the fluid to enhance the LSRV of the fluid also helps to stabilize the aphrons, thus helping to prevent their coalescence. In some embodiments, the surfactant may be incorporated into the well servicing fluid by blending, pumping, pouring, and/or injecting. If necessary, air, Nitrogen, or other gas can be incorporated into the fluid to entrain more gas.

(52) The fluid may be initially prepared containing 0.3-1.5 lb/bbl of Xanthan gum biopolymer and 1.5-2 gal/100 bbl of an anionic surfactant. The LSRV may be increased for hole cleaning and to create a resistance to movement into the formation, while the polymer encapsulation helps provide strength for the bubble wall surrounding the aphrons. The surfactant solution enables the aphrons to form, reducing the fluid density.

(53) Typical method for chemical mixing is a recipe of adding gallons of chemical per barrels of fluid pumped, sometimes referred as batch treating. The fluid properties of the wellbore fluid and cleaning fluid may be analyzed, such as resistance, viscosity, annular velocity, and the rheology or Reynolds number along with the effects of each. Understanding the effects of friction reducer dosage optimization and monitoring the fluids continuously helps determine the correct amount of friction reducer needed to effectively overcome the internal friction of the fluids and reduce the circulating pressure required for pumping operations during the job. With the optimum chemical dosing, the flow rates and fluid regime may also be adjusted. A certain flow rate (feet per minute) may be required to maintain a sufficiently turbulent flow through the lateral section of the wellbore.

(54) In horizontal wells, gravity causes debris from the drillout to build up along the lower side or bottom of the wellbore. Removing the debris from a horizontal or other non-vertical well can be difficult. Limited pump rate, eccentricity of the pipe, sharp build rates, high bottom hole temperatures, and oval-shaped wellbores can all contribute to inadequate hole cleaning. Well treatments by circulating fluids that have been specially formulated to remove such debris are often necessary to prevent buildup. In order to achieve debris transport within the range of flow conditions in various drillouts and cleanouts, a minimum level of turbulence at the fluid-debris interface may be required to initiate bedload debris transport. Turbulent flow may be needed to facilitate debris removal and provide the downhole conditions to remove the bedload and effectuate continuous hole cleaning during the drillout and/or cleanout. A subtle change in viscosity may have a direct and significant effect on the flow conditions. Improvements in drillout and/or cleanout efficiency and effectiveness may also be seen when mixing and monitoring the fluids throughout the job. In such a setup, the fluids and chemicals are pumped through the mixing plant and mixed on the fly while monitoring the chemical concentrations and fluid performance parameters.

(55) Although various embodiments of the method and apparatus of the present invention have been illustrated in the accompanying Drawings and described in the foregoing Detailed Description, it will be understood that the invention is not limited to the embodiments disclosed, but is capable of numerous rearrangements, modifications, and substitutions without departing from the spirit and scope of the invention.