PROCESS FOR PROTECTING AN ALUMINUM ALLOY PART

Abstract

Process for protecting a part comprising an aluminum-based alloy, the process comprising depositing a primer paint layer by anaphoresis over the entire part, polymerizing the primer paint layer in order to form a non-conductive polymerized primer paint layer, laser pickling, by means of a laser beam, an area of the non-conductive polymerized primer paint layer in order to form an unpainted area, trivalent chromium chemical conversion of the unpainted area in order to form a conductive protective layer and drying the part, depositing a finishing paint layer on at least a portion of the non-conductive polymerized primer paint layer, and polymerizing the finishing paint layer.

Claims

1. A process for protecting a part comprising an aluminum-based alloy, the process comprising the following steps: depositing a primer paint layer by anaphoresis over the entire part; polymerizing the primer paint layer in order to form a non-conductive polymerized primer paint layer; laser pickling, by means of a laser beam, an area of the non-conductive polymerized primer paint layer in order to form an unpainted area; trivalent chromium chemical conversion of the unpainted area in order to form a conductive protective layer; drying the part; depositing a finishing paint layer on at least a portion of the non-conductive polymerized primer paint layer; polymerizing the finishing paint layer.

2. The process according to claim 1, wherein the unpainted area is cleaned after the laser pickling.

3. The process according to claim 2, wherein the cleaning of the unpainted area is carried out by mechanical brushing.

4. The process according to claim 2, wherein the cleaning of the unpainted area is assisted by ultrasound.

5. The process according to claim 1, wherein prior to the chemical conversion, the non-conductive polymerized primer paint layer and the unpainted area are degreased with a solvent and/or an alkaline solution.

6. The process according to claim 1, wherein the non-conductive polymerized primer paint layer has a thickness greater than or equal to 10 m, preferably greater than or equal to 15 m and less than or equal to 40 m, preferably less than or equal to 30 m.

7. The process according to claim 1, wherein the laser pickling is carried out by means of a YAG laser with a wavelength of 1064 nm at a frequency comprised between 10 and 200 kHz.

8. The process according to claim 1, wherein the profile of the laser beam is Gaussian shaped or flat topped.

9. The process according to claim 1, wherein the laser beam has a fluence greater than or equal to 4 J/cm.sup.2 and the laser pickling comprises one to four passes.

10. The process according to claim 1, wherein the laser pickling is carried out with a laser beam coverage rate greater than or equal to 20% and less than or equal to 80%.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0046] Other features and advantages of the object of this disclosure will emerge from the following description of embodiments, given by way of non-limiting examples, with reference to the appended figures.

[0047] FIG. 1 is a flowchart showing the steps of a process for protecting a part comprising an aluminum-based alloy.

[0048] FIG. 2 is a sectional and perspective partial schematic view of a part with a non-conductive polymerized primer paint layer.

[0049] FIG. 3 is a sectional and perspective partial schematic view of the part of FIG. 2 after laser pickling.

[0050] FIG. 4 is a sectional and perspective partial schematic view of the part of FIG. 3 after chemical conversion and drying.

[0051] FIG. 5 is a sectional and perspective partial schematic view of the part of FIG. 4 after deposition of the finishing paint layer.

[0052] In all the figures, the elements in common are identified by identical reference numerals.

DETAILED DESCRIPTION

[0053] FIG. 1 represents a process 100 for protecting, in particular against corrosion, a part 12 comprising an aluminum-based alloy.

[0054] The process 100 comprises a first step of depositing 102 a primer paint layer by anaphoresis over the entire part 12. The step of depositing the primer paint layer by anaphoresis is followed by a step of polymerizing 104 the primer paint layer to obtain a non-conductive polymerized primer paint layer 14 over the entire part 12, as shown in FIG. 2.

[0055] It will be noted that FIG. 2 is a schematic partial sectional view of an element 10. It is therefore understood that the part 12 is entirely covered by the non-conductive polymerized primer paint layer 14. A partial sectional view was shown in order to see the part 12 and the non-conductive polymerized primer paint layer 14.

[0056] The step 102 of depositing the protective layer 14 is carried out by anaphoresis.

[0057] Anaphoresis is a process for forming the non-conductive polymerized primer paint layer 14 by immersing the part 12 in a bath of electrically charged paint, and which, under the effect of an electrical voltage applied between the part serving as anode and a counter-electrode, is deposited on the part 12. Once the deposit has reached the desired thickness, the deposit is polymerized at a temperature allowing to fix the paint on the part 12 and form the non-conductive polymerized primer paint layer 14. By way of non-limiting example, mention may be made of the electrodeposited paint system Aerocron 2200.

[0058] When the part 12 is entirely coated with the non-conductive polymerized primer paint layer 14, the part 12 is protected in particular against corrosion. However, this protective layer is non-conductive.

[0059] The process 100 comprises a step 106 of laser pickling, by means of a laser beam, an area of the non-conductive polymerized primer paint layer 14 in order to form an unpainted area 16, as shown in FIG. 3. It is understood that the part 12 is exposed in the unpainted area 16.

[0060] The laser pickling 106 may be carried out by means of a YAG laser with a wavelength of 1064 nm at a frequency comprised between 10 and 200 kHz.

[0061] The profile of the laser beam may be Gaussian shaped or flat topped.

[0062] As shown in FIG. 3, the part 12, from which the non-conductive polymerized primer paint layer 14 was removed in one area, has an unpainted area 16. It is understood that the number of unpainted areas 16 is not limited to one. FIG. 3 being a schematic figure, the unpainted area 16 is shown as having the shape of a square. It is understood that this shape is not limiting and that the unpainted area 16 may have any shape. The shape of the unpainted area 16 is defined by the passage of the laser beam over the non-conductive polymerized primer paint layer 14.

[0063] The process 100 comprises a step of trivalent chromium chemical conversion 108 of the unpainted area 16 in order to form a conductive protective layer 18, as shown in FIG. 4.

[0064] As schematically shown in FIG. 4, the non-conductive polymerized primer paint layer 14 is not altered or modified by the chemical conversion step 108. Thus, the trivalent chromium chemical conversion step 106 only takes place on the unpainted areas 16 which have been previously pickled during the laser pickling step 106 and the formation of the conductive protective layer 18 is formed only at the location of the unpainted areas 16.

[0065] The process 100 comprises a drying step 110. By way of non-limiting example, the drying step 110 may be carried out at ambient temperature under compressed air and/or in an oven at a temperature less than or equal to 60 C. (degree Celsius). It is understood that compressed air may be used at room temperature and then the part 12 may be put in a study at a temperature less than or equal to 60 C. until the part 12 is dry.

[0066] The process 100 comprises a step 112 of depositing a finishing paint layer on at least a portion of the non-conductive polymerized primer paint layer.

[0067] The process 100 comprises a step of polymerizing 114 the finishing paint layer in order to form a polymerized finishing paint layer 20 on the non-conductive polymerized primer paint layer 18, as shown schematically in FIG. 5.

[0068] The polymerized finishing paint layer 20 may not cover the entire non-conductive polymerized primer paint layer 18, as shown schematically in FIG. 5.

[0069] The process 100 may also comprise a step 116 of cleaning the unpainted area 16 after the laser pickling step 106.

[0070] When the unpainted area(s) 16 are covered with a light dusting due to laser pickling, it is advantageous to clean the unpainted areas 16 to remove these residues, for example in the form of powder, which may have formed during the laser pickling step 106.

[0071] The cleaning 116 of the unpainted area 16 may be carried out by mechanical brushing.

[0072] The cleaning 116 of the unpainted area 16 may be assisted by ultrasound.

[0073] The process 100 may also comprise a step 118 of degreasing the non-conductive polymerized primer paint layer 14 and the unpainted area 16 after the laser pickling step 106.

[0074] The degreasing step 118 may or may not be carried out after the cleaning step 116.

[0075] Thus, before the chemical conversion 108, the part 12 and the non-conductive polymerized primer paint layer 14 may be degreased 118 with a solvent and/or an alkaline solution.

[0076] This step allows to degrease the part when the non-conductive polymerized primer paint layer 14 and/or the unpainted area 16 having dirt of the fingerprint type which may result from successive handlings of the part during the previous steps.

[0077] It is understood that the degreasing step 118 is not carried out using an acid solution.

[0078] By way of non-limiting example, the solvent may be ethanol or methyl ethyl ketone (butanone-2, also called MEK in accordance with the acronym for MethylEthylKetone

[0079] By way of non-limiting example, the alkaline solution may be a solution marketed under the name Sococlean A3432.

[0080] Although the present description has been described with reference to a specific embodiment, it is obvious that various modifications and changes can be made to these examples without departing from the general scope of the invention as defined by the claims. Furthermore, individual features of the various embodiments discussed may be combined in additional embodiments. Accordingly, the description and the drawings should be considered in an illustrative rather than restrictive sense.