Method for producing a roof element of a motor vehicle and roof element having a moulded section

Abstract

A roof element and a process for the production of a roof element are provided, which may have the steps of providing a polymer mixture; admixing an organosiloxane compound with the polymer mixture; a mixing of the polymer mixture, with the organosiloxane compound admixed, with an isocyanate compound to give a polyurethane material and introduction of the polyurethane material into a mold cavity of a foaming mold in a manner such that the polyurethane material reacts to completion and a molded section of the roof element is shaped in the mold cavity wherein the organosiloxane compound is accumulated at the surface of the molded section, wherein in a surface layer of thickness from 0.5 m to 20 m of the molded section, the organosiloxane compound is accumulated; and demolding of the roof element from the foaming mold.

Claims

1. A process for the production of a roof element of a motor vehicle, comprising the steps of: providing a polymer mixture; admixing an organosiloxane compound with the polymer mixture; Mixing of the polymer mixture, with the organosiloxane compound admixed, with an isocyanate compound to give a polyurethane material and introduction of the polyurethane material into a mold cavity of a foaming mold in a manner such that the polyurethane material reacts to completion and a molded section of the roof element is shaped in the mold cavity wherein the organosiloxane compound is accumulated at the surface of the molded section, wherein in a surface layer of thickness from 0.5 m to 20 m of the molded section, the organosiloxane compound is accumulated; and Demolding of the roof element from the foaming mold.

2. The process as claimed in claim 1, wherein the quantity of the organosiloxane compound admixed with the polymer mixture is 0.5% by weight to 8% by weight.

3. The process as claimed in claim 1, wherein the molar mass of the organosiloxane compound is from 15 000 g/mol to 50 000 g/mol.

4. The process as claimed in claim 1, wherein the polymer mixture is a polyol composition.

5. The process as claimed in claim 1, wherein the molded section is shaped on a panel which comprises glass or which comprises a plastics material.

6. A roof element of a motor vehicle, comprising a molded section which has been manufactured from a material comprising polyurethane by a foaming process, wherein, at the surface of the molded section, an organosiloxane compound is accumulftated, wherein in a surface layer of thickness from 0.5 m to 20 m of the molded section, the organosiloxane compound is accumulated.

7. (canceled)

8. The roof element as claimed in claim 6, wherein the molar mass of the organosiloxane compound is from 15 000 g/mol to 50 000 g/mol.

9. The roof element as claimed in claim 8, wherein the roof element is a cover element of a roof-opening system.

10. The roof element as claimed in claim 9, wherein the mold section is a peripheral foam edging of a panel which comprises glass or which comprises a plastics material.

Description

[0030] An embodiment of a roof element of the invention and of a process for the production of the roof element are depicted in simplified diagrammatic form in the drawing, and are explained in more detail in the description below.

[0031] FIG. 1 is a plan view of a cover element of a roof-opening system of a motor vehicle;

[0032] FIG. 2 is a section through the cover element of FIG. 1 along the line II-II in FIG. 1;

[0033] FIG. 3 shows a device for the preparation of a liquid polyol composition;

[0034] FIG. 4 is a detail of a sectional view of a mold for the production of a mold section of the cover element of FIG. 1, in closed position; and

[0035] FIG. 5 is a depiction of the foaming mold corresponding to FIG. 4, but in open position.

[0036] FIGS. 1 and 2 show a cover element 1 of a roof-opening system, in other respects not depicted in any greater detail, of a vehicle roof. By means of the cover element 1 it is possible, as desired, to close, or at least to some extent open, a roof opening of the vehicle roof.

[0037] The cover element 1 comprises a glass panel 2 that is in essence rectangular, to which a glass frit and a primer have been provided.

[0038] To permit coupling of the cover element 1 to a kinematic system for roof opening there is, provided to the glass panel 2 along its periphery, a foam edging 3 into which, at each of the edges that are lateral in relation to a vertical plane running centrally along the length of the roof, there are three retaining brackets 4 embedded as inserts. The retaining brackets 4 have each been manufactured from a cathodically electrocoated metal sheet.

[0039] The foam edging 3 consists of a polyurethane material with which an organosiloxane compound has been admixed. The organosiloxane compound is concentrated/accumulated within a surface layer 5 of the foam edging 3. The surface layer 5 has a thickness of some micrometers.

[0040] FIGS. 3 to 5 depict diagrammatically the production of the foam edging 3 of the cover element 1. The production process uses a foaming mold 6, depicted in FIGS. 4 and 5, in which there is a mold cavity 7 which corresponds to the shape of the foam edging 3 and which is delimited by an upper mold section 8 and a lower mold section 9 of the foaming mold 6.

[0041] During the production of the foam edging 3, the glass panel 2, to which the glass primer and the glass frit have been provided, is placed onto the lower mold section 9 while the foaming mold 6 is in the open position depicted in FIG. 5, where the upper mold section 8 and the lower mold section 9 have been moved apart. The retaining brackets 4 are moreover fixed in a manner not depicted. The upper mold section 8 is then moved toward the lower mold section 9 to form the mold cavity 7. The polyurethane material can then be introduced into the mold cavity 7 of the closed foaming mold 6 and reacted to completion there. The retaining brackets 4 also become embedded into the polyurethane material here.

[0042] An organosiloxane compound with molar mass from 15 000 g/l to 50 000 g/l has been admixed with the polyurethane material used. During the reaction of the polyurethane material to completion, the heat produced in the reaction causes a phase separation which forces the organosiloxane compound toward the cavity-delimiting surfaces formed by the upper mold section 8, the lower mold section 9 and the glass panel 2, thus forming the surface layer 5 with relatively high concentration of the organosiloxane compound on the foam edging 3. The finished cover element 1 can then be demolded. As can be seen from FIG. 3, the polyurethane material is passed from a metering and mixing head 100 into the foaming mold 6 and, respectively, the mold cavity 7.

[0043] In the mixing head 100, a polyol composition with which the organosiloxane compound has been admixed, and which has been prepared in a device 10, and an isocyanate compound available from a container 60 are mixed with one another and then metered into the mold cavity 7.

[0044] The device 10 for the preparation of the polyol composition, which is a reactive polymer for the polyurethane system, can be seen in FIG. 3.

[0045] The device 10 comprises a feed container 12 in which the polyol composition can be stored and to which a stirrer 14 has been provided in order to eliminate any possible layering of the polyol composition as a result of storage. The storage container 12 has connection by way of a line 16, with a pump 18 arranged therein, to degassing equipment 20, which is composed of a vacuum deaerator. Attached to the vacuum deaerator there is an output line 22, which has another pump 24 and a mass flow meter 26 arranged therein and which leads to homogenizing equipment 28, composed of a toothed colloid mill. Upstream of the homogenizing equipment 28 there is arranged, on the line 22, a metering valve 52 which is a constituent of gasification equipment and by way of which an additive gas can be added to the polyol composition.

[0046] Downstream of the metering valve 52 and upstream of the homogenizing equipment, an input line 54, which has been connected to a feed container 56 for the organosiloxane compound and to which there is also a valve 58 provided, enters the line 16.

[0047] The homogenizing equipment 28 has an output line 30 which leads into a container 32 in which the prepared polymer mixture can be placed for intermediate storage, and provided to which there is a stirrer unit 34. A gauge pressure of from 1 to 6 bar prevails in the container 32. The output line 30 leads into the container 32 in a manner such that the prepared polymer mixture is introduced below the existing upper surface of the polymer mixture already present in the container 32. The upper surface, or fill level, of the polymer mixture in the container 32 is always maintained between two marks; there is a first sensor 36 provided to the lower mark and a second sensor 38 provided to the upper mark. The sensor 36 allocated to the lower mark indicates when the level falls below the specified fill level in the container 32 and further liquid polymer mixture has to be prepared. The second sensor 38 allocated to the upper mark indicates when the level rises above the specified fill level, and the preparation of the liquid polymer mixture by means of the device 10 has to be stopped.

[0048] The container 32 has connection by way of an onrunning line 40 to the metering and mixing head 100 which is allocated to the foaming mold 6 for the production of the foam edging 3 of the cover element 1 and in which the isocyanate compound is added to the polyol composition to form the polyurethane system. A return line 42 moreover leads into the container 32 and, with the ongoing line 40, forms a circuit for the supply of a plurality of processing units.

[0049] For the control of the preparation of the polyol composition, the device 10 has control equipment 44 which has connection by way of a line 46 to the mass flow meter 26 and by way of a line 48 to a gas mass flow meter 50 likewise allocated to the gasification equipment, and to the metering valve 52, by means of which an additive gas, for example carbon dioxide or an inert gas, can be introduced into the liquid polyol composition, and specifically upstream of the homogenization equipment 28 and downstream of the mass flow meter 26. The control equipment moreover has connection to the valve 58 for the metered addition of the organosiloxane compound from the feed container 56 by way of the line 54.

[0050] The polyol composition can be prepared by means of the device 10 in the manner described below.

[0051] The polyol composition, which is stirred in the storage container 12, is conveyed by means of the pump 18 into the degassing equipment 20, where it is freed from undefined gases. The degassed polymer mixture consisting of the polyol composition is then conveyed through the output line 22 by means of the pump 24. The quantity of the polyol composition is first determined here by means of the mass flow meter 26, and then, as required by said measurement, by means of the control equipment 44, additive gas is added by way of the gas mass flow meter 50 of the metering valve 52 and the organosiloxane compound is added by way of the valve 58. Downstream of the valve 58, the polyol composition, now with additive gas and with the organosiloxane compound, is passed through the homogenizing equipment 28 in order to achieve fine dispersion, in the polyol composition, of small gas bubbles composed of the additive gas. The polyol composition thus prepared is then passed into the container 32 by way of the discharge line 30 so that it can be further processed, in particular via addition of an isocyanate to give a polyurethane system that can be used for the production of the rigid-foam edging of the cover element 1 or the like.

LIST OF REFERENCE SIGNS

[0052] 1 Cover element [0053] 2 Glass panel [0054] 3 Foam edging [0055] 4 Retaining brackets [0056] 5 Surface layer [0057] 6 Foaming mold [0058] 7 Mold cavity [0059] 8 Upper mold section [0060] 9 Lower mold section [0061] 10 Device [0062] 12 Storage container [0063] 14 Stirrer [0064] 16 Line [0065] 18 Pump [0066] 20 Degassing equipment [0067] 22 Output line [0068] 24 Pump [0069] 26 Mass flow meter [0070] 28 Homogenizing equipment [0071] 30 Discharge line [0072] 32 Container [0073] 34 Stirrer unit [0074] 36 Sensor [0075] 38 Sensor [0076] 40 Ongoing line [0077] 42 Return line [0078] 44 Control equipment [0079] 46 Line [0080] 48 Line [0081] 50 Gas mass flow meter [0082] 52 Metering valve [0083] 54 Supply line [0084] 56 Storage container [0085] 58 Valve [0086] 100 Metering and mixing head