Process for manufacturing a thermoplastic composite part

Abstract

This process for producing a thermoplastic composite part by laying of at least one thermoplastic composite layer on a tool includes laying on the tool a hardened first ply before the laying of the thermoplastic composite layer. The first ply is produced beforehand to the shape of the tool and includes a first material able to experience an attractive force when it is subjected to a magnetic field, and/or to an electrical potential difference, and includes a second material of a thermoplastic resin that is chemically compatible with the resin of the thermoplastic composite layer. The first ply is clamped to the tool by the effect of a magnetic field, and/or of an electrical potential difference, established at the level of the tool. In one form of implementation, the first ply is produced on a first-ply mold that is preferably of convex shape.

Claims

1. A process for producing a thermoplastic composite part, the process comprising: preforming a first ply to match a shape of a tool wherein the first ply includes a first material having electromagnetic properties so as to experience an attractive force when it is subjected to at least one of a magnetic field, or to an electrical potential difference, and a second material comprised of a thermoplastic resin that is chemically compatible with a thermoplastic resin of a thermoplastic composite layer; laying the first ply on the tool; retaining the first ply on the tool by at least one of the effect of a magnetic field established at a level of said tool, or of an electrical potential difference with said tool; and depositing the thermoplastic composite layer, including the thermoplastic resin of the thermoplastic composite layer, on the first ply after the first ply is laid on the tool, wherein the second material of the first ply is chemically compatible with the thermoplastic resin of the thermoplastic composite layer in order to adhere with the thermoplastic resin of the thermoplastic composite layer.

2. The process as claimed in claim 1, wherein preforming the first ply includes subjecting the first material and the second material, which is deposited on said first material in the form of a thermoplastic-resin powder, to a step in which temperature is increased above a melting point and glass transition temperature of the thermoplastic-resin powder, while being retained on a first-ply mold, the shape of said first-ply mold being a counterpart of the tool.

3. The process as claimed in claim 2, wherein the first material is deposited on the first-ply mold in a first step and, in a second step, the second material is deposited by spraying the thermoplastic-resin powder onto the first material deposited on said first-ply mold.

4. The process as claimed in claim 1, wherein the first material mainly consists of woven or nonwoven wires and/or of mats, and/or of powders, that are deposited to form a layer or a plurality of superposed layers of said first material.

5. The process as claimed in claim 2, wherein the first material is deposited on the first-ply mold in widths juxtaposed with a minimum overlap to avoid a gap between the neighboring edges of two juxtaposed widths.

6. The process as claimed in claim 1, wherein the second material is deposited on the first material by electrostatic spraying.

7. The process as claimed in claim 1, wherein the first material is formed from a ferromagnetic material such as a steel, a ferritic stainless steel or a nickel-containing alloy.

8. The process as claimed in claim 1, wherein the first ply is produced in at least two portions that are juxtaposed on the tool when the first ply is laid on said tool.

9. The process as claimed in claim 8, wherein the at least two portions of the first ply are defined so as each to be produced on partial first-ply molds of mainly convex shape.

10. The process as claimed in claim 2, wherein the first material is clamped to the first-ply mold, in the step of manufacturing said first ply, by the effect of a magnetic field established at the level of said first-ply mold, and/or of an electrical potential difference with said first-ply mold.

11. The process as claimed in claim 1, wherein the first ply is retained clamped on the tool by the effect of at least one of a magnetic field established at the level of said tool, or of an electrical potential difference with said tool, during the depositing of the thermoplastic composite layer superposed on the first ply.

12. The process as claimed in claim 11, wherein the magnetic field, and/or the potential difference, established at the level of the tool is cancelled, and if needs be reversed, in a step of demolding the thermoplastic composite part produced on said tool.

Description

(1) In the drawings:

(2) FIG. 1 illustrates the main steps of the process for one mode of implementation;

(3) FIG. 2a schematically illustrates the retention, of the first material of a first ply on a first-ply mold and the spraying of the second thermoplastic-resin powder material onto the first material;

(4) FIG. 2b schematically illustrates the step of melting the second thermoplastic-resin powder material in a heated chamber;

(5) FIG. 2c schematically illustrates the laying of a thermoplastic layer to produce the part on the first ply retained on a tool by magnetic forces established at the level of the tool and/or generated by a potential difference.

DETAILED DESCRIPTION

(6) FIG. 1 synoptically shows the main steps of the process of the presently disclosed embodiment.

(7) FIGS. 2a, 2b and 2c schematically illustrate an exemplary implementation of the process.

(8) In the process 100, a first step 110 for producing a thermoplastic composite part including a stack of layers 13 includes producing a hard first ply 10 having, on the one hand, physical properties allowing it to temporarily and reversibly adhere to a tool 30 on which the part must be formed and, on the other hand, physico-chemical properties that allow it to bind with the thermoplastic resin of those layers of the part which must be deposited on said first ply.

(9) The first ply 10 is produced on a first-ply mold 20.

(10) The first ply 10 is produced with a shape that is as close as possible if not identical to the shape of the tool 30 on which the thermoplastic composite layers from which the part must be formed must be laid.

(11) Furthermore, the first ply is as thin as possible so that its thickness is relatively small relative to the thickness of the part to be produced.

(12) The first-ply mold 20 is of a shape suitable for facilitating the production and demolding of the first ply 10 from said first-ply mold. In particular, if the part to be produced is mainly concave, the first-ply mold 20 will have a complementary, mainly convex shape.

(13) To produce the first ply 10, a complex is formed including at least one first material 11 having electromagnetic properties and at least one second material 12 of a thermoplastic resin.

(14) In a first step 111 of the production of the first ply, the first material 11 is deposited on the first-ply mold 10, the shape of which first-ply mold is a geometric counterpart of the tool 30 on which the part must be formed of the part.

(15) The first material 11 is advantageously a metallic material formed from thin, woven or nonwoven, wires of a few tens of microns the flexibility of which allows said metallic material to follow the shapes of the first-ply mold 20.

(16) Depending on the electromagnetic properties of the first material 11, said first material is retained on the first-ply mold 20 by means of a magnetic field and/or an electrical potential difference, said first-ply mold being produced so that the wanted magnetic field, and/or the wanted electrical potential difference, i.e. that required to ensure the first material is retained on the first-ply mold while closely following the shape of said first-ply mold, is produced on its surface.

(17) The first material 11 may also be retained, conjointly or not with the magnetic field and/or the potential difference, by mechanical means such as clamps for example (not shown). Specifically, mechanical clamping alone may prove to be sufficient to place the first material against the first-ply mold 20 in particular if the shape of said first-material mold is exclusively convex.

(18) In a second step 112 of the production of the first ply 10, fine resin-powder particles of the second material 12 are deposited on the first material. The second material is for example deposited by electrostatic spraying.

(19) The spraying is for example carried out using a spray gun and a solution in dispersion of the resin powder if necessary.

(20) The second material 12 is deposited in a sufficient amount to ensure, in the subsequent steps of the process, binding of the fibers of a first layer of the thermoplastic composite of the part despite the shear forces generated during the laying of this first layer, the first layer being laid while being deformed to closely follow the shape of the tool and to orient the fibers in the desired directions.

(21) The spraying is for example carried out using a spray gun 21 and a solution in dispersion of the resin powder if necessary.

(22) In a third step 113 of the production of the first-ply 10, the first-ply mold 20, on which are deposited the first material 11, which is retained closely against the mold by electrostatic or magnetic forces and/or forces generated by the potential difference, and/or by mechanical clamping, and the second material 12, which is deposited in powder form on the first material, is subjected to a temperature increase, for example in a heating device 22, for example an infrared oven, or an air oven, or an autoclave, to raise the particles of the second thermoplastic-resin material 12 above their melting point and glass transition temperature, this causing the second material to adhere to the first material.

(23) When the second material 12 has bonded to the first material 11, the temperature is returned to room temperature.

(24) In a fourth step 114 of the production of the first ply, the first ply 10 is demolded and separated from the first-ply mold 20 after the electromagnetic field of the mold and/or the potential difference and/or the clamps retained up to the third step 113 have been released and if needs be reversed.

(25) At the end of the first step 110 of the process, a hard first ply 10 of the first material impregnated with the second material is thus formed.

(26) It will be noted that the obtained first ply 10 has a small thickness, substantially the thickness of the wires or of the metal sevens of the first material, but that nonetheless, despite the fact that the first ply is not very stiff because of its small thickness, the static shape thereof remains the shape acquired in the first-ply mold because of the resin of the second material heated to a melting point.

(27) The metallic material of the wires of the first material 11 is chosen from materials having suitable magnetic properties: a good magnetic permeability and/or a high coercive field and/or a magnetization saturation for example, properties generally obtained with ferromagnetic materials. When it is desired to at least partially produce the clamping with a potential difference, the first material is chosen from electrically conductive materials so as to be able to foe brought to and maintained at a desired electrical potential and to make it possible to maintain an electrical potential difference between, on the one hand, the first element 10 and, on the other hand, the tool 30 and if needs be the first-ply mold 20.

(28) In a second step 120 for producing the thermoplastic composite part, the first ply 10 produced in the first step 110 is laid on a tool 30 for molding the part to be produced.

(29) The first ply 10 is retained on the surface of the tool 30 by means of a magnetic field or, for its electrically conductive portion, an electrical potential difference between said tool and said first ply, the tool being produced from a ferromagnetic material so as to produce the magnetic field on its surface and/or from an electrically conductive material to be maintained at the wanted electrical potential difference required to ensure the first ply 10 is retained closely following the shape of said tool.

(30) The tool is for example produced from a steel or an alloy such as an Invar.

(31) If needs be, clamps hold the first ply on the tool 30 in particular on the edges of said tool.

(32) In a third step 130 for producing the thermoplastic composite part, a first thermoplastic composite layer 13 of the part is laid on the first ply 10 maintained on the tool 30 and the other thermoplastic composite layers are laid in successive layers and consolidated using a known method, for example by means of a laying head 31, until the number of plies wanted for the part is obtained.

(33) During the laying of the thermoplastic composite layers, the magnetic field or potential difference ensuring the first ply 10 is retained on the tool 30 is maintained so that, even in concave zones of the tool, the successive thermoplastic composite layers that are applied and that adhere directly or indirectly to the first ply perfectly follow the shape of the tool.

(34) In a fourth step 140 for producing the thermoplastic composite part, the thermoplastic composite part produced is demolded and separated from the tool 30 after the electromagnetic field of the tool, and/or the electrical potential difference between the tool and the first ply that is incorporated in the part at this stage of the process, and/or the clamps, which were retained during the deposition of the successive thermoplastic composite layers of the part, have been released and if needs be reversed.

(35) According to various variants of the process such as just described in a first mode of implementation, the process may be adapted depending on constraints related to the shape of the part to be produced or to the materials implemented.

(36) Thus, the first material of the first ply 10 may be formed by one or more layers of a magnetic metal material. For example from nickel, silver, ferritic stainless steel.

(37) The first material 10 may be deposited on the first-ply mold 20 in the form of wires in webs, wovens, knits, mats or even of a powder.

(38) When a plurality of widths are juxtaposed on the first-ply mold 20, preferably two neighboring widths are placed with a slight overlap in order to avoid interstitial zones that, including only resin, could form a fragile zone in the first ply.

(39) The first material 11 may be deposited on the first-ply mold 20 in the form of wires in webs, wovens, knits, mats or even of a powder.

(40) The area density of first material 11 is advantageously comprised between 20 g/m.sup.2 and 150 g/m.sup.2.

(41) Thus, according to one method of implementation, the first ply 10 that must be deposited on the tool 30 is produced in a plurality of portions that are juxtaposed on the tool.

(42) This method proves to be advantageous when the first ply 10 is of such a large size that it would be difficult to handle a first ply made up of a single element without running the risk of damaging said first ply, and/or when the shape of the first ply is complex with concave zones and convex zones, clever cutting of the ply allowing, in the latter case, first-ply portions essentially having a simple curvature able to foe produced on convex molds to be produced.

(43) Thus, according to one method of implementation of the first step 110 of the manufacture of the first ply 10, the second step 112 of depositing the second material 12 on the first material 11 is carried out before the first step III, the first material deposited on the first-ply mold 20 then already including the thermoplastic-resin powder of the second material.

(44) Advantageously, the complex formed by the first material and the thermoplastic powder of the second material is produced in an upstream step.

(45) The process thus allows a thermoplastic composite part to be produced with a first ply that is perfectly clamped to the tool, while ensuring that the resin of the first ply does not adhere to the tool, while avoiding the need for suction techniques that require seal-tight plies and that do not guarantee a homogenous pressure over the surface of the tool, and while avoiding use of the complex and expensive solution that is a counter-mold.