A CONDUCTIVE ELASTOMER, PREPARATION METHOD AND USE THEREOF

Abstract

A preparation method of a conductive elastomer includes the following steps: (1) according to the mass percent of 20˜75%, dissolving the metallic salts into deionized water to form an electrolyte solution, wherein said metallic salts is either of magnesium nitrate, sodium nitrate, zinc nitrate, cesium nitrate, calcium nitrate, neodymium nitrate, aluminum nitrate, potassium nitrate, potassium chloride, magnesium chloride, calcium chloride, sodium chloride, zinc chloride, cesium chloride, aluminum chloride or their combinations; (2) according to the mass percent of 10˜40%, mixing starches into the electrolyte solution prepared in step (1), then at the temperature of 33˜120 ° C., stirring to gelatinize the starches, forming a viscous liquid; (3) standing the viscous liquid obtained in step (2) at 25˜90° C. for 10 min to 48 h to obtain the conductive elastomer.

Claims

1. A preparation method of a conductive elastomer, comprising the following steps: (1) according to the mass percent of 20˜75%, dissolving the metallic salts into deionized water to form an electrolyte solution, wherein said metallic salts is either of magnesium nitrate, sodium nitrate, zinc nitrate, cesium nitrate, calcium nitrate, neodymium nitrate, aluminum nitrate, potassium nitrate, potassium chloride, magnesium chloride, calcium chloride, sodium chloride, zinc chloride, cesium chloride, aluminum chloride or their combinations; (2) according to the mass percent of 10˜40%, mixing starches into the electrolyte solution prepared in step (1), then at the temperature of 33˜120 ° C., stirring to gelatinize the starches, forming a viscous liquid; (3) standing the viscous liquid obtained in step (2) at 25˜90° C. for 10 min 3to 48 h to obtain the conductive elastomer.

2. The preparation method of a conductive elastomer according to claim 1, wherein said metallic salts is either of zinc nitrate, cesium nitrate, calcium nitrate, neodymium nitrate, aluminum nitrate, potassium nitrate, potassium chloride, calcium chloride, zinc chloride, cesium chloride, aluminum chloride or their combinations.

3. The preparation method of a conductive elastomer according to claim 1, wherein said starches is either original or modified corn, potato, wheat and barley, cassava, sweet potato, sticky rice starches or their combinations.

4. A conductive elastomer prepared according to the method in claim 1, wherein the resistivity of said conductive elastomer is 1˜1×10.sup.4Ω.Math.cm ; stretch ratio at elastic region is 1000˜2500%, stretch ratio at fracture is 1500%˜9000%; said conductive elastomer has bio-degradability and autofluorescence with emitting wavelength at 400˜500 nm.

5. A conductive elastomer prepared according to the method in claim 2, wherein said conductive elastomer is water soluble.

6. The application of a conductive elastomer prepared according to the method in claim 1, wherein using in the preparation of flexible circuits, conductive adhesives, conductive textile, medical and wound dressing, biomedical sealant or drug release system.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0006] The objective of this invention is to supply a kind of biodegradable, self-adhesive, highly transparent, environmentally friendly, and bio-safe conductive elastomer, preparation method and use thereof, in order to overcome the disadvantage of present conductive elastomer.

[0007] The technical solution to realize the objective is, a preparation method of a conductive elastomer, comprising the following steps:

[0008] (1) according to the mass percent of 20˜75%, dissolving the metallic salts into deionized water to form an electrolyte solution, wherein said metallic salts is either of magnesium nitrate, sodium nitrate, zinc nitrate, cesium nitrate, calcium nitrate, neodymium nitrate, aluminum nitrate, potassium nitrate, potassium chloride, magnesium chloride, calcium chloride, sodium chloride, zinc chloride, cesium chloride, aluminum chloride or their combinations;

[0009] (2) according to the mass percent of 10˜40%, mixing starches into the electrolyte solution prepared in step (1), then at the temperature of 33˜120 ° C., stirring to gelatinize the starches, forming a viscous liquid;

[0010] (3) standing the viscous liquid obtained in step (2) at 25˜90° C. for 10 min 4to 48 h to obtain the conductive elastomer.

[0011] In the present invention, said starches is either original or modified corn, potato, wheat and barley, cassava, sweet potato, sticky rice starches or their combinations.

[0012] The present invention also include a conductive elastomer prepared according to the above mentioned method, the resistivity of said conductive elastomer is 1˜1×10.sup.4Ω.Math.cm; stretch ratio at elastic region is 1000˜2500%, stretch ratio at fracture is 1500%˜9000%; said conductive elastomer has bio-degradability and autofluorescence with emitting wavelength at 400˜500 nm.

[0013] In the present invention, the conductive elastomer is water soluble when said metallic salts is either of zinc nitrate, cesium nitrate, calcium nitrate, neodymium nitrate, aluminum nitrate, potassium nitrate, potassium chloride, calcium chloride, zinc chloride, cesium chloride, aluminum chloride or their combinations.

[0014] The present invention supplies the use of a conductive elastomer, which includes using in preparations of flexible circuits, conductive adhesive, conductive textile, medical and wound dressing, biomedical sealant or drug release system.

[0015] The conductive elastomer bases on an elastic matrix that is a specific gelatinized starch. The electrolyte with high concentration of metallic salts is used as the conductive agent. The conductive elastomer is prepared by getting the specific electrolyte involved in the gelatinization process of specific starch. The stretch ratios at elastic region and fracture, and resistivity of the conductive elastomer are between 1000˜2500%, 1500%˜9000%, 1˜1×104Ω.Math.cm, respectively. It also has autofluorescence.

[0016] Compared with the prior art, the present invention solves the problem that gelatinized starches tend to loss water and become dry and brittle by supplying a stable conductive elastomer through making the specific electrolyte involved in the gelatinization process of specific starch. The conductive elastomer could be used in the preparations of flexible circuits, conductive adhesive, conductive textile, wound dressing, as well as tissue adhesion, drug release.

[0017] More importantly, this conductive elastomer has several advantages compared with the present conductive soft materials. Firstly, it is biodegradable, thus could be used for the design of biodegradable circuits, the fabrication of biodegradable conductive adhesive and conductive textiles. Secondly, it owns excellent stretchability and good stickiness, which could be used for the preparation of electric devices with high stretchability, and biomedical sealant. Thirdly, it has autofluorescence, which is helpful for the detection and monitoring the elastomer in devices or in vivo.

[0018] In summary, this invention has the following benefits compared with the existing materials and preparation methods:

[0019] 1. The raw materials for preparing the elastomer have abundant sources, are cost effective, environmentally friendly, and safe to human.

[0020] 2. The preparation method is simple with low requirement for equipment, easy to realize large scale production and environmentally friendly.

[0021] 3. This conductive elastomer simultaneously owns high elasticity, high conductivity, biodegradability, autofluorescence, good stickiness, high transparency, and is environmentally friendly and nontoxic, which could be used in the preparations of flexible circuits, conductive adhesives, conductive textile, medical and wound dressing, biomedical sealant or drug release system.

Preferred Embodiments

Embodiment 1

[0022] An electrolyte solution was prepared by dissolving 3.5g of magnesium chloride in 9 ml of deionized water at room temperature or by heating. Then 4 g of corn starch was added in the electrolyte and gelatinized at 60° C., continuously stirring to obtain a viscous liquid. Then let the viscous liquid standing at 25° C. for 40 h, forming a semi-transparent conductive elastomer.

[0023] The mechanical properties of the elastomer were measured by uniaxial tensile test. The results showed that the stretch ratios at elastic region and fracture were 1100% and 1700%, respectively. The conductivity of the elastomer was measured by constant voltage test. The results showed that the volume resistivity was 5.7×10.sup.3Ω.Math.cm. It also had autofluorescence with an emitting wavelength at 450 nm. The adhesive strength of elastomer measured by tensile detachment test on polished pure copper was 50 kPa.

[0024] The elastomer was used for the preparation of flexible circuits: The viscous liquid after gelatinization of starch was filled in a printer, and printed into circuits on a flexible substrate. The flexible circuits were formed after aging for 24 h.

[0025] The elastomer was used for the preparation of conductive textile: The viscous liquid after gelatinization of starch was placed in a vacuum chamber under a vacuum <10 kPa for 15 min. The viscous liquid was coated on textile and aged at 40° C. for 12 h, forming conductive textile whose surface resistivity is 2.4×10.sup.4Ω/□.

[0026] The elastomer could be totally dissolved in water whose volume was 15 times of that of the elastomer.

Embodiment 2

[0027] The metallic salts in Table 1 were dissolved in 10 ml of deionized water using the weight percentages shown in Table 1. Then 3 g of sweet potato starch was added in the solutions and gelatinized at 50° C., continuously stirring to form viscous liquids. Then the liquids were aged at 37° C. for 4 h to obtain the semi-transparent conductive elastomers. The volume resistivity, stretch ratios at elastic region and fracture of the elastomers were measured using methods in Embodiment 1. The results were listed in Table 1.

TABLE-US-00001 TABLE 1 Volume resistivity, stretch ratios at elastic region and fracture of the elastomers prepared with different metallic salts. Stretch ratio Stretch Weight Volume at elastic ratio at percent resistivity region fracture No. Metallic salts (%) (Ω .Math. cm) (%) (%) 1 Zinc nitrate 50 110.1 1366.4 2912.3 2 Magnesium nitrate 20 7891.1 1155.6 1510.6 3 Sodium nitrate 30 692.3 2356.7 3521.6 4 Cerium nitrate 25 45.2 1399.2 2614.2 5 Calcium nitrate 35 556.7 1268.2 2900.5 6 Neodymium nitrate 60 289.1 1366.2 6789.2 7 Aluminum nitrate 75 3.6 2157.9 3687.5 8 Potassium chloride 40 74.5 1124.1 2510.2 9 Calcium chloride 50 965.1 1241.2 8769.5 10 Sodium chloride 45 138.9 1921.9 1899.2 11 Zinc chloride 55 2166.5 1221.3 1906.5 12 Cerium chloride 65 97.2 1354.5 7566.7 13 Aluminum chloride 70 5.4 1287.2 2817.6 14 Potassium chloride 5 2.2 1355.4 2546.2 Aluminum nitrate 10 Sodium nitrate 5 15 Calcium chloride 20 6690.7 1156.2 4987.6 Neodymium nitrate 30 Zinc nitrate 20

Embodiment 3

[0028] 4 g of zinc chloride was dissolved in 8 ml of deionized water. Then the starches listed in Table 2 were added to the solutions using the weight percentages shown in Table 2, stirring under the temperature in Table 2 to obtain a viscous liquid, then let the viscous liquid standing at 60° C. for 4 h, to obtain semi-transparent conductive elastomers. The volume resistivity, stretch ratios at elastic region and fracture of the elastomers were measured and the results were listed in Table 2.

TABLE-US-00002 TABLE 2 Volume resistivity, stretch ratios at elastic region and fracture of the elastomers prepared with different starches. Stretch ratio at Stretch Weight Tem- Volume elastic ratio at Test percent perature resistivity region fracture No. Starches (%) (° C.) (Ω .Math. cm) (%) (%) 1 Corn 10 65 1230.5 1455.6 2187.3 2 Potato 25 55 2236.6 1103.6 2513.6 3 Wheat 35 65 2514.5 1261.5 3514.2 4 Barley 20 60 2615.3 1355.6 2354.2 5 Sweet potato 15 80 3621.5 1261.2 2155.2 6 Sweet potato 30 70 2531.2 1356.2 3654.3 7 Cassava 40 60 1987.6 1245.3 3123.2 8 Glutinous rice 25 60 1875.2 1231.6 2917.2 9 Modified corn 30 65 2621.3 1566.3 2899.1 10 Potato 10 Red sweet 10 55 2465.7 1366.2 3412.8 potato White sweet 15 potato

Embodiment 4

[0029] Opaque conductive elastomer was obtained by vigorously stirring the viscous liquid after gelatinization of starch in Embodiment 1 and aged at 50° C. for 2 hours. And the transparent conductive elastomer was obtained by placing the viscous liquid after gelatinization of starch in Embodiment 1 in vacuum chamber under a vacuum <10 kPa for 15 min and aged at 50° C. for 20 hours.

[0030] The transparent conductive elastomer provided in this example was used for the tissue adhesion of the myocardial defect: the rat model of myocardial defect was made, and then the elastomer (after exposure to UV irradiation to sterilization) was applied to the defect, and it was observed that the elastomer could be tightly attached to the surface of the heart and adhered the defect parts together.