Nanoparticle coating apparatus

Abstract

The present invention provides an apparatus for forming a uniform, large scale nanoparticle coating on a substrate. The apparatus comprises a source of vaporised metal nanoparticles. The apparatus further comprises a first plate (20) providing an array of spaced apart first apertures (22). The apparatus further comprises a second plate (24) aligned with and spaced apart from the first plate (20). The second plate (24) provides an array of spaced apart second apertures 26. Each second aperture (26) of the second plate (24) is aligned with a first aperture (22) of the first plate (20).

Claims

1. An apparatus for forming a uniform, large scale nanoparticle coating on a substrate, in which the apparatus comprises: a source of vaporized metal nanoparticles; a first plate providing an array of spaced apart first apertures each apertures receiving vaporized metal nanoparticles; a second plate aligned with and spaced apart from the first plate, in which the second plate provides an array of spaced apart second apertures, in which each second aperture of the second plate is aligned with a first aperture of the first plate thereby producing a stream of free nanoparticles for use in forming the uniform, large scale nanoparticle coating, where the apparatus is configured to cause differential pumping between the first and second plates to produce the stream of free nanoparticles; and a plurality of shell evaporators aligned with respective second apertures of the second plate.

2. The apparatus of claim 1, further comprising a plurality of lenses, in which each lens is associated with a corresponding one of the first apertures of the first plate.

3. The apparatus of claim 2, in which one or more of the lenses are aerodynamic lenses.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) An embodiment of the invention will now be described, by way of example only, and with reference to the accompanying drawings, in which:

(2) FIG. 1 illustrates a conventional apparatus for forming nanoparticle coatings on a substrate;

(3) FIG. 2 illustrates apparatus according to a first embodiment of the present invention for forming uniform, large scale nanoparticle coatings on a substrate;

(4) FIG. 3 illustrates a simulation of the nanoparticle deposit produced by the single point source of nanoparticles at a set distance from the conventional apparatus of FIG. 1;

(5) FIG. 4 illustrates a simulation of the nanoparticle deposit produced by the multiple point source of nanoparticles at a set distance from the apparatus of FIG. 2; and

(6) FIG. 5 illustrates apparatus according to a further embodiment of the present invention for forming uniform, large scale shell-coated nanoparticle coatings on a substrate.

DETAILED DESCRIPTION OF THE INVENTION

(7) As shown in FIG. 1, the conventional apparatus 2 for forming nanoparticle coatings on a substrate comprises a nanoparticle gas aggregation source 4 that produces nanoparticles using thermal evaporation. The nanoparticle gas aggregation source 4 produces metal vapour with a flow of He at a few mbar pressure. The supersaturated metal vapour so formed condenses to provide metal nanoparticles.

(8) The vaporised metal nanoparticles are then passed through a first aperture 6 to produce a first stream 8 of nanoparticles. This first stream 8 is then incident on a second aperture 10. The second aperture is often in the shape of a skimmer. Differential pumping may occur between the first 6 and second 10 apertures in order to remove the gas so that a stream of free nanoparticles emerges from the second aperture 10.

(9) As can be seen from FIG. 3, the conventional apparatus 2 provides a single point source 12 stream of free nanoparticles to provide a coating over a small region of the substrate. Typically the angle of divergence of the single point source stream 12 is approximately 17. As a result, it is difficult to provide a coating of nanoparticles over a large area on a substrate. In order to do this, the substrate may need to be positioned a significant distance away from the second aperture 10 of the apparatus. Furthermore, it has been found that the thickness of the nanoparticle coating provided on a substrate varies depending on the distance of that portion of the substrate from the centre of the single point source stream 12. As a result, if the nanoparticle coating is required to be of a uniform thickness, the substrate will need to be positioned even further away from the second aperture in order to provide a uniform thickness coating over a central region of the substrate. In this case, only the central region of the substrate will have a coating having a substantially uniform thickness.

(10) The present invention provides an apparatus and a method for forming a uniform, large scale nanoparticle coating on a substrate. As shown in FIG. 2, the apparatus comprises: a source of vaporised metal nanoparticles; a first plate 20 providing an array of spaced apart first apertures 22; and a second plate 24 aligned with and spaced apart from the first plate 20. The second plate 24 provides an array of spaced apart second apertures 26. Each second aperture 26 of the second plate 24 is aligned with a first aperture 22 of the first plate 20. A skimmers 29 is located adjacent each of the second apertures 26 shown in the apparatus.

(11) The source of vaporised metal nanoparticles may be prepared by any conventional method. For example, the vaporized metal nanoparticles source may produce metal vapour with a flow of helium.

(12) The term nanoparticle is used herein to refer to particles with dimensions in the range of between 1 nm and 100 nm.

(13) The dimensions and shape of each of the first 20 and second 24 plates may vary depending on the requirements for the apparatus. The separation between the first 20 and second 24 plates may vary depending on the requirements for the emerging second stream of free nanoparticles. The separation between the second plate and the substrate to be coated may also vary depending on the requirements for the coating.

(14) The apparatus shown in FIG. 2 comprises an array of first apertures 22 and an array of second apertures 26. Each array comprises 13 apertures. It is however to be understood that the array of first apertures 22 and the array of second apertures 26 may include any suitable number of apertures in any suitable configuration. Preferably, the number of first apertures 22 is the same as the number of second apertures 26. Preferably, the spacings between pairs of first apertures 22 and the configuration of the first apertures 22 is substantially the same as the spacings between respective pairs of second apertures 26 and the configuration of the second apertures 26. For example, the configuration of the array of first apertures 22 and the second apertures 26 may have any suitable shape, and may for example be selected from substantially circular, rectangular, square, ovaloid, cross-shaped, or any combination thereof.

(15) The apparatus further comprises a plurality of lenses 28. Each lens 28 may be aligned with a first aperture 22 of the first plate 20. Each lens 28 is arranged to focus nanoparticles having a predetermined dimensions into a respective first aperture 22 of the first plate 20. The lens 28 may be any suitable lenses for focusing the nanoparticles having the desired predetermined dimensions to the first apertures 22. In the apparatus illustrated in FIG. 2, the lenses 28 are aerodynamic lenses.

(16) The lenses are selected in order to provide a lens having the required internal dimensions for focusing the nanoparticles having the predetermined dimensions required to provide the coating. The size distribution of the resultant nanoparticles emerging from the apparatus may be varied by selecting different lenses having different internal dimensions.

(17) The apparatus further comprises a plurality of skimmers 29. Each skimmer 29 is arranged to be aligned with, for example located adjacent to and to extend around, a second aperture 26. It is to be understood that the apparatus may not include skimmers.

(18) Although it is not shown in FIG. 2, the first plate 20 may be located within a first chamber of the apparatus. The second plate 24 may be located within a separate chamber (for example, second chamber) of the apparatus.

(19) In use, the desired aerodynamic lenses 28 having the required internal dimensions for focusing nanoparticles having predetermined dimensions are selected and positioned adjacent to each of the first apertures 22. A source of vaporized metal nanoparticles is produced (more details?). The vaporized metal nanoparticles having the required predetermined dimensions are focused by the aerodynamic lens 28 and pass through the first apertures 22 to produce multiple first streams of vaporized metal nanoparticles. Each of the first streams is channeled through a respective skimmer 29 positioned adjacent the respective second aperture 26 of the second plate 24 of the apparatus. A stream of free nanoparticles 30 having a narrow size distribution about a predetermined nanoparticle size emerge from the apparatus to impinge on a substrate (not shown). Examples of suitable substrates include, but are not limited to, wafers and write heads for hard disk storage systems

(20) FIG. 3 illustrates a simulation of a nanoparticle coating or deposit produced on a substrate positioned at a set distance from a single aperture apparatus (as shown in FIG. 1). FIG. 4 illustrates a simulation of a nanoparticle coating or deposit produced on a substrate positioned at the same distance away from the 13 aperture apparatus as shown in FIG. 2. It can be seen from these Figures that the present invention provides a uniform coating of nanoparticles over a significantly greater area than the single aperture apparatus of FIG. 1. The apparatus of the present invention is easily scaleable to coat a required area of a substrate having any shape and/or dimensions. It is to be understood that for any given distance between the substrate and the apparatus, the number and/or configuration of apertures provided by the apparatus can be optimized.

(21) As shown in FIG. 5, the apparatus may include a plurality of shell evaporators 50. Each shell evaporator 50 is aligned with a respective second aperture 26 of the second plate 24 of the apparatus. Each shell evaporator 50 comprises an elongate heated tube 52 defining a longitudinal axis A-A. Each heated tube 52 provides an open channel 54 extending therethrough, and substantially aligned with the longitudinal axis of the tube 52. Each heated tube 52 is surrounded by a water-cooled heat shield 55 so that the rest of the apparatus is not heated by the tubes 52. Shell coating material 53 is located within the channel 54 of each tube 52. Any suitable shell coating material may be used.

(22) In use, each stream of free nanoparticles 30 passes through a shell evaporator 50. A local high vapour pressure of the shell material is produced around each nanoparticle stream 30 so that the method allows very efficient use of shell materials. The differential pressure in the nanoparticle stream prevents the shell material moving upstream from the tube into the nanoparticle source. A stream of free shell material coated nanoparticles 56 emerge from each shell evaporator 50 prior to impinging with a substrate for coating.

(23) The present invention may be used specifically to provide nanoparticle coatings on write heads for hard disk storage systems. In particular, the present invention may provide an apparatus and method for providing a substantially uniform layer of FeCo alloy on a wafer of a write head such that each write head has a high magnetization tip to maximize the magnetic field available for writing data onto the disk. It is known that Co nanoparticles embedded in Fe matrices produce films with a higher magnetization than FeCo alloys. The present invention therefore provides an apparatus and a method for providing a uniform, large scale coating of Co on a substrate, for example a wafer, comprising a Fe matrix.

(24) Although aspects of the invention have been described with reference to the embodiment shown in the accompanying drawings, it is to be understood that the invention is not limited to the precise embodiment shown and that various changes and modifications may be effected without further inventive skill and effort.