OPTICAL ELEMENT AND METHOD OF MANUFACTURING OPTICAL ELEMENT
20180003891 · 2018-01-04
Assignee
Inventors
Cpc classification
B29C45/0013
PERFORMING OPERATIONS; TRANSPORTING
B29C2045/7356
PERFORMING OPERATIONS; TRANSPORTING
G02B6/4214
PHYSICS
G02B7/028
PHYSICS
International classification
B29C45/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
An optical element is configured to transmit a light flux emitted from a light source having a single light source wavelength, and is formed from a material in which resin and glass fillers are mixed. A difference between respective refractive index change rates (dn/dT) of the resin and the glass fillers relative to a temperature change at least in a vicinity of the light source wavelength becomes 10.5×10.sup.5 or less.
Claims
1. An optical element that transmits a light flux emitted from a light source having a single light source wavelength, wherein the optical element is formed from a material in which resin and glass fillers are mixed, and a difference between respective refractive index change rates (dn/dT) of the resin and the glass fillers relative to a temperature change at least in a vicinity of the light source wavelength becomes 10.5×10.sup.−5 or less.
2. An optical element that transmits a light flux emitted from a light source having a single light source wavelength, wherein the optical element is formed from a material in which resin and glass fillers are mixed, and a difference between respective linear expansion coefficients of the resin and the glass fillers at least in an operating temperature range of the optical element becomes 6.0×10.sup.−5 or less.
3. The optical element described in claim 1, wherein transmittance of the resin in a state of being molded into a parallel flat plate with a thickness of 3 mm is 50% or more relative to light with the light source wavelength.
4. The optical element described in claim 1, wherein the resin is one selected from a group consisting of polycarbonate (PC), polymethyl methacrylate (PMMA), polyolefin resins, transparent polyamide (PA), polysulfone (PSU)/polyphenylene sulfone (PPSU), polyether sulfone (PES), polyether imide (PEI), and polyetheretherketone (PEEK).
5. The optical element described in claim 1, wherein a mixed amount of the glass fillers is 2 to 40 wt %.
6. The optical element described in claim 1, wherein the glass fillers are glass fibers.
7. The optical element described in claim 6, wherein each of the glass fibers has a configuration of a rod-like body with a cross section with a diameter of 5 to 50 μm and a length of 10 to 500 μm.
8. The optical element described in claim 1, wherein the light source wavelength is one selected from a group consisting of 850±150 nm, 1310±150 nm, and 1550±150 nm.
9. The optical element described in claim 1, wherein the optical element has optical surfaces used for optical communication arranged in an array form.
10. A method of manufacturing an optical element that transmits a light flux emitted from a light source having a single light source wavelength and is formed from a material in which resin and glass fillers are mixed, the method comprising: mixing resin and glass fillers such that a difference between respective refractive index change rates (dn/dT) of the resin and the glass fillers relative to a temperature at least in a vicinity of the light source wavelength change becomes 10.5×10.sup.−5 or less; injecting the mixed materials into a cavity formed in a mold; cooling the mixed material in the mold so as to mold an optical element; and taking out the molded optical element.
11. A method of manufacturing an optical element that is configured to transmit a light flux emitted from a light source having a single light source wavelength and is formed from a material in which resin and glass fillers are mixed, the method comprising: mixing resin and glass fillers such that a difference between respective linear expansion coefficients of the resin and the glass filler at least in an operating temperature range of the optical element becomes 6.0×10.sup.−5 or less; injecting the mixed materials into a cavity formed in a mold; cooling the mixed material in the mold so as to mold an optical element; and taking out the molded optical element.
12. The optical element described in claim 2, wherein transmittance of the resin in a state of being molded into a parallel flat plate with a thickness of 3 mm is 50% or more relative to light with the light source wavelength.
13. The optical element described in claim 2, wherein the resin is one selected from a group consisting of polycarbonate (PC), polymethyl methacrylate (PMMA), polyolefin resins, transparent polyamide (PA), polysulfone (PSU)/polyphenylene sulfone (PPSU), polyether sulfone (PES), polyether imide (PEI), and polyetheretherketone (PEEK).
14. The optical element described in claim 2, wherein a mixed amount of the glass fillers is 2 to 40 wt %.
15. The optical element described in claim 2, wherein the glass fillers are glass fibers.
16. The optical element described in claim 15, wherein each of the glass fibers has a configuration of a rod-like body with a cross section with a diameter of 5 to 50 μm and a length of 10 to 500 μm.
17. The optical element described in claim 2, wherein the light source wavelength is one selected from a group consisting of 850±150 nm, 1310±150 nm, and 1550±150 nm.
18. The optical element described in claim 2, wherein the optical element is an optical element in which optical surfaces used for optical communication are arranged in an array form.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0042]
[0043]
[0044]
[0045]
[0046]
[0047]
[0048]
[0049]
[0050]
[0051]
DESCRIPTION OF EMBODIMENTS
[0052] In one or more embodiments, the term “single light source wavelength means that a light source wavelength used for a specific purpose is single. For example, in optical communication etc., even in the case where the same optical element is used for an uplink communication and a downlink communication, there may be a case where light source wavelengths may differ. In such a case, it means that the light source wavelength at the time of the uplink communication is single, and the light source wavelength at the time of the downlink communication is single.
[0053] As glass fillers, a general-purpose E glass, C glass, A glass, S glass, D glass, NE glass, T glass, silica glass, etc. may be used. For example, it may be possible to use those prepared by selecting materials from silicon dioxides (SiO.sub.2), aluminum oxides (Al.sub.2O.sub.3), calcium oxides (CaO), titanium oxides (TiO.sub.2), boron oxides (B.sub.2O.sub.3), magnesium oxides (MgO), zinc oxides (ZnO), barium oxides (BaO), zirconium dioxides (ZrO.sub.2), lithium oxides (Li.sub.2O), sodium oxides (Na.sub.2O), potassium oxides (K.sub.2O), etc., and by adjusting the ratio of each of the selected materials.
[0054] In one or more embodiments, as the glass fillers, glass fibers (glass fibers), glass powders, glass flakes, milled fibers, or glass beads may be used. In the embodiments and examples mentioned below, description is given to glass fibers as a representative of the glass fillers.
[0055] The glass fibers can be obtained by using well-known methods of spinning long glass fibers. For example, glasses can be made into fibers by using various kinds of methods, such as the direct melt (DM) method in which glass raw materials are continuously made to glasses in a melting furnace and the resulting glasses are introduced to a forehearth and spun with bushings attached to the bottom of the forehearth, and the remelting method in which melted glasses are molded in the form of a marble, a caret, or a bar and the molded glasses are remelted and spun.
[0056] Although the diameter of a glass fiber is not particularly limited, a diameter of 5 to 50.Math.m is preferably used. The diameter thinner than 0.5.Math.m increases the contact area between glass fibers and resin and causes irregular reflection, which may result in that the transparency of a molded-product lowers. On the other hand, the diameter thicker than 50.Math.m increases a filling pressure at the time of injection molding, which may lead to the insufficient transfer to a mold. The diameter is more preferably 10 to 45.Math.m.
[0057] It should be noted that it is important that the glass fillers contain 90% or more (preferably 95% or more) particles with sizes larger than a light source wavelength relative to the whole of the glass fillers. Until now, it has been tried to mold an optical element by using resin material into which, for example, particles with diameters of 30 nm or less are mixed. However, there has been a problem that particles tend to aggregate in this resin material, there has been another problem that the surface area of particles increase and the resin material tends to become hard so that the molding becomes difficult, and furthermore, there has been still another problem that the increased surface area of particles makes the hydrophilicity higher so that the water absorption rate of the molded optical element increases and the optical properties change. On the other hand, these problems can be solved by making the glass fillers into particles larger than a light source wavelength.
[0058] Here, examples of the “optical element” include, without being limited thereto, a lens, a prism, a diffractive grating element (a diffractive lens, a diffractive prism, a diffractive plate), an optical filter (a spatial low pass filter, a wavelength band pass filter, a wavelength low pass filter, and a wavelength high pass filter, etc.), a polarizing filter (an analyzer, an azimuth rotator, a polarizing separation prism, etc.), and a phase filter (a phase plate, a hologram, etc.).
[0059] Hereinafter, embodiments of the present invention are described based on the drawings.
[0060] As shown in
[0061] The optical connector 130 includes a main body 131 made of resin, is connected to the optical fibers 132, and has a function to hold this.
[0062] As the optical fibers 132, for example, all quartz type multimode type optical fibers, or single mode type optical fibers may be used. As the configuration of the optical fibers 132, a single core optical fibers may be used. However, in one or more embodiments, a multi core optical fiber tape (ribbon) which includes two or more optical fibers, is used.
[0063] The main body 131 is molded into a thicker rectangular plate shape, and, when viewing from an upper portion in
[0064] The bottom surface 131d of the concave portion 131a on which each of the through holes 131c is exposed, is made orthogonal to an undersurface 131e of the main body 131. Moreover, as are shown in
[0065] In
[0066] The first surface 121 is a flat surface and has a function to allow light fluxes emitted from the semiconductor laser 112 of the optical module 110 to enter. The second surface 122 includes a plurality of reflective surfaces 122a disposed by being arranged along a single line, a flat joining surface 122b formed on the perimeter of the reflective surfaces 122a, and a rectangular frame-shaped protruding portion 122c formed on the outer periphery of the second surface 122 so as to surround the perimeter of the joining surface 122b. It is desirable that an inclined surface 122d is formed between the joining surface 122b and the protruding portion 122c. The third surface 123 is a flat surface and has a function to transmit light fluxes reflected from the reflective surfaces 122a.
[0067] Each of the reflective surfaces 122a has the same configuration that protrudes from the joining surface 122b, is shaped specifically in the form of an ellipse when being viewed from a front face, and has an anamorphic free curved surface capable of bending the optical axis of an entering conical divergent light flux by 90 degrees and reflecting the light flux as a conical convergent light flux. In an example shown in
[0068] The height of the protruding portion 122c from the joining surface 122b is made uniform over the whole perimeter, and larger than the protrusion amount of the reflective surface 122a. Accordingly, as shown in
[0069] In
B/A<1.0 (1)
[0070] In the optical path changing element 120, a parallel flat plate-like cover member 125 is bonded to the whole perimeter of the protruding portion 122c so as to overlap the virtual plane VP. In the case where the cover member 125 is a light blocking member, it is preferable, because it becomes possible to suppress the deterioration of the optical path changing element 120 and to prevent light rays from invading into the inside of a lens from the outside. The disposition of the cover member 125 causes a gap between the cover member 125 and the reflective surfaces 122a. Accordingly, there is no fear that the cover member 125 damages the reflective surface 122a and that, even in the case where a reflecting film is formed on the reflective surface 122a, the cover member 125 damages the reflecting film. In addition, since the cover member 125 can be disposed so as to overlaps the virtual plane VP, even in the case of laminating a substrate provided with the optical coupling apparatus 100, it is possible to contribute to the miniaturization in the lamination direction. Furthermore, the reflective surface 122a is sealed in a sealing space with the cover member 125, whereby the reflective surface 122a can be protected from the bad influence of the external environment, such as adhesion of foreign substances. Moreover, the gap between the reflective surface 122a and the virtual plane VP may be sealed with resin so as to prevent adhesion of foreign substances and dew condensation. The sealing with the cover member 125 or the resin is not necessarily performed. However, from the above-mentioned reasons, it is desirable to perform sealing with the cover member 125 or the resin. As shown in
[0071] (Molding of an Optical Path Changing Element)
[0072]
[0073] In this example, the optical path changing element is molded by using the raw material into which 2 to 40 wt % glass fibers relative to resin are mixed. An elongated bar-shaped glass fiber is crushed, the crushed glass fibers are mixed with resin materials at a ratio of 2 to 40 wt %, the resulting mixed materials are put into an injection molding machine, and then, injection molding is performed. The resins and the glass fibers are selected such that a difference between the respective refractive index change rates (dn/dT) of the resins and the glass fibers relative to a temperature change at least in the vicinity of a light source wavelength is 10.5×10.sup.5 or less, and the glass fibers are mixed into the resins so as to obtain a resin material. Alternatively, the resins and the glass fibers are selected such that a difference between the respective linear expansion coefficients of the resins and the glass fibers at least within an operating temperature range is 6.0×10.sup.−5 or less, and the glass fibers are mixed into the resins so as to obtain a resin material. It is preferable that the transmittance of the resins in a state of being molded into a parallel plate with a thickness of 3 mm is 50% or more at light source wavelengths. It is preferable that the configuration of the glass fiber is a rod-like body with a cross section with a diameter of 5 to 50.Math.m and a length of 10 to 500.Math.m. The term “wt %” refers to weight %.
[0074] As shown in
[0075] With the inclined surface MD1 a of the first molding die MD1, the first surface 121 of the optical path changing element 120 is transferred and formed, and with the inclined surface MD1b, the third surface 123 is transferred and formed. On the other hand, with the optical surface MD2 a on the mold of the second molding die MD2, the reflective surfaces 122a of the optical path changing element 120 are transferred and formed, with the joining surface transferring surface MD2b, the joining surface 122b is transferred and formed, and with the protruding portion transferring surface MD2c, the protruding portion 122c is transferred and formed. Since the protruding portion transferring surface MD2c is separated away from the optical surface MD2a on the mold, there is little fear that the bad influence at the time of molding the protruding portion 122c with the protruding portion transferring surface MD2c affects the reflective surfaces 122a molded by the optical surface transferring surface MD2a, and the configuration of the reflective surfaces 122a can be maintained with sufficient accuracy.
[0076] As shown in
[0077] Hereinafter, a preferable mode of the above-mentioned optical element is described collectively.
[0078] In the above-mentioned optical element, it is preferable that the transmittance of the above-mentioned resin in a state of being molded into a parallel flat plate with a thickness of 3 mm is 50% or more relative to a light flux with the light source wavelengths.
[0079] According to the examination results of the present inventors, in the case where the transmittance of the above-mentioned resin in a state of being molded into a parallel flat plate with a thickness of 3 mm is made to 50% or more relative to a light flux with the light source wavelengths, with an antireflection coat applied to each of the both surfaces of the plate, an improvement in transmittance of about 5% on one surface can be expected. Accordingly, it becomes possible to secure a transmittance of 60% (internal resorption component of 40%) in total. In many cases, in actual optical elements, since the length of a light ray passage passing through the inside of an optical element is about 1 mm, an internal resorption component becomes 13% (40%/3 mm). Accordingly, it becomes possible to obtain a product transmittance of 87%, which is preferable.
[0080] Moreover, it is preferable that the above-mentioned resin is any of polycarbonate (PC), polymethyl methacrylate (PMMA), polyolefin resins, transparent polyamide (PA), polysulfone (PSU)/polyphenylene sulfone (PPSU), polyether sulfone (PES), polyether imide (PEI), and polyetheretherketone (PEEK). Since such resins are excellent in transparency and has good compatibility with glass fillers, they are suitable as the raw materials of an optical element.
[0081] Moreover, the mixing (mixing-into) amount of glass fillers is preferably 2 to 40wt %. In the case where the mixing-into amount of the glass fillers is made 2wt % or more, it becomes possible to obtain effects sufficient to adjust a linear expansion coefficient. On the other hand, in the case where the mixing-into amount of the glass fillers is made 40wt % or less, it becomes possible to avoid bad influences, such as deterioration of moldability and operation failure of injection. Furthermore, even if the mixing-into amount of the glass fillers is too much, there is also a side aspect that the effect of adjustment of a linear expansion coefficient is small.
[0082] Moreover, the glass fillers are preferably glass fibers. The glass fibers being fine rod-like body have an effect to adjust a linear expansion coefficient easily by being mixed in resin.
[0083] Furthermore, the configuration of the glass fibers is a rod-like body with a cross section with a diameter of 5 to 50.Math.m and a length of 10 to 500.Math.m. With this, general glass fibers can be used.
[0084] Moreover, the light source wavelength is preferably any one of 850±150 nm, 1310±150 nm, and 1550±150 nm. Since such a light source wavelength is frequently used in optical communication, it is desirable that it can deal with this.
[0085] Moreover, the above-mentioned optical element is preferably an optical element that is used for optical communication and has optical surfaces aligned in an array form.
[0086] Hereinafter, description is given to examples usable in the above-mentioned embodiments. Here, a case of using only general purpose PC (polycarbonate) material was made into Comparative Example 1, furthermore, Comparative Example 2 was prepared by mixing glass fibers (product name: FF5) manufactured by Hoya Corporation into the same PC material, and Example 1 was prepared by mixing glass fibers (product name: BACD12) manufactured by Hoya Corporation into the same PC material. Then, a peak wavelength deviation amount, a refractive index for each wavelength, a refractive index change rate (dn/dT) relative to a temperature change (normal temperature+55° C.), a difference between the respective refractive index change rates (dn/dT) of the PC material (resin) and the glass fibers relative to a temperature change, a linear expansion coefficient in an operation temperature range, and a difference between the respective linear expansion coefficients of the PC material (resin) and the glass fibers were obtained, and the obtained values were compared with each other. In the calculation of do/dT in the vicinity of the light source wavelength, an approximate curve may be used. In the Comparative Examples and Examples, refractive indexes at the light source wavelengths.Math.=486 nm, 587 nm, and 656 nm are approximated with a linear curve, and then the value of do/dT was calculated. The results are shown in Table 1.
TABLE-US-00001 TABLE 1 Peak wavelength deviation amount in mixed-into molded-product Difference in Linear Difference in linear normal temperature Refractive index dn/dT for expansion expansion coefficient to 55° C. λ486 nm λ587 nm λ656 nm dn/dT PC material coefficient for PC material Comparative — 1.596 1.583 1.577 10.9 × 10.sup.−5 0 6.5 × 10.sup.−5 0 Example 1 only PL Comparative 27 nm 1.605 1.593 1.588 0.1 × 10.sup.−5 10.8 × 10.sup.−5 0.1 × 10.sup.−5 6.4 × 10.sup.−5 Example 2 PL + GF Example 1 12 nm 1.590 1.583 1.580 0.4 × 10.sup.−5 10.5 × 10.sup.−5 0.5 × 10.sup.−5 6.0 × 10.sup.−5 PL + GF
[0087] From the comparison results in Table 1, in Comparative Example 2, a difference between the respective refractive index change rates (dn/dT) of the resin and the glass fibers relative to the temperature change in the light source wavelength (587 nm) was 10.8×10.sup.−5, a difference between the respective linear expansion coefficients of the resin and the glass fibers in the operation temperature range of the optical element was 6.4×10.sup.−5, and a peak wavelength deviation amount was 27 nm. In contrast, in Example 1, a difference between the respective refractive index change rates (dn/dT) of the resin and the glass fibers relative to the temperature change was 10.5×10.sup.−5, a difference between the respective linear expansion coefficients o the resin and the glass fibers in the operating temperature range of the optical element was 6.0×10.sup.−5, and a peak wavelength deviation amount was reduced to 12 nm being the half of the above value. Based on the consideration for the above results, as the refractive index change rate dn/dT of the glass fibers mixed into the resin relative to a temperature change is closer to the refractive index change rate dn/dT of the resin, it is presumed that the peak wavelength deviation amount can be suppressed. Moreover, the linear expansion coefficient of the glass fibers mixed into the resin is closer to the linear expansion coefficient of the resin, it is presumed that the peak wavelength deviation amount can be suppressed.
[0088] It is clear for a person skilled in the art from the embodiments and examples written in the present specification and technical concepts that the present invention should not be limited to the embodiments and examples written in the present specification, and includes other embodiments and examples, and modification embodiments. For example, the optical element of the present invention can be used for a collimator of a small type projector and an optical pickup apparatus without being limited to the optical communication.
REFERENCE SIGNS LIST
[0089] 100 Optical Coupling Apparatus [0090] 110 Optical Module [0091] 111 Base Plate [0092] 112 Semiconductor Laser [0093] 113 Pin [0094] 120 Optical Path Changing Element [0095] 121 First Surface [0096] 122 Second Surface [0097] 123 Third Surface [0098] 125 Cover Member [0099] 130 Optical Connector [0100] 131 Main Body [0101] 131a Concave portion [0102] 131b Insertion Hole [0103] 131c Through Hole [0104] 131d Bottom Surface [0105] 131e Undersurface [0106] 131f Circular Opening [0107] 132 Optical Fiber [0108] 132a Protecting Portion [0109] 132b Fiber Bare wire