Method for fabricating single crystal piezoelectric RF resonators and filters with improved cavity definition
10771031 ยท 2020-09-08
Assignee
Inventors
Cpc classification
H03H2003/021
ELECTRICITY
H03H9/1014
ELECTRICITY
H03H2003/027
ELECTRICITY
Y10T29/42
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10T29/49005
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H03H2003/023
ELECTRICITY
International classification
H03H3/02
ELECTRICITY
H03H9/13
ELECTRICITY
Abstract
A method of fabricating an FBAR filter device including an array of resonators, each resonator comprising a single crystal piezoelectric film sandwiched between a first metal electrode and a second metal electrode, wherein the first electrode is supported by a support membrane over an air cavity, the air cavity embedded in a silicon dioxide layer over a silicon handle, with through-silicon via holes through the silicon handle and into the air cavity, the side walls of said air cavity in the silicon dioxide layer being defined by perimeter trenches that are resistant to a silicon oxide etchant.
Claims
1. A method of fabricating an FBAR filter device comprising an array of resonators, each resonator comprising a single crystal piezoelectric film sandwiched between a first metal electrode and a second metal electrode, wherein the first metal electrode is supported by a support membrane over an air cavity, the air cavity embedded in a silicon dioxide layer over a silicon handle, with through-silicon via holes through the silicon handle and into the air cavity, said air cavity in the silicon dioxide layer having side walls defined by perimeter trenches that are resistant to a silicon dioxide etchant, comprising stages of: A. fabricating the support membrane over a silicon dioxide box on the silicon handle, having through support membrane filled barriers that traverse the silicon dioxide layer, and wherein the support membrane is coated with at least a first bonding layer of the first metal electrode coupled to the support membrane by a first adhesion layer; B. fabricating a piezoelectric film coupled to a detachable carrier substrate and coated with at least a second bonding layer of the first metal electrode coupled to the piezoelectric film by a second adhesion layer; C. bonding the support membrane to the piezoelectric film by bonding the the first and second bonding layers together to sandwich the first metal electrode between the piezoelectric film and the support membrane and creating a bonded structure having a support membrane side of the support membrane and a piezoelectric layer side of the piezoelectric film; D. fabricating an array of filters by processing the piezoelectric film coupled to the support membrane from the piezoelectric layer side by removing the detachable carrier substrate, trimming the piezoelectric film, the first metal electrode and an exposed surface of the support membrane, surrounding the piezoelectric film with a passivation material and coating with the second metal electrode, and building up base sections of seal rings and contact stacks; E. fabricating an array of lids having an outer surface and an inner surface, with external terminations on the outer surface and upper sections of the seal rings and contact stacks on the inner surface, such that the external terminations are coupled to the contact stacks by through lid vias, and fabricating upper sections of the seal rings and contact stacks for coupling to the base sections of the seal rings and contact stacks by another bonding layer; F. attaching the array of filters to the array of lids by coupling the base sections of the seal rings and contact stacks to the upper sections of the seal rings and contact stacks with the another bonding layer; G. thinning the silicon handle, drilling holes through the thinned silicon handle to the silicon dioxide layer, and etching away silicon dioxide of the silicon dioxide layer; and H. dicing the array of filters into individual filters.
2. The method of claim 1 wherein stage B is performed prior to stage A.
3. The method of claim 1 wherein at least one of the thinning, drilling, or etching steps of stage G precedes Stage D.
4. The method of claim 1 wherein at least one of the thinning, drilling, or etching steps of stage G precedes Stage F.
5. The method of claim 1 wherein at least one of the fabricating steps of stage E precedes any of stages A to D.
6. The method of claim 1 wherein stage A further comprises steps of: obtaining the support membrane attached to the silicon handle by the silicon dioxide layer; creating trenches through the support membrane, the silicon dioxide layer and into the silicon handle; depositing a silicon nitride coating over a surface of the support membrane and into the trenches; removing the silicon nitride coating to exposing the surface of the support membrane, and depositing the first adhesion layer followed by a first part of the first metal electrode over the surface of the support membrane terminating with the first bonding layer.
7. The method of claim 1, wherein the support membrane attached to the silicon handle by the silicon dioxide layer of Stage A comprises single crystal silicon with an orientation of <110>, <111>or <100> and the support membrane is a wafer sliced from the single crystal of silicon.
8. The method of claim 1, wherein the support membrane attached to the silicon handle by the silicon dioxide of Stage A comprises: single crystal lithium niobate or single crystal lithium tantalate and is obtained by a process further comprising steps of: bombarding a single crystal donor wafer with hydrogen or helium ions to a depth of less than 1.5 microns to generate a membrane that is weakly coupled to the single crystal donor wafer; attaching a side of the single crystal donor wafer with the weakly coupled membrane to the silicon handle by the silicon dioxide layer that is either thermally grown or pre-deposited onto the silicon handle and/or onto the weakly coupled side of single crystal donor wafer; and exposing the single crystal donor wafer to an elevated temperature thereby rupturing bonds holding the support membrane to the single crystal donor wafer and leaving the support membrane coupled to the silicon handle by the silicon dioxide layer.
9. The method of fabricating the filter device of claim 1 wherein the through support membrane filled barriers, the silicon dioxide layer and into the silicon handle are fabricated by creating trenches by deep reactive ion etching (DRIE), lining the trenches with SiN, and filling the trenches with a filler material consisting of SiN or silicon poly-crystal.
10. The method of fabricating the filter device of claim 1 wherein the first bonding layer of stage A is selected from the group consisting of titanium, chromium and titanium-tungsten, and a first part of the first metal electrode is selected from the group consisting of tungsten, titanium-tungsten, molybdenum, aluminum and gold, and the first adhesion layer and the first part of the first metal electrode are deposited by physical vapor deposition.
11. The method of fabricating the filter device of claim 1 wherein the first adhesion layer of stage A comprises one of titanium, chromium or titanium-tungsten, and an outer layer of a first part of the first metal electrode is a thin gold layer having a thickness range of 10 to 25 nanometers deposited by physical vapor deposition.
12. The method of fabricating the filter device of claim 1 wherein stage B comprises depositing a single crystal piezoelectric layer onto a release layer coupled to the detachable carrier substrate, wherein the single crystal piezoelectric layer is deposited to a thickness of up to 1.5 microns by sputtering or Molecular Beam Epitaxy (MBE) and is selected from the group consisting of: BaxSr(1-x)TiO3 in a<111>orientation where x<0.5; AIN in a C-Axis orientation; AlxGa1-xN in a C-Axis orientation where x >0.85; and ScxAl1-xN in a C-Axis orientation where 0.05<x<0.25.
13. The method of fabricating the filter device of claim 1 wherein stage B comprises depositing a single crystal piezoelectric layer coupled by a release layer to a detachable carrier substrate, wherein the single crystal piezoelectric layer comprises a layer of single crystal lithium niobate or single crystal lithium tantalate having a thickness of up to 1.5 microns and is obtained by a process further comprising: bombarding a facet of a single crystal donor wafer of the single crystal piezoelectric layer with hydrogen or helium ions to a depth of less than 1.5 microns to generate a membrane that is weakly coupled to the facet of the single crystal donor wafer; attaching an outer surface of the weakly coupled membrane onto the release layer coupled to the carrier substrate by a surface activated wafer bonding process (SAB) or by fusing a silicon dioxide layer, pre-deposited onto the weakly coupled membrane and said release layer; and exposing the single crystal donor wafer to an elevated temperature thereby rupturing bonds holding the piezoelectric layer to the donor wafer and leaving the single crystal piezoelectric layer coupled to the release layer coupled to the carrier substrate.
14. The method of fabricating the filter device of claim 1 wherein stage B is characterized by at least one of the following: the detachable carrier substrate comprises sapphire; the release layer comprises GaN; the detachable carrier substrate and the release layer are C-axis <0001>with maximum tolerance of 0.5 degrees.
15. The method of fabricating the filter device of claim 1 wherein in Stage C, the first metal electrode comprises a first coating layer of the first adhesion layer attached to the support membrane, a second adhesion layer attaching second and third coating layers and a third adhesion layer for attaching the third coating layer to the piezoelectric film; wherein the first, second and third adhesion layers are selected from the group consisting of titanium, chromium and titanium-tungsten and one of the first and second coating layers is selected from the group consisting of tungsten, titanium-tungsten, molybdenum and aluminum and the other of the first and second coating layers is a bonding layer of gold having a thickness range of 20 to 50 nanometer, and each of the adhesion and the coating layers constituting the first metal electrode are deposited by physical vapor deposition.
16. The method of fabricating the filter device of claim 1 wherein stage C comprises bonding first and second parts of the first metal electrode together by a surface activated bonding process with at least one of the following: the surface activated bonding process is performed between two identical materials selected from the group of tungsten, molybdenum, aluminum and titanium-tungsten; the surface activated bonding process is performed between two metals having an average surface roughness of less than 0.5 nanometers with or without pre-polishing a surface of the first and second parts by CMP; the surface activated bonding process is performed by pre-activating surfaces of the first and second parts prior to bonding by plasma gas, the plasma gas selected from the group consisting of argon and nitrogen; the surface activated bonding process is performed under vacuum; the surface activated bonding process is performed under a pressure range of 5 MPa to 50 MPa; the surface activated bonding process is performed under a temperature range from room temperature to less than 300 C.
17. The method of fabricating the filter device of claim 1, wherein stage C further comprises steps of: providing a single crystal piezoelectric layer having a first side and a second side; the first side coupled to a detachable substrate by a release layer and the second side attached to a second part of the first metal electrode by the second adhesion layer; bonding a first part of the first metal electrode to the second part of the first metal electrode to form the first metal electrode that couples the support membrane to the single crystal piezoelectric layer.
18. The method of fabricating the filter device of claim 1, wherein stage D further comprises steps of: processing from the detachable carrier substrate side by removing the detachable carrier substrate and a release layer; trimming the piezoelectric film and selectively removing the piezoelectric film, first metal electrode and support membrane to fabricate the resonator stacks comprising the piezoelectric film on the first metal electrode; surrounding the resonator stacks with the passivation material; depositing an upper electrode over the piezoelectric film with upper and lower electrodes pad terminations over the passivation material, and a first part of a metal seal ring of each of the seal rings are around a perimeter of each of the individual filters over the passivation layer.
19. The process of claim 18 wherein the step of removing the detachable carrier substrate in stage D is performed by a laser lift off process.
20. The method of fabricating the filter device of claim 19 wherein the detachable carrier substrate in stage D comprises a sapphire single crystal wafer coated with GaN and the [laser lift off process comprises irradiating the GaN through the sapphire single crystal wafer using a 248 nm excimer square waveform laser.
21. The method of fabricating the filter device of claim 18 wherein removing the release layer in stage D is performed by exposure to an induction coupled plasma.
22. The method of fabricating the filter device of claim 18 wherein trimming the piezoelectric film comprises applying a scanning surface ion milling process over a surface of the piezoelectric film.
23. The method of fabricating the filter device of claim 18 wherein the selectively trimming of the piezoelectric layer, first electrode and support membrane in stage D further comprises process steps of applying photo-resist followed by selectably exposing through windows in the photo-resist and applying an induction coupled plasma to etch the piezoelectric film, first metal electrode and support membrane through said windows in the photo-resist.
24. The method of fabricating the filter device of claim 18, wherein the passivation material surrounding the resonator stacks is selected from the group consisting of SiO.sub.2, silicon nitride, Ta.sub.2O.sub.5, polyimide and Benzocyclobutene (BCB).
25. The method of fabricating the filter device of claim 18, wherein the upper electrode over the piezoelectric film, pad terminations over the passivation material and the first part of the metal seal ring around the perimeter of each of the individual filters are selected from the group consisting of tungsten, molybdenum, aluminum and gold, and are deposited by sputtering or physical vapor deposition.
26. The method of fabricating the filter device of claim 18, wherein the first and second adhesion layers are selected from the group consisting of titanium, chromium and titanium-tungsten, and are deposited by PVD onto the piezoelectric film prior to deposition of the upper electrode; over the passivation material prior to deposition of the upper and lower electrodes pad terminations, and over the passivation material prior to deposition of the first part of the metal seal ring around the perimeter each of the individual filter units of the FBAR filter device.
27. The method of fabricating the filter device of claim 1 wherein Stage E comprises: fabricating the array of lids having the inner and outer surface having through metal vias electrically connecting terminations pads on the outer surface to capture pads under the inner surface of the array of lids, and further comprising an array of second metal seal rings on the inner surface of the array of lids such that the second metal seal rings have similar shape and size to the first metal seal rings around the perimeter of each of the individual filter units in the FBAR filter device.
28. The method of fabricating the filter device of claim 27 wherein the stage E of providing the array of lids further comprises steps of: e. obtaining a silicon wafer from which to fabricate the array of lids, the silicon wafer having an inner and an outer surface; f. drilling blind via holes having blind ends from the outer surface of the silicon wafer by deep reactive ion etching (DRIE); g. depositing a silicon nitride or silicon dioxide liner layer into the blind via holes and over the outer surface of each of the array of lids; h. depositing a titanium-copper seed layer over a surface of the silicon nitride or silicon dioxide liner layer and into the blind via holes; i. electroplating copper to fill and pattern the blind via holes and to generate copper termination pads over the filled blind via holes; j. etching away the titanium-copper seed layer; k. depositing a metal finish selected from the group consisting of gold, ENIG and ENEPIG over the termination pads; l. grinding away the inner surface of each of the array of lids formed from the silicon wafer to within 25 microns of the blind ends of the copper filled blind via holes; m. thinning down each of the array of lids with plasma to remove an additional 25-30 microns of silicon, thereby exposing about 5 microns of the blind ends of the silicon nitride or silicon dioxide liner layer of the copper filled blind via holes without damaging the silicon nitride or silicon dioxide liner layer or the copper filled blind via holes; n. depositing the silicon nitride or silicon dioxide liner layer over the inner surface of each of the array of lids and exposed silicon nitride or silicon dioxide liner layer coated on the copper filled blind via holes; o. removing the silicon nitride or the silicon dioxide liner layer and protruding copper from the copper filled blind via holes by chemical mechanical polishing (CMP), thereby exposing the blind ends of the copper filled via holes in the silicon nitride or silicon dioxide liner layer coating the inner surface of each of the array of lids; p. depositing another adhesion layer selected from the group consisting of titanium, chromium and titanium-tungsten followed by a gold seed layer over the inner surface of each of the array of lids; and q. terminating the inner surface of each of the array of lids by either: applying a photo-resist and patterning with trenches over the gold seed layer; filling the trenches with a layer of gold or gold-tin mix by electroplating; stripping away the photo-resist and etching away the gold seed layer, thereby generating a gold or a gold-tin bonding layer over the termination pads and seal ring defining the perimeter of each of the individual filters on the inner surface of each of the array of lids, or applying a photo-resist and patterning with capture pads and a seal ring defining the perimeter of each of the array of lids and filling the pattern of the capture pads by screen printing nano-sized gold particles in an organic binder in a paste form; sintering the paste form at 200 C. to remove the binder, and stripping away the photo-resist; to form an array of silicon lids with attached seal rings and contact stacks.
29. The method of fabricating the filter device of claim 27 wherein the stage E of providing the array of lids further comprises steps of: obtaining a glass wafer from which to fabricate the array of lids, the glass wafer having an inner and an outer surface; laser drilling through via holes through the glass wafer; sputtering a Ti/Cu seed layer into the through via holes and over the inner and outer surfaces of the glass wafer; depositing a layer of photo-resist on both the inner and outer surfaces of the glass wafer and patterning the photo-resist deposited on the inner surface of the glass wafer to form an array of seal rings defining the perimeter of each the array of lids and an array of capture pad shapes over each of the through via holes, and patterning the deposited photo-resist on the outer surface of the glass wafer to form an array of termination pad shapes adjacent to ends of the through via holes; filling the pattern of the array of captured pad shapes and the termination pad shapes with copper by electroplating; stripping away the photo-resist, and terminating each of the array of lids by: etching the Ti/Cu seed layer from both the inner and outer surfaces of each of the array of lids and depositing a metal finish over the termination pad shapes on the outer surface, said metal finish being selected from the group consisting of gold, ENIG and ENEPIG; processing the inner surface of each of the array of lids by applying and patterning a thicker layer of photo-resist over the array of capture pad shapes and seal rings; filling the pattern of the thicker layer of the photo-resist by either (i) screen printing nano-sized gold particles and an organic binder in a paste form; sintering the paste form at 200 C. and stripping away the photo-resist, thereby fabricating a bond layer, or by (ii) electroplating gold or a gold tin mix into trenches of the thicker layer of photo-resist and stripping away the photo-resist, to form an array of glass lids with attached seal rings and contact stacks.
30. The method of fabricating the filter device of claim 29 wherein the through via holes are fabricated in the glass wafer by laser drilling from both the inner and outer surfaces of the glass wafer.
31. The method of fabricating the filter device of claim 1 wherein an array of seal rings comprises first and second metal seal rings and stage F of attaching the array of lids to the array of filters further comprises steps of: depositing a metal bonding layer on at least one of the array of second metal seal rings and capture pads coupled to the inner surface side of each of the array of lids, and the first metal seal ring and the capture pads coupled to the first and second metal electrodes of the FBAR filter device; bonding the array of lids to the array of filters by reflowing the metal bonding layer such that the first and second metal seal rings and the inner surface of each of the array of lids define a cavity over each of the array of filters.
32. The method of fabricating the filter device of claim 31 wherein the step of bonding the array of lids to the array of filters is performed by reflowing the bond layer under a vacuum and a temperature range of 150 C. to 300 C. and pressure of 50 MPa to 100 MPa.
33. The method of fabricating the filter device of claim 1 wherein stage G further comprises the steps of: drilling the holes to form the via holes through the silicon handle to the silicon dioxide layer within areas defined by the perimeter trenches, and etching away the silicon dioxide of the silicon dioxide layer within the perimeter trenches.
34. The method of fabricating the filter device of claim 33 wherein the etching away the silicon dioxide of the silicon dioxide layer within the perimeter trenches in the silicon dioxide layer and the silicon handle to form individual cavities under each of the resonator stacks, the perimeter trenches serve as etch stops.
35. The method of fabricating the filter device of claim 34 further comprising thinning the support membrane through the via holes and the air cavity to a thickness of between zero and a thickness of the piezoelectric film, which is achieved by photo-resist masking the silicon handle surface to only expose the via holes, and exposing the silicon handle and the photo-resist to inductive coupling, or microwave sourced plasma fabricated from a XeF2 and Ar gas mixture.
36. The method of claim 33 further comprising at least one of the following steps: trimming the support membrane through the via holes and the air cavity to a thickness of between zero and a thickness of the piezoelectric layer; and plugging the via holes by depositing a layer of polysilicon under a side of the silicon handle.
37. The method of fabricating the filter device of claim 33 wherein the step of drilling holes through the silicon handle to the silicon dioxide layer within the perimeter trenches comprises deep reactive ion etching (DRIE).
38. The method of fabricating the filter device of claim 33 wherein the step of etching away the silicon dioxide of the silicon dioxide layer within the perimeter trenches in the membrane, the silicon oxide dioxide layer and the silicon handle comprises exposing to liquid or vapor HF.
Description
BRIEF DESCRIPTION OF FIGURES
(1) For a better understanding of the invention and to show how it may be carried into effect, reference will now be made, purely by way of example, to the accompanying drawings.
(2) With specific reference now to the drawings in detail, it is stressed that the particulars shown are by way of example and for purposes of illustrative discussion of the preferred embodiments of the present invention only, and are presented in the cause of providing what is believed to be the most useful and readily understood description of the principles and conceptual aspects of the invention. In this regard, no attempt is made to show structural details of the invention in more detail than is necessary for a fundamental understanding of the invention; the description taken with the drawings making apparent to those skilled in the art how the several forms of the invention may be embodied in practice. In particular, it will be appreciated that the schematic illustrations are not to scale, and the thickness of some very thin layers is exaggerated. In the accompanying drawings:
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
(19)
(20)
(21)
(22)
(23)
(24)
(25)
(26)
(27)
(28)
(29)
(30)
(31)
(32)
(33)
(34)
(35)
(36)
(37)
(38)
(39)
(40)
(41)
(42)
(43)
(44)
(45)
(46)
DESCRIPTION OF EMBODIMENTS
(47) The present invention is directed to novel Bulk Acoustic Wave (BAW) resonators of the Film Bulk Acoustic Resonator (FBAR) type, and to methods of fabrication of the same.
(48) As with prior art FBAR resonators, the electrode coated single crystal piezoelectric films 14 of the resonator embodiments discussed herein are physically supported around their edges, thereby enabling them to resonate. However, it is an important feature of many embodiments described below, that the electroded single crystal piezoelectric film 14 is coupled to and thus stiffened by a low acoustic-loss support membrane 31 that has a maximum thickness of that of the piezoelectric membrane itself, so practically the support membrane 31 is required to be less than 1.5 m thick. The support membrane 31electrode 16,18,40,16piezoelectric film 14electrode 60 stack is supported around its edge to enable it to resonate.
(49) As explained in the background section, where the terms Q and K.sup.2.sub.eff are defined, the level of performance of a filter is given by its factor of merit (FOM) which is defined by the equation FOM=Q*K.sup.2.sub.eff.
(50) Attaching a support membrane 31 to the piezoelectric film 14 makes the resultant FBAR non-symmetric and generates extra overtones. It further reduces its K.sup.2.sub.eff. However, choosing high K.sup.2t piezo materials and adding a support membrane 31 consisting of a high Q material to the piezoelectric film 14 still increases the FBAR's overall FOM and provides important mechanical support to the piezo layer, especially in cases where it's thickness is reduced for high frequency applications. Additionally, the support membrane reduces the resonator's sensitivity to temperature related frequency drifts so the resulting filters are more reliable.
(51) For ease of reading, the following description of various embodiments is divided into subsections. First, with reference to
(52) The core of the resonator, i.e. the stack of support membrane 31, lower electrode materials 16, 18, 40 and piezoelectric film 14 are fabricated in two stacks A, B of continuous layers which are then conjoined.
(53)
(54)
(55)
(56) The structure of
(57) Each individual resonator is now surrounded by a passivation material 54 to separate it from adjacent individual resonators, and an adhesion layer and a second electrode 60 is applied over the piezoelectric film 14, and a contact seal ring 55 is created around each filter, and a contact pad 56 is fabricated for attachment the lower electrode of each resonator stack, giving the structure schematically shown in
(58) It is noted that at this stage of the manufacturing, the individual electrode resonator stacks are arranged into filter units and an array of filter units is fabricated simultaneously on wafers, prior to eventually singulating into individual filter units in Step H.
(59) The resonators may be packaged in various ways. One way, with variations is described with reference to
(60) With reference to
(61) Referring to
(62) Referring now to
(63) It will however be appreciated that instead of building the seal rings 180 and contact stacks 182, 184 from the lid 175, these could be built up from around the array of filters and from the electrodes of the arrays of resonators. To minimize wastage and the possibility of damaging the piezoelectric layer and electrodes when creating the seal ring, it is considered preferable to substantively build the seal ring and contact stacks on the lids 175.
(64) Referring to
(65) Referring to
(66) Finally, with reference to
(67) Now it will be appreciated that the order of the sub processes described in blocks D, E, F and G may be changed. The array of lids 75 fabricated in blocks E1 and E2 are entirely separate from the piezoelectric membrane and its support structure prior to being attached thereto in Step F, and so block E can be fabricated before or after blocks D and G.
(68) Similarly, although the process of block G1 is described after blocks D and G2 is described after the processing of block F, one can perform some or all of block G before attaching the array of filters to the array of lids or thereafter. For example, although it may be sensible to thin the handle 33 (block G1) prior to attaching the array of lids F, it may be performed thereafter. Similarly, the seal ring 180 could be fabricated from the array of filters in block D3 instead of in block E2. Indeed, one could process the structure shown in
(69) With reference to
(70) With reference to
(71) The possible arrangements of resonators to create filters is beyond the scope of this application, but methods for fabricating resonators that are coupled in series and parallel are discussed hereunder with reference to
(72) General Overview
(73) There are different candidate materials for the various components of the filter modules disclosed herein, each requiring an appropriate manufacturing route. Appropriate materials and routes for securely adhering a functional element from a specific material to an adjacent element whilst providing mechanical stability and appropriate conductivity/resistivity are described. Various alternative materials and fabrication methods for each element are provided. Thus a single product and manufacturing route with variant embodiments is described herein.
(74) The subcomponents and elements are now discussed in depth together with flowcharts showing the stages for their construction and schematic images of intermediate structures, detailing processing conditions and alternative materials to provide full enablement to various embodiments.
(75) Because the fabrication method described herein allows single crystal piezoelectric films to be fabricated and the depth of the cavities therearound to be carefully tailored, with a minimal support membrane thickness between the cavity and electrode (if the support membrane is not removed completely from opposite the piezoelectric film) improved factors of merit (FOM) are expected, particularly when compared to the polycrystalline non-epitaxially grown films currently in use.
(76) It will be appreciated that exact dimensions will vary with both the material and component specification, and typically optimization requires finding a balance between functionality, reliability and cost. Nevertheless, by way of illustrative non-limiting example, typical dimensions for the various subcomponents are also provided.
(77) Having presented a general overview of the construction and method for the FBAR resonator arrays, a generalized overview of how they can be arranged into filters and an overview of the packaging route in
(78) It will be appreciated that parts A and B shown schematically in
(79) The membrane on handle 30 (
(80)
(81) With reference to
(82) The support membrane on handle 30, which may be a commercially available product, consists of a single crystal support membrane having a maximum thickness of 1.5 microns that is coupled by a layer of silicon dioxide 32, that is typically about three to six microns (5%) thick, to a silicon wafer handle 33 that is typically in the range of from 450 microns thick (5 m) to 750 um thick (15 m) thick. The support membrane 31 may be a low resistivity silicon, for example, being N type doped with As or P. It is typically <100> or <110> or <111> oriented layer of single crystal and the choice may be influenced by the selected piezoelectric membrane.Due to the doping, the resistivity is typically below 10 -cm. The handle 33 may be P type doped, typically with Boron. The resistivity of the handle 33 is typically much higher, and is typically >1000 -cm. Such SOI (support membrane 31 on handle 33) wafers are available in various diameters including of 100 mm, 150 mm and 200 mm.
(83) There are commercially available SOI wafers that that are fabricated by ion slicing using the ion slicing (SMART CUT technology) to obtain tight tolerance device layers. Typical tolerances for SMART CUT SOI wafers with a device layer of 500 nm are available with tolerances of better than +/2.5%, i.e. +/12.5 nm. Such SOI wafers are available from vendors such as SOITEC (www.soitec.com) or Waferpro (www.waferpro.com) and the Si membrane obtained in this way can have variety of resistivities values. It will be appreciated that starting with a submicron support membrane minimizes on subsequent thinning processes.
(84) Other candidate support membranes 31 include lithium niobate and lithium tantalate, for example. These can be smart cut from appropriate single crystals of lithium niobate and lithium tantalate wafers in a process described hereinbelow for fabricating piezoelectric layers.
(85) A spalling method described below with reference to
(86) Referring to
(87) Other fabrication processes are possible. For example, alternatively, the support membrane may be etched by ICP followed by a wet etch of the SiO.sub.2 and a further dry etch of Si handle. The trenches 34 may be provided as a closed loop, or anchor points may be left, such as at the vertices between adjacent trenches 34.
(88) Alignment marks 37 may then be made on the polished back of the handle 33step A(iii), using either ICP or laser for example, providing the structure of
(89) An etch resistant coating 35, such as silicon nitride is then deposited over the support membrane 31 and into the pattern of trenches 34step A(iv), providing the structure schematically shown in
(90) Referring to
(91) The surface coating of filler 36 is then removedstep A(vi), exposing the etch resistant coating layer 35 but leaving the filler 36 filled, etch resistant coating 35 coated trenches 34, for example, polysilicon filled silicon nitride coated trenches 34 providing the structure schematically shown in
(92) The etch resistant layer 35 is now removedstep A(vii), exposing the support membrane 31, but leaving the filler 36 filled, etch resistant coating 35, lined trenches 34, providing the structure schematically shown in
(93) The support membrane 31 may now be polished using chemical mechanical polishing (CMP)step A(viii) to remove the damaged top of the filler 38 filled, etch resistant coating 35 lined trenches 34 and leaving the structure with an appropriately low surface roughness (smoothness) for following deposition and bonding processes schematically shown in
(94) With reference to
(95) As shown in
(96) The Piezoelectric Film
(97) There are a very wide range of single crystal piezoelectric materials that have good intrinsic K.sup.2.sub.eff and Q factors. The appropriate piezoelectric material for a particular filter is selected in view of the desired frequency response and the general desire to minimize dimensions of the resultant filters, whilst noting that miniaturization complicates manufacturing and may increase cost and lower yield.
(98) With reference to box B of
(99) The piezoelectric film 14 is preferably and typically single crystal. Whilst it is not inconceivable that some stacking flaws or even occasional grain boundaries may exist in a large film, and even be tolerated for some applications, once the film 14 is patterned into individual resonator membranes, the vast majority of these are typically free from serious flaws, and even if individual components including resonator films having such flaws fail quality control, these can be discarded. In general, high yields are obtained.
(100)
(101) With reference to the flowchart of
(102) Firstly a removable carrier 10 with release layer 12 is obtainedstep B(i), as shown schematically in
(103) A piezoelectric film 14 is then deposited onto the release layerstep B(ii):
(104) There are two basic routes for fabricating the piezoelectric membrane: Growing a piezoelectric membrane by Molecular Beam Epitaxial Growth (MBE) and/or sputtering Spalling from a single crystal.
(105) Growing a Piezoelectric Membrane
(106) Molecular beam epitaxy (MBE) is a high purity low energy deposition technique that allows for low point defect manufacturing. It is possible to control the ratio of the elements ratio to very high accuracy of 1% and thereby ensure a high Q factor and coupling of the film.
(107) Where there is appropriate lattice matching, the piezoelectric film 14 may be fabricated by Molecular Beam Epitaxy on a bonding layer 12 of GaN over a removable substrate 10 such as sapphire, where the structure of the surface of the sapphire substrate and its lattice spacing enables a single crystal thin film to be deposited thereonto.
(108) The <0001> plane of a removable carrier 10 made from sapphire causes the release layer 12 of GaN deposited thereon to be deposited epitaxially in an <0001> orientation. Since the lattice spacing of <111> plane of tetragonal Ba.sub.xSr.sub.(1-x)TiO.sub.3 (BST) is compatible with the <0001> plane of the sapphire Al.sub.2O.sub.3 single crystal, Ba.sub.xSr.sub.(1-x)TiO.sub.3 where x<0.5, in a <111> orientation may be epitaxially grown thereover using oxide molecular beam epitaxy (MBE).
(109) AlN and Al.sub.xG.sub.a(1-x)N and Sc.sub.xAl.sub.(1-x)N are HCP type Wurtzite crystal structures (C plane orientation). A strong C axis texture is the most important prerequisite for AlN, Al.sub.xGa.sub.(1-x)N and Sc.sub.xA.sub.l(1-x)N FBAR filters because the acoustic mode of the FBAR needs to be longitudinally activated and the piezoelectric axis of AlN and Al.sub.xGa.sub.(1-x)N is along the c-axis. The addition of gallium or scandium to the AlN lattice can increase the coupling coefficient for wider band resonators while keeping good lattice match to the epitaxial GaN release layer.
(110) Thus AlN, Al.sub.xGa.sub.(1-x)N in a C-Axis orientation where x>0.85, and Sc.sub.xAl.sub.(1-x)N in C-Axis orientation where 0.05<x<0.25 may similarly be deposited epitaxially onto a GaN release layer 12 epitaxially grown onto a sapphire substrate 10. These materials may also be deposited by sputtering, by molecular beam epitaxy, by MOCVD or by depositing a layer using molecular beam epitaxy followed by sputtering.
(111) Typical coating thicknesses of the piezoelectric film 14 are between 100 nm and 1500 nm and by way of non-limiting example, may be between 200 nm and 400 nm in the case of Ba.sub.xSr.sub.(1-x)TiO.sub.3 (BST) and in the range of from 200 nm to 1500 nm in the case of AlN, Al.sub.xGa.sub.(1-x)N or Sc.sub.xAl.sub.(1-x)N.
(112) Such epitaxially grown piezoelectric films of Ba.sub.xSr.sub.(1-x)TiO.sub.3 (BST), Al.sub.xGa.sub.(1-x)N, Sc.sub.xAl.sub.(1-x)N and AlN may have a RMS roughness of less than 1 nm, which further assists wafer to wafer film bonding for transferring the piezo layer from the donor to receiving wafer.
(113) Since there are no grain boundaries in a single crystal, the attenuation of an acoustic signal passed through the single crystal is minimal. This also minimizes the lost energy that is otherwise transferred into heat and which has to be dissipated.
(114) The low surface roughness of the single crystal or at least strongly textured Ba.sub.xSr.sub.(1-x)TiO.sub.3 (BST), AlN, Al.sub.xGa.sub.(1-x)N and Sc.sub.xAl.sub.(1-x)N films also results in reduced scattering loss and higher Q-factors. Furthermore, rough surfaces, especially at high frequencies, are a major cause of the loss of the metal electrodes interfaces because of a skin effect. The smooth interfaces obtainable between the electrode and the piezoelectric film in highly textured and single crystal films with both upper and lower electrodes deposited thereupon are thus extremely advantageous.
(115) As shown in
(116) The piezoelectric film 14 is depositedstep B(ii) shown in
(117) Creating a Piezoelectric Membrane by Spalling from a Single Crystal
(118) There are useful candidate materials for the piezoelectric films 14 which cannot be deposited onto a sapphire substrate 10 by sputtering or MBE due to their lattice spacing incompatibility. By way of example, two such materials are LiNbO.sub.3 and LiTaO.sub.3 which are, however, both available as single crystals, and have extremely high Q and coupling coefficient values.
(119) With reference to
(120) Subjecting the structure shown in
(121) Thus regardless of whether the piezoelectric film 14 is epitaxially grown or fabricated by spalling from a single crystal 17, the resultant structure in both cases is a piezoelectric film 14 of desired orientation, coupled to a sapphire substrate 10 by a GaN 12 layer as shown in
(122) Furthermore, it will be appreciated that the spalling method can be used to fabricate support membranes 31 of LiNbO.sub.3 and LiTaO.sub.3 attached to a silicon handle 33 by a silicon dioxide box 32 as described above and shown in
(123) For it to function as a resonator, the piezoelectric film 14 needs to supported around its edge, and an electrode applied to each side.
(124) In general, the first electrode is a multilayer electrode formed by depositing some of the metal layers 16A, 18A onto a support membrane 30 described hereinabove, and other metal layers 16B, 40 16C, 18B onto the piezoelectric film 14. The two bonding layers 18A, 18B are fabricated from the same material and are very smooth so may easily be bonded together.
(125) With reference to
(126) The adhesion layer 16C typically has a thickness range of 5 to 50 nanometers and the additional layer 40 of W, Mo, Al or Au typically has a thickness ranging from 50 nanometers to 150 nanometers depending on the desired resonator or filter frequency response.
(127) With reference to
(128) Because the underlying layers are very smooth, the selected conductive bonding layer 18B may be bonded to an identical bonding layer 18A that is the outermost layer deposited onto a membrane on handle structure 30 described in
(129) The First Electrode
(130) Typically, in prior art resonators, a first electrode is first deposited and then the piezoelectric film is deposited thereon. Consequently, due to the high temperature fabrication of the piezoelectric film, refractory metals such as molybdenum, tungsten, platinum or gold are traditionally required for the first electrode. In contradistinction to typical processing routes, in the embodiments and process described herein, both the first electrode and the second electrodes 60 are deposited onto the piezoelectric film 14, so a wider range of metals may be used, such as aluminum for example. It will be appreciated that aluminum has a relatively low DC resistance when compared to these refractory metals, and thus using aluminum electrode layers is expected to increase the Q factor of the filter at higher frequencies.
(131) In general, the first electrode is fabricated in two parts. A first part is formed by depositing some metal layers 16A, (40, 16C) 18A onto a support membrane 31 (steps A(ix) and A(x) of
(132) With reference to
(133) With reference to
(134) Optionally, additional electrode layers 16C, 40 may be depositedstep B(iv). For example, a low DC resistance layer such as aluminum or gold and/or a high acoustic impedance layer such as tungsten, molybdenum or titanium-tungsten may be deposited.
(135) The adhesion layer 16C typically has a thickness range of 5 to 50 nanometers and the additional layer 40 of W, TiW, Mo, Al or Au typically has a thickness ranging from 50 nanometers to 150 nanometersdepending on the desired resonator or filter frequency response.
(136) Then, with reference to
(137) Stage C of
(138) With reference to
(139) Because the underlying layers are very smooth, the selected conductive bonding layer 18A on the piezoelectric film 14 may be bonded to an identical bonding layer 18b that is the outermost layer of a membrane 31 on handle 33 structure described in
(140) The bonding layers 18A, 18B may be pure gold and may be 10 to 25 nm thick, so that when fused together, a bonding layer 18 that is 20 to 50 nm thick results. Other candidate materials for bonding metal to metal by fusing include AuIn, AuSn, or even CuCu. The coatings may be activated by plasma.
(141) Alternatively (not shown) the electrodes may be Titanium-tungsten 10/90 or 5/95, tungsten, molybdenum or aluminum, with a surface roughness of less than 0.5 nm (possibly following CMP), which may be plasma activated and bonded.
(142) It will be appreciated that intermediate layers 40 of the first electrode may be deposited prior to the bond layer 18 onto either the patterned support membrane 31, or onto the piezoelectric film 14. Thus additional layers 40 such as low DC resistance layers of aluminum for example, and/or high acoustic impedance layers such as tungsten, titanium-tungsten or molybdenum may be deposited the onto the structure of
(143) It is advisable that adhesion layers thicknesses and different material interfaces should be reduced to minimum and that the bonding layer thickness 18 should be as thin as possible in order to enhance the filter's FOM.
(144) The structure shown in
(145) Processing the bonded stack from support carrier side
(146)
(147) With reference to
(148) Then the carrier 10 is removed
(149) Residual release layer 12 and any additional coatings 13, such as bonding layers of rutile TiO.sub.2 and/or SrTiO.sub.3, Ta.sub.2N, other rare earth nitride materials, or of SiO.sub.2 between the release layer of 12 of GaN and the piezoelectric membrane 10 are removedstep D(iii) to expose the piezoelectric film 14, giving the structure of
(150) The piezoelectric film 14 is then trimmed to desired thicknessstep D(iv) giving the structure schematically shown in
(151) It is a particular feature of some embodiments that different thickness trimming of specific piezoelectric membranes of a filter array is facilitated, enabling specific resonators within a filter to have different thicknesses to obtain a wider band filter (K.sup.2eff).
(152) With reference to
(153) Referring back to
(154) Applying the Upper Electrode
(155) Somewhat, arbitrarily, the processing is described from the piezoelectric film 14 side, and so to explain how the upper electrode is fabricated Block D2 of
(156) With reference to
(157) With reference to
(158) Then, with reference to
(159) Although described for depositing aluminum, gold, molybdenum, tungsten or titanium-tungsten onto piezoelectric materials such as Ba.sub.xSr.sub.(1-x)TiO.sub.3 (BST), Al.sub.xGa.sub.(1-x)N or Sc.sub.(1-x)Al.sub.xN, AlN, LiNbO.sub.3 and LiTaO.sub.3 it will be appreciated that PVD or CVD with otherwise, low density, high conductivity electrode materials over different piezoelectric layers 14 may be used with the same method. For example, carbon nano-tubes (CNT) over single crystal piezoelectric layers may be considered. Nevertheless, typically it is desired to keep the top electrode material of the same type (and thickness) as the bottom electrode.
(160) Both the adhesion layer 16D and the subsequent electrode layer 60 may be deposited by sputtering, for example and patterned through a photo-resist lift off process.
(161) Contacts Through Cap Packaging Route
(162) The top and bottom electrode can be accessed through the membrane and handle, but for ease of manufacture, reliability and to minimize wastage, it is considered preferable to access the electrodes through a cap or lid applied over and around the second electrodes of each filter to create a cavity over each filter that is shared by the resonators of the filter. Contacts are extended from the first and second electrodes to contact pads on the outer surface of such lids. Process routes for so doing are discussed below.
(163) Creating a Seal Ring
(164) A seal ring may be built up around the perimeter of each filter array, with contacts extended from the upper and lower electrodes. The seal rings and contacts are coupled to an array of lids described below.
(165) How the seal ring may be built up is now discussed. The seal ring stands on the passivation layer 54 and is electrically disconnected from the top and bottom electrodes but contacts extending from the upper and lower electrodes are in electrical communication with external contact pads on the outer surface of the cap.
(166) It should be noted that in some filter designs not shown or discussed in detail herein, the seal ring may be connected to the ground planes of the filter, thereby assisting in cancelling parasitic capacitances between the RF input to outputs and to ground these parasitic capacitances so they can be dealt by inductors outside the filter chip itself.
(167) Referring back to
(168) When depositing the upper electrode 60 over the adhesion layer 16D, contact pads 65, 66 are deposited over the contacts 55, 56. Thus, step D(x) given in
(169)
(170) With reference to
(171) Then, in
(172) Processing the Bonded Stack from the Silicon Handle Side
(173) Previous to processing the carrier 30 and piezoelectric 14 side of the structure of
(174)
(175) Thus with reference to
(176) Thus with reference to
(177) Preferably, the remaining steps G(iii) to G(v) shown in
(178) Thus with reference to
(179) It is a particular feature of some embodiments that different thickness trimming of specific support membrane is facilitated, enabling specific resonators within a filter to have different thicknesses by selectively covering specific through silicon vias under certain resonators to obtain a wider band filter (K.sup.2eff).
(180) With reference to
(181) With reference to
(182) Coupling Resonators in Series and Parallel to Form Filters
(183) With reference to
(184) The first, multilayer electrode layers 16, 18, 40 and the piezoelectric film 14 are patterned to create individual islands of piezoelectric 14A, 14B supported by rectangular layers of the first electrode 16, 18, 40, which is the lower electrode in
(185) The coupling arrangement of adjacent piezoelectric membranes 14A, 14B and the upper electrode schematically shown in
(186) Packaging
(187) For packaging the array of filters, a corresponding array of lids is required. This array is fabricated from a wafer that is typically silicon or glass. Wafers have two faces. For ease of understanding, that to be coupled facing the membranes is referred to hereunder as the inner face, and that with termination pads thereon is referred to hereunder as the outer face.
(188) Termination pads on the outer face are electrically connected by through metal vias to capture pads on the inner face of the cap which are electrically coupled by contact stacks (described below) to the upper and lower electrodes of the resonator stacks of the filter arrays.
(189) When assembled, the lids in the array of lids are mechanically coupled to filters in the array of filters by a seal ring in an array of seal rings, each seal ring surrounding a filter. This array of seal rings may be fabricated partly on the array of filters and partly on the inner surface of the array of lids. The two parts of the array of seal rings are then joined together to package the upper parts of each filter with a seal ring and lid, thereby creating an array of cavities between the array of filters and the array of lids; one cavity, lid and seal ring per filter.
(190) Fabricating Arrays of Lids
(191)
(192) Where the lid 175 is fabricated from a semiconducting material such as a silicon wafer, to isolate the capture pads 174A, 174B, an insulating coating 135 such as silicon nitride or silicon dioxide is deposited on both sides of the lid 175 and also along the surfaces of the through via hole prior to filling the via with a conducting material.
(193) If the lid 175 is fabricated from a non-conductive material such as glass, the insulating coating 135 is not required.
(194) Opposite the seal ring contact pads 66, bonding pads 174C are provided.
(195) To distance the lid 175 from the upper electrode 60 sufficiently to allow the electrodes piezoelectric resonators to resonate, an upper cavity is required under the lid 175. To create this upper cavity, a seal ring 180 extends from the bonding layer 174C to a second bonding layer 75. Similarly contact extension stacks 182, 184 extend from the bonding pads 174A and 174B to second bonding layer. The method of fabrication of seal ring 180 is described in detail hereinbelow, but at this stage, it is noted that it may be built up from the array of filters towards the cap and attached thereto by bonding pads 174.
(196) However, as shown in
(197) In both the variant shown in
(198) Since the filter arrays include support membranes and difficult to fabricate single crystal films which have accurate dimensions, and passivation layers and electrodes, it is better engineering practice to fabricate the seal ring 180 on the lid 175 and to attach the lid 175 with seal rings 180 and contact stacks 180, 182, 184 to the structure shown in
(199) Silicon Lids
(200) The appropriate processing route depends on the materials used, and in
(201) Thus with reference to
(202) Processing from the Outer Surface (b) drilling blind via holes 138 from the outer surface of the wafer 175 by deep reactive ion etch (DRIE) using BOSCH processsee
(203) Processing from the Inner Surface (g) The inner surface of the silicon wafer 175 is ground down to within 25 microns of the end of metal filled blind vias
(204) Extending the Seal Ring (m) patterning a photo-resist 190 with a pattern of seal rings and contact stacks
(205) Two variant processes for filling the pattern to extend the seal ring are now given. In a first process the pattern is filled by electroplating. For example, gold-tin may be electroplated into the pattern to create a seal ring 180 and contact stacks 182, 184 of gold or gold-tin. In a second process, the patterned photo-resist is filled by screen printing nano-sized gold particles and organic binder in a paste form and then sintering the paste at about 200 C.
(206) Glass Lids
(207) Alternatively, the lid array may be fabricated from glass. With reference to
(208) Fabricating the Lid (E1) (i) obtaining a glass wafer 275 with inner and outer surfaces
(209) Fabricating Seal Ring and Stacks (E2) (vi) The seal ring and contacts is extended by depositing and patterning a thicker layer of photo-resist 292 over the inner surface of the lid array
(210) Finishing the Termination Pads (ix) The seed layers 274 are removed from both surfaces of the cap array 275
(211) [000280.1]Two variant processes for filling the pattern to extend the seal ring are now given. In a first process the pattern is filled by electroplating. For example, gold-tin may be electroplated into the pattern to create a seal ring 180 and contact stacks 182, 184 of gold-tin. In a second process, the patterned photo-resist is filled by screen printing nano-sized gold particles and organic binder in a paste form and then sintering the paste at about 200 C.
(212) Attaching the Array of Filters to the Array of Caps
(213) With reference to
(214) Thus with reference to the flow chart of
(215) Thus single crystal Composite FBARs having improved cavity definition are shown and described.
(216) As stated hereinabove, a main usage of such FBAR resonators is in filters for mobile telephony. It will, however, be appreciated that they can also be used in other electronic devices.
(217) Single crystal FBAR resonators and filters have the following advantages: Such filters may save up to half of the RF power wasted as heat in prior art filters because the single crystal orientation enables polarization of the excited acoustic wave. The filters disclosed herein may operate at higher frequencies since the thickness of the ultra-thin piezoelectric membrane necessary for high frequencies may be supported by an additional support membrane (composite FBAR). Having a composite electrode and structure that includes a support membrane, such filters may have second or higher harmonic mode frequencies that can extend the operating frequency range of the FBAR. This feature may be important for 5G and other high bands emerging applications. Since CMOS device processes are compatible with the disclosed filter processes described, there are opportunities to integrate such devices with the filter chip by taking advantage of the Smart-Cut SOI device layer as the substrate for such transistors. Such devices may also use the trench isolation feature disclosed to enhance power performance. Some of the single crystal FBARs disclosed herein use well-known MEMS and LED FAB manufacturing processes rather than dedicated and expensive Si FABs. This may simplify and reduce the investment and total cost to manufacture the filter device. Single crystal FBARs manufacturing processes disclosed herein use the low cost back-end processes well established and with high yields available by multiple wafer bumping and assembly houses.
(218) Although discussed hereinabove with reference to communication filters, it will be appreciated that thickness-shear-based Composite FBARs and surface generated acoustic wave-based Composite FBARs are also used in other applications. For example they are widely used in biosensors since they provide high sensitivity for the detection of biomolecules in liquids.
(219) Thus persons skilled in the art will appreciate that the present invention is not limited to what has been particularly shown and described hereinabove. Rather the scope of the present invention is defined by the appended claims and includes both combinations and sub combinations of the various features described hereinabove as well as variations and modifications thereof, which would occur to persons skilled in the art upon reading the foregoing description.
(220) In the claims, the word comprise, and variations thereof such as comprises, comprising and the like indicate that the components listed are included, but not generally to the exclusion of other components.