Semi-transparent thin-film photovoltaic mono cell
10770608 ยท 2020-09-08
Assignee
Inventors
Cpc classification
H01L31/0463
ELECTRICITY
Y02P70/50
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
H01L31/0468
ELECTRICITY
H10K30/83
ELECTRICITY
H01L31/0465
ELECTRICITY
Y02E10/549
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
H01L31/0465
ELECTRICITY
H01L31/0463
ELECTRICITY
H01L31/0468
ELECTRICITY
Abstract
The invention relates to a photovoltaic mono cell that is semi-transparent to light, comprising a plurality of active photovoltaic zones that are separated by transparent zones, said active photovoltaic zones being formed from a stack of thin films arranged on a substrate that is transparent to light, said stack of thin films consisting at least of a transparent electrode, an absorber layer and a metal electrode, said transparent zones being apertures produced at least in the metal electrode and in the absorber layer in order to allow as much light as possible to pass, characterized in that it furthermore comprises an electrically conductive collecting gate arranged either making contact with the front electrode in order to decrease the electrical resistance of the transparent electrode, or making contact with the absorber in order to facilitate collection of the electrical current generated by said mono cell.
Claims
1. A photovoltaic mono cell semi-transparent to light, comprising: a plurality of photovoltaic active zones separated by transparency zones, said photovoltaic active zones being formed of a stack of thin films comprising a transparent electrode, an absorber film and a metallic electrode which are arranged in the stated order, from a first side of the stack to a second side of the stack, on a substrate transparent to light, such that the first side of the stack is closest to the substrate; and said transparency zones being apertures made at least in the metallic electrode and in the absorber film to allow through light; an electrically conducting collection gate arranged in contact with the transparent electrode to reduce its electrical resistance and avoid direct physical or electrical contact with the metallic electrode, a first collection bus linked to the collection gate to collect electrical charges from the transparent electrode; and a second collection bus linked to the metallic electrode, the second collection bus spaced apart from the first collection bus, wherein said photovoltaic active zones furthermore contain several channels, made in the metallic electrode and the absorber film, said collection gate being separated from the metallic electrode and from the absorber film by a dielectric material, so as to reduce the series resistance of the transparent electrode while minimizing the visibility of the collection gate, wherein the collection gate substantially covers the photovoltaic active zones.
2. The photovoltaic mono cell as claimed in claim 1, wherein apertures are in the form of discontinuous or non-discontinuous rectilinear bands, or according to any other shapes, said collection gate being adapted to said apertures so as to limit visibility of said collection gate.
3. The photovoltaic mono cell as claimed in claim 1, wherein the absorber films and the metallic electrodes are less wide than the transparent electrodes, and the collection gate comprises fine metallic strips arranged on the transparent electrode and situated aligned with the absorber film.
4. The photovoltaic mono cell as claimed in claim 1, wherein said collection gate is metallic.
5. The photovoltaic mono cell as claimed in claim 1, wherein said dielectric material is transparent or semi-transparent to visible light.
6. The photovoltaic mono cell as claimed in claim 1, wherein the refractive index of the dielectric material lies between the refractive index of the transparent substrate or of the transparent electrode and that of the air.
7. The photovoltaic mono cell as claimed in claim 1, wherein the refractive index of the dielectric material lies between the refractive index of the transparent substrate or of the transparent electrode and that of a transparent optical glue which forms part of the photovoltaic mono cell.
8. The photovoltaic mono cell as claimed in claim 1, wherein said photovoltaic active zones or the transparency zones are organized into arrays of linear, circular or polygonal elementary geometric structures.
9. The photovoltaic mono cell as claimed in claim 1, wherein said transparent electrode comprises graphene or metallic nanostructures or a transparent conducting oxide such as SnO2, ITO, IZO, AZO, BZO, GZO or ZnO.
10. The photovoltaic mono cell as claimed in claim 1, wherein said absorber film comprises one or more inorganic and/or organic semi-conducting materials, based on amorphous or microcrystalline silicon, GaAs (gallium arsenide), CdTe (cadmium telluride), CIGS (copper-indium-gallium-selenium) or based on polymers.
11. The photovoltaic mono cell as claimed in claim 1, wherein said metallic electrode comprises a metal such as aluminum (Al), nickel (Ni), gold (Au), silver (Ag), copper (Cu), molybdenum (Mo), chromium (Cr), titanium (Ti) or palladium (Pd).
12. The photovoltaic mono cell as claimed in claim 1, wherein the transparent substrate comprises a solid material made of mineral glass, organic glass or else a polymer of PMMA, PET or polycarbonate type.
13. The photovoltaic mono cell as claimed in claim 1, wherein the transparent substrate is covered with an antireflection or anti-UV functional surface.
14. A photovoltaic mono cell semi-transparent to light, comprising: a plurality of photovoltaic active zones separated by transparency zones, said photovoltaic active zones being formed of a stack of thin films comprising a transparent electrode, an absorber film and a metallic electrode which are arranged in the stated order, from a first side of the stack to a second side of the stack, on a substrate transparent to light, such that the first side of the stack is closest to the substrate and the transparent electrode is in contact with the substrate; and said transparency zones being apertures made at least in the metallic electrode and in the absorber film to allow through light; an electrically conducting collection gate arranged to avoid direct physical or electrical contact with the metallic electrode and positioned either in contact with the transparent electrode to reduce its electrical resistance, or in contact with the absorber to facilitate the collection of electric current generated by said mono cell, a first collection bus linked to the collection gate to collect electrical charges from the transparent electrode; and a second collection bus linked to the metallic electrode, the second collection bus spaced apart from the first collection bus, wherein the collection gate substantially covers the photovoltaic active zones.
Description
FIGURES
(1) The invention will be better understood with the aid of its detailed description, in conjunction with the figures, in which:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14) The figures are not to scale, the relative thicknesses of the components of the mono cell being intentionally exaggerated in order to better reveal its structure.
DETAILED DESCRIPTION
(15) Referring to
(16) The semi-transparency of this known module is ensured by transparent bands perpendicular to the series interconnection zones 19, cut by etching, and then reconnected together by contact pickups.
(17) A more schematic view of this known structure of
(18) At 12 an insulation line of the transparent electrode 2 has been represented. It is obtained by the etching P1 and makes it possible to electrically insulate the front electrodes of two adjacent cells. At 13 the insulation line of the absorber has been represented. It is obtained by the etching P2 and makes it possible to electrically insulate the absorbers of two adjacent cells. At 14 the insulation line of the metallic electrode 4 has been represented. It is obtained by the etching P3 and makes it possible to electrically insulate the metallic electrodes of two adjacent cells.
(19) A schematic plan view of a photovoltaic module according to
(20) The zones which are the most visible in reality consist of the etchings corresponding to the zones E of
(21) What is seen the most in the zone E of series placement of elementary cells is the metallic contact 13 (
(22) Also seen is the line 12 corresponding to the etching of the transparent electrode 2, because of the jump of index in the stack, since one passes directly from an index of 1.5 of the glass substrate 5, to an index of 3.5 for the silicon of the absorber 3, therefore the luminous reflection on the etching line 12 will be more strong and visible.
(23) For the insulation line 14 of the metallic electrode 4, there is a break in optical continuity, since the hole in the opaque metal of the metallic electrode 4 allows through the residual light not guided by the optical system of the module, in the case where the photovoltaic module uses such an optical system to guide the light.
(24)
(25) The presence of the transparency bands leaves the etching planes P1, P2, P3 still visible as explained above, but etching lines are now seen (dashed line). The set of these etching traces (12,13,14) of the zone of placement in series E is visible and disturbs the picture quality of an image which would be arranged under the photovoltaic module, so that this known module type cannot be validly integrated into an electronic device of the cellular phone type, since the negative impact of these traces on the visibility of the image on the screen would be too harmful.
(26) We now refer to
(27) In
(28) In
(29) According to an advantageous embodiment of the photovoltaic mono cell according to the invention, certain transparency zones 6 can be replaced, at preferably regular intervals, by a conducting collection gate 8, as represented in plan view in
(30) As seen in
(31) Several possible variants for the production of such a collection gate 8 will be described in conjunction with the subsequent figures.
(32) In
(33) Another solution consists in minimizing the visible size of the collection gate 8, as represented in
(34)
(35) Another variant of collection gate 8 is represented in
(36) Another way of proceeding consists in producing a collection gate no longer arranged in relief on the transparent electrode of the transparent electrode, but to bury the collection gate inside the transparent electrode of the transparent electrode, as represented in the variants of
(37) In
(38) Another variant represented in
(39) Although the conducting line formed by the collection gate 8 will create a loss of photovoltaic collection surface in comparison with a solution without a collection gate 8, the loss will in certain cases be sufficiently low for this to be beneficial with respect to the loss induced by the transparent conducting material. Indeed, at low illumination (1000 lux), the influence of the series electrical resistance on the power generated is not noticeable, therefore the benefit of the collection gate is low or indeed zero. On the other hand, in the case of strong illumination (0.5 SUN i.e. about 50 000 lux), the series resistance of the transparent electrode 2 is heavily penalizing (i.e. a power loss of the order of 50%). Thus the collection gate causes the loss of a small part of the photovoltaic active surface either through shadowing, or through a decrease in the active surface, but on the other hand it makes it possible to utilize the whole of the potential of the photovoltaic diode. Therefore, at strong illumination the collection gate 8 definitely gains on the electrical power produced.
(40) Another advantage of this variant is that a standard supply of the absorber material is retained and that there is no need to etch the transparent electrode. Moreover the transparent electrode can be very fine (of the order of a few tens of nanometers), thereby making it possible to preserve a high transparency of the module between the collection zones.
(41) It should be noted that the variants with collection gate 8 buried in the transparent electrode 2 have additional advantages from the point of view of the fabrication efficiency. Indeed, when the collection gate 8 is inserted under the transparent electrode and between the absorber bands as represented in
(42) The first option seems to be the more economically beneficial. Indeed, if fabrication defects appear during the production of the collection gate 8, it is very simple to rework the dies at very low cost. Moreover the buried collection gate offers a large gamut of possible fabrication processes for the production of the metallic contact pickup of the collection gate 8 on the transparent electrode 2, especially as regards the temperature ranges, with no risk of deterioration of the absorber films 3 since the latter are not yet deposited during the production of the collection gate/transparent electrode contact pickup.
(43)
(44) In
(45) We now refer to
(46) The mono cell is composed of three photovoltaic active bands 1, themselves consisting of three thin films, namely a transparent electrode 2, an absorber film 3 and a metallic electrode 4. These photovoltaic active bands 1 are separated by free bands 6 corresponding to transparency zones at the level of which the absorber film 3 and the metallic electrode 4 have been etched. The photovoltaic active bands 1 contain a plurality of channels 7 which are also apertures made in these photovoltaic active bands 1 by etching of the absorber film 3 and of the metallic electrode 4.
(47) These channels 7 make it possible to place the transparent electrode 2 in electrical contact with an electrically conducting collection gate 6 so as to reduce the intrinsic resistance of the transparent electrode 2 while minimizing the visibility of this gate 6. However, so as not to reduce the electrical performance of the mono cell, the collection gate 6 is separated from the metallic electrode 4 and from the absorber film 3 of the photovoltaic active bands 1 by a dielectric material 9.
(48) The set of collection gates 8 situated on each photovoltaic active band 1 is linked at the periphery of the mono cell to a collection bus of the front face 10 which makes it possible to collect the electrical charges transported up to the transparent electrode 2. Opposite this collection bus of the front face 10 is a collection bus of the rear face 11 which makes it possible to link the metallic electrodes 4 of each photovoltaic active band 1 and thus to collect the charges transported up to said metallic electrodes 4.
(49)
(50) In a first step (
(51) In a second step (
(52) In a third step (
(53) Finally, the last step (
ADVANTAGES OF THE INVENTION
(54) The photovoltaic mono cell according to the invention makes it possible to achieve the envisaged aims. By virtue of its design, there is no longer any etching for placing in series in the active zone, nor any problem of shadowing of an elementary cell, nor any loss of surface area related to the etchings for placing in series.
(55) The photovoltaic cell according to the invention therefore makes it possible to obtain at one and the same time good optical homogeneity, improved electrical performance, and optimal useful production surface area.
(56) The techniques for fabricating such a cell remain standard, by deposition of films, lithography and etching, on standard hardware.
(57) TABLE-US-00001 List of labels used in the figures 1 Photovoltaic active zone 2 Transparent electrode 3 Absorber film 4 Metallic electrode 5 Transparent substrate 6 Transparency zone 7 Channel 8 Collection gate 9 Dielectric material 10 Collection bus of the front face 11 Collection bus of the rear face 12 Etching line of the transparent electrode (etching P1) 13 Etching line of the absorber (etching P2) 14 Etching line of the metallic electrode (etching P3) 20, 30 Adjacent photovoltaic cells 21 Zone of interruption of the transparent electrode (etching P1) 23 Zone of interruption of the absorber (etching P2) 25 Zone of interruption of the metallic electrode (etching P3)