System for flue-gas hydrate-based desalination using LNG cold energy

Abstract

A system for flue-gas hydrate-based desalination using LNG cold energy belongs to the field of hydrate technology application. The CO.sub.2 in the flue-gas is captured based on the hydrate formation. Two stage formation chambers are set to improve the hydrate formation. The two steps to purify the hydrates respectively are the gas separation and the liquid separation. The two methods of hydrate dissociation to realize the recycling of the waste heat of flue-gas and the CO.sub.2 are the heat-exchanged and the exhausted. The present invention realizes the integrated CO.sub.2 capture and seawater desalination with a proper structure and a subtle system and solves the cold energy source for hydrate-based desalination by means of using LNG cold energy. The two stage formation chambers solve the capture of CO.sub.2 in the flue-gas and guarantee the hydrate formation amounts. The two types of dissociation chambers decrease the heat emission by using the waste heat of flue-gas and realize the recycling and storage of CO.sub.2. The system will not be affected by the changes of seasons and environments and has a strong carrying capacity for the flue-gas source change. It is a system with great application value realistic.

Claims

1. A system for flue-gas hydrate-based desalination using LNG (liquefied natural gas) cold energy, wherein the system for flue-gas hydrate-based desalination comprising a refrigerating system, a flue-gas capture system, a hydrate formation and separation system, a hydrate dissociation system, a CO.sub.2 circulating system, and a control system; the said refrigerating system comprising an LNG storage tank, gasification chamber and circulating medium, the LNG gasification is endothermic and the gasification amounts of LNG are changed by the opening of a screw valve of the LNG storage tank, the cold energy is transferred to the circulating medium in the gasification chamber, the circulating medium is a closed loop by a water-delivery pump and exchanging heat with seawater and gas respectively before the formation by more heat exchangers, the seawater and gas after the heat exchange are directly to form hydrates; the said flue-gas capture system comprising a flue-gas source, heat-exchanged dissociation chamber, first-stage formation chamber and gas separation chamber, the flue-gas source exchanging heat with the hydrates to make them decompose through the heat-exchanged dissociation chamber and then entering the first-stage formation chamber by an air pump and check valve successively after the further heat exchange with the circulating medium, the flue-gas forming CO.sub.2 hydrates with the seawater in the first-stage formation chamber, the temperature-hold and pressure-tight residual gas, CO.sub.2 hydrates and remnants seawater mixtures going into the gas separation chamber by a multiphase pump, the multiphase pump having a butterfly valve which can automatically open or close according to whether the multiphase pump operates or not, the residual gas in the mixtures is separated out of the gas separation chamber by a second air pump, the left CO.sub.2 hydrates and remnants seawater in the gas separation chamber going into a second-stage formation chamber immediately by a second multiphase pump; the said hydrate formation and separation system comprising the second-stage formation chamber and a liquid separation chamber, the CO.sub.2 hydrates that formed in the first-stage formation chamber and has exhausted residual gas rapidly entering the second-stage formation chamber by a third multiphase pump, the formation rate of CO.sub.2 hydrates will increase sharply formed from the new seawater and CO.sub.2, both the massive CO.sub.2 hydrates and remnants seawater after the formation going into the liquid separation chamber by the third multiphase pump, the liquid separation chamber separating the remnants seawater from the CO.sub.2 hydrates and draining the waste water through a gate valve, the remained pure CO.sub.2 hydrates going into an exhausting dissociation chamber by a fourth multiphase pump to be decomposed, all the above multiphase pumps are controlled by the control system; the said hydrate dissociation system collecting a freshwater from the decomposed CO.sub.2 hydrates in the exhausting dissociation chamber and the heat-exchanged dissociation chamber and delivering them into a freshwater storage tank for output use, the dissociation pressure of the exhausting dissociation chamber is controlled by a third air pump and the dissociation temperature of the heat-exchanged dissociation chamber is decided by the flue-gas source; the said CO.sub.2 circulating system collecting the exhausted CO.sub.2 in the exhausting dissociation chamber and the decomposed CO.sub.2 in the heat-exchanged dissociation chamber into a CO.sub.2 gas tank, the CO.sub.2 gas tank providing CO.sub.2 gas for the second-stage formation chamber to form hydrates, the redundant CO.sub.2 is sequestrated in conventional ways; the said control system is used to control the coordinated operation of the whole system for flue-gas hydrate-based desalination using LNG cold energy, the control system controlling the periodic alternate operation of all parts intelligently, it can control and interlock the opening or closing of each valve and the start or stop of each pump as needed, it controlling the temperature of circulating medium by adjusting the LNG amounts into the gasification chamber, it controlling the seawater amounts into the two formation chambers according to the actual production requirement and automatically allotting the seawater amounts for each formation chamber from a sea basin by a second water-delivery pump and two check valves connected to it, it allotting the hydrate amounts for the heat-exchanged dissociation chamber according to the thermal capacity of the flue-gas source and allots other hydrates into the exhausting dissociation chamber.

Description

DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a system diagram of the present invention.

(2) FIG. 2 is a structure diagram of the present invention.

(3) In the figures: 1 is an LNG storage tank; 2 is a sea basin; 3 is a flue-gas source; 4 is a CO.sub.2 gas tank; 5-1 is a first-stage formation chamber; 5-2 is a second-stage formation chamber; 6 is a gas separation chamber; 7 is a liquid separation chamber; 8 is an exhausting dissociation chamber; 9 is a heat-exchanged dissociation chamber; 10 is a freshwater storage tank; 11 is a gasification chamber; 12 is a water-delivery pump; 13 is a heat exchanger; 14 is a multiphase pump; 15 is an air pump; 16 is a relief valve; 17 is a butterfly valve; 18 is a screw valve; 19 is a gate valve; 20 is a check valve.

DETAILED DESCRIPTION

(4) Following is the detailed description of the specific embodiment of the present invention combining the technical solution and accompanying drawings.

(5) According to the principle shown in FIG. 1, the structures of the system are connected as shown in FIG. 2 and the system is used to conduct the flue-gas hydrate-based desalination using LNG cold energy with the following steps:

(6) The control system starts the water-delivery pump 12 of circulating medium. In the meantime, it sets the temperature of circulating medium and gives the opening commands to the screw valve 18 of the LNG storage tank 1 to adjust the LNG amounts entering the gasification chamber 11 and to make the circulating medium reach and keep the setting temperature.

(7) The flue-gas enters the heat-exchanged dissociation chamber 9 for heat exchange with the hydrates which wait for decomposing by heating, and then enters the first-stage formation chamber 5-1 after flowing through the heat exchanger 13 by the air pump 15 to be precooled by the circulating medium. At the same time, the seawater inpours into the first-stage formation chamber 5-1 by the water-delivery pump 12 and forms CO.sub.2 hydrates with the CO.sub.2 of the flue-gas. The residual gas, remnants seawater and CO.sub.2 hydrates mixtures after the formation are fed into the gas separation chamber 6 by the multiphase pump 14. The gas after the formation of CO.sub.2 hydrates, which is mainly N.sub.2, is separated out of the mixtures by the gas separation chamber 6. And the left CO.sub.2 hydrates and seawater are continued to be pumped into the second-stage formation chamber 5-2 by the multiphase pump 14.

(8) The source of the seawater into the second-stage formation chamber 5-2 is the same as the first-stage. While the gas is supplied by the CO.sub.2 gas tank 4 and the CO.sub.2 are pumped into the second-stage formation chamber 5-2 by the air pump 15. Both the seawater and the CO.sub.2 exchange heat with the circulating medium to be precooled. Next, the remnants seawater and CO.sub.2 hydrates mixtures are pumped into the liquid separation chamber 7 by the multiphase pump 14. And the remnants waste seawater is separated by the liquid separation chamber 7 and is discharged through the gate valve 19. The CO.sub.2 hydrates enter the exhausting dissociation chamber 8 and the heat-exchanged dissociation chamber 9 by the multiphase pumps 14 respectively. And the CO.sub.2 hydrate amounts into the two dissociation chambers are allotted by the control system according to the flue-gas source 3.

(9) The exhausting dissociation chamber 8 makes the CO.sub.2 hydrates decompose by means of depressurization. The decomposed freshwater flows into the freshwater storage tank 10 by the check valve 20. The dissociation pressure is controlled by the air pump 15. And the CO.sub.2 gas is delivered into the CO.sub.2 gas tank 4 through the check valve 20 to ensure the continuous dissociation of CO.sub.2 hydrates. The heat-exchanged dissociation chamber 9 makes the CO.sub.2 hydrates decompose by means of warming and the decomposed freshwater flows into the freshwater storage tank 10 by the check valve 20. The dissociation temperature is attained by the heat exchange with the hot flue-gas source 3. And the decomposed CO.sub.2 gas enters the CO.sub.2 gas tank 4 through the relief valve 16. The CO.sub.2 stored in the CO.sub.2 gas tank 4 are mainly used for the hydrate formation of the second-stage formation chamber 5-2. And the redundant CO.sub.2 are sequestrated in conventional ways.

(10) Above is just a basic description of the present invention and the related system for flue-gas hydrate based desalination using LNG cold energy is not limited by the structures and steps in the above embodiments. Based on the said system for flue-gas hydrate based desalination using LNG cold energy, it is possible for those skilled in this art to design a similar system or use the partial function independently or the overall function in conjunction. These are all the equivalent transformation or utilization according to the technical solutions of the present invention and they shall fall within the protection scope of the present invention.