Apparatus and method for selective laser sintering an object with a void
10766197 ยท 2020-09-08
Assignee
Inventors
Cpc classification
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y30/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y50/00
PERFORMING OPERATIONS; TRANSPORTING
B29C35/0288
PERFORMING OPERATIONS; TRANSPORTING
B33Y50/02
PERFORMING OPERATIONS; TRANSPORTING
B29C64/153
PERFORMING OPERATIONS; TRANSPORTING
B29C64/393
PERFORMING OPERATIONS; TRANSPORTING
International classification
B29C64/393
PERFORMING OPERATIONS; TRANSPORTING
B33Y50/02
PERFORMING OPERATIONS; TRANSPORTING
B33Y70/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y30/00
PERFORMING OPERATIONS; TRANSPORTING
B29C64/153
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y50/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A method of producing an object from a polymer powder using a laser sintering system, whereby the laser sintering system introduces heat energy to solidify select points of a layer of polymer powder according to build data of the object and adjusts the heat energy according to solidification of select points of other layers.
Claims
1. A selective laser sintering method, the method comprising the steps of: (i) providing build data of an object, the build data comprising a plurality of cross-section patterns according to geometric description data for the object, each of the cross-section patterns comprising data specifying points in the cross-section intended for solidification, and the plurality of cross-section patterns including a cross-section pattern for a layer L.sub.0, a cross-section pattern for a layer L.sub.1, and a cross-section pattern for a layer L.sub.2 wherein the layer L.sub.1 is a layer below the layer L.sub.0, and the layer L.sub.2 is a layer below the layer L.sub.1; (ii) applying a polymer powder layer L.sub.0 coinciding with the build layer L.sub.0 on a bed of a laser sintering system; (iii) determining an amount of heat energy to introduce by electromagnetic radiation to solidify a point at a first x-y position in the powder layer L.sub.0, the point at the first x-y position being intended for solidification according to the cross-section pattern for the build layer L.sub.0; (iv) adjusting the amount of heat energy to introduce at the first x-y position in the powder layer L.sub.0 using a controller programmed to make the adjustment based on whether the build data specifies solidification of a point at the first x-y position in the cross-section pattern for the layer L.sub.1 and the cross section pattern for the layer L.sub.2, wherein the adjustment is made to inhibit unwanted fusion between the first x-y position in the powder layer L.sub.0 and the first x-y position in the layer L.sub.1; and (v) solidifying the point at the first x-y position in the polymer powder layer L.sub.0 by introducing the adjusted amount of heat energy.
2. The method of claim 1, wherein the layer L.sub.1 is adjacent to the layer L.sub.0.
3. The method of claim 2, wherein the layer L.sub.2 is adjacent to the layer L.sub.1.
4. The method of claim 2, wherein the adjusting step further comprises reducing the amount of heat energy to introduce by the electromagnetic radiation to solidify the point at the first x-y position in the powder layer L.sub.0 when the build data does not specify solidification of the point at the first x-y position in the layer L.sub.1.
5. The method of claim 1, wherein the layer L.sub.2 is below and adjacent to the layer L.sub.1.
6. The method of claim 1, wherein the step of adjusting the amount of heat energy to introduce by electromagnetic radiation to solidify a point at the first x-y position in the powder layer L.sub.0 also depends on whether the build data specifies solidification of a point at the first x-y position in one or more powder layers in a heat affected zone that would be impacted by the introduced radiation.
7. The method of claim 6, wherein the polymer powder comprises one or more of PEK, PEEK, PEKK, PEEKK, and PEKEKK.
8. The method of claim 7, wherein the polymer powder comprises PEKK.
9. The method if claim 1, wherein said adjusting is performed such that the amount of heat energy is adjusted so as to inhibit said fusion between the point at the first x-y position in the layer L.sub.0 and the point at the first x-y position in the layer L.sub.1 when the build data does not specify solidification of the point at the first x-y position in the layer L.sub.1.
10. The method of claim 1, wherein step (iv) is performed prior to step (ii).
11. A method of solidifying an x-y position in a coating of a polymer powder during a selective laser sintering build process, the method including the steps of: (i) providing build data for a plurality of layers in a selective laser sintering build, the plurality of layers comprising a current layer, a first layer below the current layer, a second layer below the first layer, and a third layer below the second layer, and the build data specifying a plurality of points for solidification in each of the layers, the plurality of points specified for solidification in the current layer including a point at an x-y position in the current layer; (ii) applying a coating of a polymer powder coinciding with the current build layer on a bed of the laser sintering system; (iii) determining an amount of heat energy to introduce by an electromagnetic radiation source to solidify the point at the x-y position in the current powder layer; (iv) adjusting the amount of heat energy to introduce by the electromagnetic radiation source to solidify the point at the x-y position in the current powder layer using a controller programmed to make the adjustment based on whether the build data specifies solidification of a point at the x-y position in two or more of: the build data for the first layer, the second layer, and the third layer, wherein the adjustment is made to inhibit unwanted fusion between the current layer and the first layer; and (v) introducing the adjusted amount of heat energy for solidification at the x-y position in the current coating of powder.
12. The method of claim 11, wherein the first layer is adjacent to the current layer, the second layer is adjacent to the first layer, and the third layer is adjacent to the second layer.
13. The method of claim 12, wherein among the two or more layers considered for the step of adjusting the point at the x-y position in at least the first layer is considered.
14. The method of claim 13, wherein the point at the x-y position in at least the second layer is also considered among the two or more layers considered for the step of adjusting.
15. The method of claim 14, wherein the point at the x-y position in the third layer is also considered for the step of adjusting.
16. The method of claim 13, wherein said adjusting is performed such that the amount of heat energy for solidification of the point at the x-y position in the current layer is greater when the build data specifies solidification of the point at the x-y position in the first layer than when the build data does not specify solidification of the point at the x-y position in the first layer.
17. The method if claim 11, wherein the amount of heat energy is adjusted so as to inhibit said fusion between the point at the x-y position in the current layer and the point at the x-y position in the first layer when the build data does not specify solidification of the point at the x-y position in the first layer.
18. The method of claim 11, wherein step (iv) is performed prior to step (ii).
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION OF THE INVENTION
(11) The present disclosure describes aspects of the present invention with reference to the exemplary embodiments illustrated in the drawings; however, aspects of the present invention are not limited to the exemplary embodiments illustrated in the drawings. It will be apparent to those of ordinary skill in the art that aspects of the present invention include many more embodiments. Accordingly, aspects of the present invention are not to be restricted in light of the exemplary embodiments illustrated in the drawings. It will also be apparent to those of ordinary skill in the art that variations and modifications can be made without departing from the true scope of the present disclosure. For example, in some instances, one or more features disclosed in connection with one embodiment can be used alone or in combination with one or more features of one or more other embodiments.
(12) The present invention is especially useful for LS with polymer powders. One such class of polymer powders is Polyaryletherketones (PAEK) polymers. PAEKs are of interest in the LS process because parts that have been manufactured from PAEK powder or PAEK granulates are characterized by a low flammability, a good biocompatibility, and a high resistance against hydrolysis and radiation. The thermal resistance at elevated temperatures as well as the chemical resistance distinguishes PAEK powders from ordinary plastic powders. A PAEK polymer powder may be a powder from the group consisting of polyetheretherketone (PEEK), polyetherketoneketone (PEKK), polyetherketone (PEK), polyetheretherketoneketone (PEEKK) or polyetherketoneetherketoneketone (PEKEKK).
(13) PEKKs are well-known in the art and can be prepared using any suitable polymerization technique, including the methods described in the following patents, each of which is incorporated herein by reference in its entirety for all purposes: U.S. Pat. Nos. 3,065,205; 3,441,538; 3,442,857; 3,516,966; 4,704,448; 4,816,556; and 6,177,518. PEKK polymers differ from the general class of PAEK polymers in that they often include, as repeating units, two different isomeric forms of ketone-ketone. These repeating units can be represented by the following Formulas I and II:
-A-C(O)BC(O)I
-A-C(O)-D-C(O)II
(14) where A is a p,p-Ph-O-Ph-group, Ph is a phenylene radical, B is p-phenylene, and D is m-phenylene. The Formula I:Formula II isomer ratio, commonly referred to as the T:I ratio, in the PEKK is selected so as to vary the total crystallinity of the polymer. The T:I ratio is commonly varied from 50:50 to 90:10, and in some embodiments 60:40 to 80:20. A higher T:I ratio such as, 80:20, provides a higher degree of crystallinity as compared to a lower T:I ratio, such as 60:40.
(15) The crystal structure, polymorphism and morphology of homopolymers of PEKK have been studied and have been reported in, for example, Cheng, Z. D. et al, Polymorphism and crystal structure identification in poly(aryl ether ketone ketone)s, Macromol. Chem. Phys. 197, 185-213 (1996), the disclosure of which is hereby incorporated by reference in its entirety. This article studied PEKK homopolymers having all para-phenylene linkages [PEKK(T)], one meta-phenylene linkage [PEKK(I)] or alternating T and I isomers [PEKK(T/I)]. PEKK(T) and PEKK(T/I) show crystalline polymorphism depending upon the crystallization conditions and methods.
(16) In PEKK(T), two crystalline forms, forms I and II, are observed. Form I can be produced when samples are crystallized from melting at low supercoolings, while Form II is typically found via solvent-induced crystallization or by cold-crystallization from the glassy state at relatively high supercooling. PEKK(I) possesses only one crystal unit cell which belongs to the same category as the Form I structure in PEKK(T). The c-axis dimension of the unit cell has been determined as three phenylenes having a zig-zag conformation, with the meta-phenylene lying on the backbone plane. PEKK(T/I) shows crystalline forms I and II (as in the case of PEKK(T)) and also shows, under certain conditions, a form III.
(17) Suitable PEKKs are available from several commercial sources under various brand names. For example, polyetherketoneketones are sold under the brand name OXPEKK polymers by Oxford Performance Materials, South Windsor, Conn., including OXPEKK-C, OXPEKK-CE, OXPEKK-D and OXPEKK-SP, OXPEKK-N, OXPEKK-ESD polymers. Polyetherketoneketone polymers are also manufactured and supplied by Arkema. In addition to using polymers with a specific T:I ratio, mixtures of polyetherketoneketones may be employed.
(18) The powders used in these applications are produced by a variety of processes such as grinding, air milling, spray drying, freeze-drying, or direct melt processing to fine powders. The heat treatment can be accomplished before or after the powders are produced, but if treated prior to forming the powders, the temperature of the powder forming process must be regulated to not significantly reduce the melting temperature or the quantity of the crystallinity formed in the heat treatment process.
(19) Although the present disclosure is provided in reference to PAEK polymers, and more specifically PEKK polymers, the present disclosure is not so limited. A person of ordinary skill in the art and familiar with this disclosure would understand that the present invention may be employed with other types of polymers useful in LS and with other materials useful in LS, including, but not limited to, metals and ceramics.
(20) In reference to
(21) The temperature of the bed 22 can be variably controlled via a controller 60 in communication with heating elements (not shown) in and or around the bed 22. Furthermore, the LS system 10 according to the invention may include a heating device above the bed 22, which preheats a newly applied powder layer up to a working temperature below a temperature at which the solidification of the powder material occurs. The heating device may be a radiative heating device (e.g., one or more radiant heaters) which can introduce heat energy into the newly applied powder layer in a large area by emitting electromagnetic radiation.
(22) A second chamber 30 is adjacent to the first chamber 20. The second chamber 30 includes a table surface 32 deposed on an end of a piston 34 deposed therein. A powder 36 for use in the LS system 10 is stored in the second chamber 30 prior to the sintering step. It will be understood to a person of ordinary skill in the art and familiar with this disclosure that while a specific embodiment of an LS system is disclosed, the present invention is not limited and different known LS systems may be employed in the practice of the present invention.
(23) During operation of the LS system 10, a spreader 40 translates across a top surface of the first chamber 20, evenly distributing a layer of powder 36 across either the top surface of the bed 22, or the material previously deposed on the bed 22. The LS system 10 preheats the powder material 36 deposed on the bed 22 to a temperature proximate to a melting point of the powder. Typically, a layer of powder is spread to have a thickness of 125 m, however the thickness of the layer of powder can be increased or decreased depending on the specific LS process and within the limits of the LS system.
(24) A laser 50 and a scanning device 54 are deposed above the bed 22. The laser 50 transmits a beam 52 to the scanner 54, which then distributes a laser beam 56 across the layer of powder 36 deposed on the bed 22 in accordance with a build data. The laser selectively fuses powdered material by scanning cross-sections generated from a three-dimensional digital description of the part on the surface of the bed having a layer of the powdered material deposed thereon. The laser 50 and the scanner 54 are in communication with the controller 60. After a cross-section is scanned, the bed 22 is lowered by one layer thickness (illustrated by the downward arrow), a new layer of powdered material is deposed on the bed 22 via the spreader 40, and the bed 22 is rescanned by the laser. This process is repeated until a build 28 is completed. During this process, the piston 34 in the second chamber is incrementally raised (illustrated by the upward arrow) to ensure that there is a sufficient supply of powder 36.
(25) In reference to
(26) The block 100 shown in
(27) In reference to
(28) The CAD model is sectioned into a plurality of successive layers corresponding to layers of the build. Each layer has a cross-section pattern of the object for construction. The cross-section pattern comprises data specifying select points in the cross-section for solidification. Each point selected for solidification in a layer has a unique x-coordinate and y-coordinate in the cross-section. A software program, for example one executing on the LS machine controller or on a computer in communication therewith, determines an amount of heat energy to introduce to each point selected for solidification. The amount of heat energy can be a number of different controls. For example, in the P800 it is possible to adjust the power of the laser, the width of the laser, the tracking speed of the laser, laser deflection velocity, the hatch pattern of the laser, and/or the contour pattern of the laser. It is possible to base the amount of heat energy introduced at select points on different inputs, including those related to the type of material and desired properties.
(29) In reference to
(30) In reference to
(31) In reference to
(32) In further reference to
(33) As discussed in the background section of the pending disclosure, the inventors have discovered that heat energy introduced to sinter a select point in L.sub.0 will penetrate several layers below L.sub.0. This is referred to as the heat affected zone (HAZ). A problem arises when a downskin portion is sintered because unsintered power in the layers below will adhere to the downskin layer, thus causing a deviation in the geometry of the formed object relative to the geometry of the CAD model.
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(35) The current common practice to correct this problem is to modify the CAD design so that the bore has a cross-section that is more oval or egg shaped. The goal of this approach is to arrive at a bore having a circular cross-section relying on the oversinter to fill in the modified geometry that adds to the upper part of the void. This method is illustrated in
(36) The inventors have discovered a method of adjusting the heat energy introduced to a select point of a layer to reduce the problems with oversinter, and more specifically the problem of fusing a select point for solidification to select points in previously deposed layers that were not solidified during the LS process.
(37) An adjustment factor according to the present invention may be succinctly described by means of the following equation, in which E.sub.adjusted is the heat energy amount per unit area actually introduced at a position, E.sub.standard is the heat energy amount per unit area without consideration of the build data and previous or subsequent layers and K is a pre-factor that depends on the total exposure time of a region to be solidified in the previous and/or the current layer:
E.sub.adjusted=K.Math.E.sub.standard(1)
(38) The pre-factor can be determined and applied according to the following method. The determination of the pre-factor can for example be made empirically by pre-tests in the same additive manufacturing device in which the three-dimensional objects shall be manufactured. In doing so, before the actual manufacturing of the object, test objects are manufactured from the same building material and are measured.
(39) The method includes the step of providing build data of an object for construction in an LS system. The build data is derived from a CAD model of the object and includes a plurality of cross-section patterns according to a geometry description of the object. This may be, for example, a CAD file. Each cross-section pattern corresponds to a layer in the layer-wise building process. Thus, each cross-section may have a thickness in the z-axis that corresponds to the thickness of the applied layers in the LS system. The cross-section pattern comprises data specifying select points in the cross-section for solidification. Each of the select points in the cross-section pattern selected for solidification has a unique position in the cross-section pattern. The select points can, for example, be represented by Cartesian coordinates in an (x,y) plane.
(40) The LS machine applies a layer L.sub.0 of a polymer powder on a bed of a laser sintering system. The thickness of L.sub.0 can correspond to a thickness of a cross-section in the build data. The LS machine then solidifies select points of the polymer powder of layer L.sub.0 by introducing heat energy to the select points by controlled electromagnetic radiation according to the cross-section pattern assigned to L.sub.0. The amount of heat energy is initially set according to previously known methods that fail to account for the geometry of the manufactured part, and more specifically fail to account for unsintered material layers (e.g., voids) proximate to the selected point. To account for these voids, the method adjusts the heat energy introduced by electromagnetic radiation to solidify a select point at a first position in the layer L.sub.0 depending on whether the build data specifies solidification of a select point at the first position in one or more of: a previous layer L.sub.n and a subsequent layer L.sub.+n.
(41) In the above described method, n is a positive integer and L.sub.1 is a layer immediately preceding layer L.sub.0, L.sub.2 is a layer immediately preceding L.sub.1, and so forth, and L.sub.+1 is the layer immediately subsequent layer L.sub.0, L.sub.+2 is the layer immediately subsequent L.sub.+1, and so forth. To correct for oversinter on downskin builds, the method adjusts the heat energy introduced by electromagnetic radiation to solidify the select point at the first position in the layer L.sub.0 depending on whether the build data specifies solidification of a select point at the first position in a layer L.sub.n. That is, the method looks to the layers previously deposed that are below the current layer L.sub.0. In some embodiments of the present invention, the method will adjust the heat energy introduced based on whether the build data specifies solidification of a select point at the first position in layer L.sub.1. In other embodiments of the present invention, the method will adjust the heat energy introduced based on whether the build data specifies solidification of a select point at the first position in layers L.sub.1, L.sub.2, and L.sub.3. In yet other embodiments of the present invention, the method will adjust the heat energy introduced based on whether the build data specifies solidification of a select point at the first position in layers L.sub.1 through L.sub.5. It is preferred that the method looks the build data in one or more layers L.sub.n in a HAZ caused by an unadjusted introduction of heat energy, i.e., the amount of heat energy originally specified according to known methods. The inventors have discovered that, for a PEKK polymer, this is typically the first three layers below the layer of construction. A person of ordinary skill in the art and familiar with this disclosure will understand the HAZ, as determined in the Z direction, will vary based on the material and the heat energy introduced into the material.
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(44) In further reference to
(45) In reference to a select point at x.sub.3, y.sub.3, L.sub.0 533 the build data at the first position in the three preceding layers specifies solidification. Therefore, there is no need to adjust the heat energy introduced at x.sub.3, y.sub.3, L.sub.0 533. If, however, the HAZ extends more than three layers, the method may reduce the heat energy introduced at the select point because build data specifies no solidification at the first position at x.sub.3, y.sub.3, L.sub.4. In reference to a select point at x.sub.4, y.sub.4, L.sub.0 534, the build data at the first position in all preceding layers specifies solidification. Therefore, there is no adjustment to the heat energy introduced at x.sub.4, y.sub.3, L.sub.0 534.
(46) In the present method, the adjustment to the heat energy introduced to the select point at the first position is made based on whether the build data at the first position in preceding layers because this is the area of the heat affected zone. This method has the advantage over the prior art that relies on thermal conductivity in large three dimensional volumes near the select point for solidification because it can more accurately account for the geometry of the object and void therein being constructed. In some embodiments of the present invention, the adjustment of heat energy introduced by electromagnetic radiation to solidify a select point at a first position in the layer L.sub.0 does not account for whether the build data specifies solidification of points other than the first position in one or more relied upon layer L.sub.n and layer L.sub.+n.
(47) As discussed above, the disclosed method is also used to inhibit fusion of subsequent layers in the solidification of upskin sinters in the LS process. Polymers in general have a relatively low thermal conductivity as compared to metals commonly used in LS or LM techniques. Such low thermal conductivity of polymer powders relative to metals is derived in part from the solid-to-powder ratio in the materials. Metals used in LS or LM techniques typically possess a solid-to-powder ratio of 100:1. By comparison, the polymer powders described herein may possess a solid-to-powder ratio of less than 50:1. Higher solid-to-powder ratios typically correspond with greater thermal conductivity, especially in metals, which may have much greater thermal conductivity in solid form relative to powder form.
(48) Accordingly, the polymer powders described herein have relatively low thermal conductivity. For example, the polymer powders may have a thermal conductivity of less than 1.0 W/K*M. In addition, there is little to no material change in the thermal conductivity between sintered polymer and powder polymer. As a result, the solidified portions of a cross-section can retain heat for a period such that when a subsequent layer is deposed on the bed having unsintered portions, the retained heat in the sintered portions may cause a fusion to the newly deposed layer. Although the oversinter problems associated with downskin sinters and the problems caused in upskin sinters with unwanted fusion in subsequent unsintered layers caused by latent heat are different, the disclosed method can be used to reduce the latter issue as well.
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(51) In further reference to