Non-hydrogenated hardstock fat

Abstract

Hardstock fat having an amount of saturated fatty acids of at least 80 wt %, wherein the amount of H3mixed triglycerides is between 45 and 60 wt %, H3mixed being a group of triglycerides consisting of triglycerol esters of 3 H fatty acids wherein H is a saturated fatty acids having a length of C16 and/or C18, wherein the triglycerol ester is composed of two different fatty acids; and wherein the amount of H2Xmixed triglycerides is at least 10 wt %, H2Xmixed being a group of triglycerides consisting of H2M triglycerides and H2O triglycerides, wherein H2M triglycerides are triglycerol esters with two H fatty acid and one M fatty acid wherein M is a saturated fatty acid of a length of C12 and/or C14, and wherein H2O triglycerides are triglycerol esters with two H fatty acid and one O fatty acid wherein O is a unsaturated fatty acid of a length of C18, wherein the H2M and H2O triglycerides are composed of three different fatty acids.

Claims

1. A spread comprising a hardstock fat and water, wherein the hardstock fat is interesterified and comprises: a lauric fat in an amount of from 25 to 35 wt %; H3.sub.mixed triglycerides in an amount of from 45 to 60 wt %, H3.sub.mixed being a group of triglycerides consisting of triglycerol esters of 3 H fatty acids, wherein H is a saturated fatty acid having a length of C16 and/or C18, wherein the triglycerol ester is composed of two different fatty acids; H2X.sub.mixed triglycerides in an amount of at least 10 wt %, H2X.sub.mixed being a group of triglycerides consisting of H2M triglycerides and H2O triglycerides, wherein H2M triglycerides are triglycerol esters with two H fatty acids and one M fatty acid, wherein M is a saturated fatty acid of a length of C12 and/or C14, and wherein H2O triglycerides are triglycerol esters with two H fatty acids and one O fatty acid wherein O is a unsaturated fatty acid of a length of C18, wherein the H2M and H2O triglycerides are composed of three different fatty acids; saturated fatty acids in a total amount of at least 80 wt %, wherein the combined amount of saturated fatty acids having a length of C12 and C14 is from 12 to 24 wt %, the amount of saturated fatty acids having a length of C16 is from 43 to 55 wt %, the combined amount of saturated fatty acids having a length of C16 and C18 is from 55 to 68 wt %, the amount of saturated fatty acids having a length of C18 is from 9 to 15 wt %, and the total amount of fully saturated fatty acids is from 80 to 85 wt %; monounsaturated fatty acids with a length of C18 (C18:1) in an amount of less than 17 wt %; polyunsaturated fatty acids in an amount of less than 3 wt %.

2. The spread of claim 1, wherein the hardstock fat is non-hydrogenated.

3. The spread of claim 1, wherein the combined amount of saturated fatty acids having a length of C12 and C14 in the hardstock fat is from 18 to 24 wt %.

4. The spread of claim 1, wherein the amount of saturated fatty acids having a length of C16 in the hardstock fat is from 48 to 55 wt %.

5. The spread of claim 1, wherein the combined amount of saturated fatty acids having a length of C16 and C18 in the hardstock fat is from 60 to 68 wt %.

6. The spread of claim 1, wherein the amount of monounsaturated fatty acids with a length of C18 (C18:1) in the hardstock fat is less than 15 wt %.

7. The spread of claim 1, wherein the ratio of palmitic acid to stearic acid in the hardstock fat is from 3 to 5.

8. The spread of claim 1, wherein the hardstock fat has a solid fat content at 10 C. (N10) of from 88 to 98, a solid fat content at 20 C. (N20) of from 75 to 90, a solid fat content at 30 C. (N30) of from 50 to 67, a solid fat content at 35 C. (N35) of from 32 to 52, a solid fat content at 40 C. (N40) of from 16 to 36.

9. The spread of claim 1, wherein the hardstock fat is a single fat.

10. A process for producing the spread of claim 1, comprising: interesterifying a mixture comprising 25 to 35 wt wt % of a lauric fat and 45 to 70 wt % of palm oil and 10 to 20 wt% of a high C18 fat which has at least 20 wt % of saturated fatty acids of C18 length; and fractionating the interesterified mixture to produce a hardstock fat, wherein hardstock fat has an amount of saturated fatty acids of at least 80 wt %, wherein the amount of H3.sub.mixed triglycerides is between 45 and 60 wt %, and wherein the amount of H2X.sub.mixed triglycerides is at least 10 wt %, combining the hardstock fat and water, to produce the spread.

11. The process of claim 10, wherein the amount of palm oil is between 55 and 67 wt %.

12. The process of claim 10, wherein the amount of high C18 fat is between 15 and 20 wt %.

13. The process of claim 10, wherein the hardstock fat comprises a combined amount of saturated fatty acids having a length of C12 and C14 from 12 to 24 wt %, an amount of saturated fatty acids having a length of C16 from 43 to 55 wt %, a combined amount of saturated fatty acids having a length of C16 and C18 from 55 to 68 wt %, an amount of saturated fatty acids having a length of C18 from 9 to 15 wt %, an amount of monounsaturated fatty acids with a length of C18 (C18:1) of less than 17 wt %, a total amount of fully saturated fatty acids from 80 to 85 wt %, and an amount of polyunsaturated fatty acids of less than 3 wt %.

14. The process of claim 10, wherein the ratio of palmitic acid to stearic acid is from 3 to 5.

15. The process of claim 10, wherein the hardstock fat has a solid fat content at 10 C. (N10) of from 88 to 98, a solid fat content at 20 C. (N20) of from 75 to 90, a solid fat content at 30 C. (N30) of from 50 to 67, a solid fat content at 35 C. (N35) of from 32 to 52, and a solid fat content at 40 C. (N40) of from 16 to 36.

16. A spread comprising a margarine fat comprising a liquid vegetable oil in an amount of 50 to 95 wt % and a hardstock fat having an amount of saturated fatty acids of at least 80 wt %; wherein the amount of H3.sub.mixed triglycerides in the hardstock fat is between 45 and 60 wt %, H3.sub.mixed being a group of triglycerides consisting of triglycerol esters of 3 H fatty acids wherein H is a saturated fatty acid having a length of C16 and/or C18, wherein the triglycerol ester is composed of two different fatty acids; and wherein the amount of H2X.sub.mixed triglycerides in the hardstock fat is at least 10 wt %, H2X.sub.mixed being a group of triglycerides consisting of H2M triglycerides and H2O triglycerides, wherein H2M triglycerides are triglycerol esters with two H fatty acids and one M fatty acid wherein M is a saturated fatty acid of a length of C12 and/or C14, and wherein H2O triglycerides are triglycerol esters with two H fatty acids and one O fatty acid wherein O is a unsaturated fatty acid of a length of C18, wherein the H2M and H2O triglycerides are composed of three different fatty acids, said hardstock fat being in an amount of 5 to 50 wt %; wherein the hardstock fat is interesterified, non-hydrogenated, and comprises a lauric fat in an amount of from 25 to 35 wt %.

17. The spread of claim 16, wherein the hardstock fat has a solid fat content at 10 C. (N10) of from 88 to 98, a solid fat content at 20 C. (N20) of from 75 to 90, a solid fat content at 30 C. (N30) of from 50 to 67, a solid fat content at 35 C. (N35) of from 32 to 52, and a solid fat content at 40 C. (N40) of from 16 to 36.

18. The spread of claim 17, wherein the hardstock fat has a solid fat content at 10 C. (N10) of from 88 to 98, a solid fat content at 20 C. (N20) of from 75 to 90, a solid fat content at 30 C. (N30) of from 50 to 67, a solid fat content at 35 C. (N35) of from 32 to 52, and a solid fat content at 40 C. (N40) of from 16 to 36.

19. The spread of claim 16, wherein the spread is fat-continuous.

20. The spread of claim 16, comprising 25-59% margarine fat and 40-66% water.

21. A spread comprising a hardstock fat and water, wherein the hardstock fat is interesterified and comprises: a lauric fat in an amount of from 25 to 35 wt %; H3.sub.mixed triglycerides in an amount of from 45 to 60 wt %, H3.sub.mixed being a group of triglycerides consisting of triglycerol esters of 3 H fatty acids, wherein H is a saturated fatty acid having a length of C16 and/or C18, wherein the triglycerol ester is composed of two different fatty acids; and H2X.sub.mixed triglycerides in an amount of at least 10 wt %, H2X.sub.mixed being a group of triglycerides consisting of H2M triglycerides and H2O triglycerides, wherein H2M triglycerides are triglycerol esters with two H fatty acids and one M fatty acid, wherein M is a saturated fatty acid of a length of C12 and/or C14, and wherein H2O triglycerides are triglycerol esters with two H fatty acids and one O fatty acid wherein O is a unsaturated fatty acid of a length of C18, wherein the H2M and H2O triglycerides are composed of three different fatty acids.

22. The spread of claim 21, further comprising: monounsaturated fatty acids with a length of C18 (C18:1) in an amount of less than 17 wt %; and polyunsaturated fatty acids in an amount of less than 3 wt %.

Description

DETAILED DESCRIPTION

(1) For the purpose of the invention H3.sub.mixed is a group of triglycerides consisting of triglycerol esters of 3H fatty acids wherein H is a saturated fatty acids having a length of C16 and/or C18. H3.sub.mixed is therefor a mix of different triglycerides PPS, PSP, PSS and SPS wherein P stands for palmitic acid (C16) and S for stearic acid (C18). For example PSP stands for a triglyceride where the two palmitic acid are present at the terminal position and the stearic acid in the middle position, and PPS is a triglyceride where a palmitic and a stearic acid are present at the terminal position and a palmitic acid in the middle position. The amount of H3.sub.mixed is the combined amount of all different H3 triglycerides composed of two different fatty acids.

(2) H2X.sub.mixed is a group of triglycerides consisting of particular H2M triglycerides and H2O triglycerides.

(3) H2M triglycerides are triglycerol esters with two H fatty acid and one M fatty acid wherein M is a saturated fatty acid of a length of C12 and/or C14. Also H2M represents a mix of different triglycerides e.g SSMy, PPMy, SPMy, SSLa, PPLa, SPLa, wherein P stands for palmitic acid (C16) and S for stearic acid (C18), My for myristic acid (C14) and La for lauric acid (C12). For example SMyP comprises a triglycerides where the a stearic acids and a palmitic acid are present on the terminal position and the myristic acid in the middle position, and SPMy a triglyceride wherein a stearic and a myristic acid are present at the terminal position and a palmitic acid at the middle position.

(4) H2O triglycerides are triglycerol esters with two H fatty acid and one O fatty acid wherein O is a unsaturated fatty acid of a length of C18 (C18:1). Suitably the monounsaturated fatty acid with a length of C18 is olein.

(5) Also H2O represents a mix of different triglycerides e.g SSO, PPO, SPO, PSO and POS, wherein P stands for palmitic acid (C16) and S for stearic acid (C18), O for oleic acid.

(6) For the purpose of the invention the amount of H2X.sub.mixed is the combined amount of particular H2M and H2O triglycerides which are composed of three different fatty acids, such as SPMy, PSMy, SMyP, SPLa, PSLa, SLaP, PSO, SPO, or POS.

(7) The terms fat and oil are used in this specification as synonyms. The term hardstock refers to a fat that is solid at room temperature. The hardstock may comprise two or more different hard fats, but is preferably a single fat. The hardstock fat may be an interesterified mixture of one or more fats.

(8) A margarine fat is a fat blend which is suitable for use as a fat in spreads, both fat-continuous and water-continuous, such a margarine fat usually includes a hardstock and a liquid oil.

(9) The term liquid oil is used in this specification for fats that are liquid at room temperature preferably also liquid at temperature below room temperature such as below 15, 10 or 5 C. Preferably the solid fat content of the liquid oil is 0 at 20 C., more preferably it is 0 at 15 C.

(10) Solid fats from which lower melting constituents have been removed will be indicated as stearin fractions. A stearin fraction for the purpose of this description and claims is defined as a triglyceride mixture or fat blend from which at least 10% of the lower melting constituents have been removed by some kind of fractionation, e.g. dry fractionation, multi-stage countercurrent dry fractionation or solvent fractionation.

(11) The lower melting constituents are indicated as olein fraction

(12) In this specification all parts, proportions and percentages are by weight; the amount of fatty acids in an oil or fat is based on the total amount of fatty acids in said oil or fat and the amount of hardstock and/or hard fat in the fat composition is based on the total weight of said fat composition, unless otherwise stated.

(13) The solid fat content (SFC) in this description and claims is expressed as N-value, essentially as defined in Fette, Seifen Anstrichmittel 80 180-186 (1978). The stabilisation profile applied is heating to a temperature of 80 C., keeping the oil for at least 10 minutes at 60 C. or higher, keeping the oil for 16 hours at 0 C. and then 30 minutes at the measuring temperature, except where indicated otherwise.

(14) Non-hydrogenated means that the fat or oil has not undergone any hydrogenation treatment. This entails the starting ingredients as well as blends and interesterified mixtures and even fractions of fats.

(15) Preferably non-hydrogenated fats have less than 5 wt % of trans-fatty acids, more preferably less than 3 wt % trans-fatty acids, or even essentially no trans-fatty acids.

(16) The present invention is suitable for more natural products. More natural means that the product has undergone less modifications or preferably even no modifications other than refining and purification. Natural also encompasses the use of non-chemical variants of treatments, for example dry (non solvent) fractionation instead of wet (solvent) fractionation, with e.g. acetone, hexane or lanza and enzymatic rearrangement instead of chemical randomisation.

(17) In a preferred embodiment of the present invention the combined amount of saturated fatty acids having a length of C12 and/or C14 is 12 to 24 wt %. Preferably the amount of saturated fatty acids with a length of C16 is from 43 to 55. Suitable amounts of saturated fatty acids having a length of C16 and C18 is 55 to 68 wt %. The amount of saturated fatty acids with a length of C18 is preferably between 9 and 15. A preferred amount of monounsaturated fatty acid with a length of C18 (C18:1) is less than 17 wt %. Preferably the amount of poly unsaturated fatty acids (PUFA), C18:2 and C18:3 is less than 3 wt %.

(18) A very suitable hardstock according to the invention is a hardstock having a combined amount of saturated fatty acids having a length of C12 and/or C14 of 18 to 24 wt %. Preferably the amount of saturated fatty acids with a length of C16 is from 48 to 55. Suitable amounts of saturated fatty acids having a length of C16 and C18 is 60 to 68 wt %. A preferred amount of monounsaturated fatty acid with a length of C18 (C18:1) is less than 15 wt %. Suitably the monounsaturated fatty acid with a length of C18 is olein. The weight percentage is given on the hardstock fat.

(19) This hardstock fat is very suitable for use in fat-continuous spread, e.g in a heart health product, where the SAFA content is less than 20 wt %, the PUFA content is at least 50 wt % and the MUFA content is at least 30 wt %, while the products is virtually free from trans-fatty acids, preferably less than 3 wt % of trans fatty acids.

(20) In one embodiment the hardstock fat according to the invention has a solid fat content of from 88 to 98 at 10 C., from 75 to 90 at 20 C., from 50 to 67 at 30 C. and from 32 to 52 at 35 C. and from 16 to 36 at 40 C.

(21) Suitably the hardstock fat has a solid fat content of from 94 to 98% at 10 C., from 85 to 90% at 20 C., from 62 to 67% at 30 C. and from 45 to 52 at 35 C., and from 30 to 36 at 40 C. This hardstock fat is very suitable for use in fat-continuous spread, e.g in a heart health product, where the SAFA content is less than 20 wt %, the PUFA content is at least 50 wt % and the MUFA content is at least 30 wt %, while the products is virtually free from trans-fatty acids, preferably less than 3 wt % of trans fatty acids.

(22) The present invention also relates to a hardstock fat comprising 15 to 40 wt % of a lauric fat and 45 to 70 wt % of palm oil and 10 to 20 wt % of a high C18 fat which has at least 40 wt % of fatty acids of C18 length.

(23) Preferably the mix of lauric fat, palm oil and high C18 fat is an interesterified mixture.

(24) Preferably the interesterification was done enzymatically.

(25) A lauric fat is a fat that has a lauric fatty acid content of at least 35 wt %, preferably at least 40 wt %. Preferably 17 to 30 wt % of a lauric fat is used in the mixture. Suitably the lauric fat is selected from the group comprising palm kernel fat, coconut fat and babassu. Also fractions of the lauric fat may used. Preferably the lauric fat is dry-fractionated to retain the naturalness of the hardstock fat.

(26) Palm oil may be present in the mixture in a preferred amount of from 55 to 67 wt %. Suitably fractions of palm oil are used herein and combinations of palm oil and or palm oil fractions are envisioned.

(27) The high C18 fat has at least 20 wt %, preferably at least 25 wt % of saturated fatty acids with C18 length. It may also be preferred that the high C18 fat has 20 to 30 wt % of saturated fatty acids of C18 length. The weight percentage is on high C18 fat. Preferably 15 to 20 wt % of high C18 fat is used in the interesterified mixture.

(28) Furthermore, in another preferred embodiment the high C18 fat is selected from the group comprising shea fat or even shea butter as it is often called, illipe pentadesma, shea olein, or shea stearin. A preferred fat is shea stearin.

(29) Suitably the hardstock fat is a single fat. The advantage of having a single hardstock fat compared to a blend of different fats is that only one type of fat needs to be prepared.

(30) Furthermore, with a single fat there is no need for blending two or more different fats in specific ratios. For the purpose of the invention a single fat is envisioned to encompass one fat but also one interesterified mixture is regarded as a single fat.

(31) Furthermore the present invention also relates to a process for producing a hardstock fat according to the invention comprising:

(32) interesterifying a mixture 15 to 40 wt % of a lauric fat and 45 to 70 wt % of palm oil and 10 to 20 wt % of a high C18 fat which has at least 20 wt % of saturated fatty acids of C18 length, optionally fractionating the interesterified mixture, such that the resulting hardstock fat has an amount of saturated fatty acids of at least 80 wt %, wherein the amount of H3.sub.mixed triglycerides is between 45 and 60 wt %, and wherein the amount of H2X.sub.mixed triglycerides is at least 10 wt %.

(33) Preferably the hardstock fat has a combined amount of saturated fatty acids having a length of C12 and C14 of 12 to 24 wt %, the combined amount of saturated fatty acids having a length of C16 and C18 of 55 to 68 wt %, the amount of saturated fatty acids with a length of C16 from 43 to 55 wt %, the amount of saturated fatty acids with a length of C18 from 9 to 15 wt %, and the total amount of fully saturated fatty acids from 80 to 85 wt %, an amount of mono-unsaturated fatty acids with a length of C18 (C18:1) of less than 17 wt %, and an amount of poly unsaturated fatty acids (PUFA) of less than 3.

(34) Preferably 25 to 35 wt % of lauric fat is used in the interesterified mixture. Suitably the lauric fat may be selected from the group comprising palm kernel fat, coconut fat and babassu fat and fractions thereof and combinations thereof.

(35) Suitably palm oil fractions are used, also combinations of fractions and/or palm oil may be used. The combined amount of the palm oil fat and/or palm oil fraction is preferably 55 to 67 wt %.

(36) Preferably the high C18 fat has at least 25 wt % of saturated fatty acids of C18 length. A preferred high C18 fat is selected from the group comprising shea fat, pentadesma, illipe, shea olein, or shea stearin. A preferred fat is shea stearin.

(37) Preferably 15 to 20 wt % of a high C18 fat is used in the interesterified mixture.

(38) In a preferred embodiment of the present invention the combined amount of saturated fatty acids having a length of C12 and/or C14 is 18 to 24 wt %. Preferably the amount of saturated fatty acids with a length of C16 is from 48 to 55. Suitable amounts of saturated fatty acids having a length of C16 and C18 is 60 to 68 wt %. A preferred amount of monosaturated fatty acid with a length of C18 (C18:1) is less than 15 wt %.

(39) Preferably the resulting fat has a solid fat content of 88 to 98 at 10 C., 75 to 90 at 20 C., 50 to 67 at 30 C. and 32 to 52 at 35 C. and 16 to 36 at 40 C. More preferably the hardstock fat has a solid fat content of 94 to 98% at 10 C., 85 to 90% at 20 C., 62 to 67% at 30 C. and 45 to 52 at 35 C., and 30 to 36 at 40 C.

(40) In a preferred embodiment of the present invention the interesterification is catalysed by enzymes. Rearrangement by enzymes enhances the naturalness of the fat of the present invention.

(41) Optionally the interesterified mixture is further fractionated. Preferably the interesterified mixture is dry-fractionated.

(42) The present invention further relates to a margarine fat comprising a liquid vegetable oil in an amount of 50 to 95 wt % and a hardstock fat according to the invention in an amount of to 50 wt %. Preferably the amount of hardstock fat in the margarine fat is 5 to 30 wt %, more preferably 5-15 wt %. The amount of liquid oil is preferably wt %, more preferably wt %. The weight percentages are on margarine fat.

(43) Suitable liquid vegetable oils for the margarine fat are selected from the group comprising rapeseed oil, sunflower oil, safflower oil, linseed oil, corn oil, groundnut oil, soybean oil, linola oil and blends thereof.

(44) Furthermore the present invention relates to a margarine or fat-continuous spread comprising a margarine fat according to the invention.

(45) In another embodiment the present invention also relates to a water-continuous spread comprising a margarine fat according to the invention.

EXAMPLES

Example 1

(46) A hardstock was prepared with the following ingredients

(47) 16% of a shea stearin, 19% of a palm kernel fat and 65% of a Palm oil fraction. The fats were mixed and interesterified.

(48) The hardstock fat had the following fatty acids profile

(49) TABLE-US-00001 C 8:0 0.8 C 10:0 0.7 C 12:0 9.3 C 14:0 3.9 C 16:0 53.9 C 18:0 13.4 C 18:1 14.4 C 18:2 2.5 C 18:3 0.0 C 20:0 0.3 C 20 mono unsat 0.0 C 22:0 0.0 H3.sub.mixed 47.8 H2X.sub.mixed 11.9 SAFA 82.2 MUFA 14.4 PUFA 2.5

Example 2

(50) A hardstock was prepared with the following ingredients

(51) 13.5% of a shea stearin, 29.5% of a palm kernel fat and 57% of a palm oil fraction. The fats were mixed and interesterified.

(52) The hardstock fat had the following fatty acids profile

(53) TABLE-US-00002 C 8:0 1.3 C 10:0 1.1 C 12:0 14.3 C 14:0 5.4 C 16:0 48.2 C 18:0 11.7 C 18:1 14.4 C 18:2 2.5 C 18:3 0.0 C 20:0 0.3 C 20 mono unsat 0.0 C 22:0 0.0 H3.sub.mixed 47.1 H2x.sub.mixed 11.5 SAFA 82.2 MUFA 14.4 PUFA 2.5

Example 3

(54) A hardstock was prepared with the following ingredients

(55) 12% of a shea stearin, 36.5% of a palm kernel fat and 51.5% of a Palm oil fraction. The fats were mixed and interesterified.

(56) The hardstock fat had the following fatty acids profile

(57) TABLE-US-00003 C 8:0 1.6 C 10:0 1.4 C 12:0 17.6 C 14:0 6.4 C 16:0 44.4 C 18:0 10.7 C 18:1 14.5 C 18:2 2.5 C 18:3 0.0 C 20:0 0.2 C 20 mono unsat 0.0 C 22:0 0.0 H3.sub.mixed 46.9 H2X.sub.mixed 10.9 SAFA 82.2 MUFA 14.5 PUFA 2.5

Example 4

(58) A margarine was prepared with the hardstock of example 1 with the following ingredients:

(59) TABLE-US-00004 % Fatblend 34.74 rapeseed oil 16% sunflower oil 74% hardstock example 1 10% Monoglyceride 0.16 Lecithine 0.05 Colourant 0.04 Flavour (fat) 0.01 Total 35 Water 63.54 Acid 0.1 Thickener 1.25 Preservative 0.1 Flavour (water) 0.01 Total 65 SAFA 20.0

Example 5

(60) A margarine spread was prepared with the hardstock of example 1 with the following ingredients:

(61) TABLE-US-00005 % Fatblend 39.45 sunflower oil 78% rapeseed oil 10% hardstock example 1 12% Monoglyceride 0.3 Lecithine 0.2 Colourant 0.04 Flavour 0.01 Total 40 Water 59.97 Acid 0.03 Total 60 SAFA 21.7

Example 6

(62) A margarine spread was prepared with the hardstock of example 1 with the following ingredients:

(63) TABLE-US-00006 % Fatblend 58.95 sunflower oil 77% rapeseed oil 11% hardstock example 1 12% Monoglyceride 0.6 Lecithine 0.4 Colourant 0.04 Flavour 0.01 Total 60 Water 39.8 Acid 0.2 Total 40 SAFA 21.5

(64) The margarine had the following fatty acid profile:

(65) TABLE-US-00007 C 8:0 0.1 C 10:0 0.1 C 12:0 1.3 C 14:0 0.6 C 16:0 11.6 C 18:0 4.6 C 18:1 29.9 C 18:2 50.1 C 18:3 0.9 C 20:0 0.1 C 20 mono unsat 0.1 C 22:0 0.3

Example 7

(66) A light margarine spread was prepared with the hardstock of example 1 with the following ingredients:

(67) TABLE-US-00008 % Fatblend 24.55 sunflower oil 87% hardstock example 1 13% Monoglyceride 0.35 Lecithine 0.05 Colourant 0.04 Flavour 0.01 Total 25 Water 66.17 Starch 6 Thickener 2.5 Preservative 0.13 Acid 0.2 Total 75

(68) The margarine had the following fatty acid profile:

(69) TABLE-US-00009 C 8:0 0.1 C 10:0 0.1 C 12:0 1.4 C 14:0 0.6 C 16:0 12.1 C 18:0 5.0 C 18:1 25.8 C 18:2 54.2 C 18:3 0.0 C 20:0 0.0 C 20 mono unsat 0.0 C 22:0 0.3

Example 8

(70) Stability test were performed on the margarine spreads and compared to a margarine spread with a hydrogenated hardstock.

(71) 35% fat margarine spreads were compared.

(72) Comparative Product:

(73) TABLE-US-00010 % Fatblend 34.74 rapeseed oil 16% sunflower oil 74% hydrogenated hardstock 10% Monoglyceride 0.16 Lecithine 0.05 Colourant 0.04 Flavour (fat) 0.01 Total 35 Water 63.54 Acid 0.1 Thickener 1.25 Preservative 0.1 Flavour (water) 0.01 Total 65 SAFA 21.7

(74) The hydrogenated hardstock is an interesterified mixture of 60% fully hardened palm kernel oil and 40% hardened palm oil.

(75) The comparative product was compared with the margarine spread from example 4.

(76) Stability Test:

(77) For 2 to 3 weeks:

(78) 12 hours at 20 C. and 12 hours at 5 C.

(79) After every week droplet size and spreadability, and visual check on emulsion breakdown was performed.

(80) After 3 weeks the comparative product had an acceptable stability, the emulsion had not broken down however the spreadability was perceived as moderate.

(81) In contrast, the margarine of example 4 had a very good stability. No emulsion break down had occurred and the spreadability was still very good.

Example 9

(82) Stability test were performed on the margarine spreads and compared to a margarine having two hardstock fats.

(83) 40% fat margarine spreads were compared.

Comparative Example

(84) TABLE-US-00011 % Fatblend 39.45 sunflower oil 76% rapeseed oil 10% hardstock 1 8% hardstock 2 6% Monoglyceride 0.3 Lecithine 0.2 Colourant 0.04 Flavour 0.01 Total 40 Water 59.97 Acid 0.03 Total 60 SAFA 23.0
hardstock 1 is an interesterified mix of 65% of a palm oil fraction and 35% of palm kernel oil.
hardstock 2 is an interesterified mix of 60% of a palm oil fraction and 40 of a shea stearin.

(85) The comparative product was compared with the margarine spread from example 5.

(86) Stability Test:

(87) For 2 to 3 weeks:

(88) 12 hours at 20 C. and 12 hours at 5 C.

(89) After every week droplet size and spreadability, and visual check on emulsion breakdown was performed.

(90) After 3 weeks both the comparative product and the margarine of example 5 had a very good stability. No emulsion break down had occurred and the spreadability was still very good. Showing that the single hardstock of the invention gives also very good products.