METHOD FOR DETECTING MOISTURE AND VOLATILE MATTER CONTENT OF RAW COAL BY USING VALUE OF BASELINE DRIFT

Abstract

The present invention relates to a method for detecting moisture and volatile matter content in raw coal using the value of baseline drift, comprising the following steps: selecting a plurality of types of standard coal having different coal ranks and different ash contents, performing a Raman spectroscopy test and a proximate analysis on each type of standard coal, calculating the value of baseline drift in the Raman spectrum, and setting up the mapping relationship between the value of baseline drift in the Raman spectrum and the characteristic parameters of the moisture and the volatile matter content. The same method and reference are used to perform a Raman spectroscopy test on raw coal to be tested, so as to calculate the value of baseline drift in a Raman spectrum of the raw coal to be tested, and obtain the moisture and volatile matter content of the raw coal to be tested.

Claims

1. A method for detecting moisture and volatile matter content of raw coal by using a value of baseline drift, comprising the following steps: step 1: selecting a variety of standard coals with different coal ranks and different ash contents, and performing Raman spectroscopy test and proximate analysis on each standard coal to obtain Raman spectral characteristic parameters as well as moisture and volatile matter content of each standard coal, calculating a value of baseline drift in Raman spectrum by using the Raman spectral characteristic parameters of each standard coal, and setting up a mapping relationship between the value of baseline drift in Raman spectrum and the moisture and the volatile matter content to establish a relevance database of baseline drift value in Raman spectrum and the moisture as well as the volatile matter content; step 2: using the same method and reference as in step 1 to perform Raman spectroscopy test on raw coal to be tested to obtain the Raman spectral characteristic parameters of the raw coal to be tested, calculating the value of baseline drift in Raman spectrum of the raw coal to be tested, obtaining the moisture and the volatile matter content of the raw coal to be tested according to the corresponding mapping relationship between the value of baseline drift in Raman spectrum and the moisture and the volatile matter content in the relevance database.

2. The method according to claim 1, wherein the Raman spectral characteristic parameters at least comprise three of the following parameters: peak intensities P.sub.A, P.sub.B, P.sub.C and P.sub.D corresponding to peak 800 cm.sup.1, peak 1800 cm.sup.1, peak D, and peak G.

3. The method according to claim 2, wherein a calculation method of the value of baseline drift in Raman spectrum is: P=(P.sub.BP.sub.A)/(P.sub.DP.sub.A), and P is the value of baseline drift in Raman spectrum.

4. The method according to claim 2, wherein a calculation method of the value of baseline drift in Raman spectrum is: P=(P.sub.BP.sub.A)/(P.sub.CP.sub.A), and P is the value of baseline drift in Raman spectrum.

5. The method according to claim 3, wherein a mapping relationship between the moisture content and the value of baseline drift in Raman spectrum is m=1.15+12.91P+79.664P.sup.269.95P.sup.3, where m is the mass fraction of moisture.

6. The method according to claim 3, wherein a mapping relationship between the volatile matter content and the value of baseline drift in Raman spectrum is V=4.41+241.44P496.77P.sup.2+316.82P.sup.3, where V is the volatile matter content.

7. The method according to claim 1, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

8. The method according to claim 2, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

9. The method according to claim 3, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

10. The method according to claim 4, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

11. The method according to claim 5, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

12. The method according to claim 6, wherein a variety of the standard coals are raw coals and each of the standard coals is a different representative coal type.

13. The method according to claim 1, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

14. The method according to claim 2, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

15. The method according to claim 3, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

16. The method according to claim 4, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

17. The method according to claim 5, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

18. The method according to claim 6, wherein the volatile matter content is volatile content in dry ash-free basis of coal.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0026] FIG. 1 is a schematic flowchart of detecting the moisture and volatile matter content of raw coal by using a value of baseline drift provided in an embodiment of the present invention.

[0027] FIG. 2 is a schematic diagram of calculating a value of baseline drift.

[0028] FIG. 3 is the original Raman spectrum of typical 10 kinds of standard coal.

[0029] FIG. 4 is a schematic diagram of a mapping relationship between a value of baseline drift and a moisture content.

[0030] FIG. 5 is a schematic diagram of a mapping relationship between a value of baseline drift and a volatile matter content.

DESCRIPTION OF THE EMBODIMENTS

[0031] In the following description, the technical solutions in the embodiments of the present invention will be clearly and thoroughly described with reference to the drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by a person of ordinary skill in the art without inventive efforts shall fall within the protection scope of the present invention.

[0032] It should be noted that the embodiments of the present invention and the features in the embodiments can be combined with each other provided that no conflict is caused.

[0033] The present invention is further described below with reference to the accompanying drawings and specific embodiments, but is not intended to limit the present invention.

[0034] Raman spectrum is a kind of inelastic scattered light. When a laser irradiates the matter, molecules of the matter will be motivated and generate a characteristic Raman spectrum. The characteristic peaks in the Raman spectrum can characterize a specific chemical structure in the matter. Since Raman spectrum is very sensitive to the structure of carbon, it is very sensitive to changes in the chemical structure of coal. Generally speaking, the peak D near 1350 cm.sup.1 in the Raman spectrum of coal can reflect the large aromatic ring structure in coal, and the peak G near 1580 cm.sup.1 can reflect the intensity of graphite crystals in coal. The present invention selects one of peak intensities P.sub.C and P.sub.D of the two most typical characteristic peaks, namely peak D and peak G, in coal combined with the peak intensities (the present invention utilizes peak intensities P.sub.A and P.sub.B corresponding to point 800 cm.sup.1 and point 1800 cm.sup.1) of another two points, thereby calculating the value of baseline drift in Raman spectrum (that is, the ratio of the value of baseline drift to the intensity of the Raman peak). Specifically, the calculation method of the value of baseline drift in Raman spectrum is: P=(P.sub.BP.sub.A)/(P.sub.CP.sub.A) or P=(P.sub.BP.sub.A)/(P.sub.DP.sub.A).

[0035] It should be noted that, based on the calculation principle of the value of baseline drift in Raman spectrum in the present invention, those skilled in the art may also choose the peak intensity of other typical characteristic peaks in coal to partially or completely replace P.sub.C and P.sub.D, and correspondingly combine the peak intensity of two peaks that are identical to or different from that selected in the present invention, so as to adopt the same or similar calculation method to obtain the value of baseline drift in Raman spectrum. Then, the mapping relationship between the value of baseline drift in Raman spectrum and the moisture as well as volatile matter content parameters can be utilized for detection of moisture and volatile matter content parameters and so on in the coal to be tested.

[0036] The following describes an embodiment of the present invention and an application example based on the embodiment.

Embodiment

[0037] The schematic flowchart of a method for detecting the moisture and volatile matter content of raw coal by using a value of baseline drift is shown in FIG. 1, and the method includes the following steps:

[0038] Step 1: Select a variety of standard coals with different coal ranks and different ash, and perform Raman spectroscopy test and proximate analysis on each standard coal to obtain the Raman spectral characteristic parameters as well as moisture and volatile matter content characteristic parameters of each standard coal. The value of baseline drift in Raman spectrum is calculated by using the Raman spectral characteristic parameters of each standard coal, and the mapping relationship between the value of baseline drift in Raman spectrum and the moisture and volatile matter content characteristic parameters is calculated to establish a relevance database of the value of baseline drift in Raman spectrum and the moisture as well as volatile matter content characteristic parameters.

[0039] Step 2: Utilize the same method and reference as in step 1 to perform Raman spectroscopy test on the raw coal to be tested to obtain the Raman spectral characteristic parameters of the raw coal to be tested, and the value of baseline drift in Raman spectrum of the raw coal to be tested is calculated. The moisture and volatile matter content of the raw coal to be tested are obtained according to the corresponding mapping relationship between the value of baseline drift in Raman spectrum and the moisture and volatile matter content characteristic parameters in the relevance database.

[0040] Specifically, the Raman spectral characteristic parameters include at least three of the following parameters: the peak intensities P.sub.A, P.sub.B, P.sub.C, P.sub.D corresponding to point 800 cm.sup.1, point 1800 cm.sup.1, peak D, and peak G.

[0041] Specifically, the calculation method of the value of baseline drift in Raman spectrum is: P=(P.sub.BP.sub.A)/(P.sub.DP.sub.A), and P is the value of baseline drift in Raman spectrum.

[0042] Specifically, the mapping relationship between the moisture content and the value of baseline drift in Raman spectrum is m=1.15+12.91P+79.664P.sup.269.95P.sup.3, where m is the mass fraction of moisture.

[0043] Specifically, the mapping relationship between the volatile matter content and the value of baseline drift in Raman spectrum is V=4.41+241.44P496.77P.sup.2+316.82P.sup.3, where V is volatile matter.

[0044] The following is an application example based on the embodiment.

[0045] 1) Select 30 kinds of standard coal, numbered 1-30, and conduct proximate analysis to obtain the moisture and volatile matter content of raw coal. The relevant data of typical 10 kinds of standard coal are shown in the following table:

TABLE-US-00001 Volatile Volatile matter Fixed content in dry Moisture content carbon Ash ash-free basis No. (M, %) (V, %) (FC, %) (A, %) (V.sub.daf) 1 14.34 24.91 53.91 6.84 31.60 2 1.83 7.54 67.49 23.14 10.05 3 3.07 28.92 51.39 16.61 36.01 4 1.28 4.85 62.02 31.85 7.25 5 8.78 32.25 54.37 4.60 37.23 6 12.47 25.78 57.11 4.64 31.10 7 1.75 9.72 68.13 20.40 12.49 8 1.50 22.74 47.40 28.35 32.42 9 22.10 34.93 35.47 7.50 49.62 10 1.62 19.05 48.88 30.45 28.04

[0046] 2) Raman tests were performed on fifty standard coal samples. The Raman test conditions are shown in the following table:

TABLE-US-00002 Laser Eyepiece Scanning Scanning wavelength Laser power multiple time range 532.16 nm 5 mw 50 10 s 800-1800 cm.sup.1

[0047] The full diagram of obtained Raman spectrum of the ten types of typical raw coal is as shown in FIG. 2. From FIG. 2, it can be seen that there is partial baseline shift in the original Raman spectrum of the coal.

[0048] 3) Take the peak intensities P.sub.A and P.sub.B corresponding to the point 800 cm.sup.1 and point 1800 cm.sup.1 in the Raman spectrum and the peak intensity P.sub.C (or P.sub.D) of the peak D (or peak G) in the Raman spectrum to calculate the value of baseline drift in Raman spectrum P. Specifically, P=(P.sub.BP.sub.A)/(P.sub.DP.sub.A) (or P=(P.sub.BP.sub.A)/(P.sub.CP.sub.A)), the value of baseline drifts of the 10 types of typical raw coals calculated by using P=(P.sub.BP.sub.A)/(P.sub.DP.sub.A) are shown in the following table:

TABLE-US-00003 Value of baseline No. drifts P 1 0.21703 2 0.06197 3 0.14295 4 0.01416 5 0.19736 6 0.22746 7 0.03766 8 0.176 9 0.49829 10 0.08

[0049] 4) The obtained value of baseline drift in Raman spectrum of the 10 types of typical raw coals and the moisture content m of corresponding typical raw coals are utilized to establish a mapping relationship, thereby obtaining m=1.15+12.91P+79.664P.sup.269.95P.sup.3, where m is the mass fraction of moisture. The obtained value of baseline drift in Raman spectrum of the 10 types of typical raw coals and the volatile matter content V of corresponding typical raw coals are utilized to establish a mapping relationship, thereby obtaining V=4.41+241.44P496.77P.sup.2+316.82P.sup.3, where V is volatile matter. The mapping relationship between m-P and V-P is shown in FIG. 4 and FIG. 5.

[0050] In this embodiment, in order to further improve the accuracy of the mapping relationship, the number of typical raw coals for test can also be increased.

[0051] 5) Take the raw coal to be tested, utilize the same method and reference, repeat the above steps 1) to 3), proximate analysis shows that the moisture content in the raw coal to be tested is m=12.76%, the volatile matter content V=42.68%, and the value of baseline drift P is 0.44293. The value of baseline drift P is substituted into the mapping relationship in step 4). The calculated moisture content is m=16.13%, and the volatile matter content is V=47.12%.

[0052] In this embodiment, the error between the moisture and volatile matter content calculated by using the value of baseline drift and the proximate analysis test value is within 5%, which shows a higher test accuracy, and the calculation method is simple. Accordingly, the present invention can realize automatic recognition of a computer and is suitable for smart control.

[0053] In the present invention, it may be considered to increase the type of coal in the coal bank to improve the adaptability of the coal type subsequently. Meanwhile, related data in the mapping relationship between the value of baseline drift in Raman spectrum and moisture as well as volatile matter content can be further modified by increasing the type of coal in coal bank as well as repeatedly measuring the Raman spectrum of each standard coal for multiple times and so on, thereby improving test accuracy and minimizing error.

[0054] The above volatile matter content is only preferred embodiments of the present invention, and do not therefore limit the implementation and protection scope of the present invention. For those skilled in the art, they should be able to realize that any solutions that are derived by making equivalent changes and obvious modifications based on the content in the specification and drawings of the present invention shall fall within the scope sought to be protected by the present invention.