METHOD AND DEVICE FOR SORTING FIBERS IN SUSPENSION IN AN AEROSOL THROUGH THE COMBINATION OF ELECTROSTATIC AND GRAVITATIONAL FORCES
20200261923 ยท 2020-08-20
Assignee
Inventors
Cpc classification
B03C3/47
PERFORMING OPERATIONS; TRANSPORTING
B03C3/14
PERFORMING OPERATIONS; TRANSPORTING
G01N2015/0019
PHYSICS
International classification
B03C3/08
PERFORMING OPERATIONS; TRANSPORTING
B03C3/47
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The invention consists of a continuous sorting method and device which highlights the trajectory differences to which fibers of different form factors and particles charged under the joint influence of electrical and gravitational forces could be subjected. Thus, according to the sorting method, the conditions exploit this difference in order to recover/collect the fibers separated from the non-fibrous particles present in the same initial aerosol or to sort fibers exhibiting different form factors.
Claims
1. A method for sorting micro- and nano-fibers in suspension in an aerosol likely to contain fibers of different sizes and possibly non-fibrous particles, comprising the following steps: a/ charging of the particles in suspension in the aerosol, by unipolar ion diffusion; b/ application of an electrical field between two electrically conductive flat surfaces, arranged substantially horizontally; the electrical field being directed in such a way that it exerts an electrostatic force on the charged particles, in opposition to the gravitational force; c/ introduction of an aerosol flow from an input of a height corresponding to at least a part of the height of the space delimited between the two flat surfaces; the flow of the flow of air being non-turbulent in the space between flat surfaces; the flow of air circulating from and/or around the input to one or more outputs; d/ recovery of the part of air flow charged with fibers and circulating at at least one of the outputs in the upper part of the space, or collection of the fibers on the flat surface on top which is in the form of a filtering membrane; the fibers recovered in the part of air flow or collected on the filtering membrane being sorted from the particles exhibiting a smaller form factor or that are non-fibrous initially present in the aerosol.
2. The sorting method according to claim 1, further comprising a step d/ simultaneous with the step d/, whereby the part of air flow charged with non-fibrous particles and circulating at at least one of the outputs in the lower part of the space is recovered, or non-fibrous particles are collected on the lower flat surface which takes the form of a filtering membrane.
3. The sorting method according to claim 2, wherein the flat surfaces are rectangular flat plates, whereby: the step c/ is performed by introduction of the aerosol into an input slit arranged in the space between plates and by circulation of a longitudinal flow of filtered air introduced on either side of the slit co-current with the aerosol flow; the step d/ is performed by recovery of the part of the air flow charged with fibers in an output channel delimited between the top flat plate and a flow-separating wall arranged between the two flat plates; if necessary, the step d/ is performed by recovery of the part of air flow charged with non-fibrous particles in an output channel delimited between the lower flat plate and a flow-separating wall arranged between the two flat plates.
4. The sorting method according to claim 2, wherein the flat surfaces are full circular plates; whereby: the step c/ is performed by introduction of the aerosol into an input slit arranged in the space between plates and by circulation of a radial flow of aerosol toward the center of the surfaces; the step d/ is performed by recovery of the part of the air flow charged with fibers in an output duct produced in the axial extension in the circular plate on top thereof; if necessary, the step d/ is performed by recovery of the part of the air flow charged with non-fibrous particles in an output duct produced in the axial extension in the circular plate below the latter.
5. The sorting method according to claim 2, wherein at least the flat surface on top is a circular filtering membrane, whereby: the step c/ is performed by introduction of the aerosol into an input slit arranged in the space between plates or in all the space between plates and by circulation of a radial flow of aerosol toward the center of the surfaces; the step d/ is performed by collection of the fibers on the filtering membrane, the air flow without fibers collected being recovered in an output orifice above the filtering membrane; if necessary, the step d/ is performed by collection of the non-fibrous particles on a filtering membrane, the air flow without particles collected being recovered in an output orifice below the filtering membrane.
6. The sorting method according to claim 1, wherein the flat surfaces are the underside faces of two openwork disks with concave circular edge, arranged horizontally coaxially to one another defining a space between them; the input being a duct produced in the axial extension of the outer disk above the latter; the output being a duct produced in the axial extension of the inner disk above the latter; the underside face of the inner disk being at least partly a filtering membrane; whereby: the step b/ is performed by application of the uniform electrical field between the two disks, the uniform electrical field being directed from bottom to top between the underside face of the outer disk and the bottom face of the inner disk; the step c/ is performed by introduction of the aerosol from the input duct; the flow of the air flow being non-turbulent in the space between the two disks; the air flow circulating from the input duct to the output duct; the step d/ is performed by collection of the fibers on the filtering membrane; the fibers collected on the filtering membrane being separated from the fibers of smaller form factors and that are non-fibrous initially present in the aerosol and having fallen through gravity in the space between faces below.
7. A device for implementing the sorting method according to claim 1, comprising: two electrically conductive flat surfaces, arranged substantially horizontally; means for applying an electrical field (E) between the two flat surfaces, from the bottom to the top; means for introducing an aerosol flow of fibers in suspension in an aerosol likely to contain factor particles of different shapes or non-fibrous particles, from an input of a height corresponding to at least a part of the height of the space delimited between the two flat surfaces; means for recovering the part of air flow charged with fibers and circulating at at least one of the outputs in the upper part of the space, or collection of the fibers on the flat surface above which is in the form of a filtering membrane.
8. The device according to claim 7, further comprising means for recovering the part of air flow charged with non-fibrous particles and circulating at at least one of the outputs in the lower part of the space, or collection of the particles on the flat surface below which is in the form of a filtering membrane.
9. The device according to claim 7, wherein the two flat surfaces are rectangular flat plates, the input being a slit arranged in the space between plates, the output being a channel delimited between the top flat plate and a flow-separating wall between the two flat plates.
10. The device according to claim 7, wherein the flat surfaces are solid circular plates, the input being a circular slit arranged in the space between plates, the output being a duct produced in the axial extension in the top circular plate.
11. The device according to claim 10, further comprising a duct for recovering the part of the flow containing the non-fibrous particles, the duct produced in the axial extension in the bottom circular plate.
12. The device according to claim 7, wherein the flat surfaces are circular surfaces, at least the top one of which comprises a filtering membrane; the input being a circular slit arranged in the space between circular surfaces, the output being a duct produced in the axial extension above the filtering membrane.
13. The device according to claim 7, wherein the flat surfaces are circular surfaces, at least the top one of which comprises a filtering membrane; the input being composed of all the space between circular surfaces, the output being a duct produced in the axial extension above the filtering membrane.
14. The device according to claim 7, wherein the flat surfaces are the bottom faces of two openwork disks with concave circular edge, arranged horizontally coaxially to one another defining a space between them; the input being a duct produced in the axial extension in the outer disk on top of the latter; the output being a duct produced in the axial extension of the inner disk on top of the latter; the bottom face of the inner disk being at least partly a filtering membrane.
15. The sorting method according to claim 1, further comprising detection and measurement of concentration in terms of number of fibers, in air.
16. The sorting method according to claim 15, further comprising detection and measurement of concentrations of WHO asbestos fibers.
Description
DETAILED DESCRIPTION
[0083] Other advantages and features will become more apparent on reading the detailed description, given in an illustrative and nonlimiting manner, with reference to the following figures in which:
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[0086]
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[0088]
[0089]
[0090]
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[0093]
[0094] Throughout the present application, the terms vertical, bottom, top, low, high, below, above, height should be understood with reference to a separation device according to the invention arranged horizontally or vertically.
[0095] Likewise, the terms input, output, upstream and downstream should be understood with reference to the direction of the flow of aerosol in a device according to the invention. Thus, the input designates a zone of the device through which the aerosol containing the fibers and the non-fibrous particles is introduced whereas that of output designates that through which the air flow charged only with fibers is discharged.
[0096] For clarity, the same elements of the sorting devices according to the examples illustrated are designated by the same numeric references.
[0097]
[0098] It is specified that previously, before the introduction of the aerosol into the device 1, the particles of the aerosol are charged negatively by unipolar ion diffusion. Within the context of the invention, the opposite, i.e. positively-charged particles, is quite conceivable.
[0099] The sorting device 1 first of all comprises two parallel flat plates 2, 3, arranged horizontally. These plates 2, 3 are electrically conductive.
[0100] At a longitudinal end of the plates 2, 3, there is arranged an input slit 4, in the middle of the space between plates, that is to say the middle of the slit 4 is at half the height h of the space between plates 2, 3. The slit 4 can for example be produced by two plates, also flat and mutually parallel, but over a height much lesser than the space between plates 2, 3.
[0101] At the other longitudinal end, there is arranged a separation wall 5, also at the middle of the space between plates 2, 3. This wall 5 therefore delimits, with the plate on top 2, a channel 6, while it delimits, with the plate below 3, a channel 7.
[0102] An electrical field E is generated, preferably uniform and preferably of constant intensity, between the plates 2, 3, the field E being directed from bottom to top. For this, for example, the bottom plate 3 is brought to the zero potential, whereas the top plate 2 is at the potential +U. In the context of the invention, it is perfectly possible to envisage the reverse, that is to say particles positively charged with an electrical field in the device equal to U.
[0103] A longitudinal flow of filtered air with non-turbulent flow is introduced from the side of the slit 4, into the space between plates 2, 3. The filtered air flow is separated into a flow q1 between the slit 4 and the plate on top 2 and a flow q2 between the slit 4 and the plate below 3.
[0104] The aerosol is then introduced through the slit 4, at a flow rate qo.
[0105] The electrically charged particles are therefore subjected to the electrical field E, which tends to draw them toward the top plate 3, unless they are too dense, in which case they will tend to be deposited on the bottom plate 2 under the action of the gravity field g.
[0106] Thus, in its travel between the plates, any particle, including a fibrous one, will be subjected to these two antagonistic force fields, field of gravity g and electrical field E.
[0107] Each particle, fibrous or not, will therefore be subjected to two opposing transverse velocities: [0108] an upward velocity due to the electrical field denoted w, such that w=Z*E, where Z is the electrical mobility of the particle, [0109] a downward velocity due to the field of gravity denoted u, such that u=*g, where is the relaxation time of the particle, and g is the Earth's field of gravity.
[0110] The trajectory of a particle will therefore result from the composition of these two transverse velocities u and w on the one hand, of its longitudinal velocity v in the non-turbulent flow on the other hand.
[0111] For a fixed geometry and flow rate, an appropriate value of the field E can therefore direct the fibers and the fine particles that are highly electrically mobile and not subject to gravity, into the top part of the space between plates 2, 3, and direct the non-fibrous particles into the bottom part 7 of this space, above all the large particles, which have little electrical mobility and are subject to gravity.
[0112] It is therefore possible to recover, in the output channel 6, the fibers separated and borne by the air flow at the flow rate Q1.
[0113] In parallel, it is possible to recover, in the output channel 7, the fibers exhibiting the lowest form factor or the non-fibrous particles borne by the air flow at the flow rate Q2.
[0114] The sum of the input flow rates q.sub.0, q.sub.1 and q.sub.2 equals the sum of the output flow rates Q.sub.1 and Q.sub.2.
[0115] Thus separated from the fibers, the large particles can no longer mask the count of the fibers for the asbestos fiber measuring application.
[0116] The inventors have corroborated, by calculations presented hereinbelow, the separation between fibers and non-fibrous particles by the combined action of electrical force resulting from a field E created between flat plates, and the Earth's field of gravity g.
[0117] In the calculations, the case of carbon fibers is considered, specifically those which were used in the experiments mentioned in the publication [3], of 3.74 m diameter, charged by unipolar ion diffusion with a product Ni*t=1.9.10.sup.7 s/cm.sup.3. The advantage of using carbon fibers is that their electrical characteristics have been particularly well studied by the authors of the publication. Another advantage is also deliberately choosing conditions conducive to revealing the action of the field of gravity relative to the action of the electrical field.
[0118] The trajectory of a particle is obtained by composing the velocities u, v, w, in which:
[0127] By eliminating dt, in the equations (1) and (2), the following is obtained:
[0128] In other words by performing the integration
[0129] Hence the final equation (3) as follows:
[0130] To calculate the relaxation time .sub.f of a fiber, the equation (4) is used:
By taking into account the experimental data from the publication [3] and according to the equation (4), the table 1 below of fiber characteristics is obtained:
TABLE-US-00001 .sub.f Z.sub.f in m.sup.2/(V*s) .sub.f in s 10 1.269 7.97*10.sup.8 3.77*10.sup.4 20 1.541 11.27*10.sup.8 4.93*10.sup.4
It is specified that the experimental data used are valid for N.sub.i*t equal to 1.9*10.sup.13 ions*s/m.sup.3, where N.sub.i is the concentration of unipolar ions and t is the dwell time.
[0137] To calculate the electrical field E which allows fibers of factor equal to 20, to arrive at the top of the space between plates, i.e. closest to the top plate, with x=L, the equation (3) for
which gives:
[0138] with Q representing the flow rate equal to 2 liters per min; 1=5 cm, L=20 cm, .sub.f=4.93*10.sup.4s, Z.sub.f=11.27*10.sup.8 m.sup.2/(V*s) and g=9.81 m/s.sup.2, an electrical field value E equal to 5.76*10.sup.4 V/m is obtained.
[0139] By using this value in the equation (3) above, all the elements are there to find the trajectory of the fibers of factor equal to 20.
[0140] For the same value E, it is also possible to find all the elements to find the trajectory of the fibers of factor equal to 10.
[0141] It is possible to proceed and do the same calculations for a volume-equivalent sphere (the indices se hereinbelow corresponding to an equivalent sphere).
[0142] Let d.sub.se be the volume diameter of a sphere equivalent to a fiber of diameter d and of length l.sub.f, then the following relationship applies:
[0143] Then, with which is the ratio between fiber length lf and diameter d, the equation (4) applies:
d.sub.se=d*(1.5*).sup.1/3.
[0144] For the calculation of the relationship time of the sphere, the equation (5) is used:
with .sub.se equal to 1.
[0145] For the calculation of electrical mobility of the spheres, the publication [1] makes it possible to determine it for a product N.sub.i*t equal to 10.sup.13 ions*s/m.sup.3.
[0146] It is possible to extrapolate to assume conditions calculated for the fibers, i.e. with N.sub.i*t equal to 1.9*10.sup.13 ions*s/m.sup.3.
[0147] To do this, the expression (15.24) on page 325 of the publication [1] is used, which makes it possible to find a multiplying coefficient equal to 1.083.
[0148] The table 2 below of characteristics of the equivalent spheres is therefore obtained:
TABLE-US-00002 d.sub.se in m .sub.se Z.sub.se in m.sup.2/(V*s) .sub.se in s 10 9.24 1 4.52*10.sup.8 4.78*10.sup.4 20 11.63 1 4.48*10.sup.8 7.59*10.sup.4
[0149] The trajectory of these two types of particles, i.e. fibers and equivalent spheres, is illustrated in
[0150] It emerges from this
[0151]
[0152]
[0153] In the variant of
[0154] In the variant of
[0155] It is possible to envisage arranging devices according to the variants of
[0156]
[0157] In the variant of
[0158] The device of
[0159] The device of
[0160]
[0161] In this variant, the flat surfaces between which the electrical field is established are composed of the bottom face 210, of the disk 200, and of the top face of a disk 300 arranged coaxially horizontal one inside the other defining a space of constant thickness between them.
[0162] Each of these two disks 200, 300 is openwork and has concave circular edge.
[0163] The bottom face 210 of the bottom disk 200 is at least partly a filtering membrane.
[0164] The aerosol of charged particles is, here, introduced through a duct 800 produced in the axial extension of the outer disk 300 on the top of the latter then circulates in the space between disks 200, 300.
[0165] The separated fibers are collected on the membrane 210, the air transporting them being discharged through an output duct 600 produced in the axial extension above the filtering membrane 210. The output duct 600 can be coaxial to the input duct 800.
[0166] Optionally, the non-fibrous particles that fall through gravity can be discharged by the air in an output duct 700 produced in the axial extension of the outer disk 300 below the latter.
[0167] Other variants and enhancements can be made without in any way departing from the scope of the invention.
[0168] Thus, if, in the embodiments illustrated, the flow rate Q1 is shown equal to that of Q2 equal to the total flow rate divided by two Q2, it is perfectly possible to envisage having Q1 different from Q2 and from Q/2.
[0169] The same goes for q0, q1 and q2 which can be different from one another and also different from q/3.
[0170] Moreover, if, in all the examples illustrated, the flat surfaces are parallel with one another and define a space of constant thickness, it is perfectly possible to envisage implementing the invention with surfaces that are not parallel and therefore with a space of variable thickness.
[0171] The invention is not limited to the examples which have just been described; it is notably possible to combine with one another features of the examples illustrated within variants that are not illustrated.
REFERENCES CITED
[0172] [1]: W. Hinds, Aerosol Technology, 2.sup.nd Edition, 1999. [0173] [2]: Zebel G., Hochrainer D., Boose C., A sampling method with separated deposition of fibres and other particles, J. Aerosol Sci., 8:205-213 (1977). [0174] [3]: Chen B. T., Yeh H. C., Hobbs C. H., Size Classification of Carbon Fiber Aerosols, Aerosol Sci. Technol., 19:109-120 (1993). [0175] [4]: Chen B. T., Yeh H. C., Johnson N. F., Design and use of a virtual impactor and an electrical classifier for generation of test fiber aerosols with narrow size distributions, J. Aerosol Sci., 27(1):83-94 (1996). [0176] [5]: Han R. J., Moss O. R., Wong B. A., Airborne Fiber Separation by Electrophoresis and Dielectrophoresis: Theory and Design Considerations, Aerosol Sci. Technol., 21:241-258 (1994). [0177] [6]: Griffiths W. D., The selective separation of aerosol particles of different shapes, J. Aerosol Sci., 18(6):761-763 (1987). [0178] [7]: Griffiths W. D., The shape selective sampling of fibrous aerosols, J. Aerosol Sci., 19(6):703-713 (1988).
[0179] [8]: Baron P. A., Deye G. J., Fernback J., Length separation of fibers, Aerosol Sci. Technol., 21:179-192 (1994). [0180] [9]: Lilienfeld, P. Rotational Electrodynamics of Airborne Fibers, J. Aerosol Sci. 4: 315-322 (1985). [0181] [10]: Deye G. J., Gao P., Baron P. A., Fernback J., Performance Evaluation of a Fiber Length Classifier, Aerosol Sci. Technol., 30:420-437 (1999). [0182] [11]: Dubey P., Ghia U., Turkevich L. A., Numerical investigation of sheath and aerosol flows in the flow combination section of a Baron fiber classifier, Aerosol Sci. Technol., 48:896-905 (2014). [0183] [12]: Ehara, K., Hagwood, C., Coakley, K. J., Novel method to Classify Aerosol Particles According to Their Mass-to-Charge Ratio, Aerosol Particle Mass Analyzer, J. Aerosol Sci, 27:217-234 (1996). [0184] [13]: Olfert, J. S., Collings, N. New Method for Particle Mass Classification: the Couette Centrifugal Particle Mass Analyser, J. Aerosol Sci, 36:1338-1352 (2005).