METHOD FOR REPAIRING COATED PRINTED CIRCUIT BOARDS

20200260592 ยท 2020-08-13

    Inventors

    Cpc classification

    International classification

    Abstract

    A method for repairing a printed circuit board (PCB) including the steps of presenting a PCB having an initial coating on a surface thereof, removing the initial coating from the surface of the PCB at least in an area in need of repair, and recoating at least the area of the PCB in need of repair by way of atomic layer deposition.

    Claims

    1. A method for repairing a printed circuit board (PCB) comprising: a) presenting a PCB having an initial coating on a surface thereof; b) removing the initial coating from the surface of the PCB at least in an area in need of repair; and c) recoating at least the area of the PCB in need of repair by way of atomic layer deposition.

    2. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of recoating at least the area of the PCB in need of repair involves recoating with nanolaminates composed of a metal oxide.

    3. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of recoating at least the area of the PCB in need of repair involves recoating with nanolaminates composed of an aluminum oxide (Al.sub.2O.sub.3) and titanium dioxide (TiO.sub.2) composition.

    4. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the initial coating is a parylene coating, an acrylic coating or a urethane coating.

    5. A method for repairing a printed circuit board (PCB) according to claim 1, further comprising the step of masking the surface of the PCB to isolate at least the area in need of repair for recoating.

    6. A method for repairing a printed circuit board (PCB) according to claim 1, further comprising the step of preparing the surface of the PCB at least in the area in need of repair for recoating by way of a plasma process.

    7. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of removing the initial coating at least in the area in need of repair involves mechanical, chemical or external energy based removal techniques.

    8. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of recoating at least the area of the PCB in need of repair involves plasma enhanced or thermal atomic layer deposition.

    9. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of recoating at least the area of the PCB in need of repair involves spatial or localized atomic layer deposition.

    10. A method for repairing a printed circuit board (PCB) according to claim 1, wherein at least the step of recoating the PCB involves utilizing a localized energy source delivered through a nozzle assembly.

    11. A method for repairing a printed circuit board (PCB) according to claim 10, further comprising the step of moving the nozzle assembly relative to the PCB.

    12. A method for repairing a printed circuit board (PCB) according to claim 1, further comprising the step of moving the PCB relative to the nozzle assembly.

    13. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of removing the initial coating from the surface of the PCB and the step of recoating the PCB involves utilizing a localized energy source delivered through a nozzle assembly.

    14. A method for repairing a printed circuit board (PCB) according to claim 1, wherein the step of recoating at least the area of the PCB in need of repair involves depositing a coating having a thickness of 50 nm to 1.

    15. A method for repairing a printed circuit board (PCB) according to claim 1, comprising recoating the entire surface of the PCB by way of atomic layer deposition.

    Description

    BRIEF DESCRIPTION OF THE DRAWINGS

    [0013] So that those having ordinary skill in the art will readily understand how to perform the method of the subject invention without undue experimentation, preferred embodiments thereof will be described in detail herein below with reference to the figures wherein:

    [0014] FIG. 1 is a schematic view of a PCB with an initial conformal coating;

    [0015] FIG. 2 is a schematic view of the PCB shown in FIG. 1, with the initial conformal coating removed in an area in need of repair;

    [0016] FIG. 3 is a schematic view of the PCB shown in FIG. 2, wherein the area in need of repair has been recoated;

    [0017] FIG. 4 is a schematic view of a PCB with an initial conformal coating, which has been removed in an area in need of repair by way of a nozzle assembly; and

    [0018] FIG. 5 is a schematic view of the PCB shown in FIG. 5, wherein the area in need of repair is recoated utilizing the nozzle assembly.

    DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

    [0019] The subject invention is directed to a new and useful method for reworking or otherwise repairing a printed circuit board (PCB), an example of which is illustrated schematically in FIG. 1 and designated generally by reference numeral 10. PCB 10 has an initial conformal coating 12 on all of the surfaces thereof, including on the surfaces of the components included thereon.

    [0020] The initial coating 12 is preferably a Parylene coating, and more preferably, the initial coating 12 is an ultra-thin Parylene C coating, which has a useful combination of electrical and physical properties, plus very low permeability to moisture and corrosive gases. Alternatively, the initial coating could be an acrylic coating or a urethane coating, as is known in the art. Additional environmentally stable coatings are also contemplated.

    [0021] The method of the subject invention includes the step of locally removing the initial coating 12 from the surface of the PCB 10 at least in an area in need of repair 14, as illustrated schematically in FIG. 2. This can be accomplished in different ways and by different means. For example, it is envisioned that the step of removing the initial coating 12 at least in the area 14 of the PCB 10 that is in need of repair could involve mechanical removal by way of rubbing, abrading or stripping using specialized media blasting. Alternatively, the step of removing the initial coating 12 could involve chemical removal using chemical stripping agents. It is also envisioned that the step of removing the initial coating 12 could involve the interaction of external energy (e.g., laser, radiation or a plasma beam) with the coating material so that the coating would be selectively removed from the PCB. Those skilled in the art will readily appreciate that the optimal coating removal technique employed will typically depend upon the type of coating to be removed from the PCB.

    [0022] The method of the subject invention further includes the step of recoating at least the area 14 of the PCB 10 that is in need of repair, as illustrated schematically in FIG. 3. In accordance with a preferred embodiment of the subject invention, the step of recoating the PCB shown in FIG. 3 is accomplished by way of atomic layer deposition (ALD), including plasma enhanced or thermal ALD.

    [0023] ALD is a thin-film deposition technique that is based on the sequential use of a gas phase chemical process. The majority of ALD reactions use two chemicals, typically called precursors. These precursors react with the surface of a material one at a time in a sequential, self-limiting manner. Through repeated cyclic exposure to separate precursors, a thin film is slowly deposited. This ensures absolute thickness control, extreme layer homogeneity nominally without porosity or pinholes and superb conformity, even of high aspect ratio surfaces often found on a PCB.

    [0024] Preferably, the step of recoating at least the area 14 of the PCB 10 that is in need of repair by way of ALD involves recoating the PCB 10 with nanolaminates 16 composed of a metal oxide. For example, the step of recoating at least the area 14 of the PCB 10 that is in need of repair involves recoating the surface area 14 of the PCB 10 with nanolaminates composed of an aluminum oxide (Al.sub.2O.sub.3) and titanium dioxide (TiO.sub.2) composition. Those skilled in the art will readily appreciate that other types of ALD coatings can be employed, such as for example coatings of silicon dioxide (Sift) compositions or the like. Other coating architectures and compositions are also contemplated. In one example, the coating deposited in the recoating step consists of a layer with nominally a single composition. In other examples, the coatings deposited in the recoating step consist of two or more alternating layers with different compositions and different or nominally a single composition doped with a second composition. Other ceramic, organic and hybrid-inorganic coating options are also contemplated.

    [0025] It is envisioned that the method of the subject invention would also include the step of masking the surface of the PCB 10 to isolate at least the area that is in need of repair for recoating. It is also envisioned that the method of the subject invention could include the step of preparing the surface of the PCB at least in the area in need of repair for recoating. This step could be accomplished by way of a plasma process, a chemical pretreatment or by other means known in the art.

    [0026] It is envisioned that the step of recoating at least the area of the PCB 10 in need of repair could involve either spatial or localized ALD. Those skilled in the art will readily appreciate that spatial ALD is an enhanced form of traditional ALD, improving the deposition rate by several orders of magnitude. Moreover, instead of filling and flushing a process chamber repeatedly, spatial ALD uses a multitude of precursor zones through which the substrates pass at high speed. Gas bearing and exhaust slits in between the precursor zones, keep the precursors from mixing avoiding parasitic deposition.

    [0027] It is envisioned that the step of recoating the PCB 10 could involve utilizing a localized energy source delivered through a nozzle assembly 18, as illustrated for example schematically in FIG. 4. The nozzle assembly 18 would preferably include an elongated tubular body with an outer diameter of about 0.25 inches, and having an energizing coil 22 provided on a distal end portion thereof (e.g., a radio frequency coil), a first inlet for receiving a plasma gas (e.g., Oxygen, Argon or Helium), a second inlet for receiving an alternate gas (e.g., an inert purge gas such as argon or nitrogen), and a deposition source inlet for receiving the metal oxide composition to be deposited by the nozzle through ALD. An example of such an assembly is disclosed in commonly assigned U.S. Patent Application Publication 2019/0037678, the disclosure of which is herein incorporated by reference in its entirety.

    [0028] The nozzle assembly 18 could also be used to remove the initial coating 12 from the area of the PCB 10 that is in need of repair. That is the nozzle assembly 18 could generate a cleaning plasma beam to locally remove or otherwise volatilize the initial coating 12 in the area of the PCB 10 that is in need of repair. Various nozzle assemblies (tube, plate, slot, etc.) with single or multiple nozzle configurations are contemplated. The method would further involve the step of moving the nozzle assembly 18 relative to the PCB 10 by way of a multi-axis maneuvering system 20, as shown for example in FIG. 5. Alternatively, the PCB 10 could be moved relative to the nozzle assembly 18 by placing the PCB on a multi-axis working surface (not shown).

    [0029] It is envisioned that the step of recoating at least the area of the PCB 10 in need of repair would involve depositing a coating by way of atomic layer deposition that has a thickness of about 50 nanometers (nm) to about 1 micron (), and more preferably, a thickness of 50-100 nm. It is further envisioned that the method could involve recoating the entire surface of the PCB by way of atomic layer deposition, rather than just recoating the area of the PCB in need of repair.

    [0030] It has been determined through experimentation that a PCB having an initial coating of Parylene C, that has been mechanically removed and recoated with nanolaminates composed of an aluminum oxide (Al.sub.2O.sub.3) and titanium dioxide (TiO.sub.2) in accordance with the method of the subject invention possesses favorable properties such as moisture and insulation resistance (MIR), hydrolytic stability, mechanical flexibility and dielectric barrier.

    [0031] While the subject disclosure has been shown and described with reference to preferred embodiments, those skilled in the art will readily appreciate that changes and/or modifications may be made thereto without departing from the scope of the subject disclosure.