NMR-BASED SYSTEMS FOR CRUDE OIL ENHANCEMENT AND METHODS THEREOF

Abstract

An NMR-based system (10) to analyze one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil, comprising an NMR device (11) for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile, said NMR having a crude oil inflow pipe (13), and is in a fluid connection (14) with a crude oil refinery facility (12); wherein said system further comprising a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing said system means to compare NMR analysis and/or crude oil theological profile of said SCOP with said time or batch resolved crude oil.

Claims

1. An NMR-based system to analyze one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil, comprising an NMR device for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile, said NMR having a crude oil inflow pipe, and is in a fluid connection with a crude oil refinery facility; wherein said system further comprising a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing said system means to compare NMR analysis and/or crude oil rheological profile of said SCOP with said time or batch resolved crude oil.

2. (canceled)

3. (canceled)

4. The NMR-based system of claim 18, wherein said NMR comprises at least one first probe and at least one second probe, thereby configuring said NMR to provide a time-resolved NMR analysis and/or rheological profile of crude oil flowing in said at least one first and at least one second probes, concurrently or interchangeably.

5. The NMR-based system of claim 4, wherein said at least one second probe is configured to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

6. An NMR-based system configured for analyzing and enhancing of crude oil; wherein the system is characterized by an NMR is in a fluid connection with both a crude oil inlet (COI) and crude oil outlet (COO); and a crude oil enhancement system (COES) interconnected to said NMR via said COO; said NMR comprising at least one first probe in fluid connection with said COI, and is configured for analyzing crude oil properties within said probe and/or for profiling said crude oil's rheology; said COES comprising one or more members of a group consisting of electric inducer, electromagnetic or mechanical vibrator, particle radiation emitter, gases super-heater in electric arcs, sonicator, ultrasound vibrations generator, radiofrequency emitter and any combination thereof.

7. (canceled)

8. The NMR-based system of claim 20, wherein said NMR further comprising at least one second probe, thereby configuring the same to provide a time-resolved NMR analysis and/or rheological profile of crude oil flowing in said at least one first and at least one second probes, concurrently or interchangeably.

9. The NMR-based system of claim 8, wherein said at least one second probe is configured to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

10. A method for enhancing crude oil comprising steps as follows: a. proving an NMR in fluid connection with a crude oil enhancement system (COES) via both NMR crude oil outlet (NMR-O) flowing analyzed crude oil from said NMR to said COES, and a COES crude oil outlet (COES-O) recycling processed crude oil form said COES to NMR inlet; b. storing, by means of computer readable medium, NMR analysis and/or rheological profile of a desired crude oil product processed in said COES (standard crude oil product); c. providing said COES with at least one crude oil cracking module (COCM) and connecting the same with said NMR by means of said NMR-O; d. processing said analyzed crude oil by means of said at least one COCM; e. recycling at least a portion of said processed crude oil from said COES to said NMR via said COCM-O; f. imaging said processed crude oil proving its NMR analysis and/or rheological profile; g. comparing the NMR analysis and/or rheological profile of said standard crude oil product (of step b) with said processed crude oil (of step f). h. if said NMR analysis and/or rheological profile are identical or set within predefined limits, flowing said crude oil to refinery; if said NMR analysis and/or rheological profile are not identical or set outside predefined limits, recycling said crude oil to further processing by said COES.

11. The method of claim 10, wherein step (a) further comprising providing said NMR with at least one first probe and configuring the same for a time-resolved analyze of crude oil; and at least one second probe, and configuring the same for a time-resolved analyze of crude oil; flowing in said at least one first and at least one second probes and imaging the same concurrently or interchangeably.

12. The NMR-based system of claim 11, further comprising step of configuring aid second probe to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

13. (canceled)

14. (canceled)

15. (canceled)

16. (canceled)

17. (canceled)

18. The NMR-based system of claim 1 further comprising a crude oil enhancement system (COES) interconnected via NMR crude oil outlet (22) to said NMR; said COES adapted for cracking of hydrocarbon oils thereby enhancing its property; wherein said NMR further comprising COES-processed-crude-oil-outlet (COES-O, 31) in fluid connection with said COES.

19. The NMR-based system of claim 1 wherein said system further comprising a crude oil enhancement system (COES) interconnected via NMR crude oil outlet (22) to said NMR; said COES adapted for cracking of hydrocarbon oils thereby enhancing its property.

20. The NMR-based system of claim 6 wherein said NMR comprises at least one first probe in a fluid connection with both NMR's crude oil inlet (NMR-I) and NMR's crude oil outlet (NMR-O) and wherein the COES is in fluid connection with said NMR-O and NMR-I.

Description

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013] Reference is now made to FIG. 1, illustrating a schematic block diagram of an NMR-based system (10) useful for analyzing one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil. System (10) comprising an NMR device (11) configured for providing time and/or batch resolved NMR-analysis and/or crude oil rheological profile. The NMR having one or more crude oil inflow pipes (13), and is in a fluid connection (14) with a crude oil refinery facility (12). The improvement is that the said system further comprising or otherwise is in communication (16) with a computer readable medium (CRM, 15), configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing the system means to compare or otherwise validate NMR analysis and/or crude oil rheological profile of the SCOP with said time or batch resolved crude oil.

[0014] Reference is now made to FIG. 2, illustrating a schematic block diagram NMR-based system (20) useful for both (a) analyzing one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil; and (b) enhancing crude oil. The system comprises an NMR device (11) for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile. The NMR is having at least one crude oil inflow pipe (13), and is in a fluid connection (14) with a crude oil refinery facility (12). The system further comprising a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing the system means to compare NMR analysis and/or crude oil rheological profile of said SCOP with said time or batch resolved crude oil. The improvement here is that the system further comprising a crude oil enhancement system (COES) interconnected via at least one NMR crude oil outlet (22) to said NMR or a plurality of NMRs. The COES adapted for cracking of hydrocarbon oils thereby enhancing its property. Reference is now made to FIG. 3A, illustrating a schematic block diagram of an industrial scalable, inline, online accurate NMR-based system for crude oil enhancement and to methods thereof an NMR-based system (30) useful for both (a) analyzing one or more of the following: (i) crude oil property, (ii) crude oil rheology of crude oil; and (b) enhancing crude oil. The system comprising, inter alia, an NMR device (11) for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile. The NMR having a crude oil inflow pipe (13), and is in a fluid connection (14) with a crude oil refinery facility (12). The system further comprises a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product (standard crude oil product, SCOP), thereby providing the system means to compare NMR analysis and/or crude oil rheological profile of the SCOP with said time or batch resolved crude oil. The system further comprises a crude oil enhancement system (COES) interconnected via at least one NMR crude oil outlet (22) to the NMR. The COES adapted for cracking of hydrocarbon oils thereby enhancing its property. The improvement here is that the NMR further comprising COES-processed-crude-oil-outlet (COES-O, 31) in fluid connection with the COES.

[0015] Reference is now made to FIG. 3B, illustrating a schematic block diagram of an NMR-based system (30) as defined above, wherein the NMR (or NMRs) comprises at least one first probe (11A) and at least one second probe (11B). Those two (or more) NMR-probes thereby configuring the NMR to provide a time-resolved or batch-resolved NMR analysis and/or rheological profile of crude oil flowing in the at least one first and at least one second probes, concurrently (probe 1 and probe 2 together, at the same time) or interchangeably (probe 1 and then probe 2, and vice versa).

[0016] It is in the scope of the invention wherein the NMR-based system comprises at least one second probe which is configured to provide a time-resolved or batch resolved NMR analysis and/or rheological profile of the COES' processed recycled crude oil.

[0017] It is also in the scope of the invention wherein an NMR-based system is configured for analyzing and enhancing of crude oil. This system is characterized by an NMR which is provided in a fluid connection with both a crude oil inlet (COI) and crude oil outlet (COO); and a crude oil enhancement system (COES) interconnected to the NMR via said COO. The NMR comprises, inter alia, at least one first probe in fluid connection with said CO, and is configured for analyzing crude oil properties within said probe and/or for profiling said crude oil's rheology. The COES comprises, inter alia, one or more members of a group consisting of electric inducer, electromagnetic or mechanical vibrator, particle radiation emitter, gases super-heater in electric arcs, sonicator, ultrasound vibrations generator, radiofrequency emitter (e.g., RF radiation having a frequency between 0.1 MHz to 300 MHz) and any combination thereof.

[0018] It is further in the scope of the invention wherein the NMR-based system is configured for analyzing and enhancing a property of crude oil before oil refinery and the system characterized by (a) an NMR comprising at least one first probe configured to enable NMR analysis and/or rheological profile of crude oil, said probe is in a fluid connection with both NMR's crude oil inlet (NMR-I) and NMR's crude oil outlet (NMR-O); and by (b) a crude oil enhancement system (COES). COES comprises one or more crude oil cracking modules, selected from a group consisting of electric inducer, electromagnetic or mechanical vibrator, particle radiation emitter, gases super-heater in electric arcs, sonicator, ultrasound vibrations generator, radiofrequency emitter and any combination thereof (COCMs), at least one of said COCMs is in fluid connection with said NMR-O and NMR-I.

[0019] It is also in the scope of the invention wherein the NMR further comprising at least one second probe, thereby configuring the same to provide a time-resolved NMR analysis and/or rheological profile of crude oil flowing in said at least one first and at least one second probes, concurrently or interchangeably.

[0020] It is also in the scope of the invention wherein the at least one second probe is configured to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

[0021] Reference is now made to FIG. 4, schematically illustrating a flow chart of a method for enhancing crude oil. The method comprising steps as follows: (a) proving an NMR in fluid connection with a crude oil enhancement system (COES) via both NMR crude oil outlet (NMR-O) flowing analyzed crude oil from said NMR to said COES, and a COES crude oil outlet (COES-O) recycling processed crude oil form said COES to NMR inlet; (b) storing, by means of computer readable medium, NMR analysis and/or rheological profile of a desired crude oil product processed in said COES (standard crude oil product); (c) providing said COES with at least one crude oil cracking module (COCM) and connecting the same with said NMR by means of said NMR-O; (d) processing said analyzed crude oil by means of said at least one COCM; (e) recycling at least a portion of said processed crude oil from said COES to said NMR via said COCM-O; (f) imaging said processed crude oil proving its NMR analysis and/or rheological profile; (g) comparing the NMR analysis and/or rheological profile of said standard crude oil product (of step b) with said processed crude oil (of step f); and (h) if said NMR analysis and/or rheological profile are identical or set within predefined limits, flowing said crude oil to refinery; if said NMR analysis and/or rheological profile are not identical or set outside predefined limits, recycling said crude oil to further processing by said COES.

[0022] It is in the scope of the invention wherein aforesaid step (a) further comprising step or steps for providing said NMR with at least one first probe and configuring the same for a time-resolved analyze of crude oil; and at least one second probe, and configuring the same for a time-resolved analyze of crude oil; flowing in said at least one first and at least one second probes and imaging the same concurrently or interchangeably.

[0023] It is in the scope of the invention wherein the method further comprising step of configuring said second probe to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

[0024] It is also in the scope of the invention wherein a method for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile is provided. The method comprises steps as follows: (a) providing an NMR having a crude oil inflow pipe (13) and a fluid connection (14) with a crude oil refinery facility (12); (b) providing a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product; and (c) comparing said oil NMR analysis and/or crude oil rheological profile of a desired crude oil product with said time and/or batch resolved NMR analysis and/or crude oil rheological profile.

[0025] It is also in the scope of the invention wherein a method for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile is provided. The method comprises steps as follows: (a) providing an NMR having a crude oil inflow pipe (13) and a fluid connection (14) with a crude oil refinery facility (12); (b) further providing a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product; (c) further providing a crude oil enhancement system (COES) interconnected via NMR crude oil outlet (22) to said NMR; (d) comparing said oil NMR analysis and/or rheological profile of said desired crude oil product with said time and/or batch resolved NMR analysis and/or crude oil rheological profile; and (e) cracking said crude oil according to the degree of resemblance of said batch resolved NMR analysis and/or crude oil rheological profile with said NMR analysis and/or rheological profile of said desired crude oil product.

[0026] It is also in the scope of the invention wherein a method for providing time and/or batch resolved NMR analysis and/or crude oil rheological profile is provided. The method comprises steps as follows: (a) providing an NMR having a crude oil inflow pipe (13) and a fluid connection (14) with a crude oil refinery facility (12); (b) further providing a computer readable medium configured to store a retrievable crude oil NMR analysis and/or crude oil rheological profile of a desired crude oil product; (c) further providing a crude oil enhancement system (COES) interconnected via NMR crude oil outlet (22) to said NMR and further comprising COES-processed-crude-oil-outlet (COES-O, 31) in fluid connection with said NMR; (d) comparing said oil NMR analysis and/or rheological profile of said desired crude oil product with said time and/or batch resolved NMR analysis and/or crude oil rheological profile; and (e) cracking said crude oil according to the degree of resemblance of said batch resolved NMR analysis and/or crude oil rheological profile with said NMR analysis and/or rheological profile of said desired crude oil product. It is also in the scope of the invention wherein this method additionally comprising a step of providing said NMR at least one first probe (11A) and at least one second probe (11B), thereby configuring said NMR to provide a time-resolved NMR analysis and/or rheological profile of crude oil flowing in said at least one first and at least one second probes, concurrently or interchangeably. It is also in the scope of the invention wherein this method additionally comprising a step of configuring said second probe to provide a time-resolved NMR analysis and/or rheological profile of said processed recycled crude oil.

[0027] It is in the scope of the invention wherein the methods and systems defined above are configured to enable ANSI/ISA 76.00.02-2002 Modular Component Interfaces for Surface-Mount Fluid Distribution Components—Part 1: Elastomeric Seals,” Instrumentation, Systems, and Automation Society (ISA), Compositional Analyzers Committee, (2002).

[0028] The above summary of the various representative embodiments of the invention is not intended to describe each illustrated embodiment or every implementation of the invention. Rather, the embodiments are chosen and described so that others skilled in the art can appreciate and understand the principles and practices of the invention. The figures and the detailed description that follow more particularly exemplify these embodiments.